Product Name

  • Name

    Sodium ethylenesulphonate

  • EINECS 221-242-5
  • CAS No. 3039-83-6
  • Article Data9
  • CAS DataBase
  • Density 1.176 g/mL at 25 °C
  • Solubility Soluble in water.
  • Melting Point -20 °C
  • Formula C2H4O3S.Na
  • Boiling Point 100℃[at 101 325 Pa]
  • Molecular Weight 130.1
  • Flash Point
  • Transport Information
  • Appearance often supplied as a concentrated (30%) aqueous solution, deep yellow-brown in colour
  • Safety 26-27-28-36/37/39
  • Risk Codes 36/37/38-42/43
  • Molecular Structure Molecular Structure of 3039-83-6 (Sodium ethylenesulphonate)
  • Hazard Symbols R36/38:Irritating to eyes and skin.;
  • Synonyms Ethenesulfonicacid, sodium salt (8CI,9CI);N-SVS 25;Sodium ethenesulfonate;Sodium vinylsulfonate;Tamol VS;Vinylsulfonic acid sodiumsalt;
  • PSA 65.58000
  • LogP 0.75590

Synthetic route

2-Chloroethanesulfonyl chloride
1622-32-8

2-Chloroethanesulfonyl chloride

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

Conditions
ConditionsYield
hydrolysis at pH 11;
2-hydroxyethane-1-sulfonyl chloride
78303-70-5

2-hydroxyethane-1-sulfonyl chloride

A

sodium 2-hydroxyethanesulfonate
1562-00-1

sodium 2-hydroxyethanesulfonate

B

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C

Na-salt of 2-chloroethane-1-sulfonic acid
15484-44-3

Na-salt of 2-chloroethane-1-sulfonic acid

Conditions
ConditionsYield
With sodium hydroxide; potassium chloride at 25℃; pH 4;A 52 % Spectr.
B n/a
C 48 % Spectr.
...Expand
sodium 2-bromethanesulfonate
4263-52-9

sodium 2-bromethanesulfonate

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

Conditions
ConditionsYield
With hydroxide In water at 10℃; under 1.66513E-07 Torr; Rate constant; var. pressure values, var. solvents and temperatures;
sodium hydrogensulfite

sodium hydrogensulfite

acetylene
74-86-2

acetylene

A

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

B

sodium 1,2-ethanedisulphonate
5325-43-9

sodium 1,2-ethanedisulphonate

Conditions
ConditionsYield
With N2 catalyst, 80°C, under pressure;
With nitrogen catalyst, 80°C, under pressure;
...Expand
2-sulfooxy-ethanesulfonic acid
461-42-7

2-sulfooxy-ethanesulfonic acid

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

Conditions
ConditionsYield
With sodium sulfate; calcium hydroxide In water at 35 - 80℃; for 1h; pH=10 - 11;
With sodium sulfate; calcium hydroxide In water at 35 - 80℃; for 1h; pH=7-11;
ethanol
64-17-5

ethanol

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

Conditions
ConditionsYield
With sulfur trioxide; sodium hydroxide at 20 - 60℃; for 8h; Large scale;
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

N,N`-dimethylethylenediamine
110-70-3

N,N`-dimethylethylenediamine

Na2[(DES)MeN(CH2)2NMe(DES)]

Na2[(DES)MeN(CH2)2NMe(DES)]

Conditions
ConditionsYield
With water at 120℃; for 12h; Michael-type addition reaction;98%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

ethenesulfonic acid
1184-84-5

ethenesulfonic acid

Conditions
ConditionsYield
With strongly-acidic ion-exchange resin DOWEXMonosphere 650C In water Product distribution / selectivity;97%
With sodium hydroxide In water for 4h;86.7%
With water Product distribution / selectivity;
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

ethylenediamine
107-15-3

ethylenediamine

sodium 2-[(2-aminoethyl)amino]ethanesulphonate
34730-59-1

sodium 2-[(2-aminoethyl)amino]ethanesulphonate

Conditions
ConditionsYield
at 30℃; for 5h; Reflux;92.11%
In water for 24h; Reflux;0.91 g
N,N,N',N'-tetrakis(3-aminopropyl)ethylenediamine
4879-98-5

