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Jinan Finer Chemical Co., Ltd

Product description: Product name 1,4-Benzoquinone CAS number 106-51-4 Assay ≥99% Appearance Yellow crystal Capacity 500mt/year Application Dyes and pharmaceutical intermedia

1,4-Benzoquinone

Cas:106-51-4

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

1,4-Benzoquinone CAS: 106-51-4 Specification Product name 1,4-Benzoquinone CAS number 106-51-4 Assay ≥99% Appearance Yellow crystal Capacity 500mt/year Application Dyes and

Factory supply 1,4-Benzoquinone

Cas:106-51-4

Min.Order:1 Kilogram

Negotiable

Type:Other

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ZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.

Usage: It can be widely used in medicine, herbicide, chemicals and dyes Package, storage and transportation: 1. In 35 kgs N.W. or 25 kgs N.W. cardboard drum lined with double plastic bags 2. Keep in cool, dry places under 10-20℃ and away from s

P-Benzoquinone

Cas:106-51-4

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,4-Benzoquinone 106-51-4

Cas:106-51-4

Min.Order:0

Negotiable

Type:Trading Company

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Suzhou Sinosun Imp.&Exp. Corporation

Water:0.5%Max; Residue on ignition:0.05%Max; Melting point: 112-116℃Appearance:yellow crystals

1,4-Benzoquinone

Cas:106-51-4

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#106-51-4;CAT#A801452

Cas:106-51-4

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Pure Chemistry Scientific Inc.

1,4-Benzoquinone Application:814872

1,4-Benzoquinone

Cas:106-51-4

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Synthetic route

4-methoxy-phenol
150-76-5

4-methoxy-phenol

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With bis-[(trifluoroacetoxy)iodo]benzene In water; acetonitrile for 0.166667h; Ambient temperature;100%
With copper(II) nitrate/zeolite H-Y Product distribution; Further Variations:; heating mode; times; microwave irradiation;100%
With manganese dioxide impregnated with nitric acid In dichloromethane for 0.5h; Ambient temperature;96%
hydroquinone
123-31-9

hydroquinone

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With barium ferrate(VI) In benzene for 0.25h; Product distribution; Heating;100%
With benzyltrimethylammonium tribromide; sodium acetate In dichloromethane; water for 2h; Ambient temperature;100%
With bis(2,2'-bipyridyl) copper(II) permanganate In dichloromethane for 0.25h; Ambient temperature;100%
phenol
108-95-2

phenol

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With CuCl2 In acetonitrile100%
With [CuII2(μ-OH)(1,2-bis(2-(bis(2-pyridylmethyl)aminomethyl)-6-pyridyl)ethane)](ClO4)3 ; dihydrogen peroxide; triethylamine In water; acetonitrile at 50℃; for 10h; Catalytic behavior; Inert atmosphere;99%
With manganese(IV) oxide; sulfuric acid; aniline at 10℃; for 1.5h;95%
hydroquinone
123-31-9

hydroquinone

A

diphenyl-2,5 furannedicarbaldehyde 3,4
36831-87-5

diphenyl-2,5 furannedicarbaldehyde 3,4

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With barium ferrate(VI) In benzene for 0.3h; Heating;A 70%
B 100%
1,4-dimethoxybezene
150-78-7

1,4-dimethoxybezene

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With bis-[(trifluoroacetoxy)iodo]benzene In methanol; water at 20℃; for 4h;100%
With manganese dioxide impregnated with nitric acid In dichloromethane for 1.5h; Ambient temperature;93%
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1h;86%
1,4-bis(trimethylsilyloxy)benzene
2117-24-0

1,4-bis(trimethylsilyloxy)benzene

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With pyridinium chlorochromate In dichloromethane at 25℃; for 2h; Mechanism; relative reaction rate;99%
With quinolinium monofluorochromate(VI) In dichloromethane for 1h; Ambient temperature;98%
With dioxochloro(trimethylsiloxy)chromate(VI) In dichloromethane for 0.333333h; Ambient temperature;97%
4-Hydroxyacetophenone
99-93-4

4-Hydroxyacetophenone

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In acetonitrile at 80℃; for 0.75h; Baeyer-Villiger Ketone Oxidation; regioselective reaction;99%
1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With sodium periodate In water at 20℃; for 0.166667h;98%
With [bis(acetoxy)iodo]benzene In acetone at 20℃; for 0.166667h;90%
With sulfuric acid; manganese triacetate In water at 35℃; Rate constant; Mechanism;
With dichromate anion
With manganese(IV) oxide; sulfuric acid
benzamide
55-21-0

benzamide

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With iodobenzene; oxone; water In acetonitrile at 20℃;98%
With sodium hydrogen sulfate; [bis(acetoxy)iodo]benzene In water; acetonitrile at 20℃; for 0.5h; Time; Solvent;80%
4-Ethoxyphenol
622-62-8

4-Ethoxyphenol

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 0.5h;97%
With bis-[(trifluoroacetoxy)iodo]benzene In water; acetonitrile for 0.166667h; Ambient temperature;93%
With oxone; tetrabutylammomium bromide In water; acetonitrile at 20℃; for 1h;92%
With Oxone In water; acetonitrile at 20℃; for 17h;79%
4-methoxyacetanilide
51-66-1

4-methoxyacetanilide

A

4-methoxy-2-nitroacetanilide
119-81-3

4-methoxy-2-nitroacetanilide

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With nitric acid; silica gel In dichloromethane for 0.166667h; Product distribution; Ambient temperature;A 97%
B 2%
1,4-dimethoxybezene
150-78-7

1,4-dimethoxybezene

A

1,4-dimethoxy-2-nitrobenzene
89-39-4

1,4-dimethoxy-2-nitrobenzene

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With nitric acid; silica gel In dichloromethane for 0.0833333h; Product distribution; Ambient temperature;A 97%
B 2%
phenol
108-95-2

phenol

A

2,4,6-Trinitrophenol
88-89-1

2,4,6-Trinitrophenol

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With NO+*18-crown-6*H(NO3)2- In various solvent(s) for 2h; Nitration; Heating;A 94%
B 5%
With Zn(NO3)2*2N2O4 In ethyl acetate at 20℃; for 0.25h;A 86%
B 8%
1,4-diethoxybenzene
122-95-2

1,4-diethoxybenzene

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1h;94%
With oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1h;94%
With ammonium cerium(IV) nitrate In water; acetonitrile at 20℃;66%
C24H23NO5

C24H23NO5

A

C17H17NO4

C17H17NO4

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃;A 94%
B n/a
4-(tert-butyldimethylsilyloxy)anisole
62790-87-8

4-(tert-butyldimethylsilyloxy)anisole

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1.5h;94%
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 1.5h;79%
4-methoxyphenylacetamide
3424-93-9

4-methoxyphenylacetamide

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With iodobenzene; oxone; water In acetonitrile at 20℃;94%
With sodium hydrogen sulfate; [bis(acetoxy)iodo]benzene In water; acetonitrile at 20℃; for 0.666667h;75%
benzene
71-43-2

benzene

A

p-benzoquinone
106-51-4

p-benzoquinone

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With [CuII2(μ-OH)(1,2-bis(2-(bis(2-pyridylmethyl)aminomethyl)-6-pyridyl)ethane)](ClO4)3 ; dihydrogen peroxide; triethylamine In water; acetonitrile at 50℃; for 40h; Catalytic behavior; Inert atmosphere;A 6.8%
B 93.2%
With dihydrogen peroxide In water for 0.25h; Reagent/catalyst; Irradiation;A n/a
B 81.5%
With tetrakis(acetonitrile)copper(I) perchlorate; dihydrogen peroxide In water; acetonitrile at 25℃; for 4h; Catalytic behavior; Reagent/catalyst;A 60%
B n/a
4-amino-phenol
123-30-8

4-amino-phenol

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With K10 montmorillonite; iodic acid for 0.00833333h; microwave irradiation;93%
With Montmorillonite K10; iodic acid at 68℃; for 0.00555556h; microwave irradiation;85%
With pyridine hydrogenfluoride; sodium nitrite Product distribution; Mechanism; other substrates, various temp.;80%
C25H23NO3

C25H23NO3

A

C17H15NO2

C17H15NO2

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃;A 93%
B n/a
N-phenylsulphonyl-Se,Se-diphenylselenimide
52867-18-2

