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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/47.html Product Name 4-Tolylboronic acid CAS No. 5720-05-

4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Gram

FOB Price: $52.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Tolylboronic Acid supplier in China

Cas:5720-05-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Manufacturer supply 4-Tolylboronic acid CAS 5720-05-8 with attractive price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Foo

Manufacturer supply 4-Tolylboronic acid CAS 5720-05-8 with attractive price

Cas:5720-05-8

Min.Order:10 Gram

FOB Price: $10.0

Type:Trading Company

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min ----------------------------------------------------------------------------------------------

High purity 4-Methylbenzeneboronic acid CAS:5720-05-8

Cas:5720-05-8

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

4-Tolylboronic acid CAS No.:5720-05-8 Name: 4-Tolylboronic acid Synonyms: 4-Methylphenylboronic acid Molecular Structure Molecular

High purity 4-Tolylboronic acid CAS No.:5720-05-8

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

4-Methylphenylboronic acid

Cas:5720-05-8

Min.Order:0 Gram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Tolylboronic Acid

Cas:5720-05-8

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 5720-05-8 4-Tolylboronic acid Manufacturer

Cas:5720-05-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Methylbenzeneboronic acid

Cas:5720-05-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Factory supply 4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

4-Tolylboronic acid-

Cas:5720-05-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

4-Tolylboronic Acid CAS 5720-05-8

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 5720-05-8 with competitive price

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 5720-05-8 4-Tolylboronic acid

Cas:5720-05-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 4-Tolylboronic Acid Synonyms: 4-Methylbenzeneboronic acid CAS:5720-05-8 MF: C9H13N Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Syntheses Material Intermediates Transporta

4-Tolylboronic Acid

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

high purity 99% cas no 5720-05-8 4-Methylphenylboronic Acid

Cas:5720-05-8

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronic acid,B-(4-methylphenyl)- 5720-05-8

Cas:5720-05-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Liquid crystal intermediates, 4-Tolylboronic acid CAS: 5720-05-8

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $21.0 / 24.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

4-Tolylboronic acid CAS: 5720-05-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

4-Tolylboronic acid CAS: 5720-05-8

Cas:5720-05-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Boronic acid,B-(4-methylphenyl)-

Cas:5720-05-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Tolylboronic Acid

Cas:5720-05-8

Min.Order:0

Negotiable

Type:Manufacturers

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Kilogram

FOB Price: $6.0 / 10.0

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS5720-05-8 4-Tolylboronic acid

Cas:5720-05-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

p-tolylboronic acid

Cas:5720-05-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

4-Tolylboronic acid

Cas:5720-05-8

Min.Order:0

Negotiable

Type:Trading Company

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Methylphenylboronic Acid

Cas:5720-05-8

Min.Order:100 Gram

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity 4-Tolylboronic acid

Cas:5720-05-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Synthetic route

tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

trimethyl-p-tolylammonium iodide
6140-15-4

trimethyl-p-tolylammonium iodide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
In methanol at 15℃; for 3h; Microwave irradiation;98%
Trimethyl borate
121-43-7

Trimethyl borate

para-chlorotoluene
106-43-4

para-chlorotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With lithium In tetrahydrofuran97.5%
diisopropopylaminoborane
22092-92-8

diisopropopylaminoborane

water
7732-18-5

water

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: diisopropopylaminoborane; para-methylphenylmagnesium bromide In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: water With hydrogenchloride In tetrahydrofuran at 0℃; for 0.583333h; Inert atmosphere;
95%
p-tolylboronic pinacol ester
195062-57-8

p-tolylboronic pinacol ester

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; polystyrene boronic acid In acetonitrile at 20℃; for 18h;94%
Stage #1: p-tolylboronic pinacol ester With potassium hydrogen difluoride In methanol at 20℃; for 0.25h;
Stage #2: With lithium hydroxide In acetonitrile at 20℃; for 20h;
85%
4-tolylboronic dimethyl ester
40881-45-6

4-tolylboronic dimethyl ester

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride In water91%
With hydrogenchloride In tetrahydrofuran; water for 5h;55%
With sulfuric acid In tetrahydrofuran
Triisopropyl borate
5419-55-6

