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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

Tosyl chloride

Cas:98-59-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White crystalline powder Comply Chroma (APHA): ≤30

High purity PARA TOLUENE SULFONYL CHLORIDE with high quality cas:98-59-9

Cas:98-59-9

Min.Order:1 Metric Ton

FOB Price: $2800.0 / 3300.0

Type:Manufacturers

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-toluene sulfochloride supplier in China

Cas:98-59-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Kono Chem Co.,Ltd

Trade Name: 4-Toluene sulfonyl chloride(PTSC) Molecular formula: C7H7ClO2S CAS No: 98-59-9 Certificate of Analysis Product Name: 4-Toluene sulfonyl chloride(PTSC) 4-Toluene sulfonyl chloride(PTSC);T

CAS: 98-59-9 Tosyl chloride hot sales

Cas:98-59-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Jinan Finer Chemical Co., Ltd

Product Description Product Name Tosyl chloride CAS No. 98-59-9 Appearance White crystalline powder Assay ≥99% Capacity 1000mt/year Min.p

Tosyl chloride

Cas:98-59-9

Min.Order:1 Gram

FOB Price: $34.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Tosyl chloride CAS NO.98-59-9

Cas:98-59-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for Tosyl Chloride Cas 98-59-9 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:White Powder Storage:Store at RT. Package:1kg/foil bag, 25kg/drum or

Bottom price high quality Tosyl Chloride Cas 98-59-9 with best purity and fast delivery

Cas:98-59-9

Min.Order:1 Kilogram

FOB Price: $90.0

Type:Trading Company

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Hefei TNJ chemical industry co.,ltd

Service we can provide: 1. mixed container: we can mix different items in one container. 2. quality control: before shipment, we can provide free sample for test. inspection before shipping. 3. packing: we can pack according to your requireme

Tosyl Chloride (PTSC) CAS 98-59-9

Cas:98-59-9

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

P-Toluene Sulfony Chloride CAS No.: 98-59-9 Technical index for purified product: Appearance: White crystalline Melting Point:67-69οCï¼› Boiling point:134οC (10 mmH

P-Toluene Sulfony Chloride

Cas:98-59-9

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Tosyl chloride

Cas:98-59-9

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

4-Methylbenzenesulfonyl chloride

Cas:98-59-9

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Tosyl chloride ( p-Toluenesulfonyl Chloride ) -- CHemwill

Cas:98-59-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

98-59-9,C7H7ClO2S

Cas:98-59-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

English name: Tosyl chloride P-Methylbenzenesulfonyl chloride; para-toluenesulfochloride; p-Methylbenzenesulfonyl chloride; p-Methylbenzenesulfonyl chloride; p-Methylbenzenesulfonyl chloride; p-Methylbenzenesulfonyl chloride; p-Methylbenzenesulfo

Tosyl chloride

Cas:98-59-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White powder Storage:Store in sealed containers at cool & dr

High purity intermediates Tosyl chloride(CAS:98-59-9)

Cas:98-59-9

Min.Order:100 Gram

Negotiable

Type:Other

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Shijiazhuang Sdyano Fine Chemical Co., Ltd

1. Best prices with satisfied quality; 2. It's clients' right to choose the package's Courier (EMS, DHL, FedEx, UPS); 3.It's clients' right to choose the packing way for his produccts from many recent effective packing w

Tosyl chloride

Cas:98-59-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Synonyms: 4-methyl-benzenesulfonylchlorid;4-toluenesulfonicacid,chloride;4-Tosyl chloride;Benzenesulfonylchloride,4-methyl-;m-methylbenzenesulfonylchloride;para-toluenesulfochloride;para-toluenesulfonchloride;p-Methylbenzenesulfonyl chloride CAS:

Tosyl chloride 98-59-9 large in supply

Cas:98-59-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:98-59-9

Cas:98-59-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

p-Toluenesulfonyl chloride

Cas:98-59-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Tosyl chloride

Cas:98-59-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Tosyl chloride

Cas:98-59-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

Bottom price high quality Tosyl Chloride Cas 98-59-9 with best purity and fast deliveryAppearance:White Powder Storage:Store at RT. Package:according to customers' requirements Application:Organic Synthesis Transportation:By air(EMS or EUB or FedEx o

Siwei Development Group Ltd.

