Analysis tests Standard Results Appearance Yellowish Crystallization Hangzhou Dingyan Chem is a leading manufacturer and supplie
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inquiryAbout Product Details Item Specification Test Results Appearance White crystalline powder Conform
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inquiryName trans-Dichlorobis(triphenylphosphine)palladium(II) Structural Formula CAS No. 13965-03-2 Molecular
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inquiryEmail Us: admin07@hsnm.com.cn Quick details of Bis(triphenylphosphine)palladium(II) chloride powder product name:Bis(triphenylphosphine)palladium(II) chloride CAS.No: 13965-03-2 appearance: yellow powder Molecular formula:C36H30Cl2P2Pd Molecular we
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inquiryhydrogenchloride
palladium
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
Stage #1: hydrogenchloride; palladium With aqua regia at 80℃; Stage #2: triphenylphosphine In ethanol at 70℃; Stage #3: In ethanol at 70℃; for 1h; Temperature; Solvent; | 100% |
bis(benzonitrile)palladium(II) dichloride
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine In chloroform isolation by filtration; | 95% |
With triphenylphosphine In not given (dry N2); dry and deoxygenated solvents; addn. of 2.2 equiv. of PPh3 to Pd-compd.; filtration; | 95% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With PPh3 In ethanol; water molar ratio borane:Pd:PPh3=1:2:4, 70°C, 2 h (pptn.); filtration, washing (H2O, EtOH, ether); extn. of PdCl2(PPh3)2 (toluene);elem. anal.; | A n/a B 95% |
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; Milling; | 92% |
trans-bis(trifluoromethanesulfonate) bis(triphenylphosphine)palladium trihydrate
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With sodium chloride In water; acetonitrile Pd-compound in CH3CN was treated with aq. NaCl; | 91% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine excess of PPh3; | 90% |
With PPh3; H2O In dimethyl sulfoxide heating a mixt. of PdCl2, PPh3 and water in DMSO under Ar (140°C) yielding a yellow-orange soln., cooling (room temp.), pptn.; filtration, washing (Et2O), drying (vac.); | 90% |
With triphenylphosphine In N,N-dimethyl-formamide Addn. of 2.4 equiv. of PPh3 to DMF soln. of PdCl2 at 140°C.; Cooling, collecting the resultant ppt.; |
tetrakis(triphenylphosphine) palladium(0)
tetrachlorosilane
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
mixt. of compds. heated at 60 °C for 14 h, under N2; volatiles collected, residue washed with Et2O; | 89% |
dichloro bis(acetonitrile) palladium(II)
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In dichloromethane Inert atmosphere; Schlenk technique; | 89% |
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzonitrile at 180℃; for 0.333333h; Inert atmosphere; Schlenk technique; | 88% |
In dichloromethane; acetonitrile at 20℃; for 0.166667h; Inert atmosphere; | 82% |
With carbon monoxide In toluene at 125℃; under 7600.51 Torr; for 4h; | 50% |
tetrakis(triphenylphosphine) palladium(0)
chloro-trimethyl-silane
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
byproducts: (Me3Si)2, (Me3Si)3O; mixt. of compds. heated at 60 °C for 4 h, under N2; volatiles collected, residue washed with Et2O; elem. anal.; | 80% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane under N2, PPh3 was added to soln. of Ir-Pd-complex in CH2Cl2 (molar ratio 3.5:1) in CH2Cl2, stirred at room temp. for 3 h; ppt. filtered off, dried under vac. (Pd-product), filtrate evapd. slowly at reduced pressure, filtered, dried under vac.; | A 80% B >99 |