Triisopropyl borate

para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: para-bromotoluene With iodine; magnesium In tetrahydrofuran at 70℃; for 1h;
Stage #2: Triisopropyl borate In tetrahydrofuran at 0℃; for 1h; Temperature; Concentration; Time;
91%
With magnesium; ethylene dibromide In tetrahydrofuran at 40 - 60℃; for 6h; Inert atmosphere;58%
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78 - -10℃;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃;
52%
With hydrogenchloride; n-butyllithium In tetrahydrofuran; hexane
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at 25℃; for 0.333333h; Inert atmosphere;
potassium (4-methylphenyl)trifluoroborate

potassium (4-methylphenyl)trifluoroborate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With aluminum oxide; water at 70℃; for 0.25h; Microwave irradiation;90%
With water; silica gel at 20℃; for 1h; Inert atmosphere;76%
With water In tetrahydrofuran at 55℃; Kinetics; Reagent/catalyst;
With silica gel; sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃;
p-toluidine
106-49-0

p-toluidine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: p-toluidine With hydrogenchloride; sodium nitrite In methanol; water at 0 - 5℃; for 0.5h;
Stage #2: With tetrahydroxydiboron In methanol; water at 20℃; for 1h;
90%
Multi-step reaction with 3 steps
1.1: tetrafluoroboric acid / water / 0.17 h / 0 °C
1.2: 1 h / 0 °C
1.3: 20 °C / Inert atmosphere
2.1: 1 h / 0 - 20 °C / Inert atmosphere
3.1: hydrogenchloride / water
View Scheme
2,3-dihydro-2-(4-methylphenyl)benzo[d][1,3,2]diazaborinin-4(1H)-one
32203-14-8

2,3-dihydro-2-(4-methylphenyl)benzo[d][1,3,2]diazaborinin-4(1H)-one

A

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

B

anthranilic acid amide
28144-70-9

anthranilic acid amide

Conditions
ConditionsYield
In 1,4-dioxane; water at 140℃; for 0.5h; Microwave irradiation; Sealed tube;A 78%
B 88%
Trimethyl borate
121-43-7

Trimethyl borate

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
In tetrahydrofuran dropwise addn. of p-tolylmagnesium bromide to borane at -70°C; stirred below -60°C for 1 h; hydrolyzed (sulfuric acid); filtration; sepn. of org. layer; extn. of aq. layer (ether); combined org. layer washed (H2O); dried (Na2SO4); concn. of soln.; crystn.; washed (hexane, H2O); IR; NMR; mass spectra;86%
p-tolyl triflate
29540-83-8

p-tolyl triflate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: p-tolyl triflate With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; diisopropopylaminoborane; triethylamine; triphenylphosphine In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
86%
tributyl(p-tolyl)stannane
31614-66-1

tributyl(p-tolyl)stannane

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With borane; water In tetrahydrofuran for 1h; Heating;85%
para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: para-bromotoluene With magnesium In tetrahydrofuran Heating;
Stage #2: With Trimethyl borate In tetrahydrofuran; diethyl ether at 20℃; for 2h;
Stage #3: With hydrogenchloride In tetrahydrofuran; diethyl ether for 1h;
85%
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.5h; Inert atmosphere;
Stage #2: With Triisopropyl borate In tetrahydrofuran; hexane at -78 - 10℃; Inert atmosphere;
85%
With Trimethyl borate; iodine; magnesium In tetrahydrofuran80%
4-tolyl iodide
624-31-7

4-tolyl iodide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-tolyl iodide With diisopropopylaminoborane; triethylamine; triphenylphosphine; palladium dichloride In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
84%
(i) (UV-irradiation), BBr3, (ii) aq. NaOH; Multistep reaction;
Trimethyl borate
121-43-7

Trimethyl borate

Triisopropyl borate
5419-55-6

Triisopropyl borate

para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: Triisopropyl borate; para-bromotoluene With magnesium; ethylene dibromide In tetrahydrofuran at 40 - 60℃; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran for 6h; Inert atmosphere; Reflux;
81%
Trimethyl borate
121-43-7

