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Kunshan Push Trading Co.,LTD

ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Good and stabilized factory price. 2.

Lithium Bromide

Cas:7550-35-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Aecochem Corp.

Lithium bromide

Cas:7550-35-8

Min.Order:0

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Lithium bromide Manufacturer/High quality/Best price/In stock

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance: White Crystal Conforms Assay%: ≥ 99

High quality 7550-35-8 Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $1300.0 / 1600.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Located in Zhengdong New District, Zhengzhou of Henan province, Henan Allgreen Chemical Co.,Ltd is comprehensive high-tech modern enterprises integrating professional R&D, production and sales. Strong technical force, with a long

Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Lithium bromide

Cas:7550-35-8

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% Lithium bromide 7550-35-8 ISO Producer

Cas:7550-35-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $10.0

Type:Manufacturers

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Win-Win chemical Co.Ltd

Stock products, own laboratory Product number 37183 English Name Lithium bromide CAS Number 7550-35-8 Purity 98% Molecular formula

Lithium bromide Cas no.7550-35-8 98%

Cas:7550-35-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: Lithium bromide Synonyms: LITHIUM HALIDE;Hydrobromic acid lithium salt;LiBr;Lithium bromide (LiBr);lithiumbromide(libr);Lithiumbromide,dihydrate;lithiummonobromide;Lithiumbromidewhitepowder CAS: 7550-35-8 MF:

7550-35-8 Lithium bromide

Cas:7550-35-8

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

After many years of efforts, we have established stable and friendly business relations with dozens of European and American pharmaceutical companies, multinational chemical companies and importers.At home and many production plants and researc

high quality Lithium bromide with reasonable price and fast delivery 7550-35-8

Cas:7550-35-8

Min.Order:1 Metric Ton

FOB Price: $10.0 / 17.0

Type:Trading Company

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

China Factory Supply CAS 7550-35-8 Lithium Bromide

Cas:7550-35-8

Min.Order:1 Gram

FOB Price: $12.0 / 15.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 7550-35-8 with competitive price

Cas:7550-35-8

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Lithium bromide

Cas:7550-35-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after the dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available &diam

Lithium bromide CAS7550-35-8

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $7.0 / 10.0

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Henan Sinotech Import&Export Corporation

CAS: 7550-35-8 MF: BrLi MW: 86.85 EINECS: 231-439-8 Meltin

Lithium bromide CAS: 7550-35-8

Cas:7550-35-8

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hangzhou Ocean Chemical Co., Ltd.

1.High purity, like 99%, 99.9%, 99.95%, 99.99%, 99.999% 2.Quality control, test sample before shipping and keep sample for 3 years after shipping; 3. Prompt shipment with professional documents; 4. Packing as your request, with ph

Lithium bromide reagent/electronic grade 99.5% high purity

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Lithium bromide

Cas:7550-35-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present,

Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $60.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Lithium bromide CAS:7550-35-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

Lithium bromide CAS:7550-35-8

Cas:7550-35-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Superiority We can customize and synthesize products that other suppliers may not be able to provide. Advantage cof, mof ligand manufacturer Product Detail

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:7550-35-8

Cas:7550-35-8

Min.Order:0

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Hebei Mojin Biotechnology Co.,Ltd

Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tr

high quality 99% Anhydrous lithium bromide CAS 7550-35-8

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

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Shanghai Terui OP New Material Technology Co., Ltd.

We have overseas warehouses in California, Nuevo Laredo, Mexico, Vancouver, Canada, Amsterdam, The Netherlands and Melbourne, Australia. Overseas warehouses can provide some of the best selling products. We look forward to cooperating with strong loc

Lithium bromide cas 7550-35-8 DDP

Cas:7550-35-8

Min.Order:1 Kilogram

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Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

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Leader Biochemical Group

Overview of Our Factories Our Factories production lines Our Factories R&D ability Our Factories warehouse Our Factorie

China Biggest Factory & Manufacturer supply Lithium bromide

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

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Hebei Miheng Trading Co., Ltd.

Lithium bromide cas 7550-35-8 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly.

Lithium bromide cas 7550-35-8

Cas:7550-35-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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HUBEI RISON CHEMICAL CO.,LTD.

