Add time:07/24/2019 Source:sciencedirect.com
The complete vibrational spectra of crystalline SODIUM BROMOACETATE (cas 1068-52-6) and sodium bromoacetate-d2 have been recorded and a vibrational assignmem proposed. The intermolecular coupling of these compounds is quite strong and the data are consistent with a centrosymmetric unit cell containing at least four molecules.The product rule calculations support a structure m which the bromine atom is rotated out of the plane of the remaining heavy atoms, but the frequency of the carbon-bromine stretching mode indicates that the degree of rotation is not large.
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