As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:928-90-5
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryColorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be sent
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:928-90-5
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryName 5-Hexyn-1-ol/Hex-5-yn-1-ol CAS NO. 928-90-5 Molecular Formula C6H10O Molecular Weight 98.14 Appearance Colorless Cl
1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
5-HEXYN-1-OL CAS:928-90-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates,
Cas:928-90-5
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
superior quality moderate price & quick delivery Appearance:Clear pale yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:928-90-5
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryProduct name: Hex-5-yn-1-ol CAS No.:928-90-5 Molecule Formula:C6H10O Molecule Weight:98.14 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS SPECIFIC
Cas:928-90-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquirycolor Colorless to pale yellow Specific Gravity 0.880 Water Solubility Slightly miscible with water. BRN 1739774 CAS DataBase Reference 928-90-5(CAS DataBase Reference) Safety Information Hazard Codes Xi Risk Statements 36/
Shanghai Massive Chemical Technology Co., Ltd. is engaged in development, production and marketing Specialty Chemicals to satisfy the changing needs of the chemical industry. We specialize in manufacturing high quality of Advanced Intermediates, Sp
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:928-90-5
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:928-90-5
Min.Order:1 bottle
Negotiable
Type:Lab/Research institutions
inquiryhigh qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Cas:928-90-5
Min.Order:0
Negotiable
Type:Manufacturers
inquiry1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Product name:5-HEXYN-1-OL Synonyms:1-Hydroxy-5-hexyne;5-hexyn-1-0l;6-Hydroxy-1-hexyne;Hex-5-yn-1-ol CAS No:928-90-5 Molecular formula:C6H10O Molecular Weight:98.14 Appearance:Colorless to pale yellow Liquid Melting point - 34 ° C (estimate)
Cas:928-90-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China
good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran
We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use
tert-butyldimethylsilyl hex-5-yn-1-yl ether
5-hexyl-1-ol
Conditions | Yield |
---|---|
With hydrogenchloride In methanol; water at 23℃; for 1h; Inert atmosphere; | 93% |
With triethylamine hydrofluoride In tetrahydrofuran at 50℃; for 19h; var. reag.: (n-Bu)4N(1+)*F(1-); | 86% |
Conditions | Yield |
---|---|
With ammonium nitrate; Montmorillonite-K10 for 0.0583333h; deprotection; microwave irradiation; | 86% |
With ethanol; pyridinium p-toluenesulfonate at 55℃; var. reag.: TsOH, MeOH, 25 deg C, 7 h; | 73% |
With pyridinium p-toluenesulfonate In ethanol at 25℃; for 3h; |
2-(chloromethyl)tetrahydropyran
5-hexyl-1-ol
Conditions | Yield |
---|---|
With sodium amide; ferric nitrate In ammonia Whiting's double elimination; | 85% |
With sodium amide In ammonia | 83% |
With Iron(III) nitrate nonahydrate; ammonia; sodium for 4h; Cooling; | 67% |
hex-5-ynoic acid
5-hexyl-1-ol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 15h; Inert atmosphere; | 82% |
With LiAlH4 In diethyl ether |
1-((hex-5-yn-1-yloxy)methyl)-4-methoxybenzene
5-hexyl-1-ol
Conditions | Yield |
---|---|
With trichlorophosphate In 1,2-dichloro-ethane at 20℃; for 0.833333h; | 80% |
With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium nitrite at 20℃; for 18h; Green chemistry; chemoselective reaction; | 72% |
