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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/48.html Product Name 4-Methoxyphenylboronic acid CAS No. 5720-07-0 Appearance White powder Assay ≥99% Capa

4-Methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:1 Gram

FOB Price: $52.0

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Methoxyphenylboronic Acid supplier in China

Cas:5720-07-0

Min.Order:1 Kilogram

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Methoxyphenylboronic Acid

Cas:5720-07-0

Min.Order:1

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 5720-07-0 4-methoxyphenylboronic acid Manufacturer

Cas:5720-07-0

Min.Order:1 Gram

FOB Price: $0.1

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sal

4-methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:0 Metric Ton

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Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Methoxyphenylboronic acid Manufacturer/High quality/In stock

Cas:5720-07-0

Min.Order:1 Kilogram

FOB Price: $3.0

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Factory supply 4-Methoxyphenylboronic Acid

Cas:5720-07-0

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

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Henan Tianfu Chemical Co., Ltd.

Product Name: 4-Methoxyphenylboronic acid Synonyms: (4-methoxyphenyl)-boronicaci;p-methoxy-benzeneboronicaci;p-methoxyphenyl-boronicaci;RARECHEM AH PB 0191;P-METHOXYPHENYLBORONIC ACID;p-methoxybenzeneboronic acid;p-Anisylboronic acid;TIMTEC-BB S

4-Methoxyphenylboronic acid 5720-07-0

Cas:5720-07-0

Min.Order:1 Metric Ton

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

P-Anisylboronic Acid; 4-Methoxyphenylboronic Acid CAS 5720-07-0

Cas:5720-07-0

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 5720-07-0 with fast shipping

Cas:5720-07-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 4-Methoxy Phenylboronic Acid Molecular Formula:C7H9BO3 Molecular Weight:152 CAS No.:5720-07-0 Appearance:Similar White Solid Powder Appearance:Similar White Solid Powder Storage:Store in cool and dry place, away from sun light. Package: 2

4-Methoxy Phenylboronic Acid

Cas:5720-07-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

Boronicacid, B-(4-methoxyphenyl)-CAS NO.: 5720-07-0

Cas:5720-07-0

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

4-Methoxyphenylboronic acid(CAS:5720-07-0)

Cas:5720-07-0

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronicacid, B-(4-methoxyphenyl)- 5720-07-0

Cas:5720-07-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:white powder/ Refer to COA Storage:Refer to COA

4-METHOXY PHENYL BORANIC ACID 5720-07-0 cas door to door

Cas:5720-07-0

Min.Order:1 Kilogram

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Qingdao Beluga Import and Export Co., LTD

4-Methoxyphenylboronic acid CAS:5720-07-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi

4-Methoxyphenylboronic acid CAS:5720-07-0

Cas:5720-07-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boronicacid, B-(4-methoxyphenyl)-

Cas:5720-07-0

Min.Order:1 Kilogram

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Methoxyphenylboronicacid

Cas:5720-07-0

Min.Order:0

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

4-methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:0 Metric Ton

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Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory supply 4-Methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:10 Kilogram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:0

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Hebei Miheng Trading Co., Ltd.

4-Methoxyphenylboronic acid CAS 5720-07-0 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to

4-Methoxyphenylboronic acid CAS 5720-07-0

Cas:5720-07-0

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:100 Gram

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Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Methoxybenzeneboronic acid

Cas:5720-07-0

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Methoxyphenylboronic Acid

Cas:5720-07-0

Min.Order:10 Gram

FOB Price: $100.0

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Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

Top supplier 4-Methoxyphenylboronic acid 5720-07-0 in China

Cas:5720-07-0

Min.Order:1 Gram

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Hefei Zhaobo Technology Co., Ltd.

4-Methoxyphenylboronic acid CAS 5720-07-0 Description Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing

4-Methoxyphenylboronic acid CAS 5720-07-0

Cas:5720-07-0

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:white to light beige crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Reagent used in the preparat

4-Methoxyphenylboronic acid

Cas:5720-07-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Boronicacid, B-(4-methoxyphenyl)-

Cas:5720-07-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Synthetic route

2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
171364-79-7

2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; polystyrene boronic acid In acetonitrile at 20℃; for 18h;99%
Stage #1: 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With potassium hydrogen difluoride In methanol at 20℃; for 0.25h;
Stage #2: With lithium hydroxide In acetonitrile at 20℃; for 20h;
95%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-4-methoxy-benzene With iodine; magnesium In tetrahydrofuran at 20 - 80℃;
Stage #2: With Trimethyl borate In tetrahydrofuran at -10 - 20℃;
97%
Stage #1: 1-bromo-4-methoxy-benzene With diisobutylaluminium hydride; magnesium; lithium chloride In tetrahydrofuran; toluene at 20℃; for 15h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
92%
Stage #1: 1-bromo-4-methoxy-benzene With magnesium In tetrahydrofuran
Stage #2: With Trimethyl borate In tetrahydrofuran for 6h; Acidic conditions;
91%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Trimethyl borate
121-43-7

Trimethyl borate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With Mg In tetrahydrofuran Mg (reflux), THF, B(OCH)3, bromobenzene-compound (-10°C) or n-butyllithium, B(OCH3)3, -78°C, THF;97%
Stage #1: 1-bromo-4-methoxy-benzene With magnesium In tetrahydrofuran
Stage #2: Trimethyl borate In tetrahydrofuran; diethyl ether at -70 - 20℃;
95%
With magnesium In tetrahydrofuran; diethyl ether aryl bromide soln. dropped to Mg in THF, filtered, Grignard soln. added dropwise to soln. of calcd. amt. of B compd. in Et2O at -70°C, warming to room temp. overnight; mixt. added to ice cold and concd. aq. H2SO4, stirred for 30 min, extd. with ether (repeatedly), dried with Na2SO4, evapn., dried in vac., elem.anal.;95%
hydrogenchloride
7647-01-0

hydrogenchloride

Pt(OB(C6H4OMe-4)OB(C6H4OMe-4)O)(dppe)
883153-46-6

Pt(OB(C6H4OMe-4)OB(C6H4OMe-4)O)(dppe)

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]
83095-83-4, 14647-25-7

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

B

2,4,6-tris(4-methoxyphenyl)boroxine
7294-51-1

2,4,6-tris(4-methoxyphenyl)boroxine

C

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
In tetrahydrofuran under N2 or Ar; to a THF soln. of Pt-contg. compd. (0.05 mmol) was addedHCl (0.1 mmol); stirring at room temp. for 2 h; addn. of hexane; the complex was filtered off and dried under vac.; elem. anal.;A 97%
B n/a
C n/a
4-methoxyphenyl magnesium bromide
13139-86-1

4-methoxyphenyl magnesium bromide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-methoxyphenyl magnesium bromide With Trimethyl borate In tetrahydrofuran at 20℃;
Stage #2: With acidic aq. solution
96%
Stage #1: 4-methoxyphenyl magnesium bromide With Trimethyl borate In tetrahydrofuran at -78 - 20℃;
Stage #2: With hydrogenchloride In water
71%
Stage #1: 4-methoxyphenyl magnesium bromide With Trimethyl borate In tetrahydrofuran at -78 - 20℃;
Stