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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales; 5.

Tetrakis(triphenylphosphine) palladium(0)

Cas:14221-01-3

Min.Order:0 Gram

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Type:Manufacturers

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Lab/Research institutions

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Shanghai Surseechem Co.,Ltd.

Our advantage products,High quality, low price 1. High quality 2. The best price 3. The fastest delivery 4. Offer high quality fine chemicals, accroding to customer’s need Springchem can quickly and efficiently provide a

Tetrakis(triphenylphosphine)palladiuM

Cas:14221-01-3

Min.Order:0 Metric Ton

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:0

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Orange powder Complies Purity 98.0%min 98.0%mi

High purity Tetrakis(triphenylphosphine) palladium(0) with high quality and best price cas:14221-01-3

Cas:14221-01-3

Min.Order:1 Gram

FOB Price: $1.0 / 10.0

Type:Manufacturers

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Tetrakis(Triphenylphosphine) Palladium(0) supplier in China

Cas:14221-01-3

Min.Order:0 Metric Ton

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Tetrakis(Triphenylphosphine) Palladium(0)

Cas:14221-01-3

Min.Order:1

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Type:Other

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:Shanghai Port

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Kilogram

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

High purity and quality best quality Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:100 Gram

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Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 14221-01-3 Tetrakis(triphenylphosphine)palladium Manufacturer

Cas:14221-01-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Gram

FOB Price: $5.0

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product s

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Gram

FOB Price: $11.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Tetrakis-(triphenylphosphane)-palladium

Cas:14221-01-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Tetrakis(triphenylphosphine)palladium(II)

Cas:14221-01-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

high quality Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Gram

FOB Price: $1000.0 / 1300.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 14221-01-3 with best quality

Cas:14221-01-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Kilogram

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Henan Sinotech Import&Export Corporation

Name: Tetrakis(triphenylphosphine)palladium(0) CAS No :14221-01-3 MF:C72H60P4Pd MW:578.62 EINECS No :238-086-9 Appearance: yellowish powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Syntheses Materi

Tetrakis(triphenylphosphine)palladium(0)

Cas:14221-01-3

Min.Order:0 Kilogram

FOB Price: $1.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

14221-01-3/Tetrakis(triphenylphosphine)palladiumCAS NO.: 14221-01-3

Cas:14221-01-3

Min.Order:1 Gram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:yellow crystal powder Storage:R.T Package:100g/bottle Application:catalyst Transportation:Express/Sea/Air Port:Any port in China

Tetrakis(triphenylphosphine)palladium cas 14221-01-3

Cas:14221-01-3

Min.Order:50 Gram

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 14221-01-3 Tetrakis(triphenylphosphine)palladium with best price

Cas:14221-01-3

Min.Order:10 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Tetrakis(triphenylphosphine)palladium 14221-01-3

Cas:14221-01-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Tetrakis(triphenylphosphine)palladium Basic information Product Name: Tetrakis(triphenylphosphine)palladium Synonyms: (beta-4)-palladiu;Tetrakis(triphenylphosphine)palladium(0), 99.8% (metals basis), Pd 9% min;Tetrakis(triphenylphosphine)palla

Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:yellow powder Storage:keep in cool and dry plac

14221-01-3 CAS Pd 9.2% Ready stock Factory Tetrakis(triphenylphosphine)palladium Pd(PPh3)4

Cas:14221-01-3

Min.Order:1 Metric Ton

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Tetrakis(triphenylphosphine)palladium CAS 14221-01-3

Cas:14221-01-3

Min.Order:1 Kilogram

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Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply Tetrakis(triphenylphosphine)palladium CAS 14221-01-3 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made

Tetrakis(triphenylphosphine)palladium CAS 14221-01-3

Cas:14221-01-3

Min.Order:1 Gram

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Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

We provide tailor-made photoinitiator solutions for different performances by custom synthesisi.blends or other technical supports low-odor uv formulations non-yellowing uv formulations benzene-free uv formulations polymeric uv formul

Tetrakis(triphenylphosphine)palladium CAS:14221-01-3

Cas:14221-01-3

Min.Order:100 Kilogram

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Type:Trading Company

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Lonwin Chemical Group Limited

Tetrakis(triphenylphosphine)palladium CAS: 14221-01-3 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure

Factory supply Tetrakis(triphenylphosphine)palladium

Cas:14221-01-3

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou Keyingchem Co.,Ltd

High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar

high quality Tetrakis(triphenylphosphine)palladium;

Cas:14221-01-3

Min.Order:1 Gram

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Synthetic route

palladium tetraammine di(hydrogen carbonate)

palladium tetraammine di(hydrogen carbonate)

triphenylphosphine
603-35-0

triphenylphosphine

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
In methanol for 1.5h; Heating / reflux;98%
triphenylphosphine
603-35-0

triphenylphosphine

palladium dichloride

palladium dichloride

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With sodium hydrogencarbonate; ascorbic acid In dimethyl sulfoxide at 20 - 60℃; for 2.33333h; Reagent/catalyst;97.6%
Stage #1: triphenylphosphine; palladium dichloride In N,N-dimethyl-formamide at 140℃; for 0.5h;
Stage #2: With hydrazine hydrate In N,N-dimethyl-formamide at 80℃;
95%
Stage #1: triphenylphosphine; palladium dichloride In dimethyl sulfoxide at 20 - 145℃; Inert atmosphere; Schlenk technique;
Stage #2: With hydrazine hydrate In dimethyl sulfoxide at 23℃;
94%
palladium dichloride

palladium dichloride

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With triphenylphosphine; hydrazine In water; N,N-dimethyl-formamide N2; refluxing PdCl2 and PPh3 (30 min), addn. of aq. N2H4 (80°C); pptn., filtration, washing (MeOH, ether), drying;95%
(1S),(2R),(3R)-acetylacetonato(1-methyl-3-phenyl-π-allyl)palladium(II)

(1S),(2R),(3R)-acetylacetonato(1-methyl-3-phenyl-π-allyl)palladium(II)

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

(R)-<1-((E)-styryl)ethyl>acetylacetone
118578-64-6

(R)-<1-((E)-styryl)ethyl>acetylacetone

Conditions
ConditionsYield
With triphenylphosphine In tetrahydrofuran excess PPh3, stirring (room temp., 50 min), pptn.; filtration, org. product isolated by preparative TLC (silica, hexane/ethyl acetate);A n/a
B 94%
[(P((C6H5)3))Pd((C6H4)2NH)]2

[(P((C6H5)3))Pd((C6H4)2NH)]2

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

9H-carbazole
86-74-8

9H-carbazole

Conditions
ConditionsYield
1 h, room temp.;A n/a
B 92%
HPd2(1+)*4P(C6H5)3*CO*ClO4(1-)={HPd2(P(C6H5)3)4(CO)(ClO4)}

HPd2(1+)*4P(C6H5)3*CO*ClO4(1-)={HPd2(P(C6H5)3)4(CO)(ClO4)}

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With triphenylphosphine In benzene dissolving freshly prepd. (HPd2(P(C6H5)3)4(CO)(ClO4))(n) and P(C6H5)3 in benzene, stirring for 1 h at 20°C; evapn. of benzene under vac. to dryness, treating residue successively with several portions of 50% alc., washing with C6H6 and drying under vac.; elem. anal.;91%
2Pd(2+)*4CH3COO(1-)*2P(C6H5)3=[Pd(P(C6H5)3)(CH3COO)2]2

2Pd(2+)*4CH3COO(1-)*2P(C6H5)3=[Pd(P(C6H5)3)(CH3COO)2]2

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With hydrogen; triphenylphosphine In toluene High Pressure; at 50°C under 40 atm of H2 for 3 h; mixed with pentane (Ar), ppt. washed with ether and pentane, dried (vac.); elem. anal.;90%
palladium(II) acetylacetonate

palladium(II) acetylacetonate

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With anthracene; magnesium; triphenylphosphine In tetrahydrofuran byproducts: magnesium acetylacetonate; Sonication; addn. of anthracene and EtBr to Mg in THF under Ar, ultrasonic bath (35 kH), addn. of the phosphine at 65°C, then of the Pd-salt during 20 min; the mixt. is cooled to 23°C, filtn., washed (pentane), dried (vac.);89.5%
Pd8(CO)10(P(C6H5)3)4

