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Synthetic route

sodium azide

sodium azide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In neat (no solvent) heating NaN3 to 275°C;;100%
In neat (no solvent) heating NaN3 to 275°C;;100%
In neat (no solvent) carbon support was impregnated with NaN3 following with drying procedureunder UHV and at 450°C; carbon support was used;
sodium carbonate
497-19-8

sodium carbonate

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With pyrographite; calcium oxide In neat (no solvent) 110°C, 1-2 Torr;;94%
With coal; CaO In neat (no solvent) 110°C, 1-2 Torr;;94%
With pyrographite In neat (no solvent) 110°C, 1-2 Torr;;92%
sodium chloride
7647-14-5

sodium chloride

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With calcium carbide In neat (no solvent) byproducts: CaCl2, C; at 900°C, diminshed yield with increase of pressure (1-10 Torr);;92%
With calcium carbide; sodium fluoride In neat (no solvent) byproducts: CaCl2, C; powdered and pressed, 0.5 Torr, 6% NaF, 875°C;;82%
With calcium carbide In neat (no solvent) reduction at 900°C;;63%
sodium sulfate
7757-82-6

sodium sulfate

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With pyrographite In neat (no solvent) 110°C, 1-2 Torr;;54%
With coal In neat (no solvent) 110°C, 1-2 Torr;;54%
With pyrographite; calcium oxide In neat (no solvent) 110°C, 1-2 Torr;;83-95
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

A

boron

boron

B

hydrogen
1333-74-0

hydrogen

C

sodium
7440-23-5

sodium

Conditions
ConditionsYield
decompn. at 500°C, heating in N2- or H2-atm.;A n/a
B 45%
C n/a
decompn. at 500°C, heating in N2- or H2-atm.;A n/a
B 45%
C n/a
sodium bromide
7647-15-6

sodium bromide

A

bromine
7726-95-6

bromine

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
Electrolysis;
dolomite

dolomite

sodium chloride
7647-14-5

sodium chloride

A

sodium
7440-23-5

sodium

B

magnesium
7439-95-4

magnesium

Conditions
ConditionsYield
In neat (no solvent) 1200°C;; simultaneous preparation of Na and Mg;;
borax

borax

magnesium
7439-95-4

magnesium

A

magnesium diboride

magnesium diboride

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In gaseous matrix slow reaction with small amounts; vigorous reaction with greater amounts and at a certain temperature;;
In gaseous matrix slow reaction with small amounts; vigorous reaction with greater amounts and at a certain temperature;;
iron acetylide

iron acetylide

sodium hydroxide
1310-73-2

sodium hydroxide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In neat (no solvent) byproducts: iron, carbon dioxide, carbon monoxide; reaction of FeC2 (70 parts metal, 30 parts carbon) with 3 parts NaOH in a cast iron crucible; passing in of CO is of advantage; further byproduct: hydrogene;;
sodium monoxide

sodium monoxide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In gas Kinetics; byproducts: O2; carrier gas (He); fast flow reactor; not isolated, detected by fluorescence;
iron(III) oxide

iron(III) oxide

sodium carbonate
497-19-8

sodium carbonate

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With iron In neat (no solvent) preparation of NaFeO2 by heating powdered Fe2O3 and Na2CO3 (stoechiometric mixture) to 900°C in an alundum-vessel, mixing with Fe-powder, heating at 2 torr to 1250°C;;
iron(III) oxide

iron(III) oxide

sodium carbonate
497-19-8

sodium carbonate

calcium hydroxide

calcium hydroxide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With pyrographite In neat (no solvent) a mixture of dry Na2CO3, Ca(OH)2, Fe2O3 is heated;;
aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

sodium carbonate
497-19-8

sodium carbonate

sodium sulfate
7757-82-6

sodium sulfate

A

sodium oxide

sodium oxide

B

carbon dioxide
124-38-9

carbon dioxide

C

sodium
7440-23-5

sodium

D

sulfur
7704-34-9

sulfur

E

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In melt Kinetics; byproducts: O2, CO; Electrolysis; solid, granular sodium salts placed in alumina crucible and tube, purgedwith argon for 3 h, heated at 840.+-.20°C; detd. by IR gas analyzer, electrochemical cell analyzer, capillary ion electrophoresis, inductively coupled plasma anal., acid titration;
sodium sulfide