Product name: 4-Toluene Sulfonyl Chloride CAS No.:98-59-9 Molecule Formula:C7H7ClO2S Molecule Weight:190.65 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality 4-Toluene Sulfonyl Chloride

Cas:98-59-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Tosyl chloride

Cas:98-59-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Tosyl chloride

Cas:98-59-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Hangzhou Yunuo Chemical Co., Ltd is located in Hangzhou city China. As a global supplier in the chemical industry, Yunuochem is to create added value for customers around the world. Sticking to such business idea of "Good faith wins the busine

Tosyl chloride 99% min

Cas:98-59-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Benzenesulfonylchloride, 4-methyl-

Cas:98-59-9

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

4-Toluenesulfonyl chloride

Cas:98-59-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

P-Toluene Sulfony Chloride

Cas:98-59-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home

Tosyl chloride china manufacture

Cas:98-59-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

para-thiocresol
106-45-6

para-thiocresol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With dihydrogen peroxide; zirconium(IV) chloride In water; acetonitrile at 25℃; for 0.0166667h;99%
With N,N,N',N'-tetrachlorobenzene-1,3-disulphonamide; tetrabutyl-ammonium chloride; water In acetonitrile at 0 - 20℃; for 0.333333h;98%
With trichloroisocyanuric acid; water In acetonitrile at 0 - 20℃; for 0.333333h;98%
triethylammonium toluene-p-sulfonate
15404-00-9

triethylammonium toluene-p-sulfonate

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With sulfuryl dichloride; triphenylphosphine In dichloromethane for 1h; Ambient temperature;99%
p-toluidine
106-49-0

p-toluidine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
Stage #1: p-toluidine With hydrogenchloride; acetic acid; sodium nitrite In water; acetonitrile at 0 - 5℃;
Stage #2: With sulfur dioxide; copper dichloride In water; acetonitrile at 20℃; for 16h;
99%
Stage #1: p-toluidine With hydrogenchloride; sodium nitrite
Stage #2: With sulfur dioxide; copper(l) chloride In acetone
di(p-tolyl) disulfide
103-19-5

di(p-tolyl) disulfide

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With dihydrogen peroxide; zirconium(IV) chloride In water; acetonitrile at 25℃; for 0.0166667h;98%
With Oxone; potassium chloride In water at 20℃; for 0.166667h;96%
With N,N,N',N'-tetrachlorobenzene-1,3-disulphonamide; tetrabutyl-ammonium chloride; water In acetonitrile at 0 - 20℃; for 0.333333h;95%
toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; triethylamine In acetone for 20h; Heating;96%
Stage #1: toluene-4-sulfonic acid With potassium phosphate; bis(trichloromethyl) carbonate In dichloromethane at 0 - 5℃; for 0.0833333h;
Stage #2: With triethylamine In dichloromethane at 20℃; for 0.5h;
96%
With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; potassium chloride at 25℃; for 0.0333333h; Neat (no solvent);94%
C15H17ClN2O2S
146404-41-3

C15H17ClN2O2S

A

1-chloro-4-(2-chloroethyl)benzene
32327-70-1

1-chloro-4-(2-chloroethyl)benzene

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With N-chloro-succinimide In tetrahydrofuran for 16h; Ambient temperature; Irradiation;A 95%
B n/a
sodium tosylate
657-84-1

sodium tosylate

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; 18-crown-6 ether In acetone for 20h; Heating;94%
Stage #1: sodium tosylate With potassium phosphate; bis(trichloromethyl) carbonate In dichloromethane at 0 - 5℃; for 0.0833333h;
Stage #2: With triethylamine In dichloromethane at 20℃; for 0.5h;
93%
With trichlorophosphate In sulfolane; acetonitrile at 68 - 72℃; for 0.666667h;87%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With chlorine In water; toluene Product distribution / selectivity;93.9%
2-chloro-1,3-dimethylimidazolinium chloride
37091-73-9