N,N,N',N'-tetrakis(3-aminopropyl)ethylenediamine

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C30H60N6O24S8(8-)*8Na(1+)

C30H60N6O24S8(8-)*8Na(1+)

Conditions
ConditionsYield
In methanol at 120℃; for 48h; Autoclave;90%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C10H22N4*BrH

C10H22N4*BrH

1,2-N,N'-bisethane

1,2-N,N'-bisethane

Conditions
ConditionsYield
With sodium hydroxide for 24h; Heating;89%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

1-amino-2-propene
107-11-9

1-amino-2-propene

C5H9NO6S2(2-)*2Na(1+)

C5H9NO6S2(2-)*2Na(1+)

Conditions
ConditionsYield
In methanol; water at 120℃; for 48h; Inert atmosphere;86%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

N1-(3-Amino-propyl)-N1-(3-{{3-[bis-(3-amino-propyl)-amino]-propyl}-[2-(bis-{3-[bis-(3-amino-propyl)-amino]-propyl}-amino)-ethyl]-amino}-propyl)-propane-1,3-diamine
179125-43-0

N1-(3-Amino-propyl)-N1-(3-{{3-[bis-(3-amino-propyl)-amino]-propyl}-[2-(bis-{3-[bis-(3-amino-propyl)-amino]-propyl}-amino)-ethyl]-amino}-propyl)-propane-1,3-diamine

C70H140N14O48S16(16-)*16Na(1+)

C70H140N14O48S16(16-)*16Na(1+)

Conditions
ConditionsYield
In methanol at 120℃; for 48h; Autoclave;85%
thymidine-5′-(Asp-Tau-OH) phosphoramidate tri(triethylammonium) salt

thymidine-5′-(Asp-Tau-OH) phosphoramidate tri(triethylammonium) salt

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

N,N-2-diaminoethanesulfonate disodium salt

N,N-2-diaminoethanesulfonate disodium salt

Conditions
ConditionsYield
With sodium hydrogencarbonate In water for 72h; Michael Addition; Reflux;85%
morpholine
110-91-8

morpholine

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

4-morpholineethanesulfonic acid
4432-31-9

4-morpholineethanesulfonic acid

Conditions
ConditionsYield
In water at 60℃; for 6h; Large scale;85%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

ethylene glycol di(2-hydroxy-3-piperazinyl)propyl ether tetrahydrochloric acid salt

ethylene glycol di(2-hydroxy-3-piperazinyl)propyl ether tetrahydrochloric acid salt

ethylene glycol di<2-hydroxy-3-(N'-sulfonoethylpiperazinyl)>propyl ether

ethylene glycol di<2-hydroxy-3-(N'-sulfonoethylpiperazinyl)>propyl ether

Conditions
ConditionsYield
With sodium hydroxide Heating;84%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

methylamine
74-89-5

methylamine

N-Methyltaurine
107-68-6

N-Methyltaurine

Conditions
ConditionsYield
With acetic acid In methanol; water at 25 - 100℃; for 3 - 170h; Product distribution / selectivity;82%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

N-phenylphenylene-1,4-diamine
101-54-2

N-phenylphenylene-1,4-diamine

A

N-(4-anilino)phenyl-vinylsulfonamide
77229-34-6

N-(4-anilino)phenyl-vinylsulfonamide

B

vinylsulfonyl chloride
6608-47-5

vinylsulfonyl chloride

Conditions
ConditionsYield
With phosphorus pentachloride; triethylamine In tolueneA 81%
B n/a
...Expand
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

sodium N,N-bis(2-hydroxyethyl)-2-aminoethanesulfonate
66992-27-6

sodium N,N-bis(2-hydroxyethyl)-2-aminoethanesulfonate

Conditions
ConditionsYield
for 24h; Reflux;81%
C82H200N8Si13

C82H200N8Si13

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C112H244N8O48S16Si13(16-)*16Na(1+)

C112H244N8O48S16Si13(16-)*16Na(1+)

Conditions
ConditionsYield
In ethanol; water at 120℃; for 72h; Michael Addition;80%
C144H348S16Si29

C144H348S16Si29

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C176H396O48S32Si29(16-)*16Na(1+)

