Dayang Chem (Hangzhou) Co.,Ltd.
Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:10170-69-1
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryHenan Tianfu Chemical Co., Ltd.
Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:10170-69-1
Min.Order:1 Kilogram
FOB Price: $1000.0
Type:Lab/Research institutions
inquiryZhuozhou Wenxi import and Export Co., Ltd
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:10170-69-1
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryHenan Wentao Chemical Product Co., Ltd.
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:10170-69-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryHangzhou J&H Chemical Co., Ltd.
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:10170-69-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryAlity Chemical Corporation
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
Suzhou Health Chemicals Co., Ltd.
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Shanghai Acmec Biochemical Technology Co., Ltd.
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:10170-69-1
Min.Order:1 bottle
Negotiable
Type:Lab/Research institutions
inquiryXi`an Eastling Biotech Co., Ltd.
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou
Antimex Chemical Limied
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Hangzhou Fandachem Co.,Ltd
Manganese,decacarbonyldi-, (Mn-Mn) cas 10170-69-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
Cas:10170-69-1
Min.Order:0
Negotiable
Type:Other
inquiryHenan Kanbei Chemical Co.,LTD
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Hunan Russell Chemicals Technology Co.,Ltd
low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China
Cas:10170-69-1
Min.Order:0
Negotiable
Type:Trading Company
inquiryShanghai Chinqesen Biotechnology Co., Ltd.
Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen
Shanghai Terui OP New Material Technology Co., Ltd.
The factory supplies Application:manufacturing supplies
Cas:10170-69-1
Min.Order:0
Negotiable
Type:Trading Company
inquiryZHEJIANG JIUZHOU CHEM CO.,LTD
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
HENAN SUNLAKE ENTERPRISE CORPORATION
Our company is a professional production leading factory in China in pharmaceutical area of many years,our products have exported to USA, Greece, Spain, UK, Australia and other countries, and we have got very good feedback from our cust
Cas:10170-69-1
Min.Order:100 Kilogram
Negotiable
Type:Trading Company
inquiryChangzhou Extraordinary Pharmatech co.,LTD
Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa
Cas:10170-69-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryENAO Chemical Co, Limited
For quick quotation, please send us the inquiry include CAS#, Structure, Chemical Name, quantity, purity, as well as any additional specifications you require, we will try to get back to you within 24 hours. Our Services Besides manufacturing,
Hebei Ruishun Trade Co.,Ltd
Profile HeBei Ruishun Trade Co.LTD, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,Seek development by credit
Cas:10170-69-1
Min.Order:500 Gram
FOB Price: $1.0
Type:Trading Company
inquiryCerametek Materials（ShenZhen）Co., Ltd.
sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a
Hangzhou Share Chemical Co., Ltd
At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi
Strem Chemicals, Inc.
1.High Quality Specialty Chemicals2.Expertise and Experience in Manufacturing High Purity, High Quality Chemicals3.Long Term Focus in Inorganics, Organometallics and Metals4.ISO 9001 CertifiedAppearance:yellow xtl.
Shanghai Run-Biotech Co., Ltd.
Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por
Finetech Industry Limited
FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the Carbon monooxide - manganese (5:1), CAS:10170-69-1 with the most competitive price an
Cas:10170-69-1
Min.Order:0
Negotiable
Type:Trading Company
inquirySynthetic route
-
-
37504-44-2
(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate
-
-
13859-41-1
sodium pentacarbonyl manganate
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Kinetics; byproducts: NaPF6, MeCN; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy; | 100% |
| In tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M NaMn(CO)5 in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)PF6 in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR; | 88% |
-
-
13859-41-1
sodium pentacarbonyl manganate
-
-
96412-38-3
pentacarbonyl(pyridine)manganese(I) tetrafluoroborate
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Kinetics; byproducts: NaBF4, pyridine; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy; | 100% |
| In tetrahydrofuran NaMn(CO)5 (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(C5H5N)BF4, 0.3 M tetra-n-butylammonium perchlorate added, react. time approx. 30 min; |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
124401-76-9
2-methylisoquinolin-2-ium trifluoromethanesulfonate
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran react. at 20°C; | 100% |
-
-
16972-33-1
pentacarbonylhydridomanganese
-
-
85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))
-
-
639-58-7
triphenyltin chloride
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14405-84-6
triphenyltinmanganesepentacarbonyl
-
C
-
1333-74-0
hydrogen
| Conditions | Yield |
|---|---|
| In tetrahydrofuran under N2, soln. of HMn(CO)5 in THF was cooled to -23°C, added tosoln. of formyl-complex in THF (-23°C), warmed slowly to room temp., Ph3SnCl was added, stirred for 1 h; solvent removed by rotary evapn., vac. sublimed at 60°C, residueeluted through silica gel column with ethyl acetate-hexane; | A 69% B 99% C >90 |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
105-39-5
chloroacetic acid ethyl ester
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14100-30-2
pentacarbonylchloromanganese(I)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR; | A 1% B 0% C 99% |
| In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR; | A 1% B 0% C 99% |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| With N-t-butylbenzaldimine; NOPF6 In tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at room temp. for 45 min; not isolated; detected by IR; | 98% |
| With N-t-butylbenzaldimine; NOPF6 In tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at -78°C for 45 min; not isolated; detected by IR; | 95% |
| With NOPF6 In not given | |
| With triethylamine; NOPF6 In tetrahydrofuran Et3N in THF added to NOPF6, suspn. of Mn complex in THF added dropwise,stirred at room temp. for 1 h; |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
999-54-2
(E)-methyl 4-chlorobut-2-enoate
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14100-30-2
pentacarbonylchloromanganese(I)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR; | A 2% B 0% C 98% |
| Conditions | Yield |
|---|---|
| In hexane byproducts: HCOOC12H25, n-C12H25OH; N2-atmosphere; closed vessel, 48 bar CO/H2, 85°C, 11 h; cooling to room temp., solvent removal (vac.), dissoln. in 5% CH2Cl2/hexane, chromy. (SiO2, 5% CH2Cl2/hexane), evapn., drying (vac.); | 96% |
-
-
159983-78-5
Mn(CO)5(CO(CH2)10CH3)
-
-
201230-82-2
carbon monoxide
-
-
1333-74-0
hydrogen
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
16972-33-1
pentacarbonylhydridomanganese
| Conditions | Yield |
|---|---|
| In tetrahydrofuran N2-atmosphere; closed vessel, 48 bar CO/H2, 60°C, 8 h; cooling to room temp., solvent removal (vac.), dissoln. in 25% CH2Cl2/pentane, chromy. (SiO2, 5% CH2Cl2/pentane), evapn., drying (vac.); | A 95% B 5% |