Lithium bromide brineCAS: 7550-35-8Molecular Formula : LiBrAppearance: Yellow transparent liquid LiBr: 50-52%Ca: 0.005%max K: 0.001%max Na: 0.02%max PH: 9-10.5Li2CrO4: 0.2-0.3%Cl: 0.25%max BrO3: 0.005%max Fe: 0.001%max Mg: 0.001%max NH4: 0.001%max SO

Lithium bromide brine

Cas:7550-35-8

Min.Order:0

Negotiable

Type:Other

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Synthetic route

lithium tetra-tert-butoxytitanate * THF

lithium tetra-tert-butoxytitanate * THF

t-BuOMgBr

t-BuOMgBr

A

magnesium penta-tert-butoxytitanate

magnesium penta-tert-butoxytitanate

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In tetrahydrofuran Ar atmosphere; 20°C; solvent removal (vacuum), extraction (hexane), crystn. (20°C, 40 h); elem. anal.;A 25%
B 100%
lithium tetra-tert-butoxytitanate * THF

lithium tetra-tert-butoxytitanate * THF

magnesium bromide

magnesium bromide

A

magnesium bis(tetra-tert-butoxytitanate)

magnesium bis(tetra-tert-butoxytitanate)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In tetrahydrofuran Ar atmosphere; 20°C; solvent removal (vacuum), extraction (hexane), crystn. on cooling (-78°C); elem. anal.;A 33%
B 100%
bromopentacarbonylmanganese(I)
14516-54-2

bromopentacarbonylmanganese(I)

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li
59501-96-1

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li

A

dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

B

racemic methyl phenyl sulfoxide
1193-82-4

racemic methyl phenyl sulfoxide

C

diphenyldisulfane
882-33-7

diphenyldisulfane

D

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;A 87%
B 41%
C 40%
D 93%
1-lithio-2,4,6-trimethylborazine

1-lithio-2,4,6-trimethylborazine

phosphorus tribromide
7789-60-8

phosphorus tribromide

A

bromobis(2,4,6-trimethylborazinyl)phosphane
1064704-42-2

bromobis(2,4,6-trimethylborazinyl)phosphane

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In diethyl ether; hexane under inert gas; soln. of borazine (3.26 mmol) in mixt. of hexane (10 ml) and Et2O (10 ml) added to soln. of PBr3 (1.63 mmol) in hexane; stirredovernight; LiBr removed by filtration; evapd. (vac.) by 2/3 of volume; kept (5°C, wk); elem. anal.;A 80%
B 90%
2,2,6,6-tetramethyl-piperidine
768-66-1

2,2,6,6-tetramethyl-piperidine

gallium(III) bromide
13450-88-9

gallium(III) bromide

A

bis(2,2,6,6-tetramethylpiperidino)gallium bromide

bis(2,2,6,6-tetramethylpiperidino)gallium bromide

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane under inert atmosphere, piperidine in hexane reacted with n-BuLi in hexane, dropwise addn. of GaBr3 in diethyl ether at room temp., refluxed for 30 min, stirred at room temp. for 12 h; evapn. of solvent, taken up in pentane, filtered, evapd. in vac.; elem. anal.;A 88%
B n/a
C14H16NO2(1+)*Br(1-)

C14H16NO2(1+)*Br(1-)

lithium trifluoromethanesulfonate
33454-82-9

lithium trifluoromethanesulfonate

A

C14H16NO2(1+)*CF3O3S(1-)

C14H16NO2(1+)*CF3O3S(1-)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In water at 20℃; for 1h;A 87%
B n/a
1,2-bis(diethylamino)diboron dibromide
101315-57-5

1,2-bis(diethylamino)diboron dibromide

dilithium N,N'-dimethylethylenediaminate
54760-74-6, 98900-11-9

dilithium N,N'-dimethylethylenediaminate

A

2,3-bis(diethylamino)-1,4-dimethyl-1,4,2,3-diazadiborinane
158752-93-3

2,3-bis(diethylamino)-1,4-dimethyl-1,4,2,3-diazadiborinane

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In hexane under N2, addn. of B-compd. in hexane to Li-compd. in hexane at -60°C with stirring, allowed to warm up to room temp., kept for 30 min at reflux; solid material sepd., distd.; elem. anal.;A 86%
B n/a
C13H14NO(1+)*Br(1-)

C13H14NO(1+)*Br(1-)

lithium trifluoromethanesulfonate
33454-82-9

lithium trifluoromethanesulfonate

A

C13H14NO(1+)*CF3O3S(1-)

C13H14NO(1+)*CF3O3S(1-)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In water at 20℃; for 1h;A 85%
B n/a
aluminium bromide
7727-15-3

aluminium bromide

neopentyl lithium
7412-67-1

neopentyl lithium

A

tris(neopentyl)aluminium
42916-36-9

tris(neopentyl)aluminium

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In hexane Addn. of neopentyllithium to a suspn. of AlBr3 in hexane at 0°C in 20 min under protective gas, refluxing (3 h).; Vac. distn. of hexane, sepn. of Al-compd. from LiBr by flask to flask vac. distn. at 120°C. Short-path vac. distn., elem. anal., mol wt.;A 82.3%
B n/a
1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)
133911-59-8

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)

