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Hangzhou Dingyan Chem Co., Ltd

Analysis tests Standard Results Appearance Yellowish Crystallization Hangzhou Dingyan Chem is a leading manufacturer and supplie

High quality Bis(triphenylphosphine)palladium(II) chloride with best price cas:13965-03-2

Cas:13965-03-2

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Bis(Triphenylphosphine)Palladium(Ii) Chloride supplier in China

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Bis(triphenylphosphine)palladium (II)chloride

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Henan Allgreen Chemical Co.,Ltd

Located in Zhengdong New District, Zhengzhou of Henan province, Henan Allgreen Chemical Co.,Ltd is comprehensive high-tech modern enterprises integrating professional R&D, production and sales. Strong technical force, with a long-term profes

Bis(triphenylphosphine)palladiuM(II) Dichloride

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Dichlorobis(triphenylphosphine)palladium

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

hot sale Bis(triphenylphosphine)palladium(II) chloride high quality

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Min.Order:100 Gram

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 13965-03-2 Bis(triphenylphosphine) Palladium (II) Chloride Manufacturer

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant produc

Bis(triphenylphosphine)palladium(II) chloride

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

Bis(triphenylphosphine)palladium(II) chloride

Cas:13965-03-2

Min.Order:1 Gram

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Dichlorobis-(triphenylphosphino)-palladium (II)

Cas:13965-03-2

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM Bis(triphenylphosphine)palladium(II) chloride

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Min.Order:100 Gram

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Leader Biochemical Group

About Product Details Item Specification Test Results Appearance White crystalline powder Conform

China Biggest factory Supply High Quality Bis(triphenylphosphine)palladium(II) chloride CAS 13965-03-2

Cas:13965-03-2

Min.Order:1 Kilogram

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Bis(triphenylphosphine)palladium(II) chloride

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 13965-03-2 with best quality

Cas:13965-03-2

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Henan Sinotech Import&Export Corporation

Name trans-Dichlorobis(triphenylphosphine)palladium(II) Structural Formula CAS No. 13965-03-2 Molecular

trans-Dichlorobis(triphenylphosphine)palladium

Cas:13965-03-2

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

Bis(triphenylphosphine)palladium(II) chloride/13965-03-2CAS NO.: 13965-03-2

Cas:13965-03-2

Min.Order:1 Gram

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Yellow crystalline powder Storage:R.T Package:500G/Bottle or at customers reqirement. Application:precious metal catalyst Transportation:Express/Sea/Air Port:Any port in China

Bis(triphenylphosphine)palladium(II)chloride cas 13965-03-2

Cas:13965-03-2

Min.Order:50 Gram

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bis(triphenylphosphine)palladium(II) chloride 13965-03-2

Cas:13965-03-2

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:Yellow powder Storage:keep in cool and dry plac

Bis(triphenylphosphine)palladium(II) chloride 9.2% Pd CAS 13965-03-2

Cas:13965-03-2

Min.Order:1 Gram

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Bis(triphenylphosphine)palladium(II) chloride Organic Palladium

Cas:13965-03-2

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Qingdao Beluga Import and Export Co., LTD

Bis(triphenylphosphine)palladium(II) chloride CAS:13965-03-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in

Bis(triphenylphosphine)palladium(II) chloride CAS:13965-03-2

Cas:13965-03-2

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bis(triphenylphosphine)palladium(II) chloride

Cas:13965-03-2

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd,Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all em

CAS 13965-03-2 Bis (triphenylphosphine) Palladium (II) Chloride

Cas:13965-03-2

Min.Order:1 Gram

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Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good q

Good Effect Bis(triphenylphosphine)palladium(II) chloride cas 13965-03-2 AKS

Cas:13965-03-2

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Guangdong Juda Chemical Industrial Co.,Limited

We provide tailor-made photoinitiator solutions for different performances by custom synthesisi.blends or other technical supports low-odor uv formulations non-yellowing uv formulations benzene-free uv formulations polymeric uv formul

Bis(triphenylphosphine)palladiuM(II) chloride CAS:13965-03-2igh Quality

Cas:13965-03-2

Min.Order:100 Kilogram

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Hangzhou Keyingchem Co.,Ltd

High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar

low price ,high quality Bis(triphenylphosphine)palladium(II) chloride

Cas:13965-03-2

Min.Order:1 Gram

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Wuhan Han Sheng New Material Technology Co.,Ltd

Email Us: admin07@hsnm.com.cn Quick details of Bis(triphenylphosphine)palladium(II) chloride powder product name:Bis(triphenylphosphine)palladium(II) chloride CAS.No: 13965-03-2 appearance: yellow powder Molecular formula:C36H30Cl2P2Pd Molecular we

trans-dichlorobis(triphenylphosphine) Palladium(II)