Conditions | Yield |
---|---|
With sodium hydride; ethylenediamine In mineral oil at 0 - 70℃; | 52% |
With sodium amide In various solvent(s) | |
With potassium tert-butylate; lithium; Trimethylenediamine at 20℃; Zipper reaction; Inert atmosphere; |
Conditions | Yield |
---|---|
With indium (III) iodide; Dimethylphenylsilane In dichloromethane at 20℃; for 1.66667h; Inert atmosphere; chemoselective reaction; | A 40% B 22 %Spectr. |
nitrite d'hexyne-5 ol-1
A
5-hexyl-1-ol
B
5-hexynal
C
(hydroxy-3 propyl)-3 isoxazole
Conditions | Yield |
---|---|
In benzene at 10 - 20℃; for 26h; Irradiation; | A 17% B 5% C 11% |
Conditions | Yield |
---|---|
With propane-1,3-diamine potassium salt |
5-hexyn-1-yl acetate
5-hexyl-1-ol
Conditions | Yield |
---|---|
With potassium hydroxide In methanol Heating; |
hex-5-ynyloxy-trimethyl-silane
5-hexyl-1-ol
Conditions | Yield |
---|---|
With sulfuric acid |
methyl hex-5-ynoate
5-hexyl-1-ol
2-(chloromethyl)tetrahydropyran
ammonia
5-hexyl-1-ol
1-chloro-4-tetrahydropyranyloxybutane
5-hexyl-1-ol
Conditions | Yield |
---|---|
Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
Stage #1: Tetrahydropyran-2-methanol With pyridine; thionyl chloride Stage #2: With ammonia; sodium amide Further stages.; | |
Multi-step reaction with 2 steps 1: 65 percent / SOCl2 / pyridine / 8 h / 45 °C 2: 85 percent / NaNH2 / Fe(NO3)3*9H2O / liquid ammonia View Scheme | |
Multi-step reaction with 2 steps 1: SOCl2 / pyridine 2: Na / liquid ammonia View Scheme |
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; isopropylamine; copper(l) chloride In ethanol for 18h; Inert atmosphere; |
1-(tert-butyldiphenylsilyloxy)-5-hexyne
5-hexyl-1-ol
Conditions | Yield |
---|---|
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); sulfuric acid; water In methanol at 20℃; for 24h; Inert atmosphere; |
1-(tert-butyldiphenylsilyloxy)-5-hexyne
A
5-hexyl-1-ol
B
6-(tert-butyldiphenylsilyloxy)hexan-2-one
Conditions | Yield |
---|---|
With 2-dicyclohexyl(2′,6′-dimethoxybiphenyl)phosphine gold(I)bis(trifluoromethanesulfonyl)imide; water In methanol at 20℃; Inert atmosphere; | A 15 %Chromat. B 85 %Chromat. |
Conditions | Yield |
---|---|
With potassium tert-butylate In tert-butyl alcohol at 40℃; for 24h; Reflux; |
5-hydroxypentanal
dimethyl 1-(1-diazo-2-oxopropyl)phosphonate
5-hexyl-1-ol
Conditions | Yield |
---|---|
With potassium carbonate In methanol at 20℃; for 5.5h; Seyferth-Gilbert Homologation; |
valeric acid
5-hexyl-1-ol
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 4-methyl-morpholine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; benzotriazol-1-ol / dichloromethane / 6 h / 20 °C 2: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 0 °C 3: potassium carbonate / methanol / 5.5 h / 20 °C View Scheme |
5-hydroxy-N,O-dimethyl-pentanohydroxamic acid
5-hexyl-1-ol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 0 °C 2: potassium carbonate / methanol / 5.5 h / 20 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere 1.2: 3.17 h / -78 - 23 °C / Inert atmosphere 2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium bromide; sodium hydrogencarbonate / dichloromethane; water / 0 °C / Inert atmosphere 2.2: 0.25 h / 0 - 23 °C / Inert atmosphere 3.1: triphenylphosphine / dichloromethane / 3.17 h / 0 - 23 °C / Inert atmosphere 4.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 - 23 °C / Inert atmosphere 5.1: hydrogenchloride / water; methanol / 1 h / 23 °C / Inert atmosphere View Scheme |
5-(tert-butyldimethyl-silyloxy)pentan-1-ol