A

1,3-bis(tert-butylamino)-1,2,3-tris(dimethylamino)triborane(5)
158819-19-3

1,3-bis(tert-butylamino)-1,2,3-tris(dimethylamino)triborane(5)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With LiNHCMe3 In toluene anhydrous and oxygen-free condns., addn. of Li-compd. in toluene to a stirred soln. of B-compd. in toluene at -78°C within 10 min, allowed to attain ambient temp., reaction time: 3 h; centrifuged, evapn. of solvent in vac., crystn. (pentane/toluene, -78°C); elem. anal.;A 81%
B n/a
dibromomethylborane
17933-16-3

dibromomethylborane

N-ethyl-N'-methylethane-1,2-diamine
111-37-5

N-ethyl-N'-methylethane-1,2-diamine

A

1-ethyl-2,3-dimethyl-1,3,2-diazaborolidine
129920-21-4

1-ethyl-2,3-dimethyl-1,3,2-diazaborolidine

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.; elem. anal.;A 72%
B n/a
triisopropylgermyllithium
43106-46-3

triisopropylgermyllithium

[Fe(η-cyclopentadienyl)(CO)2(HgBr)]

[Fe(η-cyclopentadienyl)(CO)2(HgBr)]

A

{(η-cyclopentadienyl)Fe(CO)2}2Hg

{(η-cyclopentadienyl)Fe(CO)2}2Hg

B

bis(triisopropylgermyl)mercury
24004-54-4

bis(triisopropylgermyl)mercury

C

mercury

mercury

D

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In toluene addn. of Li-compound in toluene at -30°C to Fe-compound in toluene, after 0.5h the temp. was raised to 20°-C; separation of Hg, removal of solvent in vac., addn. of hexane to the residue, pptn., removal of LiBr by washing with H2O;A 56.5%
B n/a
C 19%
D 71%
1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)
133911-59-8

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)

A

1,2,3-tris(dimethylamino)-1,3-dipiperidinotriborane(5)
158819-06-8

1,2,3-tris(dimethylamino)-1,3-dipiperidinotriborane(5)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With LiNC5H10 In cyclohexane anhydrous and oxygen-free condns., addn. of Li-compd. in cyclohexane to a stirred soln. of B-compd. in cyclohexane within 20 min, stirred for 6 h; centrifuged, evapn. of solvent in vac., dissolved in hexane, cooled to -78°C; elem. anal.;A 71%
B n/a
dibromomethylborane
17933-16-3

dibromomethylborane

N,N-diisopropyl-1,2-ethanediamine
4013-94-9

N,N-diisopropyl-1,2-ethanediamine

A

1,3-diisopropyl-2-methyl-1,3,2-diazaborolidine
129920-20-3

1,3-diisopropyl-2-methyl-1,3,2-diazaborolidine

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.; elem. anal.;A 69%
B n/a
indium(I) bromide

indium(I) bromide

(tris-(trimethylsilyl)methyl)lithium bis(tetrahydrofuran)

(tris-(trimethylsilyl)methyl)lithium bis(tetrahydrofuran)

A

tetrahedra-tetrakis[tris(trimethylsilyl)methyl]tetraindane(4)

tetrahedra-tetrakis[tris(trimethylsilyl)methyl]tetraindane(4)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In toluene Ar-atmosphere; addn. of Li-adduct to suspn. of InBr (-50°C), stirring, warming to room temp.; filtration (LiBr removal); washing (pentane), evapn. (vac.), crystn. (-50°C);A 69%
B n/a
dibromomethylborane
17933-16-3

dibromomethylborane

N,N'-diethylethylenediamine
111-74-0

N,N'-diethylethylenediamine

A

1,3-diethyl-2-methyl-1,3,2-diazaboracyclopentane
6063-64-5

1,3-diethyl-2-methyl-1,3,2-diazaboracyclopentane

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.;A 63%
B n/a
1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)
158819-22-8

1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)

A

1,4-bis(tert-butylamino)-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)
158819-07-9

1,4-bis(tert-butylamino)-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With LiNHCMe3 In hexane anhydrous and oxygen-free condns., addn. of Li-compd. in hexane to a soln. of B-compd. in hexane at -60°C within 10 min, allowed to reach ambient temp., stirred for 5 h; centrifuged, evapn. of solvent in vac., recrystn. (pentane/toluene (10:1), -78°C); elem. anal.;A 63%
B n/a
1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)
158819-22-8

1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)

A

1,2,3,4-tetrakis(dimethylamino)-1,4-bis(diphenylphosphanyl)tetraborane(6)
158819-09-1

1,2,3,4-tetrakis(dimethylamino)-1,4-bis(diphenylphosphanyl)tetraborane(6)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With LiPPh2 In toluene anhydrous and oxygen-free condns., addn. of Li-compd. in toluene to a soln. of B-compd. in toluene at -60°C, stirred for 2 d at ambient temp.; filtered, evapn. of solvent in vac., dissolved in pentane, cooled to -78°C for 14 d; elem. anal.;A 57%
B n/a
{bromo(di-isopropylamino)boryl}-tert-butyl(dibromophosphino)amine
112794-90-8

{bromo(di-isopropylamino)boryl}-tert-butyl(dibromophosphino)amine

diisopropylamine
108-18-9

diisopropylamine

A

{bromo(di-isopropylamino)boryl}-{bromo(di-isopropylamino)phosphino}-tert-butylamine
112817-48-8

