Xi'an Xszo Chem Co., Ltd.
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:1066-45-1
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryDayang Chem (Hangzhou) Co.,Ltd.
Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:1066-45-1
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryZhuozhou Wenxi import and Export Co., Ltd
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:1066-45-1
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryWuhan Han Sheng New Material Technology Co.，Ltd
Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:1066-45-1
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryHebei Nengqian Chemical Import and Export Co., LTD
Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:1066-45-1
Min.Order:1 Kilogram
FOB Price: $9.0 / 99.0
Type:Trading Company
inquiryShanghai Upbio Tech Co.,Ltd
1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:1066-45-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryQingdao Beluga Import and Export Co., LTD
TRIMETHYLTIN CHLORIDE CAS:1066-45-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte
Cas:1066-45-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryShandong Hanjiang Chemical Co., Ltd.
Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:1066-45-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHebei Quanhe Biotechnology Co. LTD
1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s
Cas:1066-45-1
Min.Order:1 Kilogram
FOB Price: $10.0 / 100.0
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co., Ltd.
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:1066-45-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryHangzhou J&H Chemical Co., Ltd.
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:1066-45-1
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryAlity Chemical Corporation
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
Shanghai Minstar Chemical Co., Ltd
TRIMETHYLTIN CHLORIDE Basic information Product Name: TRIMETHYLTIN CHLORIDE Synonyms: TriMethyltin chloride solution 1.0 M in hexanes;TriMethyltin chloride solution 1.0 M in THF;TriMethyltin chloride, 1.0 M solution in Hexanes, SpcSeal;Trimet
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Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryEAST CHEMSOURCES LIMITED
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:1066-45-1
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD
Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:1066-45-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHangzhou Huarong Pharm Co., Ltd.
Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
KAISA GROUP INC
1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:1066-45-1
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquiryHunan chemfish Pharmaceutical co.,Ltd
Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
Bluecrystal chem-union
We are a Union of chemistry in China, consists of chemists，engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:1066-45-1
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiryGIHI CHEMICALS CO.,LIMITED
Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
Kono Chem Co.,Ltd
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Shanghai Acmec Biochemical Technology Co., Ltd.
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:1066-45-1
Min.Order:1 bottle
Negotiable
Type:Lab/Research institutions
inquiryHenan Allgreen Chemical Co.,Ltd
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Xi`an Eastling Biotech Co., Ltd.
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou
Antimex Chemical Limied
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Cas:1066-45-1
Min.Order:0
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Type:Lab/Research institutions
inquiryHunan Russell Chemicals Technology Co.,Ltd
low price and high purity Application:ALD related industries,medicine and electronic materials
HANGZHOU TIANYE CHEMICALS CO., LTD.
We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate
Hubei Langyou International Trading Co., Ltd
