Factory high quality Permethrin

Min.Order / FOB Price:Get Latest Price

1 Gram	FOB Price:USD 6.0000 -8.0000

1 Gram

FOB Price:USD 6.0000 -8.0000

Min.Order :1 Gram
Purity: purity 98%-101%
Payment Terms : L/C,T/T,Other

Keywords

Permethrin 52645-53-1 Permethrin

Quick Details

Appearance:white powder
Application:Dietary supplements;Food;Additives;Pharmaceuticals;medicines;cosmetics Heart protection
PackAge:1kg/bag,5kg/bag,25kg/drum
ProductionCapacity:1|Kilogram|Day
Storage:20℃
Transportation:low temp

Superiority:

52645-53-1 - Physico-chemical Properties

Molecular Formula	C21H20Cl2O3
Molar Mass	391.29
Density	1.19
Melting Point	34-35°C
Boling Point	bp0.05 220°
Flash Point	10°C
Water Solubility	insoluble
Vapor Presure	7×10-5 Pa (20 °C)
Appearance	neat
Merck	13,7257
BRN	5765325
PH	6.5
Storage Condition	0-6°C
Stability	Stable. Incompatible with strong oxidising agents.
Refractive Index	1.6500 (estimate)
Physical and Chemical Properties	density 1.19 melting point 34-35°C water-soluble insoluble 3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Use	For high efficiency, low toxicity pesticides, used to control cotton, rice, vegetables, fruit trees, tea and other crop pests, can also control health and livestock pests

52645-53-1 - Risk and Safety

Risk Codes	R20/22 - Harmful by inhalation and if swallowed. R43 - May cause sensitization by skin contact R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R39/23/24/25 - R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R11 - Highly Flammable R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36 - Irritating to the eyes R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Safety Description	S13 - Keep away from food, drink and animal foodstuffs. S24 - Avoid contact with skin. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37 - Wear suitable protective clothing and gloves. S16 - Keep away from sources of ignition. S7 - Keep container tightly closed. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
UN IDs	UN1230 3/PG 2
WGK Germany	3
RTECS	GZ1255000
HS Code	29162090
Toxicity	LD50 orally in female rats: 3801 mg/kg (Metker); LD50 in 8 day old rats, male adult rats (mg/kg): 340.5, 1500.0 orally (Cantalamessa)

use	has strong touch killing and stomach poison effects, and has the characteristics of strong knockdown and fast insecticidal speed. It is more stable to light, and under the same conditions of use, the development of resistance to pests is also slower, and it is efficient to lepidopteran larvae. It can be used for the control of vegetables, tea, fruit trees, cotton and other crops to prevent rapae, aphids, cotton bollworms, cotton bollworms, cotton aphids, lygus, yellow striped beetle, peach little heart worm, citrus leaf miner, twenty-eight star ladybug, tea geometrid, tea caterpillar, tea moth and other pests, It also has good effects on mosquitoes, flies, fleas, cockroaches, lice and other sanitary pests. For example, to control cotton bollworm and cotton red bollworm, spray 1000~1250 times of 10% emulsifiable concentrate during the egg incubation period to treat bridge-building insects and leaf-rolling insects. Control of cotton aphid in the adult, nymphal period, with 10% emulsifiable concentrate 2000~3000 times spray, resistant cotton aphid and cotton bollworm effect is poor. To control fruit tree pests, spray 5.52kg of water with 10% emulsifiable concentrate 3.75mL/100 m2. To prevent and control sanitary pests, spray 800~1000 times of 10% emulsifiable concentrate. Control of cabbage, peach aphid, diamondback moth, Spodoptera litura, etc. with 10% emulsifiable concentrate 1000~2000 times spray. It is a high-efficiency and low-toxic insecticide. It is used to control cotton, rice, vegetables, fruit trees, tea trees and other crop pests. It can also control sanitary and livestock pests. This product is a high-efficiency and low-toxic insecticide. It is used to control cotton, rice, vegetables, fruit trees, tea trees and other crop pests. It is also used to control sanitary pests and livestock pests. Insecticidal effect is strong, and a very low concentration can cause pest poisoning and death. Most of the effective concentrations for pest control in agriculture are below 100ppm, generally 20-50ppm, and the amount of effective ingredients per mu is generally only 5-10ml.
Production method	Synthesis of 1,1, 1-trichloro-4-methyl-4-pentene-2-ol from trichloroacetaldehyde and isobutylene, After translocation, 1,1, 1-trichloro-4-methyl-3-pentene-2-ol is obtained, and then it is condensed and rearranged with triethyl orthoacetate to obtain 3, ethyl 3-dimethyl -4,6, 6-trichloro-5-hexenoate, further cyclized under the action of sodium ethoxide to 2, 2-dimethyl -3-(2, 2-dichlorovinyl) cyclopropane carboxyl ester ethyl ester, saponified into sodium salt, and then reacted with chlorine-3-phenoxybenzyl triethylamine to prepare dichloroethrin. The raw materials and intermediates of the method are easy to obtain, the operating conditions in the process are strict, the product content is generally 60-80%, processed into 3.2% or 10% emulsifiable concentrate, 0.25% powder. The interaction of trichloroacetaldehyde and isobutene to obtain (I)(II) two trichloroenol isomers. The reaction was carried out at low temperature with aluminum trichloride as a catalyst. In the presence of hydrogen chloride, acetonitrile reacts with absolute ethanol to produce iminoethyl ether hydrochloride, which further reacts with absolute ethanol to produce triethyl orthoacetate (III). In the presence of the catalyst p-toluenesulfonic acid, heating to 114~118 ℃, reaction for 3h, so that (I) is converted to (II). The translocation product is reacted with triethyl orthoacetate, the catalyst is isobutyric acid, the reaction temperature is raised from 110 ℃ to 150 ℃ for about 12h, the reaction is carried out at 150~155 ℃ for 7~8h, and the former fraction is evaporated at 0.08MPa pressure to obtain 3,3-dimethyl -4,6,6-trichlorohexene-[5]-ethyl acid (V), accompanied by (VI). (VI) is subjected to a ring-opening reaction in a hydrogen chloride-ethanol solution to obtain (V). (V) In the presence of sodium ethoxide, reaction at 40~45 ℃ for 5h, cyclization to produce 2, 2-dimethyl -3-(2, 2-dichlorovinyl)-cyclopropanecarboxylate (VII), after rectification to obtain higher purity of dichlorochrysanthemum acid ethyl ester. In the presence of lye, (VII) is refluxed for 3h and saponified to obtain the corresponding sodium salt (VIII). (VIII) reacts with m-phenoxybenzyl triethylamine chloride to produce permethrin (IX). The reaction process is as follows: The synthesis of dichlorochrysanthemum acid can be found in the literature [5].
category	flammable liquid
toxicity classification	highly toxic

Details:

Permethrin

CAS:

52645-53-1

MF:

C21H20Cl2O3

MW:

391.29

EINECS:

258-067-9

MDL No.:

MFCD00041809

Properties

Melting point:

34-35°C

Boiling point:

bp0.05 220°

Density

1.19

vapor pressure

7×10^-5 Pa (20 °C)

refractive index

1.6500 (estimate)

Flash point:

10 °C

storage temp.

0-6°C

solubility

DMF: 33 mg/ml; DMSO: 16 mg/ml; Ethanol: 14 mg/ml

Water Solubility

insoluble

Merck

13,7257

BRN

5765325

Stability:

Stable. Incompatible with strong oxidising agents.

InChIKey

RLLPVAHGXHCWKJ-UHFFFAOYSA-N

LogP

6.500

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Factory high quality Permethrin

CAS NO:52645-53-1