bis(benzonitrile)palladium(II) dichloride
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In acetonitrile under N2, soln. of Pd-complex in CH3CN was added to suspn. of equimolaramt. of Ir-complex in CH3CN, stirred at room temp. for 1 h; ppt. filtered, vac. dried (Pd-product), filtrate evapd. under reduced pressure, filtered, washed with EtOH, vac. dried; elem. anal.; | A 15% B 78% |
tetrakis(triphenylphosphine) palladium(0)
1,2-dichlorotetramethylsilane
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene mixt. of educts in benzene stirred at 20°C for 24 h under N2; dild. with pentane, crystals filtered, washed with ether, dried in vac.; elem. anal.; | 75% |
dichloro-(1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene)palladium
triphenylphosphine
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In dichloromethane room temp., 22 h; monitored by (1)H NMR; | 74% |
bis(benzonitrile)palladium(II) dichloride
4,4-dimethyl-2-pentyne
A
bis-triphenylphosphine-palladium(II) chloride
B
[(σ,π-CBu(t)=CMeCMe=CBu(t)Cl)PdCl]2
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane N2-atmosphere; addn. of 2 equiv. of pentyne derivative to Pd-complex soln. (ice-water bath), addn. of 1 equiv. PPh3 soln. (pptn.); filtration off of PPh3-complex, evapn. to dryness (0°C, reduced pressure), washing (light petroleum), drying in air; elem. anal.; | A n/a B 72% |
dichloro bis(acetonitrile) palladium(II)
acetonitrile
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In dichloromethane (Ar); Pd complex added to a soln. of Ru complex, stirred for 1 h; stirred at 0°C for 30 min, filtered, concd. (vac.), MeCN added, crystd. at -30°C for 2 d, filtered, washed (cold MeCN), dried (vac.); elem. anal.; | A n/a B 70% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane under N2, PPh3 was added to soln. of Ir-Pd-complex in CH2Cl2 (molar ratio 2.4:1), stirred at room temp. for 3 h; ppt. filtered off, dried under vac. (Pd-product), filtrate evapd. slowly at reduced pressure, filtered, dried under vac.; | A 68% B >99 |
benzylidene dichloride
tetrakis(triphenylphosphine) palladium(0)
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene byproducts: (E)-stilbene, 1,2-dichloro-1,2-diphenylethane; to soln. of Pd(PPh3)4 in benzene added PhCHCl2 under N2, stirred at room temp. for 5 h; dild. with pentanes, crystals filtered, washed with ether, dried in vac.; GLC anal.; | 64% |
bis(benzonitrile)palladium(II) dichloride
n-Butyl nitrite
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With carbon monoxide; triphenylphosphine In neat (no solvent) stirring (1 h), bubbling of CO; filtn., pptn. on addn. of pentane; elem.anal.; | A 40% B 60% |
((C5H5)Ru(C5H3C(C6H5)NC6H4CH3))2Pd2Cl2
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
B
(C5H5)Ru(C5H3C(C6H5)NC6H4CH3)PdCl(P(C6H5)3)
Conditions | Yield |
---|---|
In benzene room temp.; filtn., pptn. (hexane); elem. anal.; | A n/a B 57% |
tetrakis(triphenylphosphine) palladium(0)
p-methoxyphenylisocyanide
