Product description: Product name 1,4-Benzoquinone CAS number 106-51-4 Assay ≥99% Appearance Yellow crystal Capacity 500mt/year Application Dyes and pharmaceutical intermedia
Cas:106-51-4
Min.Order:100 Gram
FOB Price: $12.0
Type:Lab/Research institutions
inquiry1,4-Benzoquinone CAS: 106-51-4 Specification Product name 1,4-Benzoquinone CAS number 106-51-4 Assay ≥99% Appearance Yellow crystal Capacity 500mt/year Application Dyes and
Usage: It can be widely used in medicine, herbicide, chemicals and dyes Package, storage and transportation: 1. In 35 kgs N.W. or 25 kgs N.W. cardboard drum lined with double plastic bags 2. Keep in cool, dry places under 10-20℃ and away from s
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
Water:0.5%Max; Residue on ignition:0.05%Max; Melting point: 112-116℃Appearance:yellow crystals
1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:106-51-4
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With bis-[(trifluoroacetoxy)iodo]benzene In water; acetonitrile for 0.166667h; Ambient temperature; | 100% |
With copper(II) nitrate/zeolite H-Y Product distribution; Further Variations:; heating mode; times; microwave irradiation; | 100% |
With manganese dioxide impregnated with nitric acid In dichloromethane for 0.5h; Ambient temperature; | 96% |
Conditions | Yield |
---|---|
With barium ferrate(VI) In benzene for 0.25h; Product distribution; Heating; | 100% |
With benzyltrimethylammonium tribromide; sodium acetate In dichloromethane; water for 2h; Ambient temperature; | 100% |
With bis(2,2'-bipyridyl) copper(II) permanganate In dichloromethane for 0.25h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With CuCl2 In acetonitrile | 100% |
With [CuII2(μ-OH)(1,2-bis(2-(bis(2-pyridylmethyl)aminomethyl)-6-pyridyl)ethane)](ClO4)3 ; dihydrogen peroxide; triethylamine In water; acetonitrile at 50℃; for 10h; Catalytic behavior; Inert atmosphere; | 99% |
With manganese(IV) oxide; sulfuric acid; aniline at 10℃; for 1.5h; | 95% |
Conditions | Yield |
---|---|
With barium ferrate(VI) In benzene for 0.3h; Heating; | A 70% B 100% |
Conditions | Yield |
---|---|
With bis-[(trifluoroacetoxy)iodo]benzene In methanol; water at 20℃; for 4h; | 100% |
With manganese dioxide impregnated with nitric acid In dichloromethane for 1.5h; Ambient temperature; | 93% |
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1h; | 86% |
Conditions | Yield |
---|---|
With pyridinium chlorochromate In dichloromethane at 25℃; for 2h; Mechanism; relative reaction rate; | 99% |
With quinolinium monofluorochromate(VI) In dichloromethane for 1h; Ambient temperature; | 98% |
With dioxochloro(trimethylsiloxy)chromate(VI) In dichloromethane for 0.333333h; Ambient temperature; | 97% |
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In acetonitrile at 80℃; for 0.75h; Baeyer-Villiger Ketone Oxidation; regioselective reaction; | 99% |
Conditions | Yield |
---|---|
With sodium periodate In water at 20℃; for 0.166667h; | 98% |
With [bis(acetoxy)iodo]benzene In acetone at 20℃; for 0.166667h; | 90% |
With sulfuric acid; manganese triacetate In water at 35℃; Rate constant; Mechanism; | |
With dichromate anion | |
With manganese(IV) oxide; sulfuric acid |
Conditions | Yield |
---|---|
With iodobenzene; oxone; water In acetonitrile at 20℃; | 98% |
With sodium hydrogen sulfate; [bis(acetoxy)iodo]benzene In water; acetonitrile at 20℃; for 0.5h; Time; Solvent; | 80% |
Conditions | Yield |
---|---|