Cas:13965-03-2

Min.Order:1 Kilogram

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 13965-03-2 Bis(triphenylphosphine)palladium(II) chloride

Cas:13965-03-2

Min.Order:1 Kilogram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bis(triphenylphosphine) palladium dicholoride

Cas:13965-03-2

Min.Order:0

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Dichlorobis(triphenylphosphine)palladium(II)

Cas:13965-03-2

Min.Order:4 Kilogram

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Synthetic route

hydrogenchloride
7647-01-0

hydrogenchloride

palladium
7440-05-3

palladium

triphenylphosphine
603-35-0

triphenylphosphine

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
Stage #1: hydrogenchloride; palladium With aqua regia at 80℃;
Stage #2: triphenylphosphine In ethanol at 70℃;
Stage #3: In ethanol at 70℃; for 1h; Temperature; Solvent;
100%
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
With triphenylphosphine In chloroform isolation by filtration;95%
With triphenylphosphine In not given (dry N2); dry and deoxygenated solvents; addn. of 2.2 equiv. of PPh3 to Pd-compd.; filtration;95%
dihydrogen decachloro decaborate

dihydrogen decachloro decaborate

palladium dichloride

palladium dichloride

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[(Ph3P)4Pd2Cl2]closo-B10Cl10

[(Ph3P)4Pd2Cl2]closo-B10Cl10

Conditions
ConditionsYield
With PPh3 In ethanol; water molar ratio borane:Pd:PPh3=1:2:4, 70°C, 2 h (pptn.); filtration, washing (H2O, EtOH, ether); extn. of PdCl2(PPh3)2 (toluene);elem. anal.;A n/a
B 95%
tetrachloropalladium anion

tetrachloropalladium anion

triphenylphosphine
603-35-0

triphenylphosphine

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In neat (no solvent) at 20℃; Milling;92%
trans-bis(trifluoromethanesulfonate) bis(triphenylphosphine)palladium trihydrate
157319-21-6, 114403-39-3

trans-bis(trifluoromethanesulfonate) bis(triphenylphosphine)palladium trihydrate

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
With sodium chloride In water; acetonitrile Pd-compound in CH3CN was treated with aq. NaCl;91%
palladium dichloride

palladium dichloride

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
With triphenylphosphine excess of PPh3;90%
With PPh3; H2O In dimethyl sulfoxide heating a mixt. of PdCl2, PPh3 and water in DMSO under Ar (140°C) yielding a yellow-orange soln., cooling (room temp.), pptn.; filtration, washing (Et2O), drying (vac.);90%
With triphenylphosphine In N,N-dimethyl-formamide Addn. of 2.4 equiv. of PPh3 to DMF soln. of PdCl2 at 140°C.; Cooling, collecting the resultant ppt.;
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
mixt. of compds. heated at 60 °C for 14 h, under N2; volatiles collected, residue washed with Et2O;89%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

triphenylphosphine
603-35-0

triphenylphosphine

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In dichloromethane Inert atmosphere; Schlenk technique;89%
triphenylphosphine
603-35-0

triphenylphosphine

palladium dichloride

palladium dichloride

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In benzonitrile at 180℃; for 0.333333h; Inert atmosphere; Schlenk technique;88%
In dichloromethane; acetonitrile at 20℃; for 0.166667h; Inert atmosphere;82%
With carbon monoxide In toluene at 125℃; under 7600.51 Torr; for 4h;50%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
byproducts: (Me3Si)2, (Me3Si)3O; mixt. of compds. heated at 60 °C for 4 h, under N2; volatiles collected, residue washed with Et2O; elem. anal.;80%
((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl(1+)*PF6(1-)=(((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl)PF6

((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl(1+)*PF6(1-)=(((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl)PF6

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

{bis(triphenylphosphine)nitrosyl(3,6-bis(2'-pyridyl)pyridazine)cloroiridium} hexafluorophosphat

{bis(triphenylphosphine)nitrosyl(3,6-bis(2'-pyridyl)pyridazine)cloroiridium} hexafluorophosphat

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane under N2, PPh3 was added to soln. of Ir-Pd-complex in CH2Cl2 (molar ratio 3.5:1) in CH2Cl2, stirred at room temp. for 3 h; ppt. filtered off, dried under vac. (Pd-product), filtrate evapd. slowly at reduced pressure, filtered, dried under vac.;A 80%
B >99
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

