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  • Structure and antiferroelectric properties of CESIUM NIOBATE (cas 12053-66-6), Cs2Nb4O11
  • Add time:07/27/2019         Source:sciencedirect.com

    The compound cesium niobate, Cs2Nb4O11, is an antiferroelectric, as demonstrated by double hysteresis loops in the electric field versus polarization plot. The crystal structure refinement by X-ray diffraction at both 100 and 297 K shows it to have a centrosymmetric structure in point group mmm and orthorhombic space group Pnna, which is consistent with its antiferroelectric behavior. The 100-K structure data is reported herein. The lattice is comprised of niobium-centered tetrahedra and octahedra connected through shared vertices and edges; cesium atoms occupy channels afforded by the three-dimensional polyhedral network. Antiferroelectricity is produced by antiparallel displacements of niobium atoms along the c-axis at the phase transition temperature of 165 °C. The critical field for onset of ferroelectric behavior in a single-crystal sample is 9.5 kV/cm at room temperature.

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    Prev:Low temperature synthesis of CHROMIUM TELLURIDE (cas 12053-39-3)s using superlattice reactants: crystallisation of layered CrTe3 at 100°C and the decomposition into Cr2Te3
    Next: A new uranyl niobate sheet in the cesium uranyl niobate Cs9[(UO2)8O4(NbO5)(Nb2O8)2])

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