N-Trimethylsilyl-bis(trifluoromethanesulfonyl)imide: a better carbonyl activator than trimethylsilyl triflate-Science-Chemical Encyclopedia-lookchem

N-Trimethylsilyl-bis(trifluoromethanesulfonyl)imide: a better carbonyl activator than trimethylsilyl triflate
Add time:08/11/2019 Source:sciencedirect.com

N-trimethylsilyl-bis(trifluoromethanesulfonyl)imide (TMSNTf2) was readily prepared from allyltrimethylsilane and bis(trifluoromethanesulfonyl)imide. It was shown to complex carbonyl groups much more effectively than trimethylsilyl triflate. As a result, TMSNTF2 was found to be superior to TMSOTf as a catalyst for the Diels-Alder reaction of methyl acrylate with various dienes.

We also recommend Trading Suppliers and Manufacturers of TRIMETHYLSILYL CROTONATE (cas 18269-64-2). Pls Click Website Link as below: cas 18269-64-2 suppliers

Prev:Kinetic and thermodynamic studies on one-step synthesis of methyl acrylate promoted by generated ionic liquid at mild temperature
Next: First general synthesis of monosilyl acetals. Trimethylsilyl trapping of the intermediate in DIBALH reduction of carboxylic acid esters using trimethylsilyl trifluoromethanesulfonate☆)

Encyclopedia