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Titanium dioxide Basic information |
Product Name: | Titanium dioxide |
Synonyms: | UNITANE;PIGMENT WHITE 6;TIO2;TITANIC ANHYDRIDE;TITAN DIOXIDE;TITANIA;TITANIUM(+4)OXIDE;TITANIUM DIOXIDE, ANATASE |
CAS: | 13463-67-7 |
MF: | O2Ti |
MW: | 79.87 |
EINECS: | 215-280-1 |
Product Categories: | Inorganics;Indoles;Inorganic Chemicals;metal oxide;PETRO CHEM;colorant;Pharmaceutical intermediates |
Mol File: | 13463-67-7.mol |
Titanium dioxide Chemical Properties |
Melting point | 1840 °C |
Boiling point | 2900 °C |
density | 4.26 g/mL at 25 °C(lit.) |
refractive index | 2.61 |
Fp | 2500-3000°C |
storage temp. | -20°C |
form | powder |
color | White to slightly yellow |
PH | 7-8 (100g/l, H2O, 20℃)(slurry) |
Water Solubility | insoluble |
Merck | 14,9472 |
CAS DataBase Reference | 13463-67-7(CAS DataBase Reference) |
NIST Chemistry Reference | Titanium dioxide(13463-67-7) |
EPA Substance Registry System | Titanium oxide (TiO2)(13463-67-7) |
Safety Information |
Hazard Codes | Xn,Xi,C |
Risk Statements | 20-36/37/38-20/21/22-38-20/21-10-36/38-22-36-34-40 |
Safety Statements | 26-36-25-2-36/37-45-36/37/39 |
WGK Germany | - |
RTECS | XR2275000 |
TSCA | Yes |
HS Code | 28230000 |
Hazardous Substances Data | 13463-67-7(Hazardous Substances Data) |
Titanium dioxide Usage And Synthesis |
Chemical Properties | The naturally occurring dioxide exists in three crystal forms: anatase, rutile and brookite. While rutile, the most common form, has an octahedral structure. Anatase and brookite have very distorted octahedra of oxygen atoms surrounding each titanium atom. In such distorted octahedral structures, two oxygen atoms are relatively closer to titanium than the other four oxygen atoms. Anatase is more stable than the rutile form by about 8 to 12 kJ/mol (Cotton, F.A., Wilkinson, G., Murillo, C.A and M Bochmann. 1999. Advanced Inorganic Chemistry, 6th ed, p. 697, New York: John Wiley & Sons) Other physical properties are: density 4.23g/cm3; Mohs hardness 5.8 g/cm3 ( anatase and brookite) and 6.2 g/cm3 ( rutile); index of refraction 2.488 (anatase), 2.583 (brookite) and 2.609 (rutile); melts at 1,843°C; insoluble in water and dilute acids; soluble in concentrated acids. | |||||||||||||||||||||||||||||||||||||||||||||||
Uses | Titanium dioxide is an extreme white and bright compound with high index of refraction. In paints it is a white pigment and an opacifying agent.It is in house paints, water paints, lacquers, enamels, paper filling and coating, rubber, plastics, printing ink, synthetic fabrics, floor coverings, and shoe whiteners. Also, it is used in colorants for ceramics and coatings for welding rods. A rutile form of the dioxide is used in synthetic gem stones. | |||||||||||||||||||||||||||||||||||||||||||||||
Application |
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Uses | Airfloated ilmenite is used for titanium pigment manufacture. Rutile sand is suitable for welding-rod-coating materials, as ceramic colorant, as source of titanium metal. As color in the food industry. Anatase titanium dioxide is used for welding-rod-coatings, acid resistant vitreous enamels, in specification paints, exterior white house paints, acetate rayon, white interior air-dry and baked enamels and lacquers, inks and plastics, for paper filling and coating, in water paints, tanners' leather finishes, shoe whiteners, and ceramics. High opacity and tinting values are claimed for rutile-like pigments. | |||||||||||||||||||||||||||||||||||||||||||||||
Preparation |
Titanium dioxide is mined from natural deposits. It also is produced from other titanium minerals or prepared in the laboratory. Pigment-grade dioxide is produced from the minerals, rutile and ilmenite. Rutile is converted to pigment grade rutile by chlorination to give titanium tetrachloride, TiCl4. Anhydrous tetrachloride is converted back to purified rutile form by vapor phase oxidation. Anatase form is obtained by hydrolytic precipitation of titanium(IV) sulfate on heating. The mineral ilmenite is treated with concentrated sulfuric acid. Heating the sulfate solution precipitates hydrous titanium oxide. The precipitate is calcined to expel all water. Titanium dioxide also can be prepared by heating Ti metal in air or oxygen at elevated temperatures. |
CAS NO:2611-82-7
CAS NO:2611-82-7
CAS NO:458-37-7
CAS NO:1333-86-4
CAS NO:1333-86-4
CAS NO:13463-67-7
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