-
-
600-00-0
ethyl 2-bromoisobutyrate
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
A
-
14516-54-2
bromopentacarbonylmanganese(I)
-
B
-
10170-69-1
dimanganese decacarbonyl
-
C
-
16972-33-1
pentacarbonylhydridomanganese
| Conditions | Yield |
|---|---|
| In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR; | A 5% B 95% C 0% |
| In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR; | A >99 B 0% C 0% |
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14100-30-2
pentacarbonylchloromanganese(I)
-
C
-
122967-79-7
(η3-C6H5CH2)Mn(CO)4
| Conditions | Yield |
|---|---|
| With tetrachloromethane In not given byproducts: CO; Irradiation (UV/VIS); irradn. (313 nm, Ar) in alkane solns. (purged with Ar) at 200K; not isolated, IR; | A 0% B 5% C 95% |
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
122967-79-7
(η3-C6H5CH2)Mn(CO)4
| Conditions | Yield |
|---|---|
| In not given byproducts: CO; Irradiation (UV/VIS); irradn. (313 nm, Ar) in alkane solns. (purged with Ar) at 200K; not isolated, IR; | A 5% B 95% |
| In methyl cyclohexane byproducts: CO, bibenzyl; Irradiation (UV/VIS); irradn. (Ar) in methylcyclohexane soln. at 295K; bibenzyl is the major org. product (ca 80%); not isolated, IR; | |
| In not given byproducts: CO; Irradiation (UV/VIS); irradn. (313 nm, Ar) in alkane soln. (deoxygenated with Ar) at 295K; the two account for >95% of the η1 complex consumed; prolonged photolysis leads to a buildup of the Mn2(CO)10; not isolated, IR; |
-
-
13859-41-1
sodium pentacarbonyl manganate
-
-
105-39-5
chloroacetic acid ethyl ester
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14100-30-2
pentacarbonylchloromanganese(I)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar); rapid mixing at room temp.; | A 6% B 0% C 94% |
-
-
14516-54-2
bromopentacarbonylmanganese(I)
-
-
59501-96-1
[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
1193-82-4
racemic methyl phenyl sulfoxide
-
C
-
882-33-7
diphenyldisulfane
-
D
-
7550-35-8
lithium bromide
| Conditions | Yield |
|---|---|
| In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation; | A 87% B 41% C 40% D 93% |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
A
-
10170-69-1
dimanganese decacarbonyl
-
-
241802-79-9
(bis(triphenylphosphoranylidene)ammonium)[Mn(CO)4(η(2)-C60)]
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Irradiation (UV/VIS); (Ar); addn. of C60 to a soln. of manganese complex in THF, photolysis atroom temp. for 48 h; cooling, filtration, addn. of hexanes, washing ppt. with toluene and hexanes, drying in vac.; | A n/a B 93% |
| In tetrahydrofuran (Ar); addn. of C60 to a soln. of manganese complex in THF, refluxing for18 h; cooling, filtration, addn. of hexanes, washing ppt. with toluene and hexanes, drying in vac.; | A n/a B 23% |
-
-
14516-54-2
bromopentacarbonylmanganese(I)
-
-
85320-10-1
(diphenylphosphino)cyclopentadienylthallium
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
62980-80-7
tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese
| Conditions | Yield |
|---|---|
| In benzene addn. of the Mn compd. to the Tl compd. in benzene in a Ar-flushed Schlenk flask and refluxing for 18 h; cooling to room temp., filtn. through a celite plug on a glas frit, evapn., chromy. of the residue on alumina, elution of the Mn2(CO)10 with pentane, elution with benzene and evapn.; elem. anal.; | A n/a B 92% |
-
-
85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))
-
-
639-58-7
triphenyltin chloride
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14405-84-6
triphenyltinmanganesepentacarbonyl
-
C
-
1333-74-0
hydrogen
| Conditions | Yield |
|---|---|
| In tetrahydrofuran under N2, soln. of Mn-complex in THF was freeze/thaw degassed, warmed to -40°C for 10 min and then to 24°C for 1 h, Ph3SnCl was added, stirred overnight; solvent removed under vac., chromd. on silica gel in benzene; | A 92% B 70% C >90 |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