2-chloro-1,3-dimethylimidazolinium chloride

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene93.2%
phenyl benzenesulfonate
4358-63-8

phenyl benzenesulfonate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With phenylchlorosulfate; C43H43NO3PPdS; sodium carbonate In acetone at 20 - 50℃; Inert atmosphere; Sealed tube;93%
toluene
108-88-3

toluene

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With chlorosulfonic acid at 0℃; for 4h;92%
With chlorosulfonic acid at 0 - 20℃;84.21%
With chlorosulfonic acid
3-phenylpropanal p-tosylhydrazone
61124-61-6

3-phenylpropanal p-tosylhydrazone

A

p-toluenesulfonyl hydrazide hydrochloride

p-toluenesulfonyl hydrazide hydrochloride

B

5-Benzyl-1,2,3-thiadiazole
80491-28-7

5-Benzyl-1,2,3-thiadiazole

C

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With disulfur dichloride In dichloromethane at 20℃; for 0.5h; Product distribution; other reagents (SOCl2, SCl2) and time;A n/a
B 89%
C n/a
1-tosyl-1-hexadecylhydrazine
146404-40-2

1-tosyl-1-hexadecylhydrazine

A

1-Chlorohexadecan
4860-03-1

1-Chlorohexadecan

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With N-chloro-succinimide In tetrahydrofuran for 16h; Ambient temperature; Irradiation;A 88%
B n/a
With N-chloro-succinimide In tetrahydrofuran for 16h; Product distribution; Mechanism; Ambient temperature; Irradiation; reactions of N-substituted-N-tosylhydrazines with NCS and NBS;A 88%
B n/a
mesityl oxide p-tosylhydrazone
5362-76-5

mesityl oxide p-tosylhydrazone

A

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

C

4-(2-Chloro-2-methyl-propyl)-[1,2,3]thiadiazole

4-(2-Chloro-2-methyl-propyl)-[1,2,3]thiadiazole

D

5-(1-Chloro-1-methyl-ethyl)-4-methyl-[1,2,3]thiadiazole

5-(1-Chloro-1-methyl-ethyl)-4-methyl-[1,2,3]thiadiazole

Conditions
ConditionsYield
With sulfur dichloride In dichloromethane at 20℃; for 0.5h; Product distribution; other reagents (SOCl2, S2Cl2), products and time;A n/a
B n/a
C 9%
D 85%
diphenyl diselenide
1666-13-3

diphenyl diselenide

toluene-4-sulfonic acid hydrazide
1576-35-8

toluene-4-sulfonic acid hydrazide

A

p-tolyl benzeneselenosulfonate
68819-94-3

p-tolyl benzeneselenosulfonate

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With sulfuryl dichloride; triethylamine In pyridine; dichloromethane at 0℃; Product distribution; various reagents for preparation of diverse selenosulfonates; mechanism is proposed;A 83%
B 11%
p-toluenesulfonyl iodide
1950-78-3

p-toluenesulfonyl iodide

triphenyl(phenylazo)methane
981-18-0

triphenyl(phenylazo)methane

A

iodobenzene
591-50-4

iodobenzene

B

di(4-methyl)phenylthiosulfonate
2943-42-2

di(4-methyl)phenylthiosulfonate

C

p-toluenesulfonylanhydride
4124-41-8

p-toluenesulfonylanhydride

D

p-tolyl triphenylmethyl sulphone
42756-18-3

p-tolyl triphenylmethyl sulphone

E

chlorobenzene
108-90-7

chlorobenzene

F

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
In tetrachloromethane at 0℃; for 2h; Product distribution;A 82%
B n/a
C n/a
D 78%
E 1%
F n/a
1-Tosyl-1-<2-(4-methoxyphenyl)ethyl>hydrazine
141666-87-7