{bromo(di-isopropylamino)boryl}-{bromo(di-isopropylamino)phosphino}-tert-butylamine

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With lithium butanide In diethyl ether; hexane addn. of soln. of i-Pr2NH in ether and soln. of Li-butanide in hexane at 20°C to B-compound at 0°C, stirred for 2 h at room temp.; filtration, removal of solvent, recrystn. from hexane at -70°C; elem. anal.;A 55%
B n/a
{bromo(di-isopropylamino)boryl}-{bromo(di-isopropylamino)phosphino}-tert-butylamine
112817-48-8

{bromo(di-isopropylamino)boryl}-{bromo(di-isopropylamino)phosphino}-tert-butylamine

lithium
7439-93-2

lithium

A

1-tert-butyl-2,3-bis(di-isopropylamino)-1,2,3-azaphosphaboriridine
112795-10-5

1-tert-butyl-2,3-bis(di-isopropylamino)-1,2,3-azaphosphaboriridine

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In tetrahydrofuran stirred at 0°C for 3 h; evapn. to dryness, dissolved in hexane, filtration, distn. of filtrate (from ether at -70°C); elem. anal.;A 54%
B n/a
lithium nitride

lithium nitride

ammonia
7664-41-7

ammonia

gallium(III) bromide
13450-88-9

gallium(III) bromide

gallium nitride

gallium nitride

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In xylene Ar-atmosphere; heating for 80 h, solvent removal, heating at 450°C in vac., heatin at 500°C in NH3 flow overnight; detd. by X-ray diffraction, elem. anal., HRTEM, XPS;A 53%
B n/a
dibromomethylborane
17933-16-3

dibromomethylborane

N,N`-dimethylethylenediamine
110-70-3

N,N`-dimethylethylenediamine

A

1,2,3-trimethyl-[1,3,2]diazaborolidine
29173-12-4

1,2,3-trimethyl-[1,3,2]diazaborolidine

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.;A 52%
B n/a
lithium pentafluorobenzenesulfinate
36649-96-4

lithium pentafluorobenzenesulfinate

mercury dibromide

mercury dibromide

A

pentafluorophenylmercury bromide
828-72-8

pentafluorophenylmercury bromide

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In water in aq. suspension at 25°C, molar ratio of LiOS(O)C6F5 and Hg comp. = 1.0:1.1, 2 h;A 52%
B n/a
In water in aq. suspension at 25°C, molar ratio of LiOS(O)C6F5 and Hg comp. = 1.0:1.1, 2 h;A 52%
B n/a
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

bis[bis(trimethylsilyl)methyl]gallium bromide
141120-24-3

bis[bis(trimethylsilyl)methyl]gallium bromide

imidotetraphenyldiphosphinic acid
31239-06-2

imidotetraphenyldiphosphinic acid

A

bis[bis(trimethylsilyl)methyl]-imidotetraphenyldiphosphinato-O,O'-gallium

bis[bis(trimethylsilyl)methyl]-imidotetraphenyldiphosphinato-O,O'-gallium

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
In diethyl ether; hexane; pentane Ar atm.; molar ratio (Ph2PO)2NH:BuLi 1:1, stirring (-50°C), heating (2 h, room temp.), stirring (2 h), cooling (-20°C), stirring (1 h, room temp.); evapn. (vac.), drying (vac.), extraction (n-pentane), filtn., concn., crystn. (-50°C);A 48%
B n/a
1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)
133911-59-8

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)

A

1,3-di-tert-butyl-1,2,3-tris(dimethylamino)triborane(5)
158819-20-6

1,3-di-tert-butyl-1,2,3-tris(dimethylamino)triborane(5)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With Li-t-Bu In hexane anhydrous and oxygen-free condns., addn. of t-BuLi in hexane to a stirred soln. of B-compd. in hexane at -78°C, stirred at ambient temp. for 7 d; filtered, reduced in volume, cooled to -78°C; elem. anal.;A 46%
B n/a
1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)
158819-22-8

1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)

A

1,4-di-tert-butyl-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)
158819-12-6

1,4-di-tert-butyl-1,2,3,4-tetrakis(dimethylamino)tetraborane(6)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With Li-t-Bu In hexane anhydrous and oxygen-free condns., addn. of t-BuLi in hexane to a stirred soln. of B-compd. in petroleum ether at -78°C, warmed to ambient temp., stirred at ambient temp. for 7 d; filtered, reduced in volume, cooled to -78°C;A 40%
B n/a
dibromomethylborane
17933-16-3

dibromomethylborane

N-isopropylethane-1,2-diamine
19522-67-9

N-isopropylethane-1,2-diamine

A

1-isopropyl-2-methyl-1,3,2-diazaborolidine
129920-24-7

1-isopropyl-2-methyl-1,3,2-diazaborolidine

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp. (evapn. of butane), cooled to -78°C, dropwise addn. of CH3BBr2 in petroleum ether, warmed to room temp.; solvent distd. off, condensed into a trap (-196°C) at 80°C;A 37%
B n/a
3-bromo-4,5-diethyl-1,2,3-dithiaborole
91573-48-7