TIANFUCHEM--1066-45-1---TRIMETHYLTIN CHLORIDE Application:TIANFUCHEM--1066-45-1---TRIMETHYLTIN CHLORIDE
Cas:1066-45-1
Min.Order:0
Negotiable
Type:Other
inquiryBOC Sciences
We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use
Synthetic route
| Conditions | Yield |
|---|---|
| With tin(IV) chloride at -20 - 60℃; for 16h; Inert atmosphere; | 100% |
| With hydrogenchloride In chloroform 4h boiling, under inflow of gaseous HCl; | 70% |
| With HCl In chloroform 4h boiling, under inflow of gaseous HCl; | 70% |
-
-
87293-07-0
trimethyl(dimesylamino)stannane
-
-
98-88-4
benzoyl chloride
-
A
-
1066-45-1
trimethyltin(IV)chloride
-
B
-
120622-90-4
N,N-bis(methanesulfonyl)benzamide
| Conditions | Yield |
|---|---|
| In dichloromethane reflux for 48 h; evapn. of solvent, pptn. of N-benzoyldimesylamine, isolation of (CH3)3SnCl from filtrate; | A 100% B n/a |
-
-
87293-07-0
trimethyl(dimesylamino)stannane
-
-
98-88-4
benzoyl chloride
-
A
-
1066-45-1
trimethyltin(IV)chloride
-
B
-
120622-90-4
N,N-bis(methanesulfonyl)benzamide
| Conditions | Yield |
|---|---|
| In dichloromethane reflux for 48 h; evapn. of solvent, pptn. of N-benzoyldimesylamine, isolation of (CH3)3SnCl from filtrate; | A 100% B n/a |
| Conditions | Yield |
|---|---|
| With triphenylphosphine In ethanol; acetone byproducts: Ni, triphenylphosphonium sulfide; dropwise addn. of an ethanolic soln. of NiCl2*6H2O to a stirred soln. of ((CH3)3Sn)2S and triphenylphosphine in acetone; refluxing;; filtration;; | 100% |
| Conditions | Yield |
|---|---|
| stirring overnight at 60°F, N2-atmosphere; distd. at 15 Torr; | 99% |
| molar ratio of (CH3)4Sn:SnCl4=3:1; distn.; | |
| In neat (no solvent) react. Me4Sn with SnCl4 (3:1) at 130°C for 2 h; recrystn. from hexane; |
-
-
594-27-4
tetramethylstannane
-
-
1124-19-2
phenyltin trichloride
-
A
-
1066-45-1
trimethyltin(IV)chloride
-
B
-
15649-26-0
methylphenyltin(IV) dichloride
| Conditions | Yield |
|---|---|
| equimolar amts. of educts, 0°C, 1.5h; | A 99% B 85% |
| equimolar amts. of educts, 0°C, 1.5h; | A 99% B 85% |
| Conditions | Yield |
|---|---|
| In benzene-d6 byproducts: germanium-contg. polymer; (Ar); stirring (20°C, 2 d); | 99% |
| Conditions | Yield |
|---|---|
| In water; acetone dropwise addn. of an aq. soln. of NiCl2*6H2O to a stirred soln. of ((CH3)3Sn)2S in acetone at room temp.; refluxing for 5 h;; filtration;; | A 90% B 99% |
-
-
13894-35-4
O,O-dimethylphosphorylsulfenyl chloride
-
-
762-73-2
trimethyl(allyl)stannane
-
A
-
66498-87-1
S-allyl O,O-dimethyl phosphorothioate
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In tetrachloromethane from -15 deg C to RT; | A 97% B n/a |
| In tetrachloromethane addn. of soln. of sulfenyl chloride to soln. of stannane in CCl4 with cooling (-15°C) and stirring, warming to room temp.; solvent removed, distilln., (1)H-NMR; | A 97% B n/a |
-
-
940-00-1
(4-methoxyphenyl)trimethylstannane
-
-
93-61-8
N-methyl-N-phenylformamide
-
A
-
1066-45-1
trimethyltin(IV)chloride
-
B
-
123-11-5
4-methoxy-benzaldehyde
| Conditions | Yield |
|---|---|
| With trichlorophosphate at 50 - 70℃; for 3h; | A n/a B 96% |
-
-
594-27-4
tetramethylstannane
-
-
15649-24-8
butyl-methyl-tin dichloride
-
A
-
1066-45-1
trimethyltin(IV)chloride
-
B
-
15649-31-7
butyl-dimethyl-tin chloride
| Conditions | Yield |
|---|---|
| 3h, 75 to 85°C; | A 96% B 91% |
| 3h, 75 to 85°C; | A 96% B 91% |
-
-
14264-16-5, 53996-95-5, 62075-39-2, 39716-73-9
bis(triphenylphosphine)nickel(II) chloride
-
-
1070-91-3
bis(trimethyltin) sulfide
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In ethanol byproducts: Ni, triphenylphosphonium sulfide, triphenylphosphine; a mixt. of ((CH3)3Sn)2S and ((C6H5)3P)2NiCl2 in ethanol was heated at 95-100°C for 10 h;; distn.;; | 95% |
-
-
16812-43-4
bis(trimethylstannyl)methane
-
-
753-73-1
dimethyltin dichloride
-
A
-
83135-39-1
bis(chlorodimethylstannyl)methane
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) heated at 60°C for 12 h; distd. (12-15 Torr), recrystd. (C6H6); elem. anal.; | A 95% B n/a |
