Add time:07/28/2019 Source:sciencedirect.com
The Cu(OAc)2/CF3COOH (TFA) system catalyzes the aminomethylation of gaseous alkanes such as propane and ethane with trimethylamine N-oxide to give N,N-dimethylisobutylamine (1) and N,N-dimethylpropylamine (7), respectively. The corresponding trifluoroacetates are also formed as by-products from the reactions of methane and propane.
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