3-bromo-4,5-diethyl-1,2,3-dithiaborole

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

lithium hexamethyldisilazane
4039-32-1

lithium hexamethyldisilazane

A

3,4,5-triethyl-1,2,3-dithiaborole
124324-55-6

3,4,5-triethyl-1,2,3-dithiaborole

B

lithium bromide
7550-35-8

lithium bromide

C

magnesium bromide

magnesium bromide

Conditions
ConditionsYield
In diethyl ether; hexane addn. of Grignard reagent to soln. of borole in hexane (N2, -80°C), slow warming; decantation, distn., addn. of LiN(SiMe3)2 to soln. of crude distillate (hexane, 0°C), refluxing (2h), decantation, solvent evapn., distn. (high vac.); elem. anal.;A 36%
B n/a
C n/a
1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)
133911-59-8

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5)

A

1,3-dibutyl-1,2,3-tris(dimethylamino)triborane(5)
133911-59-8

1,3-dibutyl-1,2,3-tris(dimethylamino)triborane(5)

B

lithium bromide
7550-35-8

lithium bromide

Conditions
ConditionsYield
With BuLi In hexane anhydrous and oxygen-free condns., addn. of BuLi in hexane to a stirred soln. of B-compd. in hexane, warmed to ambient temp., stirred overnight; filtered, removal of solvent in vac., kept in vac. for 3 h; elem. anal.;A 36%
B n/a
3-bromo-4,5-diethyl-1,2,3-dithiaborole
91573-48-7

3-bromo-4,5-diethyl-1,2,3-dithiaborole

isopropylmagnesium bromide
920-39-8

isopropylmagnesium bromide

lithium hexamethyldisilazane
4039-32-1

lithium hexamethyldisilazane

A

4,5-diethyl-3-i-propyl-1,2,3-dithiaborole
124324-56-7

4,5-diethyl-3-i-propyl-1,2,3-dithiaborole

B

lithium bromide
7550-35-8

lithium bromide

C

magnesium bromide

magnesium bromide

Conditions
ConditionsYield
In diethyl ether; hexane addn. of Grignard reagent to soln. of borole in hexane (N2, -80°C), slow warming; decantation, distn., addn. of LiN(SiMe3)2 to soln. of crude distillate (hexane, 0°C), refluxing (2h), decantation, solvent evapn., distn. (high vac.); elem. anal.;A 31%
B n/a
C n/a
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

lithium bromide
7550-35-8

lithium bromide

lithium borohydride

lithium borohydride

Conditions
ConditionsYield
In tetrahydrofuran byproducts: sodium bromide; under N2, soln. of LiBr and NaBH4 (molar ratio 1:1) in THF stirred withglass beads at 67°C (refluxed) for 8 h;100%
In tetrahydrofuran byproducts: sodium bromide; under N2, soln. of LiBr and NaBH4 (molar ratio 1:1) in THF stirred withmagnetic stirrer at 67°C (refluxed) for 16 h;99%
In diethyl ether byproducts: sodium bromide; under N2, soln. of LiBr in Et2O stirred with magnetic stirrer for 2 min, 1 equiv of NaBH4 introduced, maintained at 35°C with stirring for 32 h;99%
(η5-pentamethylcyclopentadienyl){η4-(E)-2-methylpenta-1,3-diene}ruthenium chloride
140411-29-6

(η5-pentamethylcyclopentadienyl){η4-(E)-2-methylpenta-1,3-diene}ruthenium chloride

lithium bromide
7550-35-8

lithium bromide

{(C5(CH3)5)Ru(C5H7(CH3))Br}
140411-41-2

{(C5(CH3)5)Ru(C5H7(CH3))Br}

Conditions
ConditionsYield
In methanol dissolving the Ru complex in methanol under N2, treating with LiBr; filtration after 6 h, cooling (-30°C), crystn.; elem. anal.;100%
(C6H4N2C3H4C6H5Pd(O2CCH3))2

(C6H4N2C3H4C6H5Pd(O2CCH3))2

lithium bromide
7550-35-8

lithium bromide

(C6H4N2C3H4C6H5PdBr)2

(C6H4N2C3H4C6H5PdBr)2

Conditions
ConditionsYield
In methanol A mixt. of reagents in methanol was heated at reflux for 6 h, then stirred at room temp. for 1 h;; ppt. was washed with MeOH and Et2O; elem. anal.;;100%
(η5-1-methylpentadienyl)(η5-pentamethylcyclopentadienyl)cobalt(III) hexafluorophosphate