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With HCl In ethanol; toluene CNC6H4OMe in PhMe added dropwise to stirred suspn. of Pd(PPh3)4 in PhMeunder N2, stirred for ca. 1 h, cooled to -70°C, 0.22 M HCl/EtOH in PhMe added dropwise during ca. 2 h, stirred at -70°C for 90 min, allowed to warm to room temp. (3 h); ppt. filtered off, soln. concd., pptd. with Et2O, redissolved in (CH2Cl)2/Et2O, treated with activated charcoal, filtered, concd., pptd. by addn. of Et2O; elem. anal.; | A n/a B 55% |
With HCl In ethanol; toluene 0.26 M ethanolic soln. of HCl added dropwise (30 min) to stirred suspn.of Pd(PPh3)4 in toluene at -70°C under N2, soln. of isocyanide in toluene added dropwise during ca. 10 min, allowed to warm to room temp. (ca. 2 h); concd., Et2O added, sepd. by fractional pptn. from (CH2Cl)2/Et2O; elem.anal.; | A n/a B 16% |
cis-(PPh3)2 bis(azido)palladium(II)
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In chloroform byproducts: N2; Irradiation (UV/VIS); flash photolysis; not isolated; UV/VIS monitoring; | 53% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
[Fe((η(5)-C5H3)C(CH3)=NC6H5)]2Cl2(PPh3)2
Conditions | Yield |
---|---|
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.; | A n/a B 52% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
d,l-[Fe((η(5)-C5H3)C(CH3)=NC6H4-4-CH3)]2Cl2(PPh3)2
Conditions | Yield |
---|---|
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.; | A n/a B 8% C 46% |
2-(4-nitrophenyl)ethylamine monohydrochloride
palladium diacetate
A
bis-triphenylphosphine-palladium(II) chloride
[Pd(C6H3(CH2)2NH2-2-NO2-5-κ2C,N)Cl(PPh3)]
Conditions | Yield |
---|---|
In acetonitrile Pd(OAc)2 and 4-nitrophenethylamine*HCl in MeCN were refluxed for 16 h, suspn. was filtered through MgSO4, solvent was removed, CH2Cl2 was added,PPh3 was added and stirred for 30 min; soln. was filtered through MgSO4 and concd., ppt. was filtered off, Et2O/n-hexane (1:1) was added to filtrate, ppt. was filtered, washed with n-hexane, and air-dried; elem. anal.; | A 30% B 37% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene complex heated in C6H6 at 75°C for 15 min; (Ar); hexane added at room temp., ppt. filtered off, extd. (CH2Cl2); extract treated with hexane, ppt. reprecipitated (hexane from CH2Cl2, twice), washed (pentane), dried (vac.); elem. anal.; | A n/a B 35% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
B
(C5H5)Ru(C5H3C(CH3)NC6H4CH3)PdCl(P(C6H5)3)
Conditions | Yield |
---|---|
In benzene room temp.; filtn., pptn. (hexane); elem. anal.; | A n/a B 34% |
tetrakis(triphenylphosphine) palladium(0)
(C5H5)Rh(OC6H4(CH3)(CCl3))
A
bis-triphenylphosphine-palladium(II) chloride
B
(C5H5)Rh(OC7H4(CH3)Cl)
Conditions | Yield |
---|---|
In benzene byproducts: Ph3P; stirring (20°C, 72 h); concn., chromy. (SiO2, C6H5/EtOH), recry; | A n/a B 34% |
triphenylphosphine
A
bis-triphenylphosphine-palladium(II) chloride
[Pd([(η-(5)-C5H3)C(H)=NCH2C6H5]Fe[(η(5)-C5H4)C(H)=NCH2C6H5])ClPPh3]
[Fe((η(5)-C5H3)CH=NCH2C6H5)]2Cl2(PPh3)2
Conditions | Yield |
---|---|
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.; | A n/a B 7% C 32% |
A
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With CH3CO2Na*3H2O; triphenylphosphine In methanol stirring equimolar amts. of Na2PdCl4, ferrocene derivative and AcONa inMeOH for 3 h (room temp., protection from light; pptn.), collection (filtration), washing (MeOH), suspending in C6H6, stirring with excess of PPh3 for 30 min; filtration, evapn. of filtrate (reduced pressure), dissoln. in CHCl3, chromy. (SiO2, CHCl3), evapn. (reduced pressure), treatment with hexane (pptn.); elem. anal.; | A n/a B 5% C 15% |