-
-
83135-43-7
2,2-bis(trimethylstannyl)propane
-
-
753-73-1
dimethyltin dichloride
-
A
-
83135-44-8
2,2-bis(chlorodimethylstannyl)propane
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) 2,2-bis(trimethylstannyl)propane placed in flash with 2 mol of dimethyldichlorostannane, heated at 60°C overnight; stirred at 15-20 Torr, warmed at 0.01 Torr to 100°C, recrystd. (CCl4); elem. anal.; | A 95% B n/a |
-
-
85294-03-7
3,3-bis(trimethylstannyl)propyl ethyl sulfoxide
-
-
753-73-1
dimethyltin dichloride
-
-
91230-55-6
3,3-bis(chlorodimethylstannyl)propyl ethyl sulfoxide
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In dichloromethane mixt. of the sulfoxide (6.7 mmol) and SnMe2Cl2 (13.5 mmol) in CH2Cl2 refluxed for 12 h; solvent removed (rotary evaporator); SnMe3Cl removed (0.01 torr, 60 °C); recrystn. (CCl4/hexane); elem. anal.; mol. wt. calc.: 486.6; mol. wt. found: 506.6 (isopiestic in CH2Cl2 at 22 °C); | A 95% B n/a |
-
-
75-77-4
chloro-trimethyl-silane
-
-
19097-32-6
trimethyl(trifluoro-1-propynyl)stanane
-
A
-
6618-09-3
1,1,1-trifluoro-3-trimethylsilyl-2-propyne
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In N,N,N,N,N,N-hexamethylphosphoric triamide mixt. heating (80°C, 0.5 h); Si-compd. isolation (vac. distn., elem. anal., IR and NMR spectroscopy); | A 92% B n/a |
-
-
19429-30-2
di-tert-butyltin dichloride
-
-
1068-70-8
tris(trimethylstannyl)amine
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In dichloromethane (inert atmosphere); stirring (-78°C to room temp.); removal of CH2Cl2 and trapping Me3SnCl at -78°C by applying high vacuum, NMR monitoring; | A 0% B 92% |
-
-
594-27-4
tetramethylstannane
-
-
15649-29-3
Ethylbutylzinndichlorid
-
A
-
1066-45-1
trimethyltin(IV)chloride
-
B
-
15649-32-8
n-Butyl-ethylmethyl-zinnchlorid
| Conditions | Yield |
|---|---|
| 4h, 120 to 130°C; | A 91% B 76% |
| 4h, 120 to 130°C; | A 91% B 76% |
-
-
1529-50-6
trimethylphenoxystannane
-
-
124-63-0
methanesulfonyl chloride
-
A
-
16156-59-5
phenyl methanesulfonate
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In tetrachloromethane Kinetics; Me3SnOPh refluxed for 5 h with MeSO2Cl in CCl4 / kinetics measured at 120-150°C; Me3SnCl not isolated; detected by NMR; | A 91% B n/a |
| In further solvent(s) Kinetics; educts dissolved in CH2Br2, sealed in glass tube, heated at 120-140°C; NMR anal.; | |
| In dichloromethane Kinetics; educts dissolved in CH2Cl2, sealed in glass tube, heated at 130-160°C; NMR anal.; | |
| In benzonitrile Kinetics; educts dissolved in PhCN, sealed in glass tube, heated at 120-140°C; NMR anal.; | |
| In acetonitrile Kinetics; educts dissolved in MeCN, sealed in glass tube, heated at 100-130°C; NMR anal.; |
-
-
13894-35-4
O,O-dimethylphosphorylsulfenyl chloride
-
-
64268-27-5
p-vinylbenzyltrimethylstannane
-
A
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In diethyl ether addn. of P-compound in soln. to stirred soln. of stannane at -50-70°C; solvent removed, (CH3)3SnCl isolated, extn. with ether (5 times), solvent removed; elem. anal.; | A 91% B 87% |
| In chloroform addn. of P-compound in soln. to stirred soln. of stannane at -20-30°C over 0.5h; solvent removed, (CH3)3SnCl isolated, chromy. (silica gel, Rf 0.07, benzene:acetone 4:1); elem. anal.; | A 48% B 35% |
| In tetrachloromethane soln. of equimolar amts. of starting materials mixed at -20 and 20°C; not isolated, detd. by H-NMR; | |
| In benzene-d6 soln. of equimolar amts. of starting materials or with stannane to sulfenyl ratio of 2:1 mixed at 10°C; not isolated, detd. by H-NMR; |
-
-
16035-50-0
trimethyl(trimethylstannanylethynyl)silane
-
A
-
4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| With iron(III) chloride In tetrachloromethane; toluene at 25℃; for 1.5h; | A 90% B 90% |
| With iron(III) chloride In tetrachloromethane; cyclohexane byproducts: FeCl2; at 25°C for 1.5 h; | A 90% B n/a |
-
-
7647-01-0
hydrogenchloride
-
-
87293-07-0
trimethyl(dimesylamino)stannane
-
A
-
5347-82-0
dimesylamine