Ir(NO)(C5H4NC4H2N2C5H4N)(P(C6H5)3)2Br(1+)*PF6(1-)=(Ir(NO)(C5H4NC4H2N2C5H4N)(P(C6H5)3)2Br)PF6

Ir(NO)(C5H4NC4H2N2C5H4N)(P(C6H5)3)2Br(1+)*PF6(1-)=(Ir(NO)(C5H4NC4H2N2C5H4N)(P(C6H5)3)2Br)PF6

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl(1+)*PF6(1-)=(((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl)PF6

((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl(1+)*PF6(1-)=(((C6H5)3P)Cl2Ir(C5H4NC4H2N2C5H4N)(NO)PdCl)PF6

Conditions
ConditionsYield
In acetonitrile under N2, soln. of Pd-complex in CH3CN was added to suspn. of equimolaramt. of Ir-complex in CH3CN, stirred at room temp. for 1 h; ppt. filtered, vac. dried (Pd-product), filtrate evapd. under reduced pressure, filtered, washed with EtOH, vac. dried; elem. anal.;A 15%
B 78%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

1,2-dichlorotetramethylsilane
4342-61-4

1,2-dichlorotetramethylsilane

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In benzene mixt. of educts in benzene stirred at 20°C for 24 h under N2; dild. with pentane, crystals filtered, washed with ether, dried in vac.; elem. anal.;75%
dichloro-(1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene)palladium
570397-18-1

dichloro-(1,2-dimethoxy-4,5-bis(2-pyridylethynyl)benzene)palladium

triphenylphosphine
603-35-0

triphenylphosphine

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In dichloromethane room temp., 22 h; monitored by (1)H NMR;74%
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

4,4-dimethyl-2-pentyne
999-78-0

4,4-dimethyl-2-pentyne

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

[(σ,π-CBu(t)=CMeCMe=CBu(t)Cl)PdCl]2
64331-14-2

[(σ,π-CBu(t)=CMeCMe=CBu(t)Cl)PdCl]2

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane N2-atmosphere; addn. of 2 equiv. of pentyne derivative to Pd-complex soln. (ice-water bath), addn. of 1 equiv. PPh3 soln. (pptn.); filtration off of PPh3-complex, evapn. to dryness (0°C, reduced pressure), washing (light petroleum), drying in air; elem. anal.;A n/a
B 72%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

trans-[(1,2-dipiperidinoacetylene)RuCl(PPh3)2]Cl*THF

trans-[(1,2-dipiperidinoacetylene)RuCl(PPh3)2]Cl*THF

acetonitrile
75-05-8

acetonitrile

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[(CH3CN)2(Cl)((C6H5)3P)Ru(Cl)(C(NC5H10)C(NC5H10))PdCl2]*3CH3CN

[(CH3CN)2(Cl)((C6H5)3P)Ru(Cl)(C(NC5H10)C(NC5H10))PdCl2]*3CH3CN

Conditions
ConditionsYield
In dichloromethane (Ar); Pd complex added to a soln. of Ru complex, stirred for 1 h; stirred at 0°C for 30 min, filtered, concd. (vac.), MeCN added, crystd. at -30°C for 2 d, filtered, washed (cold MeCN), dried (vac.); elem. anal.;A n/a
B 70%
((C6H5)3P)2ClIr(C5H4NC4H2N2C5H4N)(NO)PdCl(2+)*2PF6(1-)=(((C6H5)3P)2ClIr(C5H4NC4H2N2C5H4N)(NO)PdCl)(PF6)2

((C6H5)3P)2ClIr(C5H4NC4H2N2C5H4N)(NO)PdCl(2+)*2PF6(1-)=(((C6H5)3P)2ClIr(C5H4NC4H2N2C5H4N)(NO)PdCl)(PF6)2

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

{bis(triphenylphosphine)nitrosyl(3,6-bis(2'-pyridyl)pyridazine)iridium} bis(hexafluorophosphat)

{bis(triphenylphosphine)nitrosyl(3,6-bis(2'-pyridyl)pyridazine)iridium} bis(hexafluorophosphat)

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane under N2, PPh3 was added to soln. of Ir-Pd-complex in CH2Cl2 (molar ratio 2.4:1), stirred at room temp. for 3 h; ppt. filtered off, dried under vac. (Pd-product), filtrate evapd. slowly at reduced pressure, filtered, dried under vac.;A 68%
B >99
benzylidene dichloride
98-87-3

benzylidene dichloride

tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In benzene byproducts: (E)-stilbene, 1,2-dichloro-1,2-diphenylethane; to soln. of Pd(PPh3)4 in benzene added PhCHCl2 under N2, stirred at room temp. for 5 h; dild. with pentanes, crystals filtered, washed with ether, dried in vac.; GLC anal.;64%
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

n-Butyl nitrite
544-16-1

n-Butyl nitrite

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

PdCl2COOC4H9P(C6H5)3NO

PdCl2COOC4H9P(C6H5)3NO

Conditions
ConditionsYield
With carbon monoxide; triphenylphosphine In neat (no solvent) stirring (1 h), bubbling of CO; filtn., pptn. on addn. of pentane; elem.anal.;A 40%
B 60%
((C5H5)Ru(C5H3C(C6H5)NC6H4CH3))2Pd2Cl2
668492-41-9