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 0.5h; | 97% |
With bis-[(trifluoroacetoxy)iodo]benzene In water; acetonitrile for 0.166667h; Ambient temperature; | 93% |
With oxone; tetrabutylammomium bromide In water; acetonitrile at 20℃; for 1h; | 92% |
With Oxone In water; acetonitrile at 20℃; for 17h; | 79% |
Conditions | Yield |
---|---|
With nitric acid; silica gel In dichloromethane for 0.166667h; Product distribution; Ambient temperature; | A 97% B 2% |
Conditions | Yield |
---|---|
With nitric acid; silica gel In dichloromethane for 0.0833333h; Product distribution; Ambient temperature; | A 97% B 2% |
Conditions | Yield |
---|---|
With NO+*18-crown-6*H(NO3)2- In various solvent(s) for 2h; Nitration; Heating; | A 94% B 5% |
With Zn(NO3)2*2N2O4 In ethyl acetate at 20℃; for 0.25h; | A 86% B 8% |
Conditions | Yield |
---|---|
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1h; | 94% |
With oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1h; | 94% |
With ammonium cerium(IV) nitrate In water; acetonitrile at 20℃; | 66% |
Conditions | Yield |
---|---|
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃; | A 94% B n/a |
4-(tert-butyldimethylsilyloxy)anisole
p-benzoquinone
Conditions | Yield |
---|---|
With oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1.5h; | 94% |
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1.5h; | 79% |
Conditions | Yield |
---|---|
With iodobenzene; oxone; water In acetonitrile at 20℃; | 94% |
With sodium hydrogen sulfate; [bis(acetoxy)iodo]benzene In water; acetonitrile at 20℃; for 0.666667h; | 75% |
Conditions | Yield |
---|---|
With [CuII2(μ-OH)(1,2-bis(2-(bis(2-pyridylmethyl)aminomethyl)-6-pyridyl)ethane)](ClO4)3 ; dihydrogen peroxide; triethylamine In water; acetonitrile at 50℃; for 40h; Catalytic behavior; Inert atmosphere; | A 6.8% B 93.2% |
With dihydrogen peroxide In water for 0.25h; Reagent/catalyst; Irradiation; | A n/a B 81.5% |
With tetrakis(acetonitrile)copper(I) perchlorate; dihydrogen peroxide In water; acetonitrile at 25℃; for 4h; Catalytic behavior; Reagent/catalyst; | A 60% B n/a |
Conditions | Yield |
---|---|
With K10 montmorillonite; iodic acid for 0.00833333h; microwave irradiation; | 93% |
With Montmorillonite K10; iodic acid at 68℃; for 0.00555556h; microwave irradiation; | 85% |
With pyridine hydrogenfluoride; sodium nitrite Product distribution; Mechanism; other substrates, various temp.; | 80% |
Conditions | Yield |
---|---|
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃; | A 93% B n/a |
N-phenylsulphonyl-Se,Se-diphenylselenimide
hydroquinone
A
benzenesulfonamide
B
diphenylselenide
C
p-benzoquinone
Conditions | Yield |
---|---|
In toluene for 25h; Product distribution; Heating; other N-sulfonylchalcogenimides, other quinones, var. solvent and time; | A 92% B 87% C 89% |
Conditions | Yield |
---|---|
With oxone; tetrabutylammomium bromide In water; acetonitrile at 20℃; for 1h; | 92% |
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 0.5h; | 88% |
With Oxone In water; acetonitrile at 20℃; for 17h; | 77% |
Conditions | Yield |
---|---|
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃; | A 91% B n/a |
Conditions | Yield |
---|---|
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃; | A 91% B n/a |
Conditions | Yield |
---|---|
With cerium(IV) ammonium nitrate; silica gel In dichloromethane at 20℃; | A 90% B n/a |
Conditions | Yield |
---|---|