Pd8(CO)10(P(C6H5)3)4

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With triphenylphosphine In acetone excess of P(C6H5)3 under inert gas atmosphere;;86%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; triphenylphosphine In tetrahydrofuran byproducts: NaCl, HCl, (C6H5)3PO; stirred at 25°C for 24 h; aq. layer removed, org. layer evaporated at 40°C in vacuo, residue treated with abs. C2H5OH, stirred at 60°C for 20 min, filtered, kept at -15°C for 30 min, filtered (Ar), washed (cold abs. C2H5OH), dried in vacuo; IR, NMR;84%
With sodium borohydride; triphenylphosphine In ethanol the soln. was cooled in cold water, ppt. was filtered, washed with water, EtOH, heptane;83%
With hydrazine Inorg. Synth. 13 (1972) 121;
(P(C6H5)3)2BrPdCH2COC4H9*CH2Cl2
98991-62-9

(P(C6H5)3)2BrPdCH2COC4H9*CH2Cl2

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

3,3-dimethyl-1-(triphenylphosphanylidene)butan-2-one
288390-74-9

3,3-dimethyl-1-(triphenylphosphanylidene)butan-2-one

Conditions
ConditionsYield
With potassium tert-butylate; triphenylphosphine In tetrahydrofuran Kinetics; -78°C, slow warming to room temp. over 4 h; solvent removal, extn. with Et2O, then THF, residue is Pd compd., extracts are concd., recrystn. of ppt. give phosphorane, kinetics is followedby (1)H NMR;A 84%
B 82%
palladium diacetate
3375-31-3

palladium diacetate

triphenylphosphine
603-35-0

triphenylphosphine

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With ascorbic acid In dimethyl sulfoxide at 150℃; for 0.25h; Inert atmosphere;83%
With sodium carbonate In N,N-dimethyl-formamide
In 1,2-dimethoxyethane for 0.5h;
bis(acetylacetonato)palladiumtriphenylphosphine

bis(acetylacetonato)palladiumtriphenylphosphine

triphenylphosphine
603-35-0

triphenylphosphine

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With water In benzene byproducts: acetylacetonate, triphenylphoshine oxide; under Ar, react. of PPh3 and Pd-complex in benzene, addn. of water (H2O:Pd mole ratio=20), lemon-yellow ppt.;81.8%
In benzene under Ar, react. of PPh3 and Pd-complex in anhydrous benzene over the course of 48 h; PMR;0%
Pd10(CO)12(P(C4H9)3)6

Pd10(CO)12(P(C4H9)3)6

triphenylphosphine
603-35-0

triphenylphosphine

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
In acetone react. of Pd10(CO)14(P(C4H9)3)4 with P(C6H5)3 (molar ratio 1:50);; elem. anal.;;81%
palladium dichloride

palladium dichloride

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

(phenyl)(bis-triphenylphosphine)palladium(II) chloride

(phenyl)(bis-triphenylphosphine)palladium(II) chloride

Conditions
ConditionsYield
With PPh3; n-Bu4NF*3H2O In dimethyl sulfoxide byproducts: Ph3PO, {Ph4P}Cl; heating a mixt. of PdCl2 and PPh3 in DMSO under Ar (140°C) yielding a yellow soln., addn. of a soln. of n-Bu4NF*3H2O in DMSO yielding a dark orange-red soln., which rapidly turned bright yellow, cooling (room temp.), stirring, pptn.; addn. of ethanol, complete pptn., further stirring (30 min), filtration, rinsing (ethanol, 2 times; Et2O), drying (vac.);A 80%
B n/a
With PPh3; KF In dimethyl sulfoxide byproducts: Ph3PO, {Ph4P}Cl, Pd(Ph3)4; heating a mixt. of PdCl2 and PPh3 in DMSO under Ar (140°C), addn. of anhyd. KF, heating the yellow soln. (120°C, 10 min), cooling (room temp.); filtration, washing (Et2O), drying (vac.); detn. of other compds. in the filtrate by 1H-NMR; isolation of trans-(Ph3P)2Pd(Ph)Cl from the filtrate after standing several d;A 54%
B n/a
bis(acetylacetonato)palladiumtriphenylphosphine

bis(acetylacetonato)palladiumtriphenylphosphine

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With water; triphenylphosphine In water; benzene Kinetics; byproducts: acetylacetone, triphenylphosphine oxide; monitoring by UV and (31)P-NMR spectroscopy; gravimetric determination;77%
With triphenylphosphine In benzene Kinetics; dry benzene (<0.004 M H2O); monitoring by (1)H-NMR spectroscopy;0%
bis(η3-allyl-μ-chloropalladium(II))

bis(η3-allyl-μ-chloropalladium(II))