86171-13-3
1-methylquinolin-1-ium trifluoromethanesulfonate
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran react. at 20°C; | 91% |
-
-
85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))
-
-
100-52-7
benzaldehyde
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
100-51-6
benzyl alcohol
| Conditions | Yield |
|---|---|
| With water In tetrahydrofuran under N2, soln. of Mn-complex was treated with benzaldehyde; | A 91% B 66% |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
97801-84-8
N-methylacridinium trifluoromethansulfonate
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
3295-69-0
10,10'-dimethyl-9,10,9',10'-tetrahydro-[9,9']biacridinyl
| Conditions | Yield |
|---|---|
| In acetonitrile educts mixed at -30°C, warmed to room temp.; | A 90% B 86% |
-
-
35816-56-9, 14971-26-7, 71564-22-2
pentacarbonylmanganate
-
-
27674-37-9
(acetonitrile)pentacarbonylmanganese(I) cation
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR; | 88% |
| In tetrahydrofuran byproducts: pyridine; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR; | 84% |
| In tetrahydrofuran Mn(CO)5(1-) (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(NCCH3)(1-), 0.3 M tetra-n-butylammonium perchlorate added, react. time approx. 30 min; | |
| In acetonitrile Mn(CO)5(1-) (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(NCCH3)(1+), react. time approx. 500 min; | |
| byproducts: MeCN; |
-
-
16972-33-1
pentacarbonylhydridomanganese
-
-
2206-26-0
[D3]acetonitrile
-
-
75-07-0
acetaldehyde
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
87682-27-7
CHOCH(CH3)OSi(CH3)3
| Conditions | Yield |
|---|---|
| In [D3]acetonitrile NMR tube charged with Mn complexes and CD3CN, cold acetaldehyde added, allowed to stand at room temp. for 0.5 h; chromd.; | A 8% B 76% C 88% |
-
-
13859-41-1
sodium pentacarbonyl manganate
-
-
999-54-2
(E)-methyl 4-chlorobut-2-enoate
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14100-30-2
pentacarbonylchloromanganese(I)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR; | A 12% B 0% C 88% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: NaBr, C; N2-atmosphere; mixing Mn-complex with excess carbide, THF addn., stirring (room temp., 4 h); extn. (hexanes), solvent removal (vac.); can be sublimed in vac. (50°C); | 86% |
-
-
85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))
-
-
639-58-7
triphenyltin chloride
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14405-84-6
triphenyltinmanganesepentacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran under N2, soln. of Mn-complex in THF was stirred for 0.5 h at room temp., solid Ph3SnCl was added, stirred for 0.5 h; solvent removed by rotary evapn., chromd. on silica gel (ethyl acetate-hexane), solvent removed by rotary evaporation, dissolved in hexane, placed in freezer for 2 d, filtered, vac. dried; | A 86% B 82% |
-
-
52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
-
-
623-48-3
ethyl iodoacetae
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14879-42-6
iodo(pentacarbonyl)manganese(I)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR; | A 0% B 85% C 85% |
| In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR; | A 16% B 17% C 67% |
-
-
15693-51-3
potassium[manganese(pentacarbonyl)]
-
-
999-54-2
(E)-methyl 4-chlorobut-2-enoate
-
A
-
10170-69-1
dimanganese decacarbonyl
-
B
-
14100-30-2
pentacarbonylchloromanganese(I)
-
C
-
32829-97-3
(2E,6E)-diethyl octa-2,6-dienedioate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR; | A 15% B 0% C 14% D 85% E 21% |
-
-
82495-39-4
((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylmanganese
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In diethyl ether byproducts: 1,2,4,5-tetraphenylbenzene; soln. of Mn-complex in Et2O was stirred overnight at 20°C, evapd. to dryness; residue was chromd. on silica gel/hexane column, eluted with hexane; detd. by IR; | 85% |
