Sodium ethylxanthogenate supplier

Name
Sodium ethylxanthogenate
EINECS 205-440-9
CAS No. 140-90-9
Article Data23
CAS DataBase
Density 1.558 g/cm³
Solubility soluble in water
Melting Point
Formula C₃H₅NaOS₂
Boiling Point 120.5 °C at 760 mmHg
Molecular Weight 144.194
Flash Point 26.7 °C
Transport Information UN 3342
Appearance Light yellow powder
Safety 26-36/37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols
Synonyms Carbonicacid, dithio-, O-ethyl ester, sodium salt (8CI);Xanthic acid, ethyl-, sodium salt (6CI);Aero 325;Ethylxanthic acid sodium salt;Sodium O-ethyl dithiocarbonate;Sodium ethyl xanthogenate;Sodium xanthate;Sodiumxanthogenate;Z 4;Z 4 (flotation agent);Sodium Ethyl Xanthate;
PSA 66.62000
LogP 1.50530

Synthetic route

: 75-15-0
carbon disulfide

: 64-17-5
ethanol

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran at 10 - 20℃; for 2h; Temperature;	97.4%
With sodium hydroxide In water for 4h;	80.4%
With sodium for 6h; Heating;	63%

: 141-52-6
sodium ethanolate

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With carbon disulfide

: 502-55-6
bis-ethoxythiocarbonyldisulfane

: 148-18-5
sodium N,N-diethyldithiocarbamate

A: 140-90-9
sodium O-ethyl dithiocarbonate

B: 327989-09-3
C8H15NOS4

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 502-55-6
bis-ethoxythiocarbonyldisulfane

: 55310-46-8
sodium dibenzyldithiocarbamate

A: 140-90-9
sodium O-ethyl dithiocarbonate

B: C18H19NOS4

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 327989-09-3
C8H15NOS4

A: 97-77-8
disulfiram

B: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 55310-46-8
sodium dibenzyldithiocarbamate

: C18H19NOS4

A: 10591-85-2
bis(dibenzylthiocarbamoyl)disulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 64-17-5
ethanol

CS2: CS2

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium hydroxide

: 141-52-6
sodium ethanolate

CS2: CS2

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With ethanol
With ethanol

: 75-15-0
carbon disulfide

: 141-52-6
sodium ethanolate

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
at 0 - 20℃;
catalyst

: 64-17-5
ethanol

: 534-18-9
sodium trithiocarbonate

A: sodium hydrogen sulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
In water ambient temp., 5 h;
In water ambient temp., 5 h;

...Expand

: 64-17-5
ethanol

: 124-38-9
carbon dioxide

: 534-18-9
sodium trithiocarbonate

A: sodium hydrogen sulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

C: 17201-44-4
sodium ethyl carbonate

D: sodium thiosulfate

Conditions

Conditions	Yield
In ethanol 30 min;
In ethanol 30 min;

...Expand

: 64-17-5
ethanol

: 124-38-9
carbon dioxide

: 534-18-9
sodium trithiocarbonate

A: sodium sulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

C: 17201-44-4
sodium ethyl carbonate

D: sodium thiosulfate

Conditions

Conditions	Yield
In ethanol 30 min;
In ethanol 30 min;

...Expand

: 29632-74-4
2-fluro-4-iodoaniline

: 140-90-9
sodium O-ethyl dithiocarbonate

: 54420-94-9
6-iodobenzo[d]thiazole-2-thiol

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 95℃; for 5h;	100%

: 1401454-94-1
2,15-bis(chloromethyl)-4,7,10,13-tetraoxahexadeca-1,15-diene

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1401454-99-6
S,S'-2,15-dimethylene-4,7,10,13-tetraoxahexadecane-1,16-diyl O,O'-diethyl dicarbonodithioate

Conditions

Conditions	Yield
In ethanol at 20 - 35℃; Inert atmosphere;	98%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 541-41-3
chloroformic acid ethyl ester

: 3278-35-1
S-(ethoxycarbonyl) O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With cetyltrimethylammonim bromide In N,N-dimethyl-aniline at 10 - 25℃; for 4h;	97.1%