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In dichloromethane stream of HCl for 3 h, stirring for 1 h at 20°C; pptn. of dimesylamine, filtration, isolation of (CH3)3SnCl from filtrate; | A n/a B 90% |
-
-
7647-01-0
hydrogenchloride
-
-
87293-07-0
trimethyl(dimesylamino)stannane
-
A
-
5347-82-0
dimesylamine
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In dichloromethane stream of HCl for 3 h, stirring for 1 h at 20°C; pptn. of dimesylamine, filtration, isolation of (CH3)3SnCl from filtrate; | A n/a B 90% |
-
-
119895-84-0
SiF3SiHCl2
-
-
1631-73-8
trimethylstannane
-
A
-
15195-26-3
F3SiSiH3
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) Warming of starting materials (in absence of solvent, vac. line) for 30 min to room temp.; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene), IR and NMR identification of volatile resulting compd.; | A 90% B n/a |
| In neat (no solvent) Condensing of 1 equiv. of Si-compd. with 2 equiv. of Me3SnH at -196°C (vac. line, no solvent). React. is obsd. via F-NMR only after warming (0°C, 30 min), while at -10°C (25 min) no react. occurs.; After 1 h at 0°C peaks due to SiF3SiH2Cl and unreacted SiF3SiHCl2 disappear and Me3SnCl is removed by passing the mixt. through a trap cooled to -95°C (toluene).; | A 90% B n/a |
| Conditions | Yield |
|---|---|
| In dichloromethane stoichiometric ratio, stirring (8 h, room temp.); evapn. (vac.), washing (n-hexane, toluene), drying (vac.); elem. anal.; | A 89.5% B n/a |
| In toluene stoichiometric ratio, stirring (5 d, room temp.); filtn., evapn. (vac.), washing (n-hexane), drying (vac.); | A 86% B n/a |
-
-
97607-44-8
1-trimethylsilyl-2-phenyl-2-trimethylstannyl-ethene
-
A
-
156994-84-2
1-trimethylsilyl-2-phenyl-2-chloromercuri-ethene
-
B
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| With potassium fluoride In tetrahydrofuran Solid HgCl2 is added to a soln. of the ethene-compd. in THF at room temp. After 20 h stirring KF is added.; After filtn. and removal of the solvent the residue is sublimed at 80°C/10-E2 torr, giving a highly viscous oil; elem. anal.; | A 89% B n/a |
-
-
754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
-
-
34664-54-5
(3,3-dimethyl-1-butynyl)trimethylstannane
-
A
-
6130-98-9
2,2,7,7-tetramethyl-octa-3,5-diyne
-
B
-
1066-45-1
trimethyltin(IV)chloride
-
C
-
126260-37-5
5,5,6,6,7,7,7-heptafluoro-2,2-dimethyl-3-heptyne
-
D
-
811-73-4
trimethylstannyl iodide
| Conditions | Yield |
|---|---|
| tetrakis(triphenylphosphine) palladium(0) In 1,2-dichloro-ethane 100°C, 3 h, sealed glass ampul purged with argon; 0.5 M Me3SnCCBu-t, 1 M C3F7I, catalyst concn. 1 mol % of the amount of Me3SnCCBu-t; | A 2-3 B <=2 C 88% D n/a |
| bis-triphenylphosphine-palladium(II) chloride In 1,2-dichloro-ethane 100°C, 3 h, sealed glass ampul purged with argon; 0.5 M Me3SnCCBu-t, 1 M C3F7I, catalyst concn. 1 mol % of the amount of Me3SnCCBu-t; | A 2-3 B <=2 C 87% D n/a |
| bis(benzonitrile)palladium(II) dichloride In 1,2-dichloro-ethane 100°C, 3 h, sealed glass ampul purged with argon; 0.5 M Me3SnCCBu-t, 1 M C3F7I, catalyst concn. 1 mol % of the amount of Me3SnCCBu-t; | A 2-3 B <=2 C 70% D n/a |
| Conditions | Yield |
|---|---|
| In dichloromethane stoichiometric ratio, stirring (8 h, room temp.); evapn. (vac.), washing (n-hexane, toluene), drying (vac.); elem. anal.; | A 88% B n/a |
| In toluene stoichiometric ratio, stirring (5 d, room temp.); filtn., evapn. (vac.), washing (n-hexane), drying (vac.); | A 80% B n/a |
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
7440-23-5
sodium
-
-
17310-99-5
4-methoxy-N,N,N-trimethylbenzenaminium iodide
-
-
940-00-1
(4-methoxyphenyl)trimethylstannane
| Conditions | Yield |
|---|---|
| With methyl iodide In ammonia Irradiation (UV/VIS); condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, addn. of CH3OC6H4NMe3I; irradn. with stirring for30 min, quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether; | 100% |