N-phenylsulphonyl-Se,Se-diphenylselenimide

hydroquinone
123-31-9

hydroquinone

A

benzenesulfonamide
98-10-2

benzenesulfonamide

B

diphenylselenide
1132-39-4

diphenylselenide

C

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
In toluene for 25h; Product distribution; Heating; other N-sulfonylchalcogenimides, other quinones, var. solvent and time;A 92%
B 87%
C 89%
4-n-butoxyphenol
122-94-1

4-n-butoxyphenol

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With oxone; tetrabutylammomium bromide In water; acetonitrile at 20℃; for 1h;92%
With Oxone; 4-iodophenoxyacetic acid In 2,2,2-trifluoroethanol; water at 20℃; for 0.5h;88%
With Oxone In water; acetonitrile at 20℃; for 17h;77%
C28H23NO4

C28H23NO4

A

C20H15NO3

C20H15NO3

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃;A 91%
B n/a
C23H18Cl2N2O5

C23H18Cl2N2O5

A

3-(2,4-dichlorophenoxy)-4-(4-nitrophenyl)azetidin-2-one

3-(2,4-dichlorophenoxy)-4-(4-nitrophenyl)azetidin-2-one

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With cerium(IV) ammonium nitrate; silica gel In water; acetonitrile at 20℃;A 91%
B n/a
C27H22N2O8

C27H22N2O8

A

C20H16N2O7

C20H16N2O7

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With cerium(IV) ammonium nitrate; silica gel In dichloromethane at 20℃;A 90%
B n/a
1-(4-(benzyloxy)phenyl)-3-hydroxy-2-phenoxypropan-1-one

1-(4-(benzyloxy)phenyl)-3-hydroxy-2-phenoxypropan-1-one

A

4-Benzyloxyphenol
103-16-2

4-Benzyloxyphenol

B

4-(benzyloxy)phenyl 3-hydroxy-2-phenoxypropanoate

4-(benzyloxy)phenyl 3-hydroxy-2-phenoxypropanoate

C

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With methanesulfonic acid; dihydrogen peroxide In water; acetonitrile at 50℃; for 6h; Flow reactor; Green chemistry;A 1%
B 8%
C 90%
C23H19NO5

C23H19NO5

4-(benzo[d][1,3]dioxol-5-yl)-3-phenoxyazetidin-2-one

4-(benzo[d][1,3]dioxol-5-yl)-3-phenoxyazetidin-2-one

B

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With ceric(IV) tetra-n-butylammonium nitrate; water In dichloromethane at 20℃; for 0.333333h; Reagent/catalyst; Solvent; Temperature;A 89%
B n/a
1-(4-methoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propan-1-one
92409-23-9

1-(4-methoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propan-1-one

A

4-methoxyphenyl 3-hydroxy-2-(2-methoxyphenoxy)propanoate

4-methoxyphenyl 3-hydroxy-2-(2-methoxyphenoxy)propanoate

B

4-methoxy-phenol
150-76-5

4-methoxy-phenol

C

p-benzoquinone
106-51-4

p-benzoquinone

Conditions
ConditionsYield
With methanesulfonic acid; dihydrogen peroxide In water; acetonitrile at 50℃; for 6h; Flow reactor; Green chemistry;A 9%
B 2%
C 89%
acetic anhydride
108-24-7

acetic anhydride

p-benzoquinone
106-51-4

p-benzoquinone

1,2,4-triacetoxybenzene
613-03-6

1,2,4-triacetoxybenzene

Conditions
ConditionsYield
With sulfuric acid at 40 - 50℃;100%
With sulfuric acid at 10 - 45℃; for 1h;97.4%
With sulfuric acid at 25 - 50℃; for 0.5h; Reagent/catalyst; Temperature;96%
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

p-benzoquinone
106-51-4

p-benzoquinone

norbornenoquinone
51175-59-8

norbornenoquinone

Conditions
ConditionsYield
In hexane; ethyl acetate at 0℃; for 3.5h; Diels-Alder Cycloaddition;100%
In methanol at -78 - 0℃; Inert atmosphere; optical yield given as %de;98%
In hexane; ethyl acetate at 0℃; for 4h; Diels-Alder reaction;97%
p-benzoquinone
106-51-4