bis-triphenylphosphine-palladium(II) chloride
PdCl[1,3-bis(diphenylthiophosphinoyl)indene(-1H)]
[PdCl[Ind(Ph2PS)2]]PdCl(PPh3)
Conditions | Yield |
---|---|
With polysterene-supported diisopropylethylamine In dichloromethane (under Ar, Schlenk); suspn. of Pd-complexes and polysterene-supported diisopropylethylamine in CH2Cl2 stirred overnight at room temp.; filtered, pentane added, filtered, washed with pentane, dried under vac.; elem. anal.; | 98% |
bis-triphenylphosphine-palladium(II) chloride
acrylic acid methyl ester
methyl cinnamate
Conditions | Yield |
---|---|
With sodium acetate; silver trifluoroacetate In acetonitrile at 60℃; for 24h; Heck Reaction; Schlenk technique; Inert atmosphere; | 98% |
bis-triphenylphosphine-palladium(II) chloride
acetophenone dimethylhydrazone
Conditions | Yield |
---|---|
With NaOCOCH3 In acetonitrile mixt. of freshly distilled hydrazone, Pd(PPh3)2Cl2 and NaOAc in MeCN is heated at 75°C for 48 h under Ar, mixt. is cooled to room temp.; solvent is evapd., chromy. (hexane-EtOAc 4:1); elem. anal.; | 97% |
bis-triphenylphosphine-palladium(II) chloride
triphenylphosphine
lithium bromide
bis(triphenylphosphine)palladium dibromide
Conditions | Yield |
---|---|
In chloroform; isopropyl alcohol at 20℃; for 2h; | 96% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Schlenk technique; | 96% |
bis-triphenylphosphine-palladium(II) chloride
methyl magnesium iodide
9-iodo-m-carborane
9,10-dimethyl-1,7-carborane
Conditions | Yield |
---|---|
In diethyl ether refluxed for 5-15 h under nitrogen; monitored by tlc; decomposed with water;; washed with dilute HCl and with water; dried over Na2SO4; chromd. on silica gel with petroleum ether eluent; distilled in vac.; sublimed in vac. at 30-60°C; recrystd. from pentane; elem. anal.;; | 95% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
With H2 In further solvent(s) complex soln. in aniline stirred under H2 at 90°C; aniline removed (vac.), ppt. washed (Et2O and C6H6), C6H6 filtrate concd. (vac.), pptd. (hexane under Ar), washed with hexane and Et2O, dried (vac.), recrystd. (toluene under Ar); elem. anal.; | 95% |
bis-triphenylphosphine-palladium(II) chloride
silver tetrafluoroborate
1-(azidomethyl)-2-isocyanobenzene
trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate
Conditions | Yield |
---|---|
In dichloromethane; acetone byproducts: AgCl; under N2; 1 M soln. of AgBF4 in acetone added to a suspn. of Pd-complex in CH2Cl2 at room temp., stirred for 30 min., AgCl filtered off, filtrate treated with isonitrile, stirred for 2.5 h; Et2O added, ppt. filtered off, dried under vac.; elem. anal.; | 94.3% |
bis-triphenylphosphine-palladium(II) chloride
tetraphenylimidothioxodiphosphinic acid potassium salt
Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)]PF6
Conditions | Yield |
---|---|
In methanol elem. anal.; | 94% |
bis-triphenylphosphine-palladium(II) chloride
Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)]PF6
Conditions | Yield |
---|---|
In methanol elem. anal.; | 94% |
carbon disulfide
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In not given Ru complex was treated with CS2 under basic conditions followed by addn.Pd complex; | 94% |
bis-triphenylphosphine-palladium(II) chloride
C16H17N3O4
Conditions | Yield |
---|---|
With triethylamine In methanol mixt. of Pd complex, OC(C6H4OCH3)NHNCHC5HN(CH2OH)(CH3)(OH) (1 equiv.) and triethylamine stirred and heted at reflux for 3 h; ppt. washed with MeOH, ether, dried in vac., crystd. from CHCl3/MeOH at room temp.; elem. anal.; | 94% |
