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5137-55-3 Methyl trioctyl ammonium chloride C25H54ClN
Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate, is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
Methyl trioctyl ammonium chloride Basic information |
Product Name: | Methyl trioctyl ammonium chloride |
Synonyms: | CAPRIQUAT;METHYLTRIOCTYLAMMONIUM CHLORIDE;METHYLTRIOCTYLAMINE HYDROCHLORIDE;METHYLTRI-N-OCTYLAMMONIUM CHLORIDE;ALIQUAT(R) 336;ALIQUAT(TM) 336;ALIQUAT 336;ADOGEN 464 |
CAS: | 5137-55-3 |
MF: | C25H54ClN |
MW: | 404.16 |
EINECS: | 225-896-2 |
Product Categories: | Industrial/Fine Chemicals;Ammonium Chlorides (Quaternary);-;Quaternary ammonium salt;organic intermediates;Quaternary Ammonium Compounds |
Mol File: | 5137-55-3.mol |
|
Methyl trioctyl ammonium chloride Chemical Properties |
Melting point | -20°C |
Boiling point | 240°C |
density | 0.884 g/mL at 25 °C(lit.) |
refractive index |
n |
Fp | >230 °F |
Sensitive | Hygroscopic |
BRN | 4039255 |
Stability: | Stable. Incompatible wth strong oxidizing agents. Hygroscopic. |
InChIKey | XKBGEWXEAPTVCK-UHFFFAOYSA-M |
CAS DataBase Reference | 5137-55-3(CAS DataBase Reference) |
EPA Substance Registry System | 1-Octanaminium, N-methyl-N,N-dioctyl-, chloride(5137-55-3) |
Safety Information |
Hazard Codes | Xn,N,C |
Risk Statements | 22-38-41-50/53-36/37/38-20/21/22-34 |
Safety Statements | 26-39-60-61-36-45-36/37/39 |
RIDADR | UN 2810 6.1/PG 3 |
WGK Germany | 3 |
RTECS | UZ2997500 |
F | 3-10 |
HazardClass | 6.1 |
PackingGroup | III |
HS Code | 29239000 |
MSDS Information |
Provider | Language |
---|---|
Aliquat 336 | English |
SigmaAldrich | English |
ALFA | English |
Methyl trioctyl ammonium chloride Usage And Synthesis |
Description | Methyltrioctylammonium chloride is a water insoluble quaternary ammonium salt, which is widely used as a counter ion in solvent extraction of anionic metal complexes. It is widely used as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. In comparison to traditional method of oxidizing cyclohexanol or cyclohexanone with nitric acid or potassium permanganate, the usage of methyltrioctylammonium chloride is a more environmentally friendly reaction. |
Reference | N. Pourreza, H. Zavvar Mousavi, Determination of cadmium by flame atomic absorption spectrometry after preconcentration on naphthalene– methyltrioctylammonium chloride adsorbent as tetraiodocadmate (II) ions, Analytica Chimica Acta, 2004, vol. 503, pp. 279-282 |
Chemical Properties | viscous colourless to pale orange liquid |
Definition | ChEBI: An organic chloride salt having methyltrioctylammonium as the cation. |
Safety Profile | Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl-. |
Purification Methods | A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.] |
Methyl trioctyl ammonium chloride Preparation Products And Raw materials |
Preparation Products | (5-BROMOTHIOPHEN-3-YL)METHANESULFONYL CHLORIDE-->3-NITROPHENYLMETHANESULFONYL CHLORIDE-->(4-CHLORO-PHENYL)-METHANESULFONYL CHLORIDE-->(4-BROMOTHIOPHEN-2-YL)METHANESULFONYL CHLORIDE-->1,3-Dimethyl-2-imidazolidinone-->6-BENZYLOXYPURINE-->(2-CHLORO-PHENYL)-METHANESULFONYL CHLORIDE |
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