1-Tosyl-1-<2-(4-methoxyphenyl)ethyl>hydrazine

A

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

B

1-(2-Chloroethyl)-4-methoxybenzene
18217-00-0

1-(2-Chloroethyl)-4-methoxybenzene

Conditions
ConditionsYield
With N-chloro-succinimide In tetrahydrofuran for 16h; Ambient temperature; Irradiation;A n/a
B 82%
p-toluene sulfinic acid
536-57-2

p-toluene sulfinic acid

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With tert-butylhypochlorite In dichloromethane for 2h; Ambient temperature; chloramine-T, CH2Cl2, RT;81%
With water; chlorine
With N-chloro-succinimide In tetrahydrofuran Ambient temperature; Irradiation; Yield given;
Multi-step reaction with 2 steps
1: 81 percent / CH2Cl2 / 2 h / Ambient temperature
2: 1.) n-butyllithium, 2.) SO2Cl2 / 1.) THF, hexane, -78 deg C, 2.) -78 deg C, 20 min
View Scheme
morpholine
110-91-8

morpholine

A

2(3H)-Benzothiazolone
934-34-9

2(3H)-Benzothiazolone

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
In pyridine 1)50 deg C, 2h 2)room temp., 20h;A 13%
B 81%
toluene
108-88-3

toluene

A

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

B

Toluene-2-sulfonyl chloride
133-59-5

Toluene-2-sulfonyl chloride

Conditions
ConditionsYield
With chlorosulfonic acid; sodium chloride at -0.16℃;A 80%
B 20%
With chlorosulfonic acid for 3h; Cooling with ice;A n/a
B 72.04%
With sulfuric acid; sodium chloride Edukt 4: SO3;
1-acetylcyclohexene p-tosylhydrazone
41780-85-2

1-acetylcyclohexene p-tosylhydrazone

A

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

C

4-(2-Chloro-cyclohexyl)-[1,2,3]thiadiazole

4-(2-Chloro-cyclohexyl)-[1,2,3]thiadiazole

Conditions
ConditionsYield
With sulfur dichloride In dichloromethane at 20℃; for 0.5h; Product distribution; other reagents (SOCl2, S2Cl2) and time;A n/a
B n/a
C 80%
meta-hydroxybenzaldehyde
100-83-4

meta-hydroxybenzaldehyde

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With potassium carbonate77%
4-chloromorpholine
23328-69-0

4-chloromorpholine

p-toluene sulfinic acid
536-57-2

p-toluene sulfinic acid

A

4-tosylmorpholine
6339-26-0

4-tosylmorpholine

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
In dichloromethane for 0.5h; Ambient temperature;A 76%
B 10%
sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With pyridine; (Dichloroiodo)benzene In 1,2-dichloro-ethane at 20 - 88℃; for 0.0166667h; Inert atmosphere; Reflux;74%
cis-2-hydroxymethyl-1-(2,4-dimethoxybenzyl)-3-(4,5-diphenyl-2-oxo-4-oxazolin-3-yl)-4-oxoazetidine

cis-2-hydroxymethyl-1-(2,4-dimethoxybenzyl)-3-(4,5-diphenyl-2-oxo-4-oxazolin-3-yl)-4-oxoazetidine

A

cis-3-(4,5-diphenyl-2-oxo-4-oxazolin-3-yl)-4-oxo-2-azetidinylmethyl mesylate

cis-3-(4,5-diphenyl-2-oxo-4-oxazolin-3-yl)-4-oxo-2-azetidinylmethyl mesylate

B

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
A 73%
B n/a
N,N'-bis(p-toluenesulfonyl)hydroxylamine
56410-24-3

N,N'-bis(p-toluenesulfonyl)hydroxylamine

A

bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate
62419-04-9

bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate

B

toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

C

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
With air In chloroform for 12h; Product distribution; Mechanism; Ambient temperature; various reaction conditions;A 20%
B 70%
C 5%
C19H34N2O2S
151259-26-6

