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China Biggest Factory & Manufacturer supply Perillartine 600MT/Year
China Biggest Factory & Manufacturer supply Perillartine 600MT/Year
China Biggest Factory & Manufacturer supply Perillartine 600MT/Year
China Biggest Factory & Manufacturer supply Perillartine 600MT/Year
China Biggest Factory & Manufacturer supply Perillartine 600MT/Year

China Biggest Factory & Manufacturer supply Perillartine 600MT/Year

Min.Order / FOB Price:Get Latest Price

500 Kilogram

FOB Price:USD 1.0000 -2.0000
  • Min.Order :500 Kilogram
  • Purity: 99%
  • Payment Terms : L/C,D/A,D/P,T/T,Other

Keywords

Perillartine 30950-27-7 Perillartine

Quick Details

  • Appearance:white powder
  • Application:chemicals industry
  • PackAge:25KG/Drum
  • ProductionCapacity:50|Metric Ton|Month
  • Storage:2-8°C
  • Transportation:By air /Sea/ coruier

Superiority:

Perillartine Basic information
Product Name: Perillartine
Synonyms: 1-PERILLALDEHYDE A-ANTIOXIME;1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethenyl)-, oxime, (E)-;1-Cyclohexene-1-carboxaldehyde, 4-isopropenyl-, anti-oxime;1-Perillaldehyde alpha-antioxime;1-perillaldehydealpha-antioxime;4-(1-methylethenyl)-,oxime,(e)-1-cyclohexene-1-carboxaldehyd;4-(1-Methylethenyl)-1-cyclohexene-1-carbaldehyde (E)-oxime;4-Isopropenyl-1-cyclohexene-1-carbaldehyde (E)-oxime
CAS: 30950-27-7
MF: C10H15NO
MW: 165.23
EINECS: 250-402-7
Product Categories: food additives
Mol File: 30950-27-7.mol
Perillartine Structure
 
Perillartine Chemical Properties
Melting point  102°C
Boiling point  293.09°C (rough estimate)
density  1.0203 (rough estimate)
refractive index  1.5200 (estimate)
storage temp.  under inert gas (nitrogen or Argon) at 2–8 °C
pka 11.45±0.28(Predicted)
color  Very sweet crystals
NIST Chemistry Reference Perillartine(30950-27-7)
EPA Substance Registry System 1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethenyl)-, oxime, (E)- (30950-27-7)
 
Safety Information
Risk Statements  36/37/38
Safety Statements  26-36/37/39
Toxicity LD50 orl-rat: 2500 mg/kg AFDOAQ 15,82,51
MSDS Information
 
Perillartine Usage And Synthesis
Safety Profile Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx.
 
Perillartine Preparation Products And Raw materials
 

 

Details:

 

4-tert-Butylcyclohexanone Basic information
Product Name: 4-tert-Butylcyclohexanone
Synonyms: 98-53-3;4-tert-Butylcyclohexanone, 99% 100GR;4-TERT-BUTYLCYCLOHEXANONE;P-TERT-BUTYLCYCLOHEXANONE;PARA TERTIARY BUTYL CYCLOHEXANONE;TIMTEC-BB SBB007656;4CO;AKOS BBS-00000687
CAS: 98-53-3
MF: C10H18O
MW: 154.25
EINECS: 202-678-5
Product Categories: Halogenated Heterocycles ,Pyrimidines;Carbonyl Compounds;Liquid Crystal intermediates;C10;Ketones
Mol File: 98-53-3.mol
4-tert-Butylcyclohexanone Structure
 
4-tert-Butylcyclohexanone Chemical Properties
Melting point  47-50 °C (lit.)
Boiling point  113-116 °C/20 mmHg (lit.)
density  0.893
refractive index  1.4570 (estimate)
Fp  205 °F
storage temp.  Sealed in dry,Room Temperature
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Crystalline Powder
color  White to almost white
Water Solubility  Soluble in alcohol, ethanol (0.5g/10 mL). Insoluble in water.
BRN  507309
InChIKey YKFKEYKJGVSEIX-UHFFFAOYSA-N
CAS DataBase Reference 98-53-3(CAS DataBase Reference)
NIST Chemistry Reference Cyclohexanone, 4-(1,1-dimethylethyl)-(98-53-3)
EPA Substance Registry System Cyclohexanone, 4-(1,1-dimethylethyl)- (98-53-3)
 
Safety Information
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  2
RTECS  GW1140000
TSCA  Yes
HS Code  29142990
toxicity Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits were reported to be 5 g/kg
MSDS Information
Provider Language
SigmaAldrich English
ACROS English
ALFA English
 