((C5H5)Ru(C5H3C(C6H5)NC6H4CH3))2Pd2Cl2

triphenylphosphine
603-35-0

triphenylphosphine

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

(C5H5)Ru(C5H3C(C6H5)NC6H4CH3)PdCl(P(C6H5)3)
212792-30-8

(C5H5)Ru(C5H3C(C6H5)NC6H4CH3)PdCl(P(C6H5)3)

Conditions
ConditionsYield
In benzene room temp.; filtn., pptn. (hexane); elem. anal.;A n/a
B 57%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

p-methoxyphenylisocyanide
10349-38-9

p-methoxyphenylisocyanide

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[PdCl(C(NC6H4OCH3)CHNC6H4OCH3)(P(C6H5)3)2]

[PdCl(C(NC6H4OCH3)CHNC6H4OCH3)(P(C6H5)3)2]

Conditions
ConditionsYield
With HCl In ethanol; toluene CNC6H4OMe in PhMe added dropwise to stirred suspn. of Pd(PPh3)4 in PhMeunder N2, stirred for ca. 1 h, cooled to -70°C, 0.22 M HCl/EtOH in PhMe added dropwise during ca. 2 h, stirred at -70°C for 90 min, allowed to warm to room temp. (3 h); ppt. filtered off, soln. concd., pptd. with Et2O, redissolved in (CH2Cl)2/Et2O, treated with activated charcoal, filtered, concd., pptd. by addn. of Et2O; elem. anal.;A n/a
B 55%
With HCl In ethanol; toluene 0.26 M ethanolic soln. of HCl added dropwise (30 min) to stirred suspn.of Pd(PPh3)4 in toluene at -70°C under N2, soln. of isocyanide in toluene added dropwise during ca. 10 min, allowed to warm to room temp. (ca. 2 h); concd., Et2O added, sepd. by fractional pptn. from (CH2Cl)2/Et2O; elem.anal.;A n/a
B 16%
cis-(PPh3)2 bis(azido)palladium(II)
14552-67-1, 24689-02-9, 34275-32-6

cis-(PPh3)2 bis(azido)palladium(II)

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Conditions
ConditionsYield
In chloroform byproducts: N2; Irradiation (UV/VIS); flash photolysis; not isolated; UV/VIS monitoring;53%
sodium tetrachloropalladate

sodium tetrachloropalladate

[Fe((η(5)-C5H4)C(CH3)=NC6H5)2]

[Fe((η(5)-C5H4)C(CH3)=NC6H5)2]

triphenylphosphine
603-35-0

triphenylphosphine

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[Fe((η(5)-C5H3)C(CH3)=NC6H5)]2Cl2(PPh3)2
185226-36-2, 185065-98-9

[Fe((η(5)-C5H3)C(CH3)=NC6H5)]2Cl2(PPh3)2

Conditions
ConditionsYield
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.;A n/a
B 52%
sodium tetrachloropalladate

sodium tetrachloropalladate

1,1’-bis[1-(4-methylphenylimino)ethyl]ferrocene

1,1’-bis[1-(4-methylphenylimino)ethyl]ferrocene

triphenylphosphine
603-35-0

triphenylphosphine

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[Pd([(η-(5)-C5H3)C(CH3)=NC6H5]Fe[(η(5)-C5H4)C(CH3)=NC6H5])ClPPh3]

[Pd([(η-(5)-C5H3)C(CH3)=NC6H5]Fe[(η(5)-C5H4)C(CH3)=NC6H5])ClPPh3]

d,l-[Fe((η(5)-C5H3)C(CH3)=NC6H4-4-CH3)]2Cl2(PPh3)2
223565-59-1, 185065-97-8

d,l-[Fe((η(5)-C5H3)C(CH3)=NC6H4-4-CH3)]2Cl2(PPh3)2

Conditions
ConditionsYield
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.;A n/a
B 8%
C 46%
2-(4-nitrophenyl)ethylamine monohydrochloride
29968-78-3

2-(4-nitrophenyl)ethylamine monohydrochloride

palladium diacetate
3375-31-3

palladium diacetate

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[Pd(C6H3(CH2)2NH2-2-NO2-5-κ2C,N)Cl(PPh3)]
643734-74-1