bis-triphenylphosphine-palladium(II) chloride
5-hexyl-1-ol
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol; (S)-methyl 5-amino-4-(4-bromo-1-oxoisoindolin-2-yl)-5-oxopentanoate With copper(l) iodide; triethylamine In N,N-dimethyl-formamide Inert atmosphere; Stage #2: bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 80℃; Sealed tube; | 94% |
bis-triphenylphosphine-palladium(II) chloride
trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide
Conditions | Yield |
---|---|
With CuI; 3,5-bis[(dimethylamino)methyl]phenylacetylene In diethylamine byproducts: (3,5-(Me2NCH2)2C6H3)2C2; (N2); 6 d at room temp.; evapd. (vac.), dissolved in Et2O/Et2NH, filtered, evapd. (vac.), crystd. in pentane; elem. anal.; | 93% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene a soln. of Pd-complex was added to a soln. of Cr-complex under Ar; evapn. at 80°C/10 Torr; extrn. with benzene-heptane 1:1; crystn.at -10°C; | 92.9% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In benzene a soln. of Pd-complex was added to a soln. of Cr-complex under Ar; evapn. at 80°C/10 Torr; extrn. with benzene-heptane 1:1; crystn.at -10°C; elem. anal; | 92.6% |
bis-triphenylphosphine-palladium(II) chloride
{μ-(Ph3P)2PdS2}Fe2(CO)6
Conditions | Yield |
---|---|
In not given | 92% |
bis-triphenylphosphine-palladium(II) chloride
(3-diphenylphosphino)propanethiol
dichlorobis(μ-[(3-diphenylphosphino)propanethiolato]-P,μ-S)dipalladium(II)
Conditions | Yield |
---|---|
In dichloromethane N2-atmosphere; equimolar amts., 30 min; concn. (vac.) hexane addn. crystn. (-24°C, 12 h), collection (filtration), washing (hexane), drying; | 92% |
bis-triphenylphosphine-palladium(II) chloride
N-phenylmethyl-2-pyridinecarbothioamide
Pd(Cl)(κ2-S,N-C6H4CS-N-(4-Bz)(PPh3))
Conditions | Yield |
---|---|
In ethanol at 80℃; for 3h; | 92% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In methanol at 20℃; | 92% |
bis-triphenylphosphine-palladium(II) chloride
silver tetrafluoroborate
{Pd(P(C6H5)3)2(BF4)2}
Conditions | Yield |
---|---|
In nitromethane byproducts: AgCl; stirring mixt. of Pd complex and AgBF4 in CH3NO2 at room temp. for 2 d, under anaerobic conditions;; filtration; removal of solvent in vac.; dissolving in CH2Cl2; evapn. to dryness; repptn. with CH2Cl2/(C2H5)2O/pentane; washing with pentane; drying in vac.; elem. anal.;; | 91% |
bis-triphenylphosphine-palladium(II) chloride
N-methyl N'-cyanoisothiourea sodium salt
Pd(SCNHCNNCH3)2(P(C6H5)3)2
Conditions | Yield |
---|---|
In methanol; water to suspn. of Pd-complex in MeOH was added ligand in MeOH, stirred for 24h at room temp.; filtered, washed with water, dried in vacuo; elem. anal.; | 91% |
bis-triphenylphosphine-palladium(II) chloride
N-(4-methyl-phenyl)-α-thiopicolinamide
[Pd(Cl)(κ2-S,N-C6H4CS=N-(4-MePh)(PPh3)]
Conditions | Yield |
---|---|
In ethanol to soln. ligand in EtOH Pd complex was added and heated under reflux for3 h; react. mixt. was cooled to room temp., ppt. was filtered, washed with EtOH and dried in vacuo; elem. anal.; | 91% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 65℃; for 2h; Inert atmosphere; | 91% |
bis-triphenylphosphine-palladium(II) chloride
Conditions | Yield |
---|---|
In acetone stoichiometric amts., refluxing (2 h), pptn.; | 90% |
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