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TUNGSTEN (V) CHLORIDE TUNGSTEN (V) CHLORIDE TUNGSTEN (V) CHLORIDE
ungsten(VI) chloride, WCl6, is a dark violet blue species that exists as a volatile solid under standard conditions. It is an important starting reagent in the preparation of tungsten compounds. As a d0 ion, W(VI) forms diamagnetic derivatives. WCl6 is octahedral with equivalent W-Cl distances of 2.24-2.26 ? . | |
Chemical Properties | dark grey-violet crystalline powder. Tungsten(VI) chloride is a blue-black solid at room temperature. At lower temperatures, it turns into wine red. A red form of the compound can be formed by quickly condensing its vapor, which transforms to the blue-black form on gentle heating. It is easily hydrolyzed, even by moist air, giving the orange oxychlorides WOCl4 and WO2Cl2, and then, tungsten trioxide. WCl6 is soluble in carbon disulfide, carbon tetrachloride, and phosphorus oxychloride. Methylation with trimethylaluminum forms |
ungsten(VI) chloride, WCl6, is a dark violet blue species that exists as a volatile solid under standard conditions. It is an important starting reagent in the preparation of tungsten compounds. As a d0 ion, W(VI) forms diamagnetic derivatives. WCl6 is octahedral with equivalent W-Cl distances of 2.24-2.26 ? . | |
Chemical Properties | dark grey-violet crystalline powder. Tungsten(VI) chloride is a blue-black solid at room temperature. At lower temperatures, it turns into wine red. A red form of the compound can be formed by quickly condensing its vapor, which transforms to the blue-black form on gentle heating. It is easily hydrolyzed, even by moist air, giving the orange oxychlorides WOCl4 and WO2Cl2, and then, tungsten trioxide. WCl6 is soluble in carbon disulfide, carbon tetrachloride, and phosphorus oxychloride. Methylation with trimethylaluminum forms |
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