Trimethyl borate

para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With Mg; I2 In tetrahydrofuran80%
Stage #1: para-bromotoluene With magnesium In diethyl ether for 3 - 4h; Reflux;
Stage #2: Trimethyl borate In diethyl ether at -12 - 20℃;
76%
With magnesium In tetrahydrofuran 1) Mg, THF, reflux; 2) B(OMe)3, THF, -78 to 23°C;72%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

p-toluidine
106-49-0

p-toluidine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: p-toluidine With hydrogenchloride In water at 20℃; for 0.0166667h;
Stage #2: With sodium nitrite In water at 0℃; for 0.25h;
Stage #3: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h;
78%
methanol
67-56-1

methanol

diisopropylamine borane
55124-35-1

diisopropylamine borane

para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane With magnesium; phenylmagnesium bromide In tetrahydrofuran at 20℃; for 0.166667h;
Stage #2: para-bromotoluene In tetrahydrofuran at 70℃;
Stage #3: methanol Further stages;
78%
water
7732-18-5

water

potassium (4-methylphenyl)trifluoroborate

potassium (4-methylphenyl)trifluoroborate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With 1H-imidazole; iron(III) chloride at 20℃; for 0.25h; Inert atmosphere;76%
With glass or Cs2CO3 In tetrahydrofuran; water Kinetics; hydrolysis at 55°C in THF/H2O in the presence of glass powder or Cs2CO3; not isolated;
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
In methanol at 15℃; for 3h; Microwave irradiation;76%
With [{Pd(μ-Cl){κ2-P,C-P(iPr)2(OC6H3-2-Ph)}}2]; sodium acetate In dichloromethane; water at 40℃; for 6h; Inert atmosphere;
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); N-ethyl-N,N-diisopropylamine; triphenylphosphine In ethanol at 80℃; for 4h; Miyaura Borylation Reaction; Schlenk technique; Inert atmosphere; Sealed tube;
With potassium tert-butylate In methanol at 0 - 20℃;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

diisopropylamine borane
55124-35-1

diisopropylamine borane

para-bromotoluene
106-38-7

para-bromotoluene

water
7732-18-5

water

A

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

B

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

C

B-(4-methoxyphenyl)-B-(4-methylphenyl)borinic acid

B-(4-methoxyphenyl)-B-(4-methylphenyl)borinic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane; para-bromotoluene With magnesium In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;
Stage #2: 1-bromo-4-methoxy-benzene In tetrahydrofuran at 40℃; for 14h; Inert atmosphere;
Stage #3: water In tetrahydrofuran Temperature; Inert atmosphere;
A 9%
B 12%
C 73%
borane
13283-31-3

borane

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With water In tetrahydrofuran slow addn. of 10 mmol of the Grignard reagent to a stirred soln. of borane in THF (40 mmol); the mixt. was poured into ice-water and acidified with 10% HCl;; extn. into ether three-times; the combined extracts were dried over NaSO4; removal of solvent under reduced pressure; trituration with petroleum ether; recrystn. from H2O;;71%
Cedranediol p-tolylboronate

Cedranediol p-tolylboronate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: Cedranediol p-tolylboronate With 2,2'-iminobis[ethanol]
Stage #2: With hydrogenchloride for 0.5h;
70%
Trimethyl borate
121-43-7

Trimethyl borate

para-bromotoluene
106-38-7

para-bromotoluene

magnesium
7439-95-4

magnesium

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; water In tetrahydrofuran (Ar); stirring (-30°C), stirring (room temp., overnight), hydrolysis (0°C, water, 4M HCl), evapn. of the solvent, extn. (ether); evapn. of the solvent, recrystn. (water); elem. anal.;70%
Triisopropyl borate
5419-55-6

Triisopropyl borate

C7H7BrMg*ZnCl2*LiCl

C7H7BrMg*ZnCl2*LiCl

A

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

B

di(p-tolyl)borinic acid
66117-64-4

di(p-tolyl)borinic acid

Conditions
ConditionsYield
With copper(I) iodide-lithium chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere;A 67%
B 15%
Trimethyl borate
121-43-7

Trimethyl borate

C7H7BrMg*ZnCl2*LiCl

C7H7BrMg*ZnCl2*LiCl

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With copper(I) iodide-lithium chloride In tetrahydrofuran at 20℃; Reagent/catalyst; Schlenk technique; Inert atmosphere;63%
4-trifluoromethylpyridine
3796-24-5

4-trifluoromethylpyridine

potassium (4-methylphenyl)trifluoroborate

potassium (4-methylphenyl)trifluoroborate

A

2-(p-tolyl)-4-(trifluoromethyl)pyridine
1246851-48-8

2-(p-tolyl)-4-(trifluoromethyl)pyridine

B

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver nitrate; trifluoroacetic acid In dichloromethane; water; water-d2 at 20℃; for 4h; Mechanism; Inert atmosphere;A 60%
B n/a
Trimethyl borate
121-43-7