-
-
27674-37-9
(acetonitrile)pentacarbonylmanganese(I) cation
-
-
13859-41-1
sodium pentacarbonyl manganate
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: pyridine; addn. of 5 mL of 1E-2 M NaMn(CO)5 in THF to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR; | 84% |
-
-
14516-54-2
bromopentacarbonylmanganese(I)
-
-
13859-41-1
sodium pentacarbonyl manganate
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In tetrahydrofuran (N2 or Ar); 10 min; filtn., evapn., flash chromy.(silica/CH2Cl2), determination by NMR; | 84% |
-
-
10170-69-1
dimanganese decacarbonyl
-
A
-
14100-30-2
pentacarbonylchloromanganese(I)
-
B
-
67-72-1
hexachloroethane
| Conditions | Yield |
|---|---|
| With tetrachloromethane In tetrachloromethane byproducts: CCl3; Irradiation (UV/VIS); Irradiation λ >350 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;; | A n/a B 100% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; toluene stirring Mn2(CO)10 with Me3NO*2H2O in THF (18 h), solvent removal; recrystn. (hot toluene); | 100% |
| In toluene byproducts: trimethylammonium carbonate; treatment of Mn2(CO)10 with 6 equivs. of Me3NO, boiling of product in MePh; hot filtration, crystn. (5°C); second crop from mother liquor; elem. anal.; | 98% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
77938-10-4
bis(N,N-diethylselenocarbamoyl)monoselenide
-
-
60003-30-7
bis-(N,N-diethylselenocarbamoyl)triselenide
-
-
78528-81-1
Mn(CO)4((C2H5)2NCSe2)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Irradiation (UV/VIS); slight excess of the org. compounds (1:1), irradiated for 2 h at room temp. under N2; obtained from CH2Cl2/petroleum ether, elem. anal.; | 100% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
77938-11-5
bis(N,N-morpholylselenocarbamoyl)monoselenide
-
-
77938-12-6
bis(N,N-morpholylselenocarbamoyl)triselenide
-
-
78537-30-1
Mn(CO)4(OC4H8NCSe2)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Irradiation (UV/VIS); slight excess of the org. compounds (1:1), irradiated for 2 h at room temp. under N2; obtained from CH2Cl2/petroleum ether, elem. anal.; | 100% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
75-09-2
dichloromethane
-
-
1663-45-2
1,2-bis-(diphenylphosphino)ethane
-
-
49695-20-7
fac-Mn(CO)3(chloro)(1,2-bis(diphenylphosphino)ethane)
| Conditions | Yield |
|---|---|
| In dichloromethane autoclave (N2, 130°C, 2 h); solvent removal, recrystn. (CH2Cl2/hexane); | 99% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
201230-82-2
carbon monoxide
-
-
7664-39-3
hydrogen fluoride
-
-
7637-07-2
boron trifluoride
-
-
15557-71-8
hexacarbonylmanganese(I) tetrafluoroborate
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: H2; Mn2(CO)10, BF3, CO (0.6 bar), anhydrous HF were combined and stirred in tetrafluoroethylene-perfluorovinyl ether polymer flask at room temp., 10days; dynamic vac.; | 99% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
251546-77-7, 431896-21-8, 659737-28-7, 166986-33-0, 251546-79-9
(S)-N,N'-bis(2-hydroxy-3,5-di-tert-butylbenzylidene)-1,1'-binaphthyl-2,2'-diamine
-
-
173099-93-9
Mn(OH)(C20H12(NCHC6H2(C(CH3)3)2O)2)
| Conditions | Yield |
|---|---|
| With 1,5-diazabicyclo[4.3.0]non-5-ene In N,N-dimethyl-formamide addn. of Mn2(CO)10 to soln. of ligand and DBN (120°C, stirring), stirring for 6 h; cooling, pptn. on water addn., collection (filtration), washing (cold water, EtOH), dissoln. in CH2Cl2, filtration, solvent removal (vac.); elem. anal.; | 99% |
-
-
10170-69-1
dimanganese decacarbonyl
-
A
-
13755-29-8
sodium tetrafluoroborate
-
B
-
135224-95-2
(OC)3Fe(μ-η4:η1-cyclohexadiene)Mn(CO)5
| Conditions | Yield |
|---|---|