C19H34N2O2S

A

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

B

1-chlorododecane
112-52-7

1-chlorododecane

Conditions
ConditionsYield
With N-chloro-succinimide In tetrahydrofuran for 16h; Ambient temperature; Irradiation;A n/a
B 68%
toluene-p-sulfonyl bromide
1950-69-2

toluene-p-sulfonyl bromide

triphenyl(phenylazo)methane
981-18-0

triphenyl(phenylazo)methane

A

bromobenzene
108-86-1

bromobenzene

B

di(4-methyl)phenylthiosulfonate
2943-42-2

di(4-methyl)phenylthiosulfonate

C

p-tolyl triphenylmethyl sulphone
42756-18-3

p-tolyl triphenylmethyl sulphone

D

chlorobenzene
108-90-7

chlorobenzene

E

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

Conditions
ConditionsYield
In tetrachloromethane for 30h; Product distribution; Heating;A 67%
B n/a
C 56%
D 6%
E n/a
4-methylbenzenesulfinyl chloride
10439-23-3

4-methylbenzenesulfinyl chloride

but-3-en-1-ynyl-trimethyl-silane
2696-32-4

but-3-en-1-ynyl-trimethyl-silane

A

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

B

[3-Chloro-4-(toluene-4-sulfinyl)-but-1-ynyl]-trimethyl-silane

[3-Chloro-4-(toluene-4-sulfinyl)-but-1-ynyl]-trimethyl-silane

C

[1-Chloro-4-(toluene-4-sulfinyl)-buta-1,2-dienyl]-trimethyl-silane

[1-Chloro-4-(toluene-4-sulfinyl)-buta-1,2-dienyl]-trimethyl-silane

Conditions
ConditionsYield
aluminium trichloride In diethyl ether Ambient temperature;A n/a
B 66%
C n/a
Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

rac-(tetrahydrofuran-2-yl)methyl 4-methylbenzenesulfonate
34583-63-6

rac-(tetrahydrofuran-2-yl)methyl 4-methylbenzenesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 1h;100%
With potassium hydroxide93%
With potassium iodide; silver(l) oxide In dichloromethane at 40℃;91%
2-aminopyridine
504-29-0

2-aminopyridine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(2-pyridyl)-p-toluenesulfonamide
52776-76-8

N-(2-pyridyl)-p-toluenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
at 20℃; for 0.1h;88%
With sodium carbonate In water82.1%
8-amino quinoline
578-66-5

8-amino quinoline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methyl-N-quinolin-8-yl-benzenesulfonamide
10304-39-9

4-methyl-N-quinolin-8-yl-benzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With pyridine at 130℃; for 0.05h; Microwave irradiation; Inert atmosphere;97%
With pyridine at 130℃; for 0.166667h;90%
tryptamine
61-54-1

tryptamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-tosyl tryptamine
86658-78-8

N-tosyl tryptamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 2h;100%
With triethylamine In dichloromethane at 0 - 20℃;99%
With triethylamine In dichloromethane at 0 - 20℃; for 2h;99%
m-Anisidine
536-90-3

m-Anisidine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-tosyl-m-anisidine
58750-87-1

N-tosyl-m-anisidine

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 28h;100%
With triethylamine In dichloromethane at 4℃;100%
With triethylamine In tetrahydrofuran at 20℃; for 15h;95%
2-aminoacetophenone
551-93-9

2-aminoacetophenone

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(2-acetylphenyl)-4-methylbenzenesulfonamide
1859-70-7

N-(2-acetylphenyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃; for 10.5h;100%
With triethylamine In dichloromethane at 4℃;100%
With pyridine In dichloromethane at 20℃; for 1h;97%
1-amino-naphthalene
134-32-7

1-amino-naphthalene

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-tosyl-1-naphthylamine
18271-17-5

N-tosyl-1-naphthylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With pyridine98%
at 20℃; for 0.166667h;94%
4-Aminobiphenyl
92-67-1

4-Aminobiphenyl

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-([1,1'-biphenyl]-4-yl)-4-methylbenzenesulfonamide
65690-69-9

N-([1,1'-biphenyl]-4-yl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With pyridine at 0 - 20℃; for 15h; Inert atmosphere;75%
With pyridine
cyclohexylamine
108-91-8

cyclohexylamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-cyclohexyl-p-toluenesulfonamide
80-30-8

N-cyclohexyl-p-toluenesulfonamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h; Inert atmosphere;100%
With pyridine at 0 - 25℃; Inert atmosphere; Schlenk technique;99%
With triethylamine In tetrahydrofuran at 0 - 20℃;95%
p-toluidine
106-49-0

p-toluidine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methyl-N-(4-methylphenyl)benzenesulfonamide
599-86-0