sodium sulfide

aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

sodium carbonate
497-19-8

sodium carbonate

sodium sulfate
7757-82-6

sodium sulfate

A

sodium oxide

sodium oxide

B

carbon dioxide
124-38-9

carbon dioxide

C

sodium
7440-23-5

sodium

D

sulfur
7704-34-9

sulfur

E

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In melt Kinetics; byproducts: O2, CO; Electrolysis; solid, granular sodium salts placed in alumina crucible and tube, purgedwith argon for 3 h, heated at 840.+-.20°C; detn. by IR gas analyzer, electrochemical cell analyzer, capillary ion electrophoresis, inductively coupled plasma anal., acid titration;
aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

cryolite

cryolite

A

sodium
7440-23-5

sodium

B

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In melt Electrolysis; Al2O3-cryolite melt;; Na permeates through the carbon-bottom-plate of the bath and can be periodically removed;;
In melt Electrolysis; Al2O3-cryolite melt;; Na permeates through the carbon-bottom-plate of the bath and can be periodically removed;;
sodium nitride

sodium nitride

A

sodium azide

sodium azide

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In neat (no solvent) decompn. upon heating;
sodium azide

sodium azide

A

nitrogen
7727-37-9

nitrogen

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In solid Irradiation (UV/VIS); photolysis of up to 5.0 GPa compressed solid NaN3;
In neat (no solvent) Irradiation (UV/VIS); λ=2537 Å; -268.93°C, next heating to 600 K;
In neat (no solvent) decompn. in vac. at 275°C;
bismuth
7440-69-9

bismuth

sodium
7440-23-5

sodium

sodium bismuthide

sodium bismuthide

Conditions
ConditionsYield
In neat (no solvent) heating a mixture of Na and Bi (molar ratio 3 : 1) at 775°C under Ar;;100%
determined by thermal analysis;;
determined by chemical methods;;
tellurium

tellurium

sodium
7440-23-5

sodium

disodium telluride

disodium telluride

Conditions
ConditionsYield
In neat (no solvent) Na was warmed in high vacuum and added to liquid Te in N2 atmosphere, NH3 was condensed over the mixture, the NH3 was slowly evaporated;; tempered at 400-500°C, stored under N2;;100%
In neat (no solvent) Na was warmed in high vacuum and added to liquid Te in N2 atmosphere, NH3 was condensed over the mixture, the NH3 was slowly evaporated;; tempered at 400-500°C, stored under N2;;100%
In neat (no solvent) Te heated to 620 .-+. 20°C was added in small portions to 300°C hot Na, excess of Na was distilled off;;80%
Conditions
ConditionsYield
In neat (no solvent, solid phase) (inert gas), mixed, heated to 500°C for 24 h, stayed at 500°C for 2 days, heated to 800°C for 2 days, held at 800°C for 10 days; slowly cooled to room temp., elem. anal., XRD;100%
manganese
7439-96-5

manganese

tellurium

tellurium

silver
7440-22-4

silver

sodium
7440-23-5

sodium

Na1.03Mn0.96Ag1.02Te2

Na1.03Mn0.96Ag1.02Te2

Conditions
ConditionsYield
In neat (no solvent, solid phase) (inert gas), mixed, heated to 500°C for 24 h, stayed at 500°C for 2 days, heated to 800°C for 2 days, held at 800°C for 10 days; slowly cooled to room temp., elem. anal., XRD;100%
antimony
7440-36-0

antimony

sodium
7440-23-5

sodium

rubidium

rubidium

Na16(RbRb6)Sb7

Na16(RbRb6)Sb7

Conditions
ConditionsYield
In neat (no solvent) byproducts: RbSb; molar ratio Na:Rb:Sb stoichiometric to 2:1:1; heating (12 h to 873 K; 120 h, 873 K), cooling (48 h, room temp.); XRD;100%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

sodium
7440-23-5

sodium

disodium tetracarbonylferrate

disodium tetracarbonylferrate

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide (Ar); react. metal carbonyl with Na in HMPA for 1 h at 20°C;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

sodium
7440-23-5

sodium

sodium tetracarbonylruthenate(II)

sodium tetracarbonylruthenate(II)

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide (Ar); react. metal carbonyl with Na in HMPA for 1 h at 20°C;99%
In ammonia NH3 (liquid); NH3 distilled onto Na/Ru mixture (acetone/dry ice bath) under vac., slowly warmed to 235 K, vigorously stirred for ca. 60 min, warmed to 260 K; dried (vac., 260 K, 3.5 h);

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