p-benzoquinone

5,6-dichlorocyclohex-2-ene-1,4-dione
5273-62-1

5,6-dichlorocyclohex-2-ene-1,4-dione

Conditions
ConditionsYield
With sulfuryl dichloride; triethylamine In diethyl ether for 0.5h;100%
With chloroform; chlorine
With sulfuryl dichloride
p-benzoquinone
106-51-4

p-benzoquinone

hydroquinone
123-31-9

hydroquinone

Conditions
ConditionsYield
With nickel In tetrahydrofuran at 20℃; for 0.166667h; Reduction;100%
With boron trifluoride diethyl etherate; sodium iodide In acetonitrile at 0℃; for 0.0833333h;99%
With hydrazine hydrate In acetonitrile at 20℃; for 18h; Irradiation;99%
sulfure de pentamethylene
1613-51-0

sulfure de pentamethylene

p-benzoquinone
106-51-4

p-benzoquinone

2,5-dihydroxyphenylthianium perchlorate

2,5-dihydroxyphenylthianium perchlorate

Conditions
ConditionsYield
With perchloric acid In acetone at 0℃;100%
sulfure de pentamethylene
1613-51-0

sulfure de pentamethylene

p-benzoquinone
106-51-4

p-benzoquinone

1-(2,5-dihydroxyphenyl)thianium bromide
89706-15-0

1-(2,5-dihydroxyphenyl)thianium bromide

Conditions
ConditionsYield
With hydrogen bromide In acetone at 0℃;100%
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

p-benzoquinone
106-51-4

p-benzoquinone

1α,4α,4aβ,10aα,5β,8β,8aα,9aβ-octahydro-1,4:5,8-dimethanoanthracene-9,10-dione
78548-82-0

1α,4α,4aβ,10aα,5β,8β,8aα,9aβ-octahydro-1,4:5,8-dimethanoanthracene-9,10-dione

Conditions
ConditionsYield
In benzene at 40℃; for 20h;100%
In dichloromethane at 20℃; for 24h; Diels-Alder reaction;100%
In ethanol at 0℃; for 0.5h; Diels-Alder Cycloaddition;98%
thiophenol
108-98-5

thiophenol

p-benzoquinone
106-51-4

p-benzoquinone

2-(phenylthio)benzene-1,4-diol
18231-96-4

2-(phenylthio)benzene-1,4-diol

Conditions
ConditionsYield
In methanol100%
With methanol at 20℃; for 6h;99%
In methanol for 0.166667h; Ambient temperature;95%
Diphenylphosphine oxide
4559-70-0

Diphenylphosphine oxide

p-benzoquinone
106-51-4

p-benzoquinone

(2,5-dihydroxyphenyl)diphenylphosphine oxide
13291-46-8

(2,5-dihydroxyphenyl)diphenylphosphine oxide

Conditions
ConditionsYield
In toluene for 1.66667h;100%
With water In toluene at 80℃; for 12h; Inert atmosphere; Schlenk technique;98%
In toluene for 20h; Inert atmosphere; Reflux;88.1%
In toluene at 75 - 110℃; for 1h; Michael Addition; Inert atmosphere;86%
In toluene
9,10-dimethylanthracene
781-43-1

9,10-dimethylanthracene

p-benzoquinone
106-51-4

p-benzoquinone

9,10-Dimethyl-12,15-dioxo-11,12,15,16-tetrahydro-triptycen
115163-71-8

9,10-Dimethyl-12,15-dioxo-11,12,15,16-tetrahydro-triptycen

Conditions
ConditionsYield
With magnesium(II) perchlorate In acetonitrile at 24.9℃; dependence of kobs on ;100%
With magnesium(II) perchlorate In acetonitrile100%
In chloroform-d1 at 24.85℃; Quantum yield;65%
With p-benzoquinone*2thymol eutectic for 0.5h; Diels-Alder reaction;95 % Spectr.
With magnesium(II) perchlorate In [D3]acetonitrile at 24.84℃; Kinetics; Further Variations:; Reagents; Diels-Alder reaction;
diphenyl phosphorohydrazidate
33862-44-1

diphenyl phosphorohydrazidate

p-benzoquinone
106-51-4

p-benzoquinone

C18H15N2O4P

C18H15N2O4P

Conditions
ConditionsYield
In benzene at 25℃;100%
cis-3-thiabicyclo<3.3.1>nonane
20742-48-7

cis-3-thiabicyclo<3.3.1>nonane

p-benzoquinone
106-51-4

p-benzoquinone

(1R,5S)-3-(2,5-Dihydroxy-phenyl)-3-thionia-bicyclo[3.3.1]nonane; hydrogen sulfate