| With sodium amalgam In tetrahydrofuran (Ar), reduced Mn-complex (45 min at 0°C, 30 min at 20°C) added at -70°C, stirred for 1 h; solvent removed in vacuo at -30°C, extracted four times with pentane at -25°C (Mn2(CO)10 as by-product), extracted two times with CH2Cl2, solvent removed, dried in high vacuum, (all steps at <-20°C), elem. anal.; | A n/a B 98% |
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| In acetone Irradiation (UV/VIS); degassing with N2 for 20 min., Mn:Rh = 20:1, photolyzing for 2.25 h; removing the solvent, washing with hexane; | 97% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Irradiation (UV/VIS); under N2, irradiation for 20 h,; chromy. (silicic acid, elution CH2Cl2), elem. anal.; | 97% |
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: CO; under inert gas, Mn2(CO)10 contg. ampoule was evacuated under cooling, equimolar amt. of CF3-compd. was condensed into ampoule, heating sealed ampoule at 80 °C for 110 h and at 100 °C for 96 h; fractionated subl. under inert gas, elem. anal.; | 97% |
| In neat (no solvent) heated at 90-130°C in sealed ampoules; fractional sublimation; |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
14100-30-2
pentacarbonylchloromanganese(I)
| Conditions | Yield |
|---|---|
| With thionyl chloride In dichloromethane Product distribution / selectivity; Inert atmosphere; | 96% |
| With sulfuryl dichloride In dichloromethane (N2), soln. of the complex treated with SO2Cl2 at room temp. with stirring, stirred for 30 min at room temp.; solvent and excess SO2Cl2 removed under vacuum, washed with ethanol, dried in vacuo, elem. anal.; | 91% |
| With tetrachloromethane; dimethylglyoxal In tetrachloromethane Irradiation (UV/VIS); under N2, soln. of Mn-complex and biacetyl in CCl4 irradiated (436 nm) at 23.5°C; monitored by UV-vis spectra or IR spectra; |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
6737-42-4
1,3-bis-(diphenylphosphino)propane
-
-
148447-53-4
fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridomanganese(I)
| Conditions | Yield |
|---|---|
| In propan-1-ol under Ar, refluxed for 6 h; cooled, solvent removed, extd. (benzene), addn. of hexane, filtered, washed with hexane, dried under vac.; elem. anal.; | 96% |
| In propan-1-ol (Ar); using Schlenk techniques; (Organometallics 1993, 12, 1714-1719); |
-
-
10170-69-1
dimanganese decacarbonyl
| Conditions | Yield |
|---|---|
| With Na/Hg In tetrahydrofuran under Ar, redn. with Na/Hg, soln. cooled to -70°C, addn. of Fe-compd., slowly warmed to room temp.; centrifuged, washed with H2O, acetone and pentane, dried (vac., 6 h); | 96% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
13859-41-1
sodium-manganese pentacarbonyl
| Conditions | Yield |
|---|---|
| With sodium amalgam In tetrahydrofuran inert atm., 2 h, filtration,; solvent removal (vac., room temp.); | 95% |
| With sodium amalgam In tetrahydrofuran 0.1% sodium amalgam added to soln. Mn2(CO)10 in THF, mixt. stirrred vigorously for 1 h; excess amalgam removed from yellow soln., soln. passed through Celite; | |
| With sodium amalgam In tetrahydrofuran filtration; recrystn. (addn. of n-hexane); |
| Conditions | Yield |
|---|---|
| In toluene at 0 - 20℃; for 24h; Inert atmosphere; Schlenk technique; | 95% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
829-84-5
dicyclohexylphosphane
| Conditions | Yield |
|---|---|
| With hydrogenchloride; n-butyllithium In tetrahydrofuran; diethyl ether; hexane all steps under Ar and under air and moisture exclusion, addn. of a soln. of BuLi (hexane) to a soln. of phosphane(hydrido)Mn complex (fresh prepd. from Mn2(CO)10, KHB(s-Bu)3, HCl-ether and the phosphane in THF); evapg. of solvent, washing (hexane); | 94% |
-
-
10170-69-1
dimanganese decacarbonyl
-
-
66034-78-4
pentacarbonyl(perchlorato)manganese
| Conditions | Yield |
|---|---|
| With TFAA In water stirring (0°C, 1.5 h); evapn. (vac.), drying (MgSO4), CH2Cl2 addn., filtering, pptn. on Et2O addn., drying (vac.); | 94% |
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