With methanesulfonic acid; dihydrogen peroxide In water; acetonitrile at 50℃; for 6h; Flow reactor; Green chemistry; | A 1% B 8% C 90% |
Conditions | Yield |
---|---|
With ceric(IV) tetra-n-butylammonium nitrate; water In dichloromethane at 20℃; for 0.333333h; Reagent/catalyst; Solvent; Temperature; | A 89% B n/a |
1-(4-methoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propan-1-one
B
4-methoxy-phenol
C
p-benzoquinone
Conditions | Yield |
---|---|
With methanesulfonic acid; dihydrogen peroxide In water; acetonitrile at 50℃; for 6h; Flow reactor; Green chemistry; | A 9% B 2% C 89% |
Conditions | Yield |
---|---|
With sulfuric acid at 40 - 50℃; | 100% |
With sulfuric acid at 10 - 45℃; for 1h; | 97.4% |
With sulfuric acid at 25 - 50℃; for 0.5h; Reagent/catalyst; Temperature; | 96% |
Conditions | Yield |
---|---|
In hexane; ethyl acetate at 0℃; for 3.5h; Diels-Alder Cycloaddition; | 100% |
In methanol at -78 - 0℃; Inert atmosphere; optical yield given as %de; | 98% |
In hexane; ethyl acetate at 0℃; for 4h; Diels-Alder reaction; | 97% |
Conditions | Yield |
---|---|
With sulfuryl dichloride; triethylamine In diethyl ether for 0.5h; | 100% |
With chloroform; chlorine | |
With sulfuryl dichloride |
Conditions | Yield |
---|---|
With nickel In tetrahydrofuran at 20℃; for 0.166667h; Reduction; | 100% |
With boron trifluoride diethyl etherate; sodium iodide In acetonitrile at 0℃; for 0.0833333h; | 99% |
With hydrazine hydrate In acetonitrile at 20℃; for 18h; Irradiation; | 99% |
Conditions | Yield |
---|---|
With perchloric acid In acetone at 0℃; | 100% |
sulfure de pentamethylene
p-benzoquinone
1-(2,5-dihydroxyphenyl)thianium bromide
Conditions | Yield |
---|---|
With hydrogen bromide In acetone at 0℃; | 100% |
cyclopenta-1,3-diene
p-benzoquinone
1α,4α,4aβ,10aα,5β,8β,8aα,9aβ-octahydro-1,4:5,8-dimethanoanthracene-9,10-dione
Conditions | Yield |
---|---|
In benzene at 40℃; for 20h; | 100% |
In dichloromethane at 20℃; for 24h; Diels-Alder reaction; | 100% |
In ethanol at 0℃; for 0.5h; Diels-Alder Cycloaddition; | 98% |
Conditions | Yield |
---|---|
In methanol | 100% |
With methanol at 20℃; for 6h; | 99% |
In methanol for 0.166667h; Ambient temperature; | 95% |
Diphenylphosphine oxide
p-benzoquinone
(2,5-dihydroxyphenyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
In toluene for 1.66667h; | 100% |
With water In toluene at 80℃; for 12h; Inert atmosphere; Schlenk technique; | 98% |
In toluene for 20h; Inert atmosphere; Reflux; | 88.1% |
In toluene at 75 - 110℃; for 1h; Michael Addition; Inert atmosphere; | 86% |
In toluene |
9,10-dimethylanthracene
p-benzoquinone
9,10-Dimethyl-12,15-dioxo-11,12,15,16-tetrahydro-triptycen
Conditions | Yield |
---|---|
With magnesium(II) perchlorate In acetonitrile at 24.9℃; dependence of kobs on ; | 100% |
With magnesium(II) perchlorate In acetonitrile | 100% |
In chloroform-d1 at 24.85℃; Quantum yield; | 65% |
With p-benzoquinone*2thymol eutectic for 0.5h; Diels-Alder reaction; | 95 % Spectr. |
With magnesium(II) perchlorate In [D3]acetonitrile at 24.84℃; Kinetics; Further Variations:; Reagents; Diels-Alder reaction; |
Conditions | Yield |
---|---|
In benzene at 25℃; | 100% |
cis-3-thiabicyclo<3.3.1>nonane
p-benzoquinone
Conditions | Yield |
---|---|
With sulfuric acid In acetone at 0℃; | 100% |
(E)-8-Nitro-octa-1,3-diene
p-benzoquinone
Conditions | Yield |
---|---|
In toluene at 110℃; for 15h; | 100% |
Conditions | Yield |
---|---|