Na(1+)*C6H13COFe(CO)3P(C6H5)3(1-)
82456-28-8

Na(1+)*C6H13COFe(CO)3P(C6H5)3(1-)

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

2-decen-4-one
63024-86-2

2-decen-4-one

C

dec-1-en-4-one
65807-57-0

dec-1-en-4-one

Conditions
ConditionsYield
With triphenylphosphine In tetrahydrofuran The mixt. of reagents in THF was stirred for 45 min at -78°C, allowed to warm to room temp. (CO atm.);;; ether was added, complex was filtered, filtrate was washed with water, dried over MgSO4, distilled;;A 75%
B n/a
C n/a
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With buta-1,3-diene; diethylamine; triphenylphosphine In acetone to soln. of Pd-complex in acetone under N2 at 0°C was added butadiene, cooled, mixt. was stirred at room temp. for 2 h, mixt. was cooled to 0°C, diethylamine was added, PPh3 was added, mixt. was stirred at 0°C for 1 h; filtered off under N2, washed under N2 with ice-cold solvents: acetone, acetone/H2O and acetone, dried in vac.;69%
Pd(2+)*2P(C6H5)3*SO4(2-) = Pd(P(C6H5)3)2SO4

Pd(2+)*2P(C6H5)3*SO4(2-) = Pd(P(C6H5)3)2SO4

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

2Pd*4P(C6H5)3*CO=Pd2(P(C6H5)3)4(CO)

2Pd*4P(C6H5)3*CO=Pd2(P(C6H5)3)4(CO)

Conditions
ConditionsYield
With sodium hydroxide; carbon monoxide; triphenylphosphine In sulfuric acid; butan-1-ol byproducts: CO2, H2SO4; 40°C, 1 h, filtering off ppt. (Pd(PPh3)4), sepg. org. phase, washing with H2O, addn. of 1 N aq. NaOH; Pd(PPh3)4: washing with EtOH, Et2O, drying in vac.; elem. anal.; carbonyl complex: filtering, washing with EtOH and hexane, drying in vac.; elem. anal.;A 17.3%
B 62.1%
bis(η3-allyl-μ-chloropalladium(II))

bis(η3-allyl-μ-chloropalladium(II))

Na(1+)*C5H11COFe(CO)4(1-)
82456-27-7

Na(1+)*C5H11COFe(CO)4(1-)

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

non-2-en-4-one
32064-72-5

non-2-en-4-one

Conditions
ConditionsYield
With triphenylphosphine In tetrahydrofuran The mixt. of reagents in THF was stirred for 45 min at -78°C, allowed to warm to room temp. (Ar atm.);; ether was added, complex was filtered, filtrate was washed with water, dried over MgSO4, distilled;;A 56%
B 50%
(CH2CHCH2CH2OCO)Pd(P(C6H5)3)2Cl

(CH2CHCH2CH2OCO)Pd(P(C6H5)3)2Cl

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

Conditions
ConditionsYield
With triphenylphosphine In diethylene glycol Kinetics; byproducts: α-methylene-γ-butyrolactone; a high-vac. bulb was charged with Pd-complex (solvate with 0.3 CH2Cl2) PPh3, and diglyme and sealed, soln. was heated at 130°C for 5 h; in a sep. run reaction was monitored by IR spectroscopy, rate consts. are given; soln. was cooled, concd. in vacuo, the resulting slurry was heated until homogeneous, cooled, filtered, ppt. was rinsed with Et2O, dried in vacuo; Pd(PPh3)4 was identified by comparison with authentic sample (IR, (1)H NMR) and by (31)P NMR;52%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[(Me3SiN=PPh2)2C=Ge→Ge=C(PPh2=NSiMe3)2]
360788-73-4

[(Me3SiN=PPh2)2C=Ge→Ge=C(PPh2=NSiMe3)2]

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

[Me3SiN=PPh2)2C=GeCl2]
868528-45-4

[Me3SiN=PPh2)2C=GeCl2]