(1R,5S)-3-(2,5-Dihydroxy-phenyl)-3-thionia-bicyclo[3.3.1]nonane; hydrogen sulfate

Conditions
ConditionsYield
With sulfuric acid In acetone at 0℃;100%
(E)-8-Nitro-octa-1,3-diene
88888-43-1

(E)-8-Nitro-octa-1,3-diene

p-benzoquinone
106-51-4

p-benzoquinone

(4aR,5R,8aS)-5-(4-Nitro-butyl)-4a,5,8,8a-tetrahydro-[1,4]naphthoquinone

(4aR,5R,8aS)-5-(4-Nitro-butyl)-4a,5,8,8a-tetrahydro-[1,4]naphthoquinone

Conditions
ConditionsYield
In toluene at 110℃; for 15h;100%
p-benzoquinone
106-51-4

p-benzoquinone

1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

Conditions
ConditionsYield
With aluminium trichloride; zinc In tetrahydrofuran for 0.4h; Ambient temperature;100%
With formic acid In toluene at 120℃; for 10h; Inert atmosphere; chemoselective reaction;57%
With hydrogen; tetra-(n-butyl)ammonium iodide In water at 110℃; under 15001.5 Torr; for 24h; chemoselective reaction;57%
With ruthenium; hydrogen at 80℃; under 37503.8 Torr; for 1h; Reagent/catalyst; Ionic liquid; chemoselective reaction;
phenyltellurotrimethylsilane
73296-31-8

phenyltellurotrimethylsilane

p-benzoquinone
106-51-4

p-benzoquinone

1,4-bis(trimethylsilyloxy)benzene
2117-24-0

1,4-bis(trimethylsilyloxy)benzene

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h; reductive silylation;100%
p-benzoquinone
106-51-4

p-benzoquinone

(E,E)-2-pyridyldimethyl(buta-1,3-dienyl)silane
270589-03-2

(E,E)-2-pyridyldimethyl(buta-1,3-dienyl)silane

[1,4]naphthoquinone
130-15-4

[1,4]naphthoquinone

Conditions
ConditionsYield
With hydrogenchloride In water at 20℃; for 38h;100%
With hydrogenchloride In water at 20℃; for 38h; Product distribution; Further Variations:; Reagents; Solvents; Diels-Alder reaction;100%
p-benzoquinone
106-51-4

p-benzoquinone

(E,E)-2-pyridyldimethyl(3-methylbuta-1,3-dienyl)silane
270589-04-3

(E,E)-2-pyridyldimethyl(3-methylbuta-1,3-dienyl)silane

6-methyl-1,4-naphthoquinone
605-93-6

6-methyl-1,4-naphthoquinone

Conditions
ConditionsYield
With hydrogenchloride In water at 20℃; for 38h;100%
With hydrogenchloride In water at 20℃; for 38h; Diels-Alder reaction;100%
tetrafluoroboric acid

tetrafluoroboric acid

1,1'-diacetylferrocene
1273-94-5

1,1'-diacetylferrocene

p-benzoquinone
106-51-4

p-benzoquinone

1,1'-diacetylferriceniumtetra-fluoroborate

1,1'-diacetylferriceniumtetra-fluoroborate

Conditions
ConditionsYield
In diethyl ether; chloroform Dropwise addn. (Ar) of ferrocene complex in dry chloroform to org. compd. in the presence of HBF4 (Et2O) at -10°C, and stirring (1 h, room temp.) of resulting soln.; Isolation of resulting compd. by filtn. and silica gel chromy.;100%
1,3-bis(trimethylsilyl)-1,3-diaza-2-germa(II)indane
117226-57-0