[Pd(C6H3(CH2)2NH2-2-NO2-5-κ2C,N)Cl(PPh3)]

Conditions
ConditionsYield
In acetonitrile Pd(OAc)2 and 4-nitrophenethylamine*HCl in MeCN were refluxed for 16 h, suspn. was filtered through MgSO4, solvent was removed, CH2Cl2 was added,PPh3 was added and stirred for 30 min; soln. was filtered through MgSO4 and concd., ppt. was filtered off, Et2O/n-hexane (1:1) was added to filtrate, ppt. was filtered, washed with n-hexane, and air-dried; elem. anal.;A 30%
B 37%
{Pd(CHCHCOOCH3)(P(C6H5)3)2(Cl)}

{Pd(CHCHCOOCH3)(P(C6H5)3)2(Cl)}

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

{Pd(CH(COOCH3)CH(P(C6H5)3))(P(C6H5)3)(Cl)}

{Pd(CH(COOCH3)CH(P(C6H5)3))(P(C6H5)3)(Cl)}

Conditions
ConditionsYield
In benzene complex heated in C6H6 at 75°C for 15 min; (Ar); hexane added at room temp., ppt. filtered off, extd. (CH2Cl2); extract treated with hexane, ppt. reprecipitated (hexane from CH2Cl2, twice), washed (pentane), dried (vac.); elem. anal.;A n/a
B 35%
((C5H5)Ru(C5H3C(CH3)NC6H4CH3))2Pd2Cl2

((C5H5)Ru(C5H3C(CH3)NC6H4CH3))2Pd2Cl2

triphenylphosphine
603-35-0

triphenylphosphine

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

(C5H5)Ru(C5H3C(CH3)NC6H4CH3)PdCl(P(C6H5)3)
212792-29-5

(C5H5)Ru(C5H3C(CH3)NC6H4CH3)PdCl(P(C6H5)3)

Conditions
ConditionsYield
In benzene room temp.; filtn., pptn. (hexane); elem. anal.;A n/a
B 34%
tetrakis(triphenylphosphine) palladium(0)
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

(C5H5)Rh(OC6H4(CH3)(CCl3))
186821-00-1

(C5H5)Rh(OC6H4(CH3)(CCl3))

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

B

(C5H5)Rh(OC7H4(CH3)Cl)
212378-76-2

(C5H5)Rh(OC7H4(CH3)Cl)

Conditions
ConditionsYield
In benzene byproducts: Ph3P; stirring (20°C, 72 h); concn., chromy. (SiO2, C6H5/EtOH), recry;A n/a
B 34%
sodium tetrachloropalladate

sodium tetrachloropalladate

1,1'-ferocene-bis-(carbaldehyde-N-benzylimine)

1,1'-ferocene-bis-(carbaldehyde-N-benzylimine)

triphenylphosphine
603-35-0

triphenylphosphine

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[Pd([(η-(5)-C5H3)C(H)=NCH2C6H5]Fe[(η(5)-C5H4)C(H)=NCH2C6H5])ClPPh3]
223537-68-6

[Pd([(η-(5)-C5H3)C(H)=NCH2C6H5]Fe[(η(5)-C5H4)C(H)=NCH2C6H5])ClPPh3]

[Fe((η(5)-C5H3)CH=NCH2C6H5)]2Cl2(PPh3)2
223565-58-0, 223537-59-5

[Fe((η(5)-C5H3)CH=NCH2C6H5)]2Cl2(PPh3)2

Conditions
ConditionsYield
With Na(CH3COO) * 3 H2O In methanol; benzene stirring (room temp., 2 d, dark), filtering, washing (MeOH), air-drying,PPh3 soln. (C6H6) addn., stirring (room temp., 3 h); filtering, evapn., extg. (CH2Cl2), filtering, chromy. (SiO2, CH2Cl2), concg.; elem. anal.;A n/a
B 7%
C 32%
sodium tetrachloropalladate(II)

sodium tetrachloropalladate(II)

[Fe(η(5)-C5H5)(η(5)-C5H4CH2CH2N=CH(C6H3Cl2-2,6))]

[Fe(η(5)-C5H5)(η(5)-C5H4CH2CH2N=CH(C6H3Cl2-2,6))]

A

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[Pd((η(5)-C5H5)Fe[η(5)-C5H3CH2CH2N=CHC6H3Cl2-2,6])Cl(PPh3)]

[Pd((η(5)-C5H5)Fe[η(5)-C5H3CH2CH2N=CHC6H3Cl2-2,6])Cl(PPh3)]