| With para-dinitrobenzene; methyl iodide In ammonia Irradiation (UV/VIS); condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, addn. of p-dinitrobenzene and then addn. of CH3OC6H4NMe3I; irradn. with stirring for 30 min, quenching by addn. of MeI inexcess; evapn. of ammonia, treatment with water, extn. with ether; | 34% |
| With methyl iodide In ammonia condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, then addn. of CH3OC6H4NMe3I; holding in dark for 30 min; quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether; | 14% |
| With para-dinitrobenzene; methyl iodide In ammonia condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, addn. of p-dinitrobenzene and then addn. of CH3OC6H4NMe3I, holding in dark for 30 min, quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether; | 0% |
-
-
91-16-7
1,2-dimethoxybenzene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
134952-94-6
(2,3-dimethoxyphenyl)trimethylstannane
| Conditions | Yield |
|---|---|
| With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In diethyl ether; hexane BuLi in hexane added to stirred soln. of veratrole and TMEDA in Et2O at 0°C, warmed to 22°C, stirred 1h, cooled to -80°C, addn. of (CH3)3SnCl in Et2O, warmed to 22°C, after 90 min H2O was added, stirred (room temp. overnight); Et2O layer washed with water, dried (Na2SO4), filtered, concentrated under reduced pressure, distn. (Kugelrohr, 110°C, 0.04 mmHg); elem. anal.;; | 100% |
-
-
70600-14-5
1,5-dihydro-s-indacene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
106161-63-1
1-(trimethylstannyl)-1,5-dihydro-s-indacene
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran; hexane byproducts: LiCl; To a soln. of s-indacene in THF at -78°C n-BuLi in hexane was added, mixt. allowed to warm slowly to 5-10°C; this soln. was added to a soln. of Me3SnCl in hexane;; LiCl was filtered; solvent was removed in vac., oil was crystd. on standing; elem. anal.;; | 100% |
-
-
492-97-7
2,2'-Bithiophene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
143367-56-0
5,5'-bis(trimethylstannyl)-2,2'-bithiophene
| Conditions | Yield |
|---|---|
| Stage #1: 2,2'-Bithiophene With n-butyllithium In tetrahydrofuran; hexane at -40 - 25℃; for 2h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at -40 - 25℃; for 3h; | 100% |
| Stage #1: 2,2'-Bithiophene With n-butyllithium In tetrahydrofuran; hexane at -40 - 20℃; for 0.583333h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane Inert atmosphere; | 93% |
| Stage #1: 2,2'-Bithiophene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1.5h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at 20℃; for 1h; | 90% |
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
7440-23-5
sodium
-
-
17311-01-2
(4-cyanophenyl)trimethylammonium iodide
-
-
58666-77-6
(4-cyanophenyl)trimethylstannane
| Conditions | Yield |
|---|---|
| With methyl iodide In ammonia condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, then addn. of CNC6H4NMe3I; holding in dark for 0.08 h; quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether; | 100% |
| With methyl iodide In ammonia Irradiation (UV/VIS); condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, addn. of CNC6H4NMe3I; irradn. with stirring for 0.08 h, quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether; | 100% |
| With para-dinitrobenzene; methyl iodide In ammonia condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, addn. of p-dinitrobenzene and then addn. of CNC6H4NMe3I; holding in dark for 0.08 h; quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether; | 35% |
| Conditions | Yield |
|---|---|
| In water byproducts: KCl; | 100% |
-
-
6089-04-9
3-(tetrahydropyran-2'-yloxy)propyne
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
711029-24-2
2-(1-trimethylstannyl-3-propynyloxy) tetrahydropyran
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran; hexane (Ar); soln. of n-BuLi in hexane was added dropwise to soln. of alkyne inTHF at -78°C; mixt. was stirred at -78°C for 30 min; Sn c ompd. was added; mixt. was stirred for 30 min and slowly warmed from -78°C to -30°C; extd. (ether/H2O); aq. phase washed (ether); combined org. phase dried (MgSO4); filtered; concd.; | 100% |