5-hexyl-1-ol
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium bromide; sodium hydrogencarbonate / dichloromethane; water / 0 °C / Inert atmosphere 1.2: 0.25 h / 0 - 23 °C / Inert atmosphere 2.1: triphenylphosphine / dichloromethane / 3.17 h / 0 - 23 °C / Inert atmosphere 3.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 - 23 °C / Inert atmosphere 4.1: hydrogenchloride / water; methanol / 1 h / 23 °C / Inert atmosphere View Scheme |
5-tert-butyldimethylsilyloxypentanal
5-hexyl-1-ol
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: triphenylphosphine / dichloromethane / 3.17 h / 0 - 23 °C / Inert atmosphere 2: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 - 23 °C / Inert atmosphere 3: hydrogenchloride / water; methanol / 1 h / 23 °C / Inert atmosphere View Scheme |
1,1-dibromo-6-(tert-butyldimethylsiloxy)hex-1-ene
5-hexyl-1-ol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 - 23 °C / Inert atmosphere 2: hydrogenchloride / water; methanol / 1 h / 23 °C / Inert atmosphere View Scheme |
3,4-dihydro-2H-pyran
5-hexyl-1-ol
2-(hex-5-yn-1-yloxy)tetrahydro-2H-pyran
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In dichloromethane at 0℃; for 1.25h; | 100% |
With water; sodium hydrogencarbonate; 8-aminopyrene-1,3,6-trisulfonic acid, trisodium salt | 98% |
toluene-4-sulfonic acid In dichloromethane | 98% |
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol With ethylmagnesium bromide Stage #2: chloro-trimethyl-silane Stage #3: With sulfuric acid In tetrahydrofuran | 100% |
Stage #1: 5-hexyl-1-ol With n-butyllithium In tetrahydrofuran at -78℃; Inert atmosphere; Stage #2: chloro-trimethyl-silane In tetrahydrofuran at -78 - 0℃; Inert atmosphere; Stage #3: With hydrogenchloride In tetrahydrofuran; water at 0 - 20℃; Inert atmosphere; | 100% |
Stage #1: 5-hexyl-1-ol With dmap; n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: chloro-trimethyl-silane at -78 - 20℃; for 2h; Inert atmosphere; | 99% |
5-hexyl-1-ol
tert-butyldimethylsilyl chloride
tert-butyldimethylsilyl hex-5-yn-1-yl ether
Conditions | Yield |
---|---|
With dmap; triethylamine In dichloromethane for 20h; Ambient temperature; | 100% |
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 0.333333h; Inert atmosphere; | 100% |
With 1H-imidazole; dmap In dichloromethane at 20℃; for 1h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; | 100% |
With triethylamine In diethyl ether at 0℃; for 3h; | 99% |
With triethylamine In dichloromethane at 0 - 20℃; for 14h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With zirconocene dichloride In hexane; 1,2-dichloro-ethane at 20℃; for 22h; Addition; | 100% |
Conditions | Yield |
---|---|
With rhodium hydrido (PEt3)3 complex; trifluorormethanesulfonic acid; P(p-CH3OC6H4)3 In acetone for 10h; Heating; | 100% |
5-hexyl-1-ol
A
(E)-6-iodo-5-hexen-1-ol
B
(Z)-6-iodo-5-hexene-1-ol
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 3.5h; Heating; Stage #2: With iodine In dichloromethane at 0℃; for 1.3h; Title compound not separated from byproducts; | A 100% B n/a |
Multi-step reaction with 2 steps 1: 2,2'-azobis(isobutyronitrile) / tetrahydrofuran / 14 h / 80 - 90 °C / Inert atmosphere 2: iodine / dichloromethane / 14 h / 80 - 90 °C / Inert atmosphere View Scheme |
Conditions | Yield |
---|---|
With pyridine; dmap In dichloromethane at 0 - 20℃; for 1h; | 100% |
With dmap; triethylamine In dichloromethane at 0 - 20℃; | 100% |
With triethylamine In dichloromethane at 0 - 20℃; | 99% |
4-(4-bromophenyl)-3-butyn-1-ol
5-hexyl-1-ol
6-(4-(4-hydroxy-1-butynyl)phenyl)-5-hexyn-1-ol