1,3-bis(trimethylsilyl)-1,3-diaza-2-germa(II)indane

p-benzoquinone
106-51-4

p-benzoquinone

2C6H4(N(Si(CH3)3))2(2-)*2Ge(3+)*(OC6H4O)(2-)

2C6H4(N(Si(CH3)3))2(2-)*2Ge(3+)*(OC6H4O)(2-)

Conditions
ConditionsYield
In toluene monomer feed ratio germylene : p-benzoquinone = 4.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.;100%
In tetrahydrofuran monomer feed ratio germylene : p-benzoquinone = 2.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.;96%
In toluene monomer feed ratio germylene : p-benzoquinone = 2.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.;91%
In toluene monomer feed ratio germylene : p-benzoquinone = 1.0 : 1.0, at -78°C under Ar for 1 h; elem. anal.;86%
bis(β-dimethylaminoethoxy)tin

bis(β-dimethylaminoethoxy)tin

p-benzoquinone
106-51-4

p-benzoquinone

Sn(OCH2CH2N(CH3)2)2(OC6H4O)

Sn(OCH2CH2N(CH3)2)2(OC6H4O)

Conditions
ConditionsYield
In benzene under N2, soln. of C6H4O2 in benzene added to Sn compd. in benzene at 22-24°C, refluxed with stirring for 2 h; ppt. filtered off, washed with benzene, dried; elem. anal.;100%
bis[bis(trimethylsilyl)amino]germanium(II)
59863-12-6

bis[bis(trimethylsilyl)amino]germanium(II)

p-benzoquinone
106-51-4

p-benzoquinone

Ge(N(Si(CH3)3)2)2OC6H4O

Ge(N(Si(CH3)3)2)2OC6H4O

Conditions
ConditionsYield
In benzene (Ar); stirring (1 h, 25°C); soln. filtn. off, drying (vac.);100%
In toluene (Ar); stirring (1 h, -78, 0 or 50°C); soln. filtn. off, drying (vac.); elem. anal.;100%
In diethyl ether (Ar); stirring (1 h, 0°C); soln. filtn. off, drying (vac.);99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

p-benzoquinone
106-51-4

p-benzoquinone

[palladium(0)(triphenylphosphine)2(p-benzoquinone)]
490039-51-5, 57036-58-5

[palladium(0)(triphenylphosphine)2(p-benzoquinone)]

Conditions
ConditionsYield
In benzene under N2 atm. to suspn. Pd(PPh3)4 in benzene was added soln. benzoquinone in benzene and stirred for 30 min; soln. was concd., ether-hexane was added;100%
pine pitch

pine pitch

p-benzoquinone
106-51-4

p-benzoquinone

(4aR,4bS,7R,10aR,10bS,12R,12aR)-13-isopropyl-7,10a-dimethyl-1,4-dioxo-4,4a,5,6,6a,7,8,9,10,10a,10b,11,12,12a-tetradecahydro-1H-4b,12-ethenochrysene-7-carboxylic acid

(4aR,4bS,7R,10aR,10bS,12R,12aR)-13-isopropyl-7,10a-dimethyl-1,4-dioxo-4,4a,5,6,6a,7,8,9,10,10a,10b,11,12,12a-tetradecahydro-1H-4b,12-ethenochrysene-7-carboxylic acid

Conditions
ConditionsYield
With 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In hexane; benzene at 20℃; for 1h; Reactivity; Reagent/catalyst; Solvent; Darkness;100%
3,4-di-tert-butyl-2,5-dimethylthiophene 1-oxide
1243058-70-9

3,4-di-tert-butyl-2,5-dimethylthiophene 1-oxide

p-benzoquinone
106-51-4

p-benzoquinone

C20H28O3S

C20H28O3S

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.0833333h; Diels-Alder reaction;100%
2-bromothiophenol
6320-02-1

2-bromothiophenol

p-benzoquinone
106-51-4

p-benzoquinone

2-((2-bromophenyl)thio)benzene-1,4-diol
1310712-82-3

2-((2-bromophenyl)thio)benzene-1,4-diol

Conditions
ConditionsYield
In methanol100%
With methanol at 20℃; for 6h;93%
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