With aluminium trichloride; zinc In tetrahydrofuran for 0.4h; Ambient temperature; | 100% |
With formic acid In toluene at 120℃; for 10h; Inert atmosphere; chemoselective reaction; | 57% |
With hydrogen; tetra-(n-butyl)ammonium iodide In water at 110℃; under 15001.5 Torr; for 24h; chemoselective reaction; | 57% |
With ruthenium; hydrogen at 80℃; under 37503.8 Torr; for 1h; Reagent/catalyst; Ionic liquid; chemoselective reaction; |
phenyltellurotrimethylsilane
p-benzoquinone
1,4-bis(trimethylsilyloxy)benzene
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 0.5h; reductive silylation; | 100% |
p-benzoquinone
(E,E)-2-pyridyldimethyl(buta-1,3-dienyl)silane
[1,4]naphthoquinone
Conditions | Yield |
---|---|
With hydrogenchloride In water at 20℃; for 38h; | 100% |
With hydrogenchloride In water at 20℃; for 38h; Product distribution; Further Variations:; Reagents; Solvents; Diels-Alder reaction; | 100% |
p-benzoquinone
(E,E)-2-pyridyldimethyl(3-methylbuta-1,3-dienyl)silane
6-methyl-1,4-naphthoquinone
Conditions | Yield |
---|---|
With hydrogenchloride In water at 20℃; for 38h; | 100% |
With hydrogenchloride In water at 20℃; for 38h; Diels-Alder reaction; | 100% |
Conditions | Yield |
---|---|
In diethyl ether; chloroform Dropwise addn. (Ar) of ferrocene complex in dry chloroform to org. compd. in the presence of HBF4 (Et2O) at -10°C, and stirring (1 h, room temp.) of resulting soln.; Isolation of resulting compd. by filtn. and silica gel chromy.; | 100% |
1,3-bis(trimethylsilyl)-1,3-diaza-2-germa(II)indane
p-benzoquinone
Conditions | Yield |
---|---|
In toluene monomer feed ratio germylene : p-benzoquinone = 4.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.; | 100% |
In tetrahydrofuran monomer feed ratio germylene : p-benzoquinone = 2.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.; | 96% |
In toluene monomer feed ratio germylene : p-benzoquinone = 2.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.; | 91% |
In toluene monomer feed ratio germylene : p-benzoquinone = 1.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.; | 86% |
Conditions | Yield |
---|---|
In benzene under N2, soln. of C6H4O2 in benzene added to Sn compd. in benzene at 22-24°C, refluxed with stirring for 2 h; ppt. filtered off, washed with benzene, dried; elem. anal.; | 100% |
bis[bis(trimethylsilyl)amino]germanium(II)
p-benzoquinone
Conditions | Yield |
---|---|
In benzene (Ar); stirring (1 h, 25°C); soln. filtn. off, drying (vac.); | 100% |
In toluene (Ar); stirring (1 h, -78, 0 or 50°C); soln. filtn. off, drying (vac.); elem. anal.; | 100% |
In diethyl ether (Ar); stirring (1 h, 0°C); soln. filtn. off, drying (vac.); | 99% |
tetrakis(triphenylphosphine) palladium(0)
p-benzoquinone
[palladium(0)(triphenylphosphine)2(p-benzoquinone)]
Conditions | Yield |
---|---|
In benzene under N2 atm. to suspn. Pd(PPh3)4 in benzene was added soln. benzoquinone in benzene and stirred for 30 min; soln. was concd., ether-hexane was added; | 100% |
p-benzoquinone
Conditions | Yield |
---|---|
With 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In hexane; benzene at 20℃; for 1h; Reactivity; Reagent/catalyst; Solvent; Darkness; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 0.0833333h; Diels-Alder reaction; | 100% |
2-bromothiophenol
p-benzoquinone
2-((2-bromophenyl)thio)benzene-1,4-diol
Conditions | Yield |
---|---|
In methanol | 100% |
With methanol at 20℃; for 6h; | 93% |
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