C

[Pd(3-ClC6H3CH=NCH2CH2C5H4Fe(η(5)-C5H5))Cl(PPh3)2]

[Pd(3-ClC6H3CH=NCH2CH2C5H4Fe(η(5)-C5H5))Cl(PPh3)2]

Conditions
ConditionsYield
With CH3CO2Na*3H2O; triphenylphosphine In methanol stirring equimolar amts. of Na2PdCl4, ferrocene derivative and AcONa inMeOH for 3 h (room temp., protection from light; pptn.), collection (filtration), washing (MeOH), suspending in C6H6, stirring with excess of PPh3 for 30 min; filtration, evapn. of filtrate (reduced pressure), dissoln. in CHCl3, chromy. (SiO2, CHCl3), evapn. (reduced pressure), treatment with hexane (pptn.); elem. anal.;A n/a
B 5%
C 15%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

PdCl[1,3-bis(diphenylthiophosphinoyl)indene(-1H)]
1133953-50-0

PdCl[1,3-bis(diphenylthiophosphinoyl)indene(-1H)]

[PdCl[Ind(Ph2PS)2]]PdCl(PPh3)
1310823-90-5

[PdCl[Ind(Ph2PS)2]]PdCl(PPh3)

Conditions
ConditionsYield
With polysterene-supported diisopropylethylamine In dichloromethane (under Ar, Schlenk); suspn. of Pd-complexes and polysterene-supported diisopropylethylamine in CH2Cl2 stirred overnight at room temp.; filtered, pentane added, filtered, washed with pentane, dried under vac.; elem. anal.;98%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl cinnamate
103-26-4

methyl cinnamate

Conditions
ConditionsYield
With sodium acetate; silver trifluoroacetate In acetonitrile at 60℃; for 24h; Heck Reaction; Schlenk technique; Inert atmosphere;98%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

acetophenone dimethylhydrazone
13466-32-5

acetophenone dimethylhydrazone

((C6H5)3P)PdCl((C6H5)C(CH2)NN(CH3)2)

((C6H5)3P)PdCl((C6H5)C(CH2)NN(CH3)2)

Conditions
ConditionsYield
With NaOCOCH3 In acetonitrile mixt. of freshly distilled hydrazone, Pd(PPh3)2Cl2 and NaOAc in MeCN is heated at 75°C for 48 h under Ar, mixt. is cooled to room temp.; solvent is evapd., chromy. (hexane-EtOAc 4:1); elem. anal.;97%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

triphenylphosphine
603-35-0

triphenylphosphine

lithium bromide
7550-35-8

lithium bromide

bis(triphenylphosphine)palladium dibromide
25044-96-6, 23523-33-3, 22180-53-6

bis(triphenylphosphine)palladium dibromide

Conditions
ConditionsYield
In chloroform; isopropyl alcohol at 20℃; for 2h;96%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

sym-bis(2-pyridyl)tetraphenylcarbodiphosphorane

sym-bis(2-pyridyl)tetraphenylcarbodiphosphorane

[(CDPPy2)PdCl]Cl

[(CDPPy2)PdCl]Cl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Schlenk technique;96%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

methyl magnesium iodide
917-64-6

methyl magnesium iodide

9-iodo-m-carborane
17157-02-7

9-iodo-m-carborane

9,10-dimethyl-1,7-carborane
92528-35-3

9,10-dimethyl-1,7-carborane

Conditions
ConditionsYield
In diethyl ether refluxed for 5-15 h under nitrogen; monitored by tlc; decomposed with water;; washed with dilute HCl and with water; dried over Na2SO4; chromd. on silica gel with petroleum ether eluent; distilled in vac.; sublimed in vac. at 30-60°C; recrystd. from pentane; elem. anal.;;95%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[((C6H5)3P)3(P(C6H5)2)2Pd3Cl](1+)*Cl(1-)=[(P(C6H5)3)3(P(C6H5)2)2Pd3Cl]Cl

[((C6H5)3P)3(P(C6H5)2)2Pd3Cl](1+)*Cl(1-)=[(P(C6H5)3)3(P(C6H5)2)2Pd3Cl]Cl

Conditions
ConditionsYield
With H2 In further solvent(s) complex soln. in aniline stirred under H2 at 90°C; aniline removed (vac.), ppt. washed (Et2O and C6H6), C6H6 filtrate concd. (vac.), pptd. (hexane under Ar), washed with hexane and Et2O, dried (vac.), recrystd. (toluene under Ar); elem. anal.;95%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

1-(azidomethyl)-2-isocyanobenzene
496963-67-8

1-(azidomethyl)-2-isocyanobenzene

trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate
676491-68-2

trans-chlorobis(triphenylphosphine)(2-(azidomethyl)phenylisocyanido)palladium tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane; acetone byproducts: AgCl; under N2; 1 M soln. of AgBF4 in acetone added to a suspn. of Pd-complex in CH2Cl2 at room temp., stirred for 30 min., AgCl filtered off, filtrate treated with isonitrile, stirred for 2.5 h; Et2O added, ppt. filtered off, dried under vac.; elem. anal.;94.3%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

ammonium hexafluorophosphate

ammonium hexafluorophosphate

tetraphenylimidothioxodiphosphinic acid potassium salt
17162-84-4

tetraphenylimidothioxodiphosphinic acid potassium salt

Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)]PF6
220171-77-7

Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(S)(C6H5)2)]PF6

Conditions
ConditionsYield
In methanol elem. anal.;94%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

ammonium hexafluorophosphate

ammonium hexafluorophosphate

K[(OPPh2)(SePPh2)N]

K[(OPPh2)(SePPh2)N]

Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)]PF6
220171-80-2

Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)(1+)*PF6(1-)=[Pd(P(C6H5)3)2(N(P(O)(C6H5)2)P(Se)(C6H5)2)]PF6

Conditions
ConditionsYield
In methanol elem. anal.;94%
carbon disulfide
75-15-0

carbon disulfide

bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

[Ru(bis(diphenylphosphino)methane)2(S2CNC4H8NH2)](BF4)2

[Ru(bis(diphenylphosphino)methane)2(S2CNC4H8NH2)](BF4)2

[(dppm)2Ru(S2CNC4H8NCS2)Pd(PPh3)2](BF4)2

[(dppm)2Ru(S2CNC4H8NCS2)Pd(PPh3)2](BF4)2

Conditions
ConditionsYield
In not given Ru complex was treated with CS2 under basic conditions followed by addn.Pd complex;94%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

C16H17N3O4
116324-89-1

C16H17N3O4

[Pd(P(C6H5)3)(OC(C6H4OCH3)NNCHC5HN(CH2OH)(CH3)O)]

[Pd(P(C6H5)3)(OC(C6H4OCH3)NNCHC5HN(CH2OH)(CH3)O)]

Conditions
ConditionsYield
With triethylamine In methanol mixt. of Pd complex, OC(C6H4OCH3)NHNCHC5HN(CH2OH)(CH3)(OH) (1 equiv.) and triethylamine stirred and heted at reflux for 3 h; ppt. washed with MeOH, ether, dried in vac., crystd. from CHCl3/MeOH at room temp.; elem. anal.;94%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

5-hexyl-1-ol
928-90-5

5-hexyl-1-ol

(S)-methyl 5-amino-4-(4-bromo-1-oxoisoindolin-2-yl)-5-oxopentanoate

(S)-methyl 5-amino-4-(4-bromo-1-oxoisoindolin-2-yl)-5-oxopentanoate

(S)-methyl 5-amino-4-(4-(6-hydroxyhex-1-yn-1-yl)-1-oxoisoindolin-2-yl)-5-oxopentanoate

(S)-methyl 5-amino-4-(4-(6-hydroxyhex-1-yn-1-yl)-1-oxoisoindolin-2-yl)-5-oxopentanoate

Conditions
ConditionsYield
Stage #1: 5-hexyl-1-ol; (S)-methyl 5-amino-4-(4-bromo-1-oxoisoindolin-2-yl)-5-oxopentanoate With copper(l) iodide; triethylamine In N,N-dimethyl-formamide Inert atmosphere;
Stage #2: bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 80℃; Sealed tube;
94%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

3,5-bis[(dimethylamino)methyl]phenyl iodide

3,5-bis[(dimethylamino)methyl]phenyl iodide

trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide
267231-63-0

trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide

Conditions
ConditionsYield
With CuI; 3,5-bis[(dimethylamino)methyl]phenylacetylene In diethylamine byproducts: (3,5-(Me2NCH2)2C6H3)2C2; (N2); 6 d at room temp.; evapd. (vac.), dissolved in Et2O/Et2NH, filtered, evapd. (vac.), crystd. in pentane; elem. anal.;93%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

(CH3C5H4)2Cr2(μSCMe3)2(μ-S)

(CH3C5H4)2Cr2(μSCMe3)2(μ-S)

(CH3C5H4CrCl)2S(SC(CH3)3)2PdP(C6H5)3*C6H6

(CH3C5H4CrCl)2S(SC(CH3)3)2PdP(C6H5)3*C6H6

Conditions
ConditionsYield
In benzene a soln. of Pd-complex was added to a soln. of Cr-complex under Ar; evapn. at 80°C/10 Torr; extrn. with benzene-heptane 1:1; crystn.at -10°C;92.9%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium

dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium

(C5H5CrCl)2S(SC(CH3)3)2PdP(C6H5)3

(C5H5CrCl)2S(SC(CH3)3)2PdP(C6H5)3

Conditions
ConditionsYield
In benzene a soln. of Pd-complex was added to a soln. of Cr-complex under Ar; evapn. at 80°C/10 Torr; extrn. with benzene-heptane 1:1; crystn.at -10°C; elem. anal;92.6%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

Fe2(CO)6(μ-S)2(2-)

Fe2(CO)6(μ-S)2(2-)

{μ-(Ph3P)2PdS2}Fe2(CO)6
75249-92-2

{μ-(Ph3P)2PdS2}Fe2(CO)6

Conditions
ConditionsYield
In not given92%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

(3-diphenylphosphino)propanethiol
109863-55-0

(3-diphenylphosphino)propanethiol

dichlorobis(μ-[(3-diphenylphosphino)propanethiolato]-P,μ-S)dipalladium(II)
247221-21-2

dichlorobis(μ-[(3-diphenylphosphino)propanethiolato]-P,μ-S)dipalladium(II)

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; equimolar amts., 30 min; concn. (vac.) hexane addn. crystn. (-24°C, 12 h), collection (filtration), washing (hexane), drying;92%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

N-phenylmethyl-2-pyridinecarbothioamide
52379-37-0

N-phenylmethyl-2-pyridinecarbothioamide

Pd(Cl)(κ2-S,N-C6H4CS-N-(4-Bz)(PPh3))
1612222-05-5

Pd(Cl)(κ2-S,N-C6H4CS-N-(4-Bz)(PPh3))

Conditions
ConditionsYield
In ethanol at 80℃; for 3h;92%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

(E)-2-((4-oxo-4H-chromen-3-yl)methylene)-N-phenylhydrazinecarbothioamide

(E)-2-((4-oxo-4H-chromen-3-yl)methylene)-N-phenylhydrazinecarbothioamide

C35H27ClN3O2PPdS

C35H27ClN3O2PPdS

Conditions
ConditionsYield
In methanol at 20℃;92%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

{Pd(P(C6H5)3)2(BF4)2}
130759-89-6

{Pd(P(C6H5)3)2(BF4)2}

Conditions
ConditionsYield
In nitromethane byproducts: AgCl; stirring mixt. of Pd complex and AgBF4 in CH3NO2 at room temp. for 2 d, under anaerobic conditions;; filtration; removal of solvent in vac.; dissolving in CH2Cl2; evapn. to dryness; repptn. with CH2Cl2/(C2H5)2O/pentane; washing with pentane; drying in vac.; elem. anal.;;91%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

N-methyl N'-cyanoisothiourea sodium salt
67944-71-2

N-methyl N'-cyanoisothiourea sodium salt

Pd(SCNHCNNCH3)2(P(C6H5)3)2
375368-48-2

Pd(SCNHCNNCH3)2(P(C6H5)3)2

Conditions
ConditionsYield
In methanol; water to suspn. of Pd-complex in MeOH was added ligand in MeOH, stirred for 24h at room temp.; filtered, washed with water, dried in vacuo; elem. anal.;91%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

N-(4-methyl-phenyl)-α-thiopicolinamide
21259-34-7

N-(4-methyl-phenyl)-α-thiopicolinamide

[Pd(Cl)(κ2-S,N-C6H4CS=N-(4-MePh)(PPh3)]
1372812-01-5

[Pd(Cl)(κ2-S,N-C6H4CS=N-(4-MePh)(PPh3)]

Conditions
ConditionsYield
In ethanol to soln. ligand in EtOH Pd complex was added and heated under reflux for3 h; react. mixt. was cooled to room temp., ppt. was filtered, washed with EtOH and dried in vacuo; elem. anal.;91%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

C26H20IN4

C26H20IN4

C44H35N4P(1+)

C44H35N4P(1+)

Conditions
ConditionsYield
In tetrahydrofuran at 65℃; for 2h; Inert atmosphere;91%
bis-triphenylphosphine-palladium(II) chloride
13965-03-2

bis-triphenylphosphine-palladium(II) chloride

palladium dichloride

palladium dichloride

bis(triphenylphosphine)dichloro-μ,.mu'.-dichlorodipalladium(II)

bis(triphenylphosphine)dichloro-μ,.mu'.-dichlorodipalladium(II)

Conditions
ConditionsYield
In acetone stoichiometric amts., refluxing (2 h), pptn.;90%
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