: 1326703-36-9
2,15-bis(chloromethyl)-7,10-dioxa-4,13-dithiahexadeca-1,15-diene

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1401455-02-4
S,S'-2,15-dimethylene-7,10-dioxa-4,13-dithiahexadecane-1,16-diyl O,O'-diethyl dicarbonodithioate

Conditions

Conditions	Yield
In ethanol at 20 - 35℃; Inert atmosphere;	97%

: 2106-02-7
2-chloro-4-fluoroaniline

: 140-90-9
sodium O-ethyl dithiocarbonate

: 6-fluoro-1,3-benzothiazole-2(3H)-thione

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 4h;	96%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 32278-97-0
bis(dichlorostibino)methane

: {Sb(S2COC2H5)2}2CH2

Conditions

Conditions	Yield
In methanol byproducts: NaCl; addition of a solution of 6.00 mmol of NaS2COEt in 20 ml CH3OH drop by drop to a solution of 1.50 mmol of (Cl2Sb)2CH2 (1 hour) and stirring at 25°C, 3 - 5 hours;; filtration, washing with CH3OH and drying; elem. anal.;;	96%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 107-05-1
3-chloroprop-1-ene

: 7124-50-7
S-allyl O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With cetyltrimethylammonim bromide at 25℃; for 6.5h;	95.3%

: 908126-51-2
di-n-propylammonium hydrogen sulphate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 759-94-4
S-ethyl N,N-di-n-propylthiocarbamate

Conditions

Conditions	Yield
Stage #1: di-n-propylammonium hydrogen sulphate; sodium O-ethyl dithiocarbonate With dihydrogen peroxide In water at 40℃; for 1h; Green chemistry; Stage #2: With sulfuric acid In water at 70℃; for 1h; pH=7; Green chemistry;	94%

: 10369-54-7
μ-oxo-bis{bromotrimethyl-λ5-stibane}

: 140-90-9
sodium O-ethyl dithiocarbonate

: 140405-09-0
{(CH3)3SbS2COC2H5}2O

Conditions

Conditions	Yield
In dichloromethane byproducts: NaBr; addition of a twofold excess of NaS2COEt to a suspension of 2 mmol of (Me3SbBr)2O in 10 ml CH2Cl2 at -30°C, stirring (2 hours), filtration and evaporation;; recrystallization from diethyl ether; elem. anal.;;	93%

: 14780-97-3
tetraethylammonium chloropentacarbonyltungstate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 922713-51-7
(CH3CH2)4N(1+)*W(CO)4(SSCOCH2CH3)(1-)=((CH3CH2)4N)[W(CO)4(SSCOCH2CH3)]

Conditions

Conditions	Yield
In acetonitrile byproducts: NaCl, CO; under N2; Schlenk technique; mixt. of W compd. and Na salt in CH3CN refluxed for 2 h; evapn. under vac., residue dissolved in THF/acetone (10/1), filtration through silica/celite, filtrate evapd., residue washed with Et2O; elem. anal.;	93%

: 93614-78-9, 4549-82-0
3-(2-methylphenyl)prop-2-en-1-al

: 140-90-9
sodium O-ethyl dithiocarbonate

: 108-91-8
cyclohexylamine

: 3-cyclohexyl-4-hydroxy-6-(2-methylphenyl)-1,3-thiazinane-2-thione

Conditions

Conditions	Yield
In chloroform at 61℃; for 1.83333h;	92.7%

...Expand

: 65087-26-5
diisopropylammonium hydrogen sulphate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 63644-60-0
diisopropyl-thiocarbamic acid S-ethyl ester

Conditions

Conditions	Yield
Stage #1: diisopropylammonium hydrogen sulphate; sodium O-ethyl dithiocarbonate With dihydrogen peroxide In water at 45℃; for 1.5h; Green chemistry; Stage #2: With sulfuric acid In water at 75℃; for 2.2h; pH=7; Green chemistry;	92%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 115-09-3
methylmercury(II) chloride

: 104855-65-4
CH3Hg(S2COCH2CH3)

Conditions

Conditions	Yield
In dichloromethane MeHgCl dissolved in CH2Cl2 was treated with ligand, stirred at room temp. for 1 h; filtered, evapd. in open air, redissolved in CH2Cl2, filtered, covered with petroleum ether, crystd. in reflrigerator, filtered, dried in vacuo;elem. anal.;	91.7%