Conditions
ConditionsYield
In tetrahydrofuran (N2); dropwise addn. of a soln. of germanium compd. in THF to a soln. ofpalladium complex in THF at 0°C, stirring at room temp. for 18 h; evapn., extn. with Et2O, filtration, concn.;A 47%
B n/a
[(Et3P)2Pd(μ-S)(μ-CH2O)Ge(N(SiMe3)2)2]
700834-72-6

[(Et3P)2Pd(μ-S)(μ-CH2O)Ge(N(SiMe3)2)2]

carbon monoxide
201230-82-2

carbon monoxide

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

[Ge(N(Si(CH3)3)2)2SC(O)CH2O]
700834-74-8

[Ge(N(Si(CH3)3)2)2SC(O)CH2O]

Conditions
ConditionsYield
With PPh3 In toluene air-free technique; toluene was distd. to Pd-Ge complex and PPh3; CO (1 atm) added; soln. stirred for 8 d; volatiles evapd.; toluene distd.; CO (1 atm) added; soln. stirred for 12 d; volatiles removed; C5H12 added; filtered; volatiles from filtrate removed ; redissolved in C6H6; CuCl added; stirred for 15 min; volatiles removed; suspnd. in C5H12; filtered; volatiles removed; dissolved in C6H6; passed through silica gel; elem. anal.;A n/a
B 43%
bis(cyclopentadienyl)dihydrozirconium
37342-98-6

bis(cyclopentadienyl)dihydrozirconium

bis(μ-1,2-ethanedithiolato-S,S':S)bis[(triphenylphosphine)palladium(II)]

bis(μ-1,2-ethanedithiolato-S,S':S)bis[(triphenylphosphine)palladium(II)]

A

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

B

(C5H5)2Zr(SCH2CH2S)Pd(SCH2CH2S)Zr(C5H5)2*C6H6

(C5H5)2Zr(SCH2CH2S)Pd(SCH2CH2S)Zr(C5H5)2*C6H6

Conditions
ConditionsYield
With benzene In benzene byproducts: hydrogen; react. of zirconocene dihydride and the palladium complex in benzene at 21°C for 20 h under dry nitrogen; identification by NMR and X-ray diffraction;A n/a
B 30%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

benzoyl chloride
98-88-4

benzoyl chloride

PdCl(COPh)(PPh3)2

PdCl(COPh)(PPh3)2

Conditions
ConditionsYield
In benzene 35°C, 10 min;100%
In benzene-d6 15 min at room temp. or heating to 140°C;99%
mixt. of compds. stirred for 13 h at 21 °C, under N2; evapd., washed with Et2O, dried; elem. anal.;95%
With iodobenzene In benzene 35°C, 10 min;91%
In toluene N2 or Ar-atmosphere;90%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

triethylphosphane telluride
2935-45-7

triethylphosphane telluride

palladium (II) telluride

palladium (II) telluride

Conditions
ConditionsYield
In toluene under inert atm., using standard drybox or Schlenk techniques, soln. of Pd- and Te-compounds heated to reflux for 40 min, pptn.; collected, washed, dried in vac., single phase (XRD); elem. anal.;100%
triphenyl phosphite
101-02-0

triphenyl phosphite

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

tetrakis(triphenyl phosphite)palladium(0)
22372-54-9

tetrakis(triphenyl phosphite)palladium(0)

Conditions
ConditionsYield
In benzene excess of P(OPh)3 was added to a soln. of the Pd complex in benzene;100%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

trityl tetrafluoroborate
341-02-6

trityl tetrafluoroborate

acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

bis(triphenylphosphine)(methyl acetylacetato)palladium(II) tetrafluoroborate
80583-72-8

bis(triphenylphosphine)(methyl acetylacetato)palladium(II) tetrafluoroborate

Conditions
ConditionsYield
In acetone; benzene (N2); a soln. of CPh3BF4 and methyl acetoacetate in acetone was added to a soln. of the Pd complex in benzene, the soln. was agitated for 48 h; recrystn. from acetone-ether; elem. anal.;100%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

2,5-dimethoxy-7,7,8,8-tetramethyl-7,8-disila-bicyclo[4.2.0]octa-1,3,5-triene-3,4-dicarboxylic acid dimethyl ester
305348-16-7

2,5-dimethoxy-7,7,8,8-tetramethyl-7,8-disila-bicyclo[4.2.0]octa-1,3,5-triene-3,4-dicarboxylic acid dimethyl ester