(η5-1-methylpentadienyl)(η5-pentamethylcyclopentadienyl)cobalt(III) hexafluorophosphate

lithium bromide
7550-35-8

lithium bromide

(η3-trans-1-methylpentadienyl)(η5-pentamethylcyclopentadienyl)cobalt(III) bromide

(η3-trans-1-methylpentadienyl)(η5-pentamethylcyclopentadienyl)cobalt(III) bromide

Conditions
ConditionsYield
In acetone LiBr added at room temp. to stirred soln. of Co complex in acetone; reacted at room temp. for 30 min; solvent removed in vac.; dissolved in min. amt. of benzene; filtered through Celite; solvent removed; dried under vac.;100%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl triflate

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl triflate

lithium bromide
7550-35-8

lithium bromide

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl][bis(tricyclohexylphosphine)]nickel(II)

trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;100%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-yl trifluoromethanesulfonate
1437769-76-0

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-yl trifluoromethanesulfonate

lithium bromide
7550-35-8

lithium bromide

triethylphosphine
554-70-1

triethylphosphine

trans-bromo[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-yl][bis(triethylphosphine)]nickel(II)

trans-bromo[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-yl][bis(triethylphosphine)]nickel(II)

Conditions
ConditionsYield
In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere;100%
trans-{PdCl2(1C-diphenylphosphinomethyl-2C-methyl-o-carborane)2
130214-50-5

trans-{PdCl2(1C-diphenylphosphinomethyl-2C-methyl-o-carborane)2

lithium bromide
7550-35-8

lithium bromide

2Pd(2+)*2Cl(1-)*2B10H8C2(CH3)CH2P(C6H5)2(2-)*2H(1+) = {PdCl(B10H9C2(CH3)CH2P(C6H5)2)}2

2Pd(2+)*2Cl(1-)*2B10H8C2(CH3)CH2P(C6H5)2(2-)*2H(1+) = {PdCl(B10H9C2(CH3)CH2P(C6H5)2)}2

Conditions
ConditionsYield
In propan-1-ol refluxing Pd-complex and 10-fold excess of LiBr in propanol until soln. fading, pptn. on cooling; filtration, washing (water, MeOH, hexane), drying; elem. anal.; isomer product mixt. not sepd.;99%
N,N-dimethyl-3-furancarboselenoamide
127802-49-7

N,N-dimethyl-3-furancarboselenoamide

lithium bromide
7550-35-8

lithium bromide

palladium dichloride

palladium dichloride

PdBr(N,N-dimethyl-furan-3-carboselenoamido)

PdBr(N,N-dimethyl-furan-3-carboselenoamido)

Conditions
ConditionsYield
In methanol stirred overnight at room temp.; ppt. collected, washed (MeOH), dried (air); elem.anal.;99%
(η(5)-C5H4CH2CH2OSO2C6H4CH3)Mn(CO)3
215460-58-5

(η(5)-C5H4CH2CH2OSO2C6H4CH3)Mn(CO)3

lithium bromide
7550-35-8

lithium bromide

(η(5)-C5H4CH2CH2Br)Mn(CO)3
215460-59-6

(η(5)-C5H4CH2CH2Br)Mn(CO)3

Conditions
ConditionsYield
In acetone byproducts: lithium tosylate; N2-atmosphere; refluxing Mn-complex with slight excess of LiBr overnight; evapn., extn. into CH2Cl2, filtration off of Li-tosylate (Celite), chromy. (SiO2, CH2Cl2);99%
trans-[PdCl2(P{(CH2)14}3P)]
887279-82-5

trans-[PdCl2(P{(CH2)14}3P)]

lithium bromide
7550-35-8

lithium bromide

trans-[PdBr2(P{(CH2)14}3P)]
887279-84-7

trans-[PdBr2(P{(CH2)14}3P)]

Conditions
ConditionsYield
In tetrahydrofuran99%
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;99%
BeLiO4P

BeLiO4P

lithium bromide
7550-35-8

lithium bromide

Lithiumbromoberyllophosphat

Lithiumbromoberyllophosphat

Conditions
ConditionsYield
With H2O In water High Pressure; starting materials and H2O placed in gold ampoule, sealed, heated (autoclave, 36h, 550°C, 3723 bar), cooled in an oven in 6h to room temp.; washed, dried;;98.5%
[(η(5)-pentamethylcyclopentadienyl)RuCl]4

[(η(5)-pentamethylcyclopentadienyl)RuCl]4

1,2,3-triphenylcyclopropenyl bromide
23147-72-0

1,2,3-triphenylcyclopropenyl bromide

lithium bromide
7550-35-8

lithium bromide

(η5-pentamethylcyclopentadienyl)(η3-triphenylcyclopropenyl)dibromoruthenium(IV)

(η5-pentamethylcyclopentadienyl)(η3-triphenylcyclopropenyl)dibromoruthenium(IV)