4-methyl-N-(4-methylphenyl)benzenesulfonamide

Conditions
ConditionsYield
With pyridine In dichloromethane at 20℃; for 16h;100%
With pyridine at 0 - 25℃;100%
In water at 110℃; for 0.0833333h; Microwave irradiation; Green chemistry; chemoselective reaction;98%
4-chloro-aniline
106-47-8

4-chloro-aniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methyl-N-(4-chlorophenyl)benzenesulfonamide
2903-34-6

4-methyl-N-(4-chlorophenyl)benzenesulfonamide

Conditions
ConditionsYield
In pyridine; acetonitrile at 20℃; for 16h;100%
In ethanol; water at 25℃; for 0.333333h;96%
With (Na1752K0.144Ca0365Mg0.065)(Al2044Si2774O96)*19.16H2O In ethanol at 25 - 30℃; for 0.25h; Sonication; Green chemistry;95%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(4-Methoxy-phenyl)-4-methyl-benzenesulfonamide
1150-26-1

N-(4-Methoxy-phenyl)-4-methyl-benzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With pyridine for 16h; Reflux;97%
With dendritic fibrous nanosilica KCC-1 3-aminopropyl-functionalized supported on Fe3O4 magnetic nanocatalyst In water at 20℃; for 0.5h; Solvent; Temperature; Reagent/catalyst; Time; Green chemistry;97%
2-phenylaniline
90-41-5

2-phenylaniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-biphenyl-2-yl-4-methylbenzenesulfonamide
24310-30-3

N-biphenyl-2-yl-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With sodium hydrogencarbonate In water; acetone at 25℃; for 0.25h;97%
With pyridine at 0 - 25℃; for 1h;92%
ethanolamine
141-43-5

ethanolamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(2-hydroxy-ethyl)-4-methyl-benzenesulfonamide
14316-14-4

N-(2-hydroxy-ethyl)-4-methyl-benzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;100%
With triethylamine In dichloromethane at 0 - 20℃; for 24h;99%
With pyridine at 5 - 20℃;96%
1-pentanamine
110-58-7

1-pentanamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methyl-N-pentylbenzenesulfonamide
106011-68-1

4-methyl-N-pentylbenzenesulfonamide

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 12h;100%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;89%
With triethylamine In dichloromethane at 0℃; for 0.0833333h;85%
propargyl alcohol
107-19-7

propargyl alcohol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

propargyl p-toluenesulfonate
6165-76-0

propargyl p-toluenesulfonate

Conditions
ConditionsYield
With sodium hydroxide In diethyl ether; water at 0 - 20℃; for 17h;100%
With potassium hydroxide In diethyl ether at -5 - 20℃;96%
With potassium hydroxide In diethyl ether at -5 - 0℃; for 0.5h;95%
3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(3,5-dimethylphenyl)-4-methyl-benzenesulfonamide
114097-28-8

N-(3,5-dimethylphenyl)-4-methyl-benzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With silica gel at 20℃;95%
With triethylamine In dichloromethane at 0 - 20℃;82%
4-amino-N,N-dimethylaniline
99-98-9

4-amino-N,N-dimethylaniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(4-(dimethylamino)phenyl)-4-methylbenzenesulfonamide
19766-55-3

N-(4-(dimethylamino)phenyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With pyridine for 1h; Reflux;100%
With caesium carbonate In acetonitrile at 25℃; for 0.333333h;93%
indium In acetonitrile at 20℃; for 6h;90%
4-nitro-aniline
100-01-6

4-nitro-aniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-(4-nitrophenyl)-4-methylbenzenesulfonamide
734-25-8

N-(4-nitrophenyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With (Na1752K0.144Ca0365Mg0.065)(Al2044Si2774O96)*19.16H2O In ethanol at 25 - 30℃; for 2h; Sonication; Green chemistry;96%
With pyridine In dichloromethane at 20℃; for 12h;94%
2-nitro-aniline
88-74-4