(Ph3P)2Pd(η2-1,2(SiMe2)2C6(COOMe)2(OMe)2)

(Ph3P)2Pd(η2-1,2(SiMe2)2C6(COOMe)2(OMe)2)

Conditions
ConditionsYield
In not given not isolated;100%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

p-benzoquinone
106-51-4

p-benzoquinone

[palladium(0)(triphenylphosphine)2(p-benzoquinone)]
490039-51-5, 57036-58-5

[palladium(0)(triphenylphosphine)2(p-benzoquinone)]

Conditions
ConditionsYield
In benzene under N2 atm. to suspn. Pd(PPh3)4 in benzene was added soln. benzoquinone in benzene and stirred for 30 min; soln. was concd., ether-hexane was added;100%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

bis(2-[2-(phenylsulfanyl)phenylsulfanyl]phenyl) disulfide
58485-11-3

bis(2-[2-(phenylsulfanyl)phenylsulfanyl]phenyl) disulfide

bis(2-[2-(phenylthio)phenylsulfanyl]benzenethiolato)palladium
943309-06-6

bis(2-[2-(phenylthio)phenylsulfanyl]benzenethiolato)palladium

Conditions
ConditionsYield
In benzene (Ar); Pd complex (1 equiv.) was added to soln. of thioether in C6H6 at room temp.; mixt. was stirred for 12 h; solvent removed (vac.); recrystd. (CHCl3/CH3CN); elem. anal.;100%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

4-(iodobutadiynyl)benzonitrile

4-(iodobutadiynyl)benzonitrile

iodo((4-cyanophenyl)butadiynyl)bis(triphenylphosphine)palladium

iodo((4-cyanophenyl)butadiynyl)bis(triphenylphosphine)palladium

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;100%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

1,2-dichloro-2-butene
13602-13-6

1,2-dichloro-2-butene

trans-bis(triphenylphosphine)palladium dichloride
28966-81-6

trans-bis(triphenylphosphine)palladium dichloride

Conditions
ConditionsYield
With diethylamine In tetrahydrofuran byproducts: P(C6H5)3, 1,3-butadiene; Ar, stirred for 24 h at room temp.; volatiles removed, ppt. washed (acetone), solvent removed; NMR;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

1,3-dichloro-1,1,3,3-tetrafluoro-propan-2-one
127-21-9

1,3-dichloro-1,1,3,3-tetrafluoro-propan-2-one

trans-bis(triphenylphosphine)palladium dichloride
28966-81-6

trans-bis(triphenylphosphine)palladium dichloride

Conditions
ConditionsYield
In Petroleum ether condensing excess ketone onto suspn. of Pt-complex (-196°C), sealing, warming to room temp., shaking for 24 h; removal of volatiles, filtration, washing (Et2O), drying (vac.);99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

1,4-dichloro-2-butene
764-41-0

1,4-dichloro-2-butene

trans-bis(triphenylphosphine)palladium dichloride
28966-81-6

trans-bis(triphenylphosphine)palladium dichloride

Conditions
ConditionsYield
With diethylamine In tetrahydrofuran byproducts: P(C6H5)3, 1,3-butadiene; Ar, stirred for 24 h at room temp.; volatiles removed, ppt. washed (acetone), solvent removed; NMR;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

chloropentafluoroacetone
79-53-8

chloropentafluoroacetone

trans-bis(triphenylphosphine)palladium dichloride
28966-81-6

trans-bis(triphenylphosphine)palladium dichloride

Conditions
ConditionsYield
In diethyl ether condensing excess ketone onto suspn. of Pt-complex (-196°C), sealing, warming to room temp., shaking for 24 h; removal of volatiles, filtration, washing (Et2O), drying (vac.);99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

5-bromo-2-(methylsulfonyl)pyrimidine
38275-48-8

5-bromo-2-(methylsulfonyl)pyrimidine

5-{bromobis(triphenylphosphine)palladio}-2-methylsulfonylpyrimidine

5-{bromobis(triphenylphosphine)palladio}-2-methylsulfonylpyrimidine

Conditions
ConditionsYield
In 1,2-dichloro-ethane 70°C (N2-atmosphere); evapn., washing (Et2O); elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

carbon diselenide
506-80-9

carbon diselenide

(P(C6H5)3)2PdC2Se4

(P(C6H5)3)2PdC2Se4

Conditions
ConditionsYield
In hexane byproducts: PPh3; (N2); to a solution of the Pd-complex was added an excess of CSe2; at room temp.; stirred for 2 h; decanted; washed (hexane); dried (high vac.); elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