: 111-26-2
hexan-1-amine

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1504-75-2
3-(4-methylphenyl)acrylaldehyde

: 3-n-hexyl-4-hydroxy-6-(4-methylphenyl)-1,3-thiazinane-2-thione

Conditions

Conditions	Yield
In methanol at 65℃; for 1.08333h;	91.7%

...Expand

: 140-90-9
sodium O-ethyl dithiocarbonate

: 104-94-9
4-methoxy-aniline

: 122-40-7
jasminaldehyde

: 5-pentyl-3-(4-methoxyphenyl)-4-hydroxy-6-phenyl-1,3-thiazinane-2-thione

Conditions

Conditions	Yield
In dichloromethane at 25℃; for 1.66667h;	90.7%

...Expand

: ((Pd(μ-I)((CH2)2S(O)Me))2)

: 140-90-9
sodium O-ethyl dithiocarbonate

: Pd{(CH2)2(SO)(CH3)}(S2COC2H5)

Conditions

Conditions	Yield
In dichloromethane Addn. of org. compd. to suspn. of Pd-complex (CH2Cl2) using n-Bu4NI as phase transfer catalyst and stirring. The yellow solid is dissolved within 6 min.; Washing of ppt. with H2O (3 times), removal of solvent, recrystn. of residue from n-hexane/CH2Cl2, elem. anal.;	90%
In dichloromethane Addn. of org. compd. to suspn. of Pd-complex (CH2Cl2) and stirring. The yellow solid is dissolved within 15 min.;	79%

: 14104-20-2
silver tetrafluoroborate

: bis(η5-cyclopentadinyl)dihydridomolybdenum

: 140-90-9
sodium O-ethyl dithiocarbonate

: [((C5H5)2MoH2)2AgS2COC2H5]

Conditions

Conditions	Yield
In acetone (N2); NaS2COEt/acetone added at -30°C to soln. of Mo complex andAgBF4 in acetone; ppt. isolated, washed (Et2O), chromd. (SiO2, CH2Cl2/acetone), recrystd.(acetone); elem. anal.;	90%

...Expand

: dioxomolybdenum(VI) dibromide bis(dimethylsulfoxide)

: 140-90-9
sodium O-ethyl dithiocarbonate

: MoO2Br(O-ethyl dithiocarbonate)(dimethylsulfoxide)

Conditions

Conditions	Yield
In dichloromethane byproducts: NaBr, Me2SO; suspn. of Na-compound in CH2Cl2 added to soln. of Mo-compound in CH2Cl2 in 1:1 molar ratio with constant stirring; stirred for 3 h; filtered; washed with CH2Cl2; excess solvent removed; dried in vacuo; washed repeatedly with dried benzene; elem. anal.;	89%

: {C5H5Ni(P(C4H9-n)3)2}Cl

: 140-90-9
sodium O-ethyl dithiocarbonate

: 52247-33-3
C5H5Ni(P(C4H9-n)3)SC(S)OC2H5

Conditions

Conditions	Yield
In water room temp.; with excess of NaSC(S)OC2H5; extn. of the brown ppt. with ether or benzene; drying, evapn. in vac.; recrystn. from benzene or benzene/hexane;	88%
In water

: iron(III) chloride hexahydrate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 1180915-75-6
[Fe(diphenylphosphinoethane)(ethyl xanthate)2]

Conditions

Conditions	Yield
With ascorbic acid In ethanol; dichloromethane; water soln. of ascorbic acid in EtOH/H2O (9:1 v/v) was added with stirring to soln. of FeCl3*6H2O in EtOH, heated to 70°C, soln. of dppe in CH2Cl2 was added, stirred for 15 min, cooled to r.t., soln. of Na-xanthate in EtOH was added; filtered off, washed with water, EtOH, Et2O, crystd. from CHCl3/Et2O (4:1), elem. anal.;	88%
With HCl; NH2OHHCl In ethanol; dichloromethane byproducts: NaCl; soln. of NH2OHHCl in EtOH was added to soln. of FeCl3*6H2O and aq. HCl in EtOH, warmed at 60-70°C for 10 min, filtered, soln. of dppe in CH2Cl2 was added to filtrate, stirred for 15-20 min, filtered, soln. of Na-xanthate in EtOH was added; filtered, washed with water, 90% EtOH, Et2O, crystd. form CH2Cl2/Et2O (6:1), elem. anal.;