2-nitro-aniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methyl-N-(2-nitrophenyl)benzene sulfonamide
6380-13-8

4-methyl-N-(2-nitrophenyl)benzene sulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With pyridine In dichloromethane at 20℃; for 48h;90%
With pyridine In dichloromethane at 20℃; for 16h;75%
dimethyl amine
124-40-3

dimethyl amine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N,N,4-trimethylbenzenesulfonamide
599-69-9

N,N,4-trimethylbenzenesulfonamide

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 25℃; for 1h;100%
99%
With cesium fluoride supported on Celite at 50℃; for 0.75h; chemoselective reaction;91%
isopropylamine
75-31-0

isopropylamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-isopropyl-p-toluenesulfonamide
21230-07-9

N-isopropyl-p-toluenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃;100%
With pyridine; dmap In dichloromethane at 0 - 20℃; for 16h;99%
With pyridine at 0 - 25℃; Inert atmosphere; Schlenk technique;99%
ethylenediamine
107-15-3

ethylenediamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

ditosylethylenediamine
4403-78-5

ditosylethylenediamine

Conditions
ConditionsYield
In pyridine at 20℃;100%
With pyridine at 0 - 20℃;95%
With sodium hydroxide In diethyl ether at 20℃;94%
Trimethylenediamine
109-76-2

Trimethylenediamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N,N'-ditoluenesulfonyl-1,3-diaminopropane
53364-99-1

N,N'-ditoluenesulfonyl-1,3-diaminopropane

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran; water at 0.2℃; for 3h; Inert atmosphere;100%
at 80℃; for 0.5h;95%
With potassium carbonate In tetrahydrofuran; water at 23℃; for 10h;95%
aniline
62-53-3

aniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

phenyl toluenesulfonamide
68-34-8

phenyl toluenesulfonamide

Conditions
ConditionsYield
With pyridine for 16h; Reflux;100%
With pyridine In dichloromethane at 20℃; for 16h;100%
With triethylamine In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;100%
2-carbomethoxyaniline
134-20-3

2-carbomethoxyaniline

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

methyl N-tosylanthranilate
50998-74-8

methyl N-tosylanthranilate

Conditions
ConditionsYield
In pyridine at 25℃;100%
Stage #1: 2-carbomethoxyaniline With pyridine In dichloromethane at 25℃; for 1h; Inert atmosphere;
Stage #2: p-toluenesulfonyl chloride In dichloromethane at 25℃; for 24h; Inert atmosphere;
99%
In pyridine at 0℃; for 1h;98%
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-ethoxyethyl p-toluenesulfonate
17178-11-9

2-ethoxyethyl p-toluenesulfonate

Conditions
ConditionsYield
With pyridine at 0℃;100%
With sodium hydroxide In tetrahydrofuran; water85%
With triethylamine In dichloromethane at 20℃; for 4h;81.1%
4-nitro-phenol
100-02-7

4-nitro-phenol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-nitrophenyl 4-methylbenzenesulfonate
1153-45-3

4-nitrophenyl 4-methylbenzenesulfonate

Conditions
ConditionsYield
Stage #1: 4-nitro-phenol; p-toluenesulfonyl chloride With potassium carbonate In acetone at 20 - 25℃; for 2.5h;
Stage #2: With hydrogenchloride In water; acetone
100%
With triethylamine In dichloromethane at 20℃; for 24h; Inert atmosphere;99%
With potassium carbonate for 0.0833333h; microwave irradiation;98%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-methyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate)
2387-43-1

2-methyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate)

Conditions
ConditionsYield
With pyridine at 20℃; for 16h; Inert atmosphere;100%
With pyridine at 0 - 20℃;90%
With pyridine In chloroform81%
2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-phenoxyethanol tosylate
43224-81-3

2-phenoxyethanol tosylate

Conditions
ConditionsYield
Stage #1: 2-Phenoxyethanol; p-toluenesulfonyl chloride With dmap In dichloromethane at 20℃;
Stage #2: With triethylamine In dichloromethane at 20℃;
100%
With pyridine86%
With pyridine at 20℃; for 4h;24%
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