Trimethyl borate

C7H7BrMg*ZnCl2*LiCl

C7H7BrMg*ZnCl2*LiCl

A

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

B

di(p-tolyl)borinic acid
66117-64-4

di(p-tolyl)borinic acid

Conditions
ConditionsYield
With copper(I) iodide-lithium chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere;A 52%
B 18%
Triisopropyl borate
5419-55-6

Triisopropyl borate

para-chlorotoluene
106-43-4

para-chlorotoluene

A

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

B

toluene
108-88-3

toluene

Conditions
ConditionsYield
With magnesium In tetrahydrofuran byproducts: Mg(2+); Electrolysis; electrolysis carried out in a single-compartment cell at room temp., starting materials dissolved in THF containing (CF3SO2)2NLi, solvent and excess B(OiPr)3 evaporated under vacuum, medium hydrolysed at 0°C with an HCl or H2SO4 soln.; extraction with Et2O (3 x 20 ml if the solvent evaporated or 3 x 60 ml otherwise), organic phase dried over sodium or magnesium sulfate and concentrated under vacuum, side product phenol formation avoided by work-up under inert atmosphere;A 46%
B n/a
2-Chlorobenzonitrile
873-32-5

2-Chlorobenzonitrile

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-Cyano-4'-methylbiphenyl
114772-53-1

2-Cyano-4'-methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In n-heptane; water at 60℃; for 1.66667h; Suzuki Coupling; Inert atmosphere;100%
With potassium carbonate In water; isopropyl alcohol at 100℃; for 7h; Catalytic behavior; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With bis({5-chloro-2-[(4-chlorophenyl)(hydroxyimino)methyl]phenyl})cyclodipalladachl-orane-1,3,4-tris(ylium)-2-uide; tetra(n-butyl)ammonium hydroxide; potassium carbonate; tri tert-butylphosphoniumtetrafluoroborate In N,N-dimethyl-formamide at 130℃; for 0.666667h; Suzuki-Miyaura coupling; Microwave irradiation;99%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

4-acetyl-4'-methylbiphenyl
5748-38-9

4-acetyl-4'-methylbiphenyl

Conditions
ConditionsYield
With C23H35N4O4Pd(1+)*Br(1-); potassium carbonate In water at 100℃; for 1h; Suzuki-Miyaura Coupling;100%
With potassium phosphate In N,N-dimethyl-formamide at 120℃; for 5h; Suzuki Coupling;100%
With potassium carbonate In water at 80℃; for 10.5h; Suzuki-Miyaura Coupling; Green chemistry;100%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

Conditions
ConditionsYield
With air; palladium diacetate In methanol at 20℃; for 5h;100%
With p-benzoquinone; (IPr)Pd(OAc)2(H2O) In methanol at 20℃; for 24h;100%
With sodium hydroxide In water at 120 - 130℃; Microwave irradiation;99%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-bromo-N-(3-methyl-5-isoxazolyl)benzenesulfonamide
184042-10-2

4-bromo-N-(3-methyl-5-isoxazolyl)benzenesulfonamide

4-(4-tolyl)-N-(3-methyl-5-isoxazolyl)benzenesulfonamide
184036-44-0

4-(4-tolyl)-N-(3-methyl-5-isoxazolyl)benzenesulfonamide

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 80℃; for 24h; Suzuki coupling;100%
With sodium carbonate; tetrakis (triphenylphosphine)palladium (O) In ethanol; toluene at 80℃; for 24h; biphasic mixture;100%
bromobenzene
108-86-1

bromobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In pyridine for 3h; Suzuki cross-coupling; Heating;100%
With potassium carbonate; carbapalladacycle complex*periodic mesoporous organosilica for 24h; Suzuki coupling; Heating;100%
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation;100%
iodobenzene
591-50-4

iodobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In water at 80℃; Catalytic behavior; Suzuki-Miyaura Coupling; Green chemistry;100%
With aluminum oxide; potassium fluoride; palladium at 100℃; for 4h; Suzuki reaction;99%
With sodium hydroxide; tetrabutylammomium bromide; palladium on activated charcoal at 100℃; for 2h; Suzuki-Miyaura cross-coupling;99%
4-tolyl iodide
624-31-7

