Add time:08/05/2019         Source:sciencedirect.com

The reactions of dimethylthiocarbamoyl chloride with a number of neutral and ionic iron carbonyl complexes in tetrahydrofuran are described. A variety of unusual products were obtained, viz. Fe(CO)2(S2CNMe2)2 from Fe(CO)5; Fe(CO)2(S2CNMe2)(CSNMe2) from Fe2)CO)9, Fe3(CO)12, and Fe(CO)42−; [Fe-(CO)2(S2CNMe2)(CNMe2)(CNMe2)2S]+ from Fe(CO)42−, and Fe4(CO)12S(CSNMe2)-(CNMe2) from Fe2(CO)82−, as well as Fe2(CO)6(CSSEt)2 from Fe2(CO)9 and ClCSSEt. The structures and behavior and some reactions of these complexes are described.

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