C176H396O48S32Si29(16-)*16Na(1+)

Conditions
ConditionsYield
With 2,2-dimethoxy-2-phenylacetophenone In tetrahydrofuran; methanol for 4h; UV-irradiation;80%
3-({3-[{3-[(3-amino-propyl)-dimethyl-silanyl]-propyl}-methyl-(3-{tris-[3-(bis-{3-[(3-amino-propyl)-dimethyl-silanyl]-propyl}-methyl-silanyl)-propyl]-silanyl}-propyl)-silanyl]-propyl}-dimethyl-silanyl)-propylamine

3-({3-[{3-[(3-amino-propyl)-dimethyl-silanyl]-propyl}-methyl-(3-{tris-[3-(bis-{3-[(3-amino-propyl)-dimethyl-silanyl]-propyl}-methyl-silanyl)-propyl]-silanyl}-propyl)-silanyl]-propyl}-dimethyl-silanyl)-propylamine

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C112H244N8O48S16Si13(16-)*16Na(1+)

C112H244N8O48S16Si13(16-)*16Na(1+)

Conditions
ConditionsYield
In methanol; water at 120℃; for 48h; Inert atmosphere;78%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C86H204N30

C86H204N30

C150H300N30O96S32(32-)*32Na(1+)

C150H300N30O96S32(32-)*32Na(1+)

Conditions
ConditionsYield
In methanol at 120℃; for 48h; Autoclave;78%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

1,6-N,N'-bis(piperazinyl)hexane tetrahydrobromic acid salt

1,6-N,N'-bis(piperazinyl)hexane tetrahydrobromic acid salt

1,6-N,N'-bishexane

1,6-N,N'-bishexane

Conditions
ConditionsYield
With sodium hydroxide Heating;74%
4-aminobutyrylaldehyde diethylacetal
6346-09-4

4-aminobutyrylaldehyde diethylacetal

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

sodium 2-[(4,4-diethoxybutyl)amino]ethanesulfonate

sodium 2-[(4,4-diethoxybutyl)amino]ethanesulfonate

Conditions
ConditionsYield
In water for 20h; Reflux;74%
3-{dimethyl-[3-(tris-{3-[(3-amino-propyl)-dimethyl-silanyl]-propyl}-silanyl)-propyl]-silanyl}-propylamine

3-{dimethyl-[3-(tris-{3-[(3-amino-propyl)-dimethyl-silanyl]-propyl}-silanyl)-propyl]-silanyl}-propylamine

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

8Na(1+)*C48H104N4O24S8Si5(8-)

8Na(1+)*C48H104N4O24S8Si5(8-)

Conditions
ConditionsYield
In methanol; water at 120℃; for 48h; Inert atmosphere;73%
In ethanol; water at 120℃; for 72h; Michael Addition;73%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C18H12O6S2(2-)*2Na(1+)

C18H12O6S2(2-)*2Na(1+)

Conditions
ConditionsYield
With sodium acetate; trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) In 1-methyl-pyrrolidin-2-one; N,N-dimethyl-formamide at 100℃; for 18h; Heck reaction;70%
C64H156S8Si13

C64H156S8Si13

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C80H180O24S16Si13(8-)*8Na(1+)

C80H180O24S16Si13(8-)*8Na(1+)

Conditions
ConditionsYield
With 2,2-dimethoxy-2-phenylacetophenone In tetrahydrofuran; methanol; water for 3h; UV-irradiation;70%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

3-(aminopropyl)triethylsilane
17887-09-1

3-(aminopropyl)triethylsilane

C13H29NO6S2Si(2-)*2Na(1+)

C13H29NO6S2Si(2-)*2Na(1+)

Conditions
ConditionsYield
In methanol; water at 120℃; for 48h; Inert atmosphere;65%
C69H156N6O3Si9
1258837-28-3

C69H156N6O3Si9

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

C93H192N6O39S12Si9(12-)*12Na(1+)

C93H192N6O39S12Si9(12-)*12Na(1+)

Conditions
ConditionsYield
In methanol; water at 120℃; for 48h; Inert atmosphere;63%
In water Michael Addition;57%
2-hydroxy-3-iodonaphthalene-1,4-dione
35135-38-7