4-tolyl iodide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

Conditions
ConditionsYield
With sodium carbonate In ethanol; water at 80℃; for 0.166667h; Catalytic behavior; Suzuki-Miyaura Coupling;100%
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;99%
With potassium phosphate tribasic trihydrate In ethanol; water at 60℃; for 0.166667h; Suzuki-Miyaura cross-coupling reaction;99%
2-Pyridone
142-08-5

2-Pyridone

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

1-(4-methylphenyl)-1,2-dihydropyridin-2-one
19006-80-5

1-(4-methylphenyl)-1,2-dihydropyridin-2-one

Conditions
ConditionsYield
With pyridine; 4 Angstroem MS; oxygen; copper diacetate In dichloromethane at 20℃;100%
With pyridine; copper diacetate; 4 A molecular sieve In dichloromethane at 20℃; for 48h; Arylation;75%
With copper diacetate; 4 A molecular sieve; triethylamine In pyridine; dichloromethane at 20℃; for 48h; Arylation;38%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.166667h; Suzuki-Miyaura reaction;100%
With sodium carbonate; polystyrene-supported N-heterocyclic carbene-Pd catalyst In N,N-dimethyl-formamide at 20℃; for 24h; Suzuki reaction;99%
With C28H38Cl2N2O6PdS2(2-)*2Na(1+); potassium carbonate In ethanol; water at 70℃; for 1.5h; Suzuki coupling;99%
o-cyanobromobenzene
2042-37-7

o-cyanobromobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-Cyano-4'-methylbiphenyl
114772-53-1

2-Cyano-4'-methylbiphenyl

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate In 1,4-dioxane; water at 50℃; for 5h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With potassium carbonate; [1-cyclohexyl-3-(di-pyridin-2-yl-methyl)-urea][PdCl2] In water at 100℃; for 1h; Suzuki-Miyaura coupling;99%
With potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; for 0.0833333h; Suzuki cross-coupling reaction;99%
para-bromotoluene
106-38-7

para-bromotoluene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In pyridine for 4h; Suzuki cross-coupling; Heating;100%
With potassium phosphate; 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride; bis(η3-allyl-μ-chloropalladium(II)) In 1,4-dioxane at 80℃; for 12h; Suzuki cross-coupling;100%
With potassium phosphate; [Pd(Ph2PCH2CH(CH3)O)2] In tetrahydrofuran; water at 20℃; for 5h; Suzuki cross-coupling reaction;99%
para-iodoanisole
696-62-8

para-iodoanisole

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With potassium carbonate In water at 80℃; for 2h; Suzuki Coupling;100%
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;99%
With water; triethylamine; Pd(OAc)2EnCatTM In N,N-dimethyl-formamide at 120℃; for 0.25h; Suzuki-Miyaura reaction; microwave irradiation;99%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

trifluoro-methanesulfonic acid 4-diisopropylcarbamoyl-phenyl ester
188112-24-5

trifluoro-methanesulfonic acid 4-diisopropylcarbamoyl-phenyl ester

N,N-diisopropyl-4'-methyl-[1,1'-biphenyl]-3-carboxamide
188112-26-7

N,N-diisopropyl-4'-methyl-[1,1'-biphenyl]-3-carboxamide

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; lithium chloride In ethanol; toluene Heating;100%
cyclohexenone
930-68-7

cyclohexenone

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

3-(p-tolyl)cyclohexan-1-one
99495-15-5

3-(p-tolyl)cyclohexan-1-one

Conditions
ConditionsYield
With chloroform; caesium carbonate; triphenylphosphine; palladium diacetate In toluene at 80℃; for 24h;100%
[Rh(OH)(cod)]2; β‐cyclodextrin In water at 50℃; for 6h; Product distribution; Further Variations:; Catalysts; Reaction partners; Temperatures;99%
With 1,5-cis,cis-cyclooctadiene; rhodium-grafted hydrotalcite In 1,4-dioxane at 100℃; for 4h;99%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

benzyl chloride
100-44-7

benzyl chloride

1-methyl-4-(phenylmethyl)benzene
620-83-7

1-methyl-4-(phenylmethyl)benzene

Conditions
ConditionsYield
With potassium phosphate; SP-4-[1,3-bis[2,6-diisopropylphenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro[2-(1-methyl-1H-imidazol-2-yl-κN3)phenyl-κC]palladium(II) In ethanol at 60℃; for 2h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With potassium phosphate tribasic trihydrate In ethanol at 80℃; for 0.166667h; Catalytic behavior; Suzuki-Miyaura Coupling;99%
With C34H41Cl2N3OPd; potassium tert-butylate In water; isopropyl alcohol at 80℃; for 15h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
2-bromoanisole
578-57-4