...Expand

: 75-15-0
carbon disulfide

: 64-17-5
ethanol

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran at 10 - 20℃; for 2h; Temperature;	97.4%
With sodium hydroxide In water for 4h;	80.4%
With sodium for 6h; Heating;	63%

: 141-52-6
sodium ethanolate

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With carbon disulfide

: 502-55-6
bis-ethoxythiocarbonyldisulfane

: 148-18-5
sodium N,N-diethyldithiocarbamate

A: 140-90-9
sodium O-ethyl dithiocarbonate

B: 327989-09-3
C8H15NOS4

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 502-55-6
bis-ethoxythiocarbonyldisulfane

: 55310-46-8
sodium dibenzyldithiocarbamate

A: 140-90-9
sodium O-ethyl dithiocarbonate

B: C18H19NOS4

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 327989-09-3
C8H15NOS4

A: 97-77-8
disulfiram

B: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 55310-46-8
sodium dibenzyldithiocarbamate

: C18H19NOS4

A: 10591-85-2
bis(dibenzylthiocarbamoyl)disulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;

...Expand

: 64-17-5
ethanol

CS2: CS2

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With sodium hydroxide

: 141-52-6
sodium ethanolate

CS2: CS2

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With ethanol
With ethanol

: 75-15-0
carbon disulfide

: 141-52-6
sodium ethanolate

: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
at 0 - 20℃;
catalyst

: 64-17-5
ethanol

: 534-18-9
sodium trithiocarbonate

A: sodium hydrogen sulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

Conditions

Conditions	Yield
In water ambient temp., 5 h;
In water ambient temp., 5 h;

...Expand

: 64-17-5
ethanol

: 124-38-9
carbon dioxide

: 534-18-9
sodium trithiocarbonate

A: sodium hydrogen sulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

C: 17201-44-4
sodium ethyl carbonate

D: sodium thiosulfate

Conditions

Conditions	Yield
In ethanol 30 min;
In ethanol 30 min;

...Expand

: 64-17-5
ethanol

: 124-38-9
carbon dioxide

: 534-18-9
sodium trithiocarbonate

A: sodium sulfide

B: 140-90-9
sodium O-ethyl dithiocarbonate

C: 17201-44-4
sodium ethyl carbonate

D: sodium thiosulfate

Conditions

Conditions	Yield
In ethanol 30 min;
In ethanol 30 min;

...Expand

: 29632-74-4
2-fluro-4-iodoaniline

: 140-90-9
sodium O-ethyl dithiocarbonate

: 54420-94-9
6-iodobenzo[d]thiazole-2-thiol

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 95℃; for 5h;	100%

: 1401454-94-1
2,15-bis(chloromethyl)-4,7,10,13-tetraoxahexadeca-1,15-diene

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1401454-99-6
S,S'-2,15-dimethylene-4,7,10,13-tetraoxahexadecane-1,16-diyl O,O'-diethyl dicarbonodithioate

Conditions

Conditions	Yield
In ethanol at 20 - 35℃; Inert atmosphere;	98%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 541-41-3
chloroformic acid ethyl ester

: 3278-35-1
S-(ethoxycarbonyl) O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With cetyltrimethylammonim bromide In N,N-dimethyl-aniline at 10 - 25℃; for 4h;	97.1%

: 1326703-36-9
2,15-bis(chloromethyl)-7,10-dioxa-4,13-dithiahexadeca-1,15-diene

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1401455-02-4
S,S'-2,15-dimethylene-7,10-dioxa-4,13-dithiahexadecane-1,16-diyl O,O'-diethyl dicarbonodithioate

Conditions

Conditions	Yield
In ethanol at 20 - 35℃; Inert atmosphere;	97%

: 2106-02-7
2-chloro-4-fluoroaniline

: 140-90-9
sodium O-ethyl dithiocarbonate

: 6-fluoro-1,3-benzothiazole-2(3H)-thione

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 4h;	96%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 32278-97-0
bis(dichlorostibino)methane

