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Aluminum oxide Basic information |
Aluminum oxide Chemical Properties |
Melting point | 2040 °C(lit.) |
Boiling point | 2980°C |
density | 3.97 |
vapor pressure | 17 mm Hg ( 20 °C) |
refractive index | 1.765 |
Fp | 2980°C |
storage temp. | -20°C |
solubility | Miscible with ethanol. |
form | powder |
color | White to pink |
PH | 7.0±0.5 ( in H2O) |
Water Solubility | INSOLUBLE |
Merck | 14,356 |
InChIKey | PNEYBMLMFCGWSK-UHFFFAOYSA-N |
CAS DataBase Reference | 1344-28-1(CAS DataBase Reference) |
NIST Chemistry Reference | Aluminum oxide(1344-28-1) |
EPA Substance Registry System | Aluminum oxide (Al2O3)(1344-28-1) |
Safety Information |
Hazard Codes | Xi,F |
Risk Statements | 36/37/38-67-36/38-11-36 |
Safety Statements | 26-24/25-16-7-36 |
RIDADR | UN1219 - class 3 - PG 2 - Isopropanol, solution |
WGK Germany | - |
RTECS | BD1200000 |
F | 3 |
TSCA | Yes |
HazardClass | 8 |
HS Code | 28181010 |
Hazardous Substances Data | 1344-28-1(Hazardous Substances Data) |
Toxicity | Chronic inhalation of Al2O3 dusts may cause lung damage. |
Aluminum oxide Usage And Synthesis |
Chemical Properties | white powder |
Physical properties | Al2O3 Colorless hexagonal crystal; refractive index 1.768; density 3.965 g/cm3 (at 25°C); mp 2072°C; bp 2980°C; insoluble in water α-Al2O3 Colorless rhombic crystal; mp between 2005 to 2025°C ; density 4.022 g/m3 ; hardness 9Moh γ-Al2O3 white microscopic crystal Al2O3•H2O colorless rhombic crystal; refractive index 1.624; density 3.014 g/cm3 Al2O3•3H2O white monoclinic crystal; refractive index 1.577; density 2.420 g/cm3 All forms are insoluble in water. |
Uses | Occurs in nature in abundance; the principal forms are bauxites and laterites. The mineral corundum is used to produce precious gems, such as ruby and sapphire. Activated aluminas are used extensively as adsorbents because of their affinity for water and other polar molecules; and as catalysts because of their large surface area and appropriate pore sturcture. As adsorbents, they are used for drying gases and liquids; and in adsorption chromatography. Catalytic properties may be attributed to the presence of surface active sites (primarily OH– , O2– , and Al3+ ions). Such catalytic applications include sulfur recovery from H2S (Clauss catalysis); dehydration of alcohols, isomerization of olefins; and as a catalyst support in petroleum refining. |
Uses |
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