Conditions
ConditionsYield
In tetrahydrofuran under N2; a THF soln. of the Ru complex, triphenylcyclopropenyl bromide and LiBr was stirred overnight; solvent was removed under reduced pressure, extd. with CH2Cl2, filtered, CH2Cl2 was removed under reduced pressure, chromy. on silica gel; elem. anal.;98.5%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl trifluoromethanesulfonate
1437769-72-6

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl trifluoromethanesulfonate

lithium bromide
7550-35-8

lithium bromide

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II)
447405-44-9

trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;98.2%
μ-dichloro bis-(1,2,6-η3-4-t-butyl-1-methylcyclohexenyl) dipalladium

μ-dichloro bis-(1,2,6-η3-4-t-butyl-1-methylcyclohexenyl) dipalladium

lithium bromide
7550-35-8

lithium bromide

μ-dibromo bis-(1,2,6-η3-4-t-butyl-1-methylcyclohexenyl) dipalladium

μ-dibromo bis-(1,2,6-η3-4-t-butyl-1-methylcyclohexenyl) dipalladium

Conditions
ConditionsYield
In not given from corresponding dichloro complex by exchange with LiBr by the method of Robinson and Shaw, J. Chem. Soc., 1964, 5002; chromy. (CH2Cl2, on SiO2), recrystn. (petroleum ether);98%
[PtCl2(P(OC6H4OCH3)3)2]
144613-92-3

[PtCl2(P(OC6H4OCH3)3)2]

lithium bromide
7550-35-8

lithium bromide

[PtBr2(P(OC6H4OCH3)3)2]
176510-13-7

[PtBr2(P(OC6H4OCH3)3)2]

Conditions
ConditionsYield
In dichloromethane (N2); stirring (2 h); concn. (vac.), pptn. with EtOH, filtration, washing (H2O; EtOH; pentane), drying (vac.); elem. anal.;98%
(C4HN(adamantyl)Me2(2,6-diisopropylphenyl))AuCl

(C4HN(adamantyl)Me2(2,6-diisopropylphenyl))AuCl

lithium bromide
7550-35-8

lithium bromide

C27H39AuBrN

C27H39AuBrN

Conditions
ConditionsYield
With air In acetone at 20℃; for 24h;98%
(1,3-bis(3'-butylimidazol-2'-ylidene)benzene)disilver(I) dichloride

(1,3-bis(3'-butylimidazol-2'-ylidene)benzene)disilver(I) dichloride

lithium bromide
7550-35-8

lithium bromide

bis(μ-1,3-bis(3'-butylimidazol-2'-ylidene)benzene-k-C)tetra-μ3-bromotetrasilver(I)

bis(μ-1,3-bis(3'-butylimidazol-2'-ylidene)benzene-k-C)tetra-μ3-bromotetrasilver(I)

Conditions
ConditionsYield
In acetone Inert atmosphere;98%
chloro(dimethylsulfide) gold(I)
29892-37-3

chloro(dimethylsulfide) gold(I)

3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-3H-imidazolium hexafluorophosphate

3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-3H-imidazolium hexafluorophosphate

lithium bromide
7550-35-8

lithium bromide

bromido[3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-1,3-dihydro-2H-imidazol-2-ylidene]gold(I)

bromido[3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-1,3-dihydro-2H-imidazol-2-ylidene]gold(I)

Conditions
ConditionsYield
Stage #1: 3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-3H-imidazolium hexafluorophosphate With silver(l) oxide In methanol; dichloromethane at 20℃; Inert atmosphere; Darkness;
Stage #2: chloro(dimethylsulfide) gold(I); lithium bromide In methanol; dichloromethane at 20℃; for 6h; Inert atmosphere; Darkness;
98%
(N,N'-dibutylbenzimidazolin-2-ylidene)gold(I) chloride

(N,N'-dibutylbenzimidazolin-2-ylidene)gold(I) chloride

lithium bromide
7550-35-8

lithium bromide

(N,N'-dibutylbenzimidazolin-2-ylidene)gold(I) bromide

(N,N'-dibutylbenzimidazolin-2-ylidene)gold(I) bromide

Conditions
ConditionsYield
In acetone Au complex and LiBr (10-fold excess) dissolved in acetone, mixt. stirredat ambient temp. for 24 h; evapn. under vac., residue dissolved in CH2Cl2, soln. dried over MgSO4, filtered, filtrate evapd. under vac., column chromy. (silica gel, CH2Cl2), evapn. under vac.;97.6%
Pd((C5NH4)2C4N2H2)Cl2
97226-52-3

Pd((C5NH4)2C4N2H2)Cl2

lithium bromide
7550-35-8

lithium bromide

Pd((C5NH4)2C4N2H2)Br2
97226-54-5

Pd((C5NH4)2C4N2H2)Br2

Conditions
ConditionsYield
In acetonitrile to suspn. of Pd(dppn)Cl2 in acetonitrile is added LiBr (molar ratio 1:1) and mixt. is stirred at room temp. for 10 days; ppt. is filtered, washed with water, ethanol, Et2O and dried under vac.; elem. anal.;97%
(1,3-bis(tert-butyl)imidazol-2-ylidene)gold(I) chloride