: {Sb(S2COC2H5)2}2CH2

Conditions

Conditions	Yield
In methanol byproducts: NaCl; addition of a solution of 6.00 mmol of NaS2COEt in 20 ml CH3OH drop by drop to a solution of 1.50 mmol of (Cl2Sb)2CH2 (1 hour) and stirring at 25°C, 3 - 5 hours;; filtration, washing with CH3OH and drying; elem. anal.;;	96%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 107-05-1
3-chloroprop-1-ene

: 7124-50-7
S-allyl O-ethyl dithiocarbonate

Conditions

Conditions	Yield
With cetyltrimethylammonim bromide at 25℃; for 6.5h;	95.3%

: 908126-51-2
di-n-propylammonium hydrogen sulphate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 759-94-4
S-ethyl N,N-di-n-propylthiocarbamate

Conditions

Conditions	Yield
Stage #1: di-n-propylammonium hydrogen sulphate; sodium O-ethyl dithiocarbonate With dihydrogen peroxide In water at 40℃; for 1h; Green chemistry; Stage #2: With sulfuric acid In water at 70℃; for 1h; pH=7; Green chemistry;	94%

: 10369-54-7
μ-oxo-bis{bromotrimethyl-λ5-stibane}

: 140-90-9
sodium O-ethyl dithiocarbonate

: 140405-09-0
{(CH3)3SbS2COC2H5}2O

Conditions

Conditions	Yield
In dichloromethane byproducts: NaBr; addition of a twofold excess of NaS2COEt to a suspension of 2 mmol of (Me3SbBr)2O in 10 ml CH2Cl2 at -30°C, stirring (2 hours), filtration and evaporation;; recrystallization from diethyl ether; elem. anal.;;	93%

: 14780-97-3
tetraethylammonium chloropentacarbonyltungstate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 922713-51-7
(CH3CH2)4N(1+)*W(CO)4(SSCOCH2CH3)(1-)=((CH3CH2)4N)[W(CO)4(SSCOCH2CH3)]

Conditions

Conditions	Yield
In acetonitrile byproducts: NaCl, CO; under N2; Schlenk technique; mixt. of W compd. and Na salt in CH3CN refluxed for 2 h; evapn. under vac., residue dissolved in THF/acetone (10/1), filtration through silica/celite, filtrate evapd., residue washed with Et2O; elem. anal.;	93%

: 93614-78-9, 4549-82-0
3-(2-methylphenyl)prop-2-en-1-al

: 140-90-9
sodium O-ethyl dithiocarbonate

: 108-91-8
cyclohexylamine

: 3-cyclohexyl-4-hydroxy-6-(2-methylphenyl)-1,3-thiazinane-2-thione

Conditions

Conditions	Yield
In chloroform at 61℃; for 1.83333h;	92.7%

...Expand

: 65087-26-5
diisopropylammonium hydrogen sulphate

: 140-90-9
sodium O-ethyl dithiocarbonate

: 63644-60-0
diisopropyl-thiocarbamic acid S-ethyl ester

Conditions

Conditions	Yield
Stage #1: diisopropylammonium hydrogen sulphate; sodium O-ethyl dithiocarbonate With dihydrogen peroxide In water at 45℃; for 1.5h; Green chemistry; Stage #2: With sulfuric acid In water at 75℃; for 2.2h; pH=7; Green chemistry;	92%

: 140-90-9
sodium O-ethyl dithiocarbonate

: 115-09-3
methylmercury(II) chloride

: 104855-65-4
CH3Hg(S2COCH2CH3)

Conditions

Conditions	Yield
In dichloromethane MeHgCl dissolved in CH2Cl2 was treated with ligand, stirred at room temp. for 1 h; filtered, evapd. in open air, redissolved in CH2Cl2, filtered, covered with petroleum ether, crystd. in reflrigerator, filtered, dried in vacuo;elem. anal.;	91.7%