[tricarbonyl(η(6)-4-chloroanisole)manganese]BF4
166543-63-1

[tricarbonyl(η(6)-4-chloroanisole)manganese]BF4

cis-[(Pd(PPh3)2Cl)(4-MeOC6H4)(Mn(CO)3)]BF4
166543-69-7

cis-[(Pd(PPh3)2Cl)(4-MeOC6H4)(Mn(CO)3)]BF4

Conditions
ConditionsYield
In toluene nitrogen atmosphere; equimolar amts.; stirring (35°C, dark; pptn.); filtration, washing (OEt2), drying (vac.); elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

tricarbonyl(η(6)-chlorobenzene)manganese hexafluorophosphate
57812-91-6

tricarbonyl(η(6)-chlorobenzene)manganese hexafluorophosphate

cis-[(Pd(PPh3)2Cl)(C6H5)(Mn(CO)3)]PF6
166543-65-3

cis-[(Pd(PPh3)2Cl)(C6H5)(Mn(CO)3)]PF6

Conditions
ConditionsYield
In toluene nitrogen atmosphere; equimolar amts.; stirring (room temp., 18 h, dark; pptn.); filtration, washing (OEt2), drying (vac.); elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

N-benzyl-2-iodo-N-methylaniline
677027-04-2

N-benzyl-2-iodo-N-methylaniline

trans-[Pd(C6H4N(Me)CH2Ph-2)I(PPh3)2]
677027-15-5

trans-[Pd(C6H4N(Me)CH2Ph-2)I(PPh3)2]

Conditions
ConditionsYield
In benzene (Ar); addn. of palladium complex to a soln. of ligand in benzene, stirring at room temp. for 24 h; evapn., pptn. with Et2O;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

1,3-dialkyl-5-fluoro-6-iodouracil
113170-76-6

1,3-dialkyl-5-fluoro-6-iodouracil

iodo(1,2,3,4-tetrahydro-1,3-dialkyl-2,4-dioxo-5-fluoro-6-pyrimidinyl)bis(triphenylphosphine)palladium

iodo(1,2,3,4-tetrahydro-1,3-dialkyl-2,4-dioxo-5-fluoro-6-pyrimidinyl)bis(triphenylphosphine)palladium

Conditions
ConditionsYield
In benzene reaction at room temp.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

N-methylated-4-chloropyridinium triflate
1207740-88-2

N-methylated-4-chloropyridinium triflate

trans-chloro(4-hydro-1-methyl-4-pyridylidene)bis(triphenylphosphine)palladium(II) triflate

trans-chloro(4-hydro-1-methyl-4-pyridylidene)bis(triphenylphosphine)palladium(II) triflate

Conditions
ConditionsYield
In toluene byproducts: PPh3; (Ar); std. Schlenk technique; suspn. of triflate salt and Pd compd. (1.01 equiv.) in toluene was stirred at 60°C for 17 h; cooled to room temp.; filtered through Celite; residue dissolved in CH2Cl2; filtered; evapd. (vac.); elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

bromo(-)-menthylpropiolate

bromo(-)-menthylpropiolate

trans-bromo(bis(triphenylphosphine))(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II)

trans-bromo(bis(triphenylphosphine))(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II)

Conditions
ConditionsYield
In dichloromethane inert atmosphere, Schlenk technique; soln. of Pd-complex treated with menthyl propiolate at ambient temp., mixt. stirred for 30 min; solvent removed (vac.), column chromy. (petroleum ether/CH2Cl2 as eluant), solvent removed; elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

1-bromo-(-)-menthyl propiolate
1346267-01-3

1-bromo-(-)-menthyl propiolate

trans-bromo(3-((-)-menthoxy)-3-oxy-1-propynyl)bis(triphenylphosphine)palladium(II)

trans-bromo(3-((-)-menthoxy)-3-oxy-1-propynyl)bis(triphenylphosphine)palladium(II)