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine; tetrakis(triphenylphosphine) palladium(0) In dichloromethane at 50℃; Sonogashira reaction; | 100% |
4-(4-bromophenyl)-4-pentyn-1-ol
5-hexyl-1-ol
6-(4-(5-hydroxy-1-pentynyl)phenyl)-5-hexyn-1-ol
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine; tetrakis(triphenylphosphine) palladium(0) In dichloromethane at 50℃; Sonogashira reaction; | 100% |
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol; para-iodoanisole With copper(l) iodide; N-ethyl-N,N-diisopropylamine; triphenylphosphine In tetrahydrofuran for 1h; Sonogashira coupling; Stage #2: bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran for 12h; | 100% |
With copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triethylamine In tetrahydrofuran at 20℃; Sonogashira Cross-Coupling; Inert atmosphere; | 96% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 2.5h; | 94% |
Conditions | Yield |
---|---|
Stage #1: 4-tolyl iodide With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 0.166667h; Stage #2: 5-hexyl-1-ol at 20℃; | 100% |
With C24H28Cl2N2PPd; tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 110℃; for 6h; Sonogashira Cross-Coupling; Inert atmosphere; | 96% |
With potassium phosphate; copper(l) iodide; (E)-1,1-diphenyl-2-(pyridin-2-ylmethylene)hydrazine; dichloro bis(acetonitrile) palladium(II) In N,N-dimethyl-formamide at 70℃; for 5h; Sonogashira cross-coupling; | 73% |
Conditions | Yield |
---|---|
With Amberlyst In hexane at 20℃; for 14h; Inert atmosphere; | 100% |
5-hexyl-1-ol
1,4-dioxaspiro[4.5]dec-7-en-8-yl trifluoromethanesulfonate
Conditions | Yield |
---|---|
With copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triethylamine In tetrahydrofuran at 20℃; Sonogashira Cross-Coupling; Inert atmosphere; | 100% |
5-hexyl-1-ol
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine In N,N-dimethyl-formamide at 50℃; Inert atmosphere; | 100% |
5-hexyl-1-ol
4-methoxy-benzoyl chloride
1-((hex-5-yn-1-yloxy)methyl)-4-methoxybenzene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 18h; Inert atmosphere; | 100% |
5-hexyl-1-ol
6-azidohexan-1-ol
6-(4-(4-hydroxybutyl)-1H-1,2,3-triazol-1-yl)hexan-1-ol
Conditions | Yield |
---|---|
With polyvinylpyrrolidone coated copper(I) oxide nanoparticles In water at 37℃; for 48h; Sonication; | 99.8% |
Conditions | Yield |
---|---|
With pyridine at 0℃; for 16h; | 99% |
With 1-methyl-1H-imidazole; triethylamine In toluene at 20℃; for 1h; Cooling with ice; | 99.7% |
With pyridine at 0℃; for 6h; | 98% |
5-hexyl-1-ol
6-bromo-1-hexyne
Conditions | Yield |
---|---|
With carbon tetrabromide; triphenylphosphine In dichloromethane at 20℃; for 1h; Inert atmosphere; | 99% |
With bromine; triphenylphosphine In acetonitrile at 0℃; | 87% |
With carbon tetrabromide; triphenylphosphine In diethyl ether for 1h; Ambient temperature; | 65% |
Conditions | Yield |
---|---|
With pyridine at 20℃; for 3h; | 99% |
With pyridine for 3h; Ambient temperature; | 97% |
With dmap; potassium carbonate In ethyl acetate | 95% |
5-hexyl-1-ol
tert-butylchlorodiphenylsilane
1-(tert-butyldiphenylsilyloxy)-5-hexyne
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol With 1H-imidazole In dichloromethane at 0℃; for 0.166667h; Stage #2: tert-butylchlorodiphenylsilane In dichloromethane at 0 - 20℃; for 17h; | 99% |
With 1H-imidazole In tetrahydrofuran at 20℃; | 96% |
With 1H-imidazole In tetrahydrofuran at 20℃; for 2h; | 96% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 12h; Inert atmosphere; | 99% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 18h; Inert atmosphere; | 99% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine In tetrahydrofuran at 20℃; | 98% |