: 111-26-2
hexan-1-amine

: 140-90-9
sodium O-ethyl dithiocarbonate

: 1504-75-2
3-(4-methylphenyl)acrylaldehyde

: 3-n-hexyl-4-hydroxy-6-(4-methylphenyl)-1,3-thiazinane-2-thione

Conditions

Conditions	Yield
In methanol at 65℃; for 1.08333h;	91.7%

...Expand

: 140-90-9
sodium O-ethyl dithiocarbonate

: 104-94-9
4-methoxy-aniline

: 122-40-7
jasminaldehyde

: 5-pentyl-3-(4-methoxyphenyl)-4-hydroxy-6-phenyl-1,3-thiazinane-2-thione

Conditions

Conditions	Yield
In dichloromethane at 25℃; for 1.66667h;	90.7%

...Expand

: ((Pd(μ-I)((CH2)2S(O)Me))2)

: 140-90-9
sodium O-ethyl dithiocarbonate

: Pd{(CH2)2(SO)(CH3)}(S2COC2H5)

Conditions

Conditions	Yield
In dichloromethane Addn. of org. compd. to suspn. of Pd-complex (CH2Cl2) using n-Bu4NI as phase transfer catalyst and stirring. The yellow solid is dissolved within 6 min.; Washing of ppt. with H2O (3 times), removal of solvent, recrystn. of residue from n-hexane/CH2Cl2, elem. anal.;	90%
In dichloromethane Addn. of org. compd. to suspn. of Pd-complex (CH2Cl2) and stirring. The yellow solid is dissolved within 15 min.;	79%

Sodium ethylxanthogenate Specification

The IUPAC name of Sodium ethylxanthogenate is sodium ethoxymethanedithioate. With the CAS registry number 140-90-9, it is also named as Carbonodithioic acid, O-ethyl ester, sodium salt. The product's categories are Classes of Metal Compounds; Na (Sodium) Compounds (excluding Simple Sodium Salts); Typical Metal Compounds. Besides, it is light yellow powder, which should be stored in sealed and dry place away from oxidizing agents. In addition, its molecular formula is C₃H₅NaOS₂ and molecular weight is 144.18.

The other characteristics of this product can be summarized as: (1)EINECS: 205-440-9; (2)ACD/LogP: 1.94; (3)# of Rule of 5 Violations: 0; (4)ACD/LogD (pH 5.5): -0.35; (5)ACD/LogD (pH 7.4): -1.68; (6)ACD/BCF (pH 5.5): 1; (7)ACD/BCF (pH 7.4): 1; (8)ACD/KOC (pH 5.5): 1.39; (9)ACD/KOC (pH 7.4): 1; (10)#H bond acceptors: 1; (11)#H bond donors: 0; (12)#Freely Rotating Bonds: 2; (13)Polar Surface Area: 80.12 Å²; (14)Density: 1.558 g/cm³; (15)Flash Point: 26.7 °C; (16)Enthalpy of Vaporization: 34.38 kJ/mol; (17)Boiling Point: 120.5 °C at 760 mmHg; (18)Vapour Pressure: 18.2 mmHg at 25 °C.

Preparation of Sodium ethylxanthogenate: this chemical can be prepared by Carbon disulfide, Ethanol and Sodium hydroxide. The reaction equation is as follows:

Uses of Sodium ethylxanthogenate: this chemical can be used as molybdenum reagent and flotation agents of ore. Moreover, it is used for drying of crop in agriculture. And it also can be used to produce leprosy drug and used as rubber vulcanization accelerator in industry.

When you are using this chemical, please be cautious about it as the following: it is irritating to eyes, respiratory system and skin. In case of contact with eyes, please rinse immediately with plenty of water and seek medical advice. And you should wear suitable protective clothing, gloves and eye/face protection.

People can use the following data to convert to the molecule structure.
(1)SMILES: [Na+].[S-]C(=S)OCC
(2)InChI: InChI=1/C3H6OS2.Na/c1-2-4-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
(3)InChIKey: RZFBEFUNINJXRQ-REWHXWOFAP
(4)Std. InChI: InChI=1S/C3H6OS2.Na/c1-2-4-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
(5)Std. InChIKey: RZFBEFUNINJXRQ-UHFFFAOYSA-M

Product Name

Sodium ethylxanthogenate

Synthetic route

Sodium ethylxanthogenate Specification

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