Conditions
ConditionsYield
In dichloromethane byproducts: PPh3; under inert atmosphere; suspn. of Pd(PPh3)4 in CH2Cl2 treated with ligand at ambient temp.; stirred for 30 min; solvent removed in vac.; purified by column chromy. (silica gel, petroleum ether-CH2Cl2); solvent removed; elem. anal.;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

N-(4-methoxyphenyl)-2,2,2-trifluoroacetimidoyl iodide
134481-27-9

N-(4-methoxyphenyl)-2,2,2-trifluoroacetimidoyl iodide

trans-Pd(η1-C(CF3)N(p-methoxyphenyl))(triphenylphosphine)2
1352411-00-7

trans-Pd(η1-C(CF3)N(p-methoxyphenyl))(triphenylphosphine)2

Conditions
ConditionsYield
In benzene treatment of trifluoroacetimidoyl deriv. with palladium compd. in benzene at room temp. for 24 h;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

ClC(CF3)N(n-C6H13)
143681-38-3

ClC(CF3)N(n-C6H13)

PdCl(η1-C(CF3)N(n-C6H13))(triphenylphosphine)2
1352411-02-9

PdCl(η1-C(CF3)N(n-C6H13))(triphenylphosphine)2

Conditions
ConditionsYield
In benzene treatment of trifluoroacetimidoyl deriv. with palladium compd. in benzene at room temp. for 24 h;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

trans-NC5H4CHCHC6F4Br
862672-29-5

trans-NC5H4CHCHC6F4Br

[PdBr(C6F4CHCHC5H4N)(PPh3)2]
1346687-91-9

[PdBr(C6F4CHCHC5H4N)(PPh3)2]

Conditions
ConditionsYield
In not given reaction of palladium compd. with aryl bromide at room temp., heating at45°C for 4 h;99%
In water reaction of palladium compd. with aryl bromide at room temp. in THF/H2O (6:1), heating at 45°C for 4 h;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

4-(bromohexatriynyl)benzonitrile

4-(bromohexatriynyl)benzonitrile

bromo((4-cyanophenyl)hexatriynyl)bis(triphenylphosphine)palladium

bromo((4-cyanophenyl)hexatriynyl)bis(triphenylphosphine)palladium

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

C31H26ClPSSi

C31H26ClPSSi

C49H40P2PdSSi

C49H40P2PdSSi

Conditions
ConditionsYield
Stage #1: C31H26ClPSSi With sodium hexamethyldisilazane In tetrahydrofuran at -40℃;
Stage #2: tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; Reagent/catalyst;
99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

10-bromo-5,15-diphenylporphyrin

10-bromo-5,15-diphenylporphyrin

triphenyl-arsane
603-32-7

triphenyl-arsane

H2(C4H2NC)4H(C6H5)2PdBr(As(C6H5)3)2

H2(C4H2NC)4H(C6H5)2PdBr(As(C6H5)3)2

Conditions
ConditionsYield
In toluene at 105°C (Ar); evapn., trituration (ether);99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

10-bromo-5,15-diphenylporphyrin

10-bromo-5,15-diphenylporphyrin

triphenylphosphine
603-35-0

triphenylphosphine

H2(C4H2NC)4H(C6H5)2PdBr(P(C6H5)3)2

H2(C4H2NC)4H(C6H5)2PdBr(P(C6H5)3)2

Conditions
ConditionsYield
In toluene at 105°C (Ar); evapn., trituration (ether);99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

[10-bromo-5,15-diphenylporphyrinato]-magnesium(II)
193265-35-9

[10-bromo-5,15-diphenylporphyrinato]-magnesium(II)

triphenylphosphine
603-35-0

triphenylphosphine

Ni(C4H2NC)4H(C6H5)2PdBr(P(C6H5)3)2
219134-12-0

Ni(C4H2NC)4H(C6H5)2PdBr(P(C6H5)3)2

Conditions
ConditionsYield
In toluene at 105°C (Ar); evapn., trituration (ether);99%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

C9H11IO2

C9H11IO2

[(2-hydroxymethyl-4-methoxy-5-(methyl))phenyl]iodobis(triphenyl-phosphine)palladium

[(2-hydroxymethyl-4-methoxy-5-(methyl))phenyl]iodobis(triphenyl-phosphine)palladium

Conditions
ConditionsYield
In toluene at 20℃; for 16h; Sealed tube; Sonication;99%
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