2-hydroxy-3-iodonaphthalene-1,4-dione

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

E-3-(2-hydroxy-1,4-dioxo-1,4-dihydronaphthalen-3-yl)vinylsulfonic acid

E-3-(2-hydroxy-1,4-dioxo-1,4-dihydronaphthalen-3-yl)vinylsulfonic acid

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In water for 2h; Heck reaction; Heating;62%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

acetylacetone
123-54-6

acetylacetone

polymer, molecular weight: 1100; monomer(s): sodium vinylsulfonate; 2,4-pentanedione

polymer, molecular weight: 1100; monomer(s): sodium vinylsulfonate; 2,4-pentanedione

Conditions
ConditionsYield
With dihydrogen peroxide; horseradish peroxidase In water at 20℃; for 24h;36%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

acetylacetone
123-54-6

acetylacetone

polymer, molecular weight: 2400; monomer(s): sodium vinylsulfonate; 2,4-pentanedione

polymer, molecular weight: 2400; monomer(s): sodium vinylsulfonate; 2,4-pentanedione

Conditions
ConditionsYield
With dihydrogen peroxide; horseradish peroxidase In water at 20℃; for 48h;36%
sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

acetylacetone
123-54-6

acetylacetone

polymer, molecular weight: 2900; monomer(s): sodium vinylsulfonate; 2,4-pentanedione

polymer, molecular weight: 2900; monomer(s): sodium vinylsulfonate; 2,4-pentanedione

Conditions
ConditionsYield
With dihydrogen peroxide; horseradish peroxidase In water at 25℃; for 24h;36%
(R)-1-phenyl-ethyl-amine
3886-69-9

(R)-1-phenyl-ethyl-amine

sodium vinylsulfonate
3039-83-6

sodium vinylsulfonate

sodium (R)-2-(1-phenylethylamino)ethanesulfonate
1257064-35-9

sodium (R)-2-(1-phenylethylamino)ethanesulfonate

Conditions
ConditionsYield
In water for 120h; Reflux;25%

Sodium ethylenesulphonate Specification

The ethenesulfonic acid,sodium salt (1:1), with the CAS register number 3039-83-6, has other names as ethenesulfonicacid,sodiumsalt; ethylenesulfonic acid sodium salt; sodium vinylsulfonate; sodium vinylsulphonate; sodium ethylenesulfonate; sodium ethylenesulphonate; vinyl sulfonate, sodium salt; vinylsulfonic acid sodium salt.

The physical characteristics could be summarized as: (1)ACD/LogP: -0.30; (2)ACD/LogD(pH5.5): -3.8; (3)ACD/LogD(pH7.4): -3.8; (4)ACD/BCF(pH5.5): 1; (5)ACD/BCF(pH7.4): 1; (6)ACD/KOC(pH5.5): 1; (7)ACD/KOC(pH7.4): 1; (8)#Hbondacceptors: 3; (9)#Hbonddonors: 1; (10)#FreelyRotatingBonds: 1; (11)PolarSurfaceArea: 62.75.

This chemical is often supplied as a concentrated (30%) aqueous solution, deep yellow-brown in colour, and it is sensitive to light and is stable in air while incompatible with strong oxidizing agents.

Being a kind of irritant chemical, it is harmful to eyes, respiratory system and skin and may cause sensitisation by inhalation and skin contact. So while dealing with this chemical, you should follow the below instructions. Wear suitable protective clothing, gloves and eye/face protection. If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And after contacting with skin, wash immediately with plenty of ... (to be specified by the manufacturer).

As for its usage, it is often applied in the synthesis of some propionyl and also be usde in synthetic fibre and monomer conversion of various polymer. Besides, it could be used as the electroplate brightener, surface active agent and pharmaceutic intermediates.

In addition, you could refer to the following data information to get the molecular structure:
SMILES:[Na+].[O-]S(=O)(=O)\C=C
InChI:InChI=1/C2H4O3S.Na/c1-2-6(3,4)5;/h2H,1H2,(H,3,4,5);/q;+1/p-1
InChIKey:BWYYYTVSBPRQCN-REWHXWOFAC

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