2-bromoanisole

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-methoxy-4'-methylbiphenyl
92495-53-9

2-methoxy-4'-methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.25h; Suzuki-Miyaura reaction;100%
With Pd/C; potassium carbonate In ethanol; water at 100℃; for 3h; Suzuki-Miyaura Coupling;95%
With cetyltrimethylammonim bromide; sodium hydroxide In water at 25℃; for 1h; Catalytic behavior; Suzuki Coupling; Microwave irradiation;94%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

1-(1,1-dimethylethyl) 3-ethyl 4-{[(trifluoromethyl)sulfonyl]oxy}-1,2,5,6-tetrahydropyridine-1,3-dicarboxylate
176525-98-7

1-(1,1-dimethylethyl) 3-ethyl 4-{[(trifluoromethyl)sulfonyl]oxy}-1,2,5,6-tetrahydropyridine-1,3-dicarboxylate

1-tert-butyl 3-ethyl 4-(p-tolyl)-5,6-dihydropyridine-1,3(2H)-dicarboxylate

1-tert-butyl 3-ethyl 4-(p-tolyl)-5,6-dihydropyridine-1,3(2H)-dicarboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water for 4h; Inert atmosphere; Reflux;100%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium hydrogencarbonate In ethanol at 80℃; Suzuki-Miyaura cross-coupling;
diphenyl diselenide
1666-13-3

diphenyl diselenide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-tolyl phenyl selenide
83859-32-9

4-tolyl phenyl selenide

Conditions
ConditionsYield
With Cu NPs/Ac In dimethyl sulfoxide at 20 - 100℃; for 4h; Sealed tube; Sonication;100%
With [2,2]bipyridinyl; copper(l) iodide In water; dimethyl sulfoxide at 100℃; for 12h;98%
With silver nitrate In 1,4-dioxane at 100℃; for 6h;96%
chlormadinone acetate
302-22-7

chlormadinone acetate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

17-acetoxy-6-(4-methylphenyl)pregna-4,6-diene-3,20-dione

17-acetoxy-6-(4-methylphenyl)pregna-4,6-diene-3,20-dione

Conditions
ConditionsYield
With potassium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In toluene at 100℃; for 13h; Suzuki-Miyaura coupling;100%
With potassium carbonate; PdCl2(PPh2(CH2)4PPh2) In toluene at 100℃; for 13h; Suzuki-Miyaura cross-coupling;100%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 4-(4-tolyl)benzoate
49742-56-5

methyl 4-(4-tolyl)benzoate

Conditions
ConditionsYield
With potassium phosphate; second generation phosphine dendrimer-stabilized palladium In 1,4-dioxane for 20h; Suzuki coupling; Heating;100%
With sodium carbonate; bis(dibenzylideneacetone)-palladium(0); C78H99N6P(6+)*6Br(1-) In methanol; water at 65℃; for 3h; Reactivity; Kinetics; Reagent/catalyst; Time; Suzuki-Miyaura cross-coupling; Inert atmosphere;100%
With potassium phosphate tribasic heptahydrate In 1,4-dioxane for 20h; Suzuki coupling; Reflux;100%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

sodium (4-methylphenyltrihydroxyborate)

sodium (4-methylphenyltrihydroxyborate)

Conditions
ConditionsYield
With sodium hydroxide In toluene100%
With sodium hydroxide In water; toluene Reflux;
cyclohexenone
930-68-7

cyclohexenone

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

(R)-3-p-tolyl-cyclohexanone
610273-86-4

(R)-3-p-tolyl-cyclohexanone

Conditions
ConditionsYield
With potassium hydroxide; [{Rh(C2H4)2Cl}2]; (1-methyl-1-phenylethyl)cyclohexanol biphenol phosphite In 1,4-dioxane; water at 23℃; for 15h;100%
With BF4(1-)*C68H44N2O4P2Rh(1+); water; potassium hydroxide In 1,4-dioxane at 60℃; for 1h; Anaerobic conditions; Combinatorial reaction / High throughput screening (HTS); optical yield given as %ee; enantioselective reaction;99%
Stage #1: 4-methylphenylboronic acid With chlorobis(ethylene)rhodium(I) dimer; C21H26O4S In tetrahydrofuran at 60℃; for 0.5h; Inert atmosphere;
Stage #2: cyclohexenone With potassium dihydrogenphosphate In tetrahydrofuran; water at 60℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
99%
2-(thiophen-2-ylethynyl)-benzaldehyde

