Add time:08/21/2019         Source:sciencedirect.com

B-Alkylpinacolboranes, derived from rhodium-catalyzed hydroboration of allyl ethers with pinacolborane, react with 1,4-Benzoquinone (cas 106-51-4) under acidic, oxidizing conditions, to afford, after subsequent hydrogenation, 2-substituted hydroquinones in isolated, purified yields of about 50% based on 1,4-benzoquinone. The product hydroquinones have potential use as precursors to poly(arylene ether) and related aromatic polymers.

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