(1,3-bis(tert-butyl)imidazol-2-ylidene)gold(I) chloride

lithium bromide
7550-35-8

lithium bromide

(1,3-bis(tert-butyl)imidazol-2-ylidene)gold(I) bromide

(1,3-bis(tert-butyl)imidazol-2-ylidene)gold(I) bromide

Conditions
ConditionsYield
In acetone soln. of Au carbene complex and LiBr in acetone was stirred for 16 h; solvent removed (vac.); residue dissolved (partially) in CH2Cl2; soln. passed through a short plug of silica; solvent evapd; elem. anal.;97%
In acetone at 20℃; for 24h;85%
In acetone byproducts: LiCl; stirring soln. of gold compd. and lithium bromide in acetone at room temp. for 24 h; evapn., addn. of CH2Cl2, drying over MgSO4, filtration over silica gel, concn., addn. of pentane, filtration, washing with cold pentane, drying,elem. anal.;73%
[Ir(η5-C5Me5)(CO)(CF2CF3)I]

[Ir(η5-C5Me5)(CO)(CF2CF3)I]

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

lithium bromide
7550-35-8

lithium bromide

[iridium(III)(Cp*)(carbonyl)(perfluoroethyl)(bromide)]
1262658-90-1

[iridium(III)(Cp*)(carbonyl)(perfluoroethyl)(bromide)]

Conditions
ConditionsYield
In dichloromethane Schlenk technique, under N2; Ir complex (0.067 mmol) treated with Ag(OTf) (0.335 mmol) in CH2Cl2 soln. overnight, filtered, filtrate removed, treated with soln. of LiBr (0.192 mmol) for 1 h; solvent removed in vac., residue extracted with CH2Cl2, filtered, solvent removed under vac.; elem. anal.;97%
C29H37IrOP2S2

C29H37IrOP2S2

lithium bromide
7550-35-8

lithium bromide

C29H36BrIrP2S2

C29H36BrIrP2S2

Conditions
ConditionsYield
In toluene at 20℃; for 1h;97%
dihydrogen tetrachloropalladate(II)

dihydrogen tetrachloropalladate(II)

lithium bromide
7550-35-8

lithium bromide

ruphos
787618-22-8

ruphos

[HRuPhos]2[Pd2Br6]

[HRuPhos]2[Pd2Br6]

Conditions
ConditionsYield
Stage #1: dihydrogen tetrachloropalladate(II); ruphos In acetone at 18 - 27℃; for 0.5h;
Stage #2: lithium bromide In water; acetone
97%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl triflate

4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl triflate

lithium bromide
7550-35-8

lithium bromide

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

trans-bromo[4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II)

trans-bromo[4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;96.1%
[(η6-hexamethylbenzene)2Fe][PF6]2

[(η6-hexamethylbenzene)2Fe][PF6]2

lithium bromide
7550-35-8

lithium bromide

bis(η6-hexamethyl(benzene))iron(II) bromide

bis(η6-hexamethyl(benzene))iron(II) bromide

Conditions
ConditionsYield
In acetone filtration, washing (acetone) ,drying (vac.); elem. anal.;96%
[(C6H5(CH3)2P)ClPt((CH3)2NCH2CHCHCH2N(CH3)2)PtCl(P(CH3)2C6H5)]
82371-20-8

[(C6H5(CH3)2P)ClPt((CH3)2NCH2CHCHCH2N(CH3)2)PtCl(P(CH3)2C6H5)]

lithium bromide
7550-35-8

lithium bromide

[(C6H5(CH3)2P)BrPt((CH3)2NCH2CHCHCH2N(CH3)2)PtBr(P(CH3)2C6H5)]
82371-22-0

[(C6H5(CH3)2P)BrPt((CH3)2NCH2CHCHCH2N(CH3)2)PtBr(P(CH3)2C6H5)]

Conditions
ConditionsYield
In acetone educts refluxed together in acetone for 4 h; evapd. in vac., recrystd. from CH2Cl2-light petroleum; elem. anal.;96%
[Re(CH3O)(OClO3)(CO)(NO)(P(C6H5)3)2]*H2O
98481-43-7

[Re(CH3O)(OClO3)(CO)(NO)(P(C6H5)3)2]*H2O

lithium bromide
7550-35-8

lithium bromide

[ReBr(OCH3)(CO)(NO)(P(C6H5)3)2]
98481-45-9

[ReBr(OCH3)(CO)(NO)(P(C6H5)3)2]

Conditions
ConditionsYield
In methanol; dichloromethane dissolving Re methoxide in CH2Cl2-methanol (1:1) under N2; heating soln. to reflux; addn. of LiBr;; dichloromethane removed under reduced pressure; pptn.;;96%
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