2-(thiophen-2-ylethynyl)-benzaldehyde

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-(2-thienyl)-3-(4-methylphenyl)-1H-inden-1-ol

2-(2-thienyl)-3-(4-methylphenyl)-1H-inden-1-ol

Conditions
ConditionsYield
With tricyclohexylphosphine; tris(dibenzylideneacetone)dipalladium (0) In methanol at 100℃; for 5h;100%
morpholine
110-91-8

morpholine

o-(phenylethynyl)benzaldehyde
59046-72-9

o-(phenylethynyl)benzaldehyde

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

3-morpholino-1-(4-methylphenyl)-2-phenyl-1H-indene

3-morpholino-1-(4-methylphenyl)-2-phenyl-1H-indene

Conditions
ConditionsYield
With tricyclohexylphosphine; allyl(cyclopentadiene)palladium(II) In N,N-dimethyl-formamide at 80℃; for 1h;100%
2-[4-(4-iodo-3,5-dimethyl-1H-pyrazol-1-yl)phenyl]ethanol
616878-80-9

2-[4-(4-iodo-3,5-dimethyl-1H-pyrazol-1-yl)phenyl]ethanol

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-{4-[3,5-dimethyl-4-(4-methylphenyl)-1H-pyrazol-1-yl]phenyl}ethanol

2-{4-[3,5-dimethyl-4-(4-methylphenyl)-1H-pyrazol-1-yl]phenyl}ethanol

Conditions
ConditionsYield
With potassium carbonate; bis-triphenylphosphine-palladium(II) chloride In 1,2-dimethoxyethane; water for 16h; Heating / reflux;100%
3-(6-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine
863783-61-3

3-(6-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

5,6-Dimethyl-3-(6-p-tolyl-quinolin-4-yloxy)-[2,2']bipyridine

5,6-Dimethyl-3-(6-p-tolyl-quinolin-4-yloxy)-[2,2']bipyridine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; N,N-dimethyl-formamide at 70℃; for 3h;100%
3-(7-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine
863783-73-7

3-(7-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

5,6-Dimethyl-3-(7-p-tolyl-quinolin-4-yloxy)-[2,2']bipyridine

5,6-Dimethyl-3-(7-p-tolyl-quinolin-4-yloxy)-[2,2']bipyridine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; N,N-dimethyl-formamide at 70℃; for 1h;100%
2-(4-chloro-2-methoxyphenoxy)-6-fluoropyridine

2-(4-chloro-2-methoxyphenoxy)-6-fluoropyridine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-fluoro-6-[(3-methoxy-4'-methylbiphenyl-4-yl)oxy]pyridine

2-fluoro-6-[(3-methoxy-4'-methylbiphenyl-4-yl)oxy]pyridine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 105℃; for 48h;100%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,2-dimethoxyethane; water at 105℃; for 48h; Inert atmosphere;100%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-chloro-6-phenyl-furo[2,3-b]pyrazine
67718-18-7

2-chloro-6-phenyl-furo[2,3-b]pyrazine

C19H14N2O
1011736-51-8

C19H14N2O

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; N,N-dimethyl-formamide at 100℃; for 0.166667h; Suzuki coupling; microwave irradiation;100%
1-Chloro-4-iodobenzene
637-87-6

1-Chloro-4-iodobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-chloro-4'-methylbiphenyl
19482-11-2

4-chloro-4'-methylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; tetrabutylammomium bromide In 1,4-dioxane; water at 120℃; for 2h; Suzuki Coupling; Inert atmosphere;100%
With potassium carbonate In ethanol; water at 20℃; for 0.5h; Catalytic behavior; Suzuki-Miyaura Coupling; Irradiation;99%
With sodium hydroxide In ethanol; water at 25℃; for 3h; Suzuki Coupling;94%

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