4-tert-Butylcyclohexanone Usage And Synthesis
Chemical Properties WHITE TO ALMOST WHITE CRYSTALLINE POWDER
Occurrence Has apparently not been reported to occur in nature.
Uses 4-tert-Butylcyclohexanone is used as a perfuming agents and in cosmetic.
Preparation By hydrogenation of p-ferr-butylphenol. Care must be taken that no free p-tert-butylphenol remains, because it is a sensitizer and depigmenting agent(Opdyke, 1974).
Preparation N-Chlorosuccinimide (NCS) (8.0 g, 0.060 mol) and toluene (200 mL) were cooled to 0 C° in a 1-L, threenecked, round-bottomed flask equipped with a mechanical stirrer, a thermometer, a dropping funnel, and an argon inlet tube. Dimethyl sulfoxide (6.0 mL, 0.10 mol) was added and the mixture was cooled to -25 C° using a tetrachloromethane/dryice bath. A solution of 4-tert-butylcyclohexanol (6.24 g, 0.04 mol; mixture of E and Z isomers) in toluene (40 mL) was added dropwise over 5 min, stirring was continued for 2 h at -25 C°, and then a solution of triethylamine (6.0 g, 0.06 mol) in toluene (10 mL) was added dropwise over 3 min. The cooling bath was removed, and, after 5 min, diethyl ether (400 mL) was added. The organic phase was washed with 1% aq. hydrochloric acid (100 mL) and then with water (2 × 100 mL), and dried over anhydrous magnesium sulfate. The solvents were evaporated under reduced pressure, and the residue was transferred to a 50-mL, round-bottomed flask and bulb-to-bulb distilled at 120 C° (25 mmHg) to yield 5.72 g (93%) of 4-tertbutylcyclohexanone 1794; mp 41–45 C°. Recrystallization from petroleum ether at -20 C° gave an 88% recovery of 1794 with mp 45–46 C°.
Synthesis Reference(s) Chemistry Letters, 24, p. 507, 1995
Journal of the American Chemical Society, 94, p. 7586, 1972 DOI: 10.1021/ja00776a056
Tetrahedron Letters, 16, p. 3775, 1975
Purification Methods Purify it via the semicarbazone (crystallised from EtOH with m 203-205o), hydrolyse this with dilute HCl and steam distil it. The distillate is extracted into Et2O, dried, evaporated and the residue is recrystallised from pentane, aqueous EtOH or EtOH [Houlihan J Org Chem 27 3860 1962]. The oxime recrystallises from 1,2-dichloropropane and has m 137.5-138.5o. [Harvill et al. J Org Chem 15 58 1950, Beilstein 7 IV 82.]
 
4-tert-Butylcyclohexanone Preparation Products And Raw materials
Perillartine Basic information
Product Name: Perillartine
Synonyms: 1-PERILLALDEHYDE A-ANTIOXIME;1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethenyl)-, oxime, (E)-;1-Cyclohexene-1-carboxaldehyde, 4-isopropenyl-, anti-oxime;1-Perillaldehyde alpha-antioxime;1-perillaldehydealpha-antioxime;4-(1-methylethenyl)-,oxime,(e)-1-cyclohexene-1-carboxaldehyd;4-(1-Methylethenyl)-1-cyclohexene-1-carbaldehyde (E)-oxime;4-Isopropenyl-1-cyclohexene-1-carbaldehyde (E)-oxime
CAS: 30950-27-7
MF: C10H15NO
MW: 165.23
EINECS: 250-402-7
Product Categories: food additives
Mol File: 30950-27-7.mol
Perillartine Structure
 
Perillartine Chemical Properties
Melting point  102°C
Boiling point  293.09°C (rough estimate)
density  1.0203 (rough estimate)
refractive index  1.5200 (estimate)
storage temp.  under inert gas (nitrogen or Argon) at 2–8 °C
pka 11.45±0.28(Predicted)
color  Very sweet crystals
NIST Chemistry Reference Perillartine(30950-27-7)
EPA Substance Registry System 1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethenyl)-, oxime, (E)- (30950-27-7)
 
Safety Information
Risk Statements  36/37/38
Safety Statements  26-36/37/39
Toxicity LD50 orl-rat: 2500 mg/kg AFDOAQ 15,82,51
MSDS Information
 
Perillartine Usage And Synthesis
Safety Profile Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx.
 
Perillartine Preparation Products And Raw materials

 

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