-
-
17715-69-4
1-Bromo-2,4-dimethoxybenzene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
134952-91-3
(2,4-dimethoxyphenyl)trimethylstannane
| Conditions | Yield |
|---|---|
| With magnesium In tetrahydrofuran aryl halide added to stirred suspn. of Mg turnings in THF (under N2), heated at reflux for 90 min, cooled to room temp., addn. of (CH3)3SnCl, stirred at room temp. for 2h;; partitioned between Et2O and H2O, aq. phase extd. with Et2O, organic phase washed with H2O, dried (MgSO4), filtered, concentrated under reduced pressure, filtered through deep pad of silica (THF/hexane (1:19)); elem. anal.;; | 100% |
-
-
29150-63-8
benzo(1,2-b;3,4-b′;5,6-b′′)trithiophene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
1289556-30-4
2,5,8-tris(trimethylstannyl)benzo[1,2-b:3,4-b’:5,6-b’’]trithiophene
| Conditions | Yield |
|---|---|
| Stage #1: benzo(1,2-b;3,4-b′;5,6-b′′)trithiophene In tetrahydrofuran; hexane at 0 - 20℃; for 6h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at 20℃; Inert atmosphere; | 100% |
| Stage #1: benzo(1,2-b;3,4-b′;5,6-b′′)trithiophene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Schlenk technique; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere; Schlenk technique; | 94% |
| Stage #1: benzo(1,2-b;3,4-b′;5,6-b′′)trithiophene With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere; Reflux; | 82% |
| Stage #1: benzo(1,2-b;3,4-b′;5,6-b′′)trithiophene With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 6h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at 0℃; Inert atmosphere; | 75% |
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
165190-76-1
4,7-bis(thiophen-2-yl)-2,1,3-benzothiadiazole
-
-
1025451-57-3
4,7-bis(5-(trimethylstannyl)thiophene-2-yl)benzo[c][1,2,5]thiadiazole
| Conditions | Yield |
|---|---|
| Stage #1: 4,7-bis(thiophen-2-yl)-2,1,3-benzothiadiazole With 2,2,6,6-tetramethylpiperidinyl-lithium Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - 20℃; | 100% |
| Stage #1: 4,7-bis(thiophen-2-yl)-2,1,3-benzothiadiazole With 2,2,6,6-tetramethyl-piperidine; n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at -78 - 20℃; for 12h; | 89% |
| Stage #1: 4,7-bis(thiophen-2-yl)-2,1,3-benzothiadiazole With lithium diisopropyl amide In tetrahydrofuran at -78℃; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78℃; | 85% |
| Conditions | Yield |
|---|---|
| Stage #1: toluene With (-)-sparteine at -78℃; Stage #2: With n-butyllithium at -78 - 20℃; for 0.5h; Stage #3: trimethyltin(IV)chloride at -78℃; for 2h; | 100% |
| Conditions | Yield |
|---|---|
| Stage #1: C21H24O2S3 With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Schlenk technique; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere; | 100% |
-
-
4891-44-5
2-(2-ethylhexyl)thiophen
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
1429306-71-7
(5-(2-ethylhexyl)thiophen-2-yl)trimethylstannane
| Conditions | Yield |
|---|---|
| Stage #1: 2-(2-ethylhexyl)thiophen With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Schlenk technique; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - 20℃; Inert atmosphere; Schlenk technique; | 100% |
| Stage #1: 2-(2-ethylhexyl)thiophen With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1.5h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at 20℃; Inert atmosphere; | 86.5% |
| Stage #1: 2-(2-ethylhexyl)thiophen With n-butyllithium In tetrahydrofuran; hexane at -78 - 0℃; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at -78 - 20℃; | |
| Stage #1: 2-(2-ethylhexyl)thiophen With n-butyllithium In tetrahydrofuran; hexane at -78 - 0℃; for 2h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at -78 - 20℃; | |
| Stage #1: 2-(2-ethylhexyl)thiophen With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - 20℃; Inert atmosphere; | 0.68 g |
-
-
1693-86-3
3-hexylthiophene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
154717-22-3