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; Schlenk technique; Inert atmosphere; | 99% |
Stage #1: 5-hexyl-1-ol With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Stage #2: benzyl bromide In tetrahydrofuran at 0 - 20℃; for 90h; | 99% |
With tetra-(n-butyl)ammonium iodide; potassium hydride In tetrahydrofuran at 0 - 25℃; Inert atmosphere; | 97% |
5-hexyl-1-ol
p-methoxybenzyl chloride
1-((hex-5-yn-1-yloxy)methyl)-4-methoxybenzene
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 18h; Inert atmosphere; | 99% |
With sodium hydride In mineral oil | 99% |
Stage #1: 5-hexyl-1-ol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 2h; Inert atmosphere; Stage #2: p-methoxybenzyl chloride With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; mineral oil at 20℃; for 24h; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; Sonogashira coupling; | 99% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 13h; Sonogashira coupling; | 99% |
Stage #1: 5-hexyl-1-ol; o-nitroiodobenzene With bis-triphenylphosphine-palladium(II) chloride; triethylamine; triphenylphosphine In N,N-dimethyl-formamide for 0.5h; Sonogashira coupling; Inert atmosphere; Stage #2: With copper(l) iodide In N,N-dimethyl-formamide at 20℃; for 5.16667h; Sonogashira coupling; Inert atmosphere; | 71% |
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol With triethyl borane; dichloroindium hydride In tetrahydrofuran; hexane at -78℃; for 2.5h; Stage #2: p-nitrobenzene iodide With 1,3-dimethyl-2-imidazolidinone; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; trifuran-2-yl-phosphane In tetrahydrofuran; hexane for 0.5h; Heating; | 99% |
Stage #1: 5-hexyl-1-ol With indium(III) chloride; triethyl borane; diisobutylaluminium hydride In tetrahydrofuran; hexane at -78℃; for 2.5h; Stage #2: p-nitrobenzene iodide With trifuran-2-yl-phosphane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In tetrahydrofuran; hexane at 66℃; for 0.5h; Further stages.; | 99% |
Conditions | Yield |
---|---|
With copper(l) iodide; diisopropylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride at 84℃; for 6h; Sonogashira coupling; | 99% |
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol With indium(III) chloride; triethyl borane; diisobutylaluminium hydride In tetrahydrofuran; hexane at -40℃; for 2.5h; Stage #2: 3-methoxy-1-iodobenzene With trifuran-2-yl-phosphane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In tetrahydrofuran; hexane at 66℃; for 0.5h; Further stages.; | 99% |
Conditions | Yield |
---|---|
With sodium azide; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium L-ascorbate; copper(l) iodide In dimethyl sulfoxide at 20℃; for 1.5h; | 99% |
triisopropylsilyl chloride
5-hexyl-1-ol
6-(triisopropyl-silanyl)hex-5-yn-1-ol
Conditions | Yield |
---|---|
Stage #1: 5-hexyl-1-ol With ethylmagnesium bromide In tetrahydrofuran for 8h; Heating; Stage #2: triisopropylsilyl chloride In tetrahydrofuran for 18h; Heating; Further stages.; | 99% |
Stage #1: 5-hexyl-1-ol With ethylmagnesium chloride In tetrahydrofuran at 20℃; Inert atmosphere; Reflux; Stage #2: triisopropylsilyl chloride In tetrahydrofuran for 4h; Inert atmosphere; Reflux; | 85% |
Stage #1: 5-hexyl-1-ol With ethylmagnesium chloride In tetrahydrofuran for 16h; Heating; Stage #2: triisopropylsilyl chloride In tetrahydrofuran for 6h; Heating; | 80% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View