Add time:08/20/2019         Source:sciencedirect.com

The infrared and Raman spectra of solid K2NiF6 was studied. All the active frequencies ν1, ν2, ν3, ν4, and ν5 belonging to the isolated ion point group (Oh) were ascertained. Several lattice modes were also found in the Raman spectrum. Force constant calculations were carried out for both the general quadratic potential function and the Urey-Bradley potential and the results are compared with those for a similar tetravalent hexafluoro complex K2PtF6.

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