(3-hexylthiophene-5-yl)trimethylstannane
| Conditions | Yield |
|---|---|
| Stage #1: 3-hexylthiophene With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃; for 1h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - 20℃; for 14h; | 100% |
| Stage #1: 3-hexylthiophene With lithium diisopropyl amide Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78℃; | 98% |
| Stage #1: 3-hexylthiophene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In diethyl ether; hexane for 1h; Reflux; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; diethyl ether; hexane at 0 - 20℃; for 2h; | 92% |
| Stage #1: 3-hexylthiophene With n-butyllithium In tetrahydrofuran at -78 - 20℃; for 4h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - 20℃; Inert atmosphere; | 82.4% |
| With lithium diisopropyl amide |
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| Stage #1: 7-bromo-N,N-bis(4-methoxyphenyl)-9,9-dimethyl-9H-fluoren-2-amine With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - -20℃; Inert atmosphere; | 100% |
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| Stage #1: N,N-bis(4-methoxyphenyl)-4,4-dimethyl-4H-indeno[1,2-b]thiophen-6-amine With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - -20℃; Inert atmosphere; | 100% |
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| Stage #1: 4,8-(1,12-dodecylenedioxy)benzo[1,2-b:4,5-b']dithiophene With n-butyllithium In tetrahydrofuran at 20℃; for 0.0333333h; Inert atmosphere; Glovebox; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran for 0.00277778h; Glovebox; | 100% |
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| Stage #1: 4-{2-[2-(2-methoxyethoxy)ethoxy]ethyl}-4H-dithieno[3,2-b:2',3'-d]pyrrole With n-butyllithium In tetrahydrofuran at -78 - 5℃; for 3h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78℃; for 5h; | 100% |
-
-
1329426-09-6
2-(3,4,5-tris(dodecyloxy)phenyl)thiophene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
1329426-11-0
2-(3,4,5-tridodecyloxyphenyl)-5-trimethylstannylthiophene
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran at -40℃; | 100% |
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
1595320-51-6
5′-hexyl-2,2′-bithiophene-5-trimethylstannane
| Conditions | Yield |
|---|---|
| Stage #1: 2-hexylthieno[3,2-b]thiophene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane at 20℃; | 100% |
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| Stage #1: 2-bromo-5-(4,5-dibutoxy-2-(5-phenylthiophen-2-yl)phenyl)thiophene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; hexane | 100% |
-
-
773093-00-8
2-(5’-bromo-[2,2’-bithiophen]-5-yl)-1,3-dioxolane
-
-
1066-45-1
trimethyltin(IV)chloride
| Conditions | Yield |
|---|---|
| Stage #1: 2-(5’-bromo-[2,2’-bithiophen]-5-yl)-1,3-dioxolane With n-butyllithium In tetrahydrofuran; water at -78 - 0℃; for 2h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; water at -78 - 20℃; Inert atmosphere; | 99.9% |
| Stage #1: 2-(5’-bromo-[2,2’-bithiophen]-5-yl)-1,3-dioxolane With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 2h; Inert atmosphere; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at -78 - 20℃; Inert atmosphere; | 99.8% |
-
-
1271438-65-3
2-(2'-butyl-1'-octyl)thiophene
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
1362165-84-1
2-(2-butyloctyl)-5-trimethylstannylthiophen
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran | 99.2% |
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
73893-87-5
(S)-2-(2-Methylbutyl)thiophene
-
-
1362166-27-5
(S)-2-(2-methylbutyl)-5-trimethylstannylthiophene
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran | 99.1% |
-
-
1066-45-1
trimethyltin(IV)chloride
-
-
226085-20-7
1-tert-butyldimethylsilyl-3-trimethylstannyl-7-azaindole
| Conditions | Yield |
|---|---|
| Stage #1: 3-bromo-1-(tert-butyldimethylsilyl)-1H-pyrrolo[2,3-b]pyridine With tert.-butyl lithium In tetrahydrofuran; pentane at -90℃; for 0.0833333h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran; diethyl ether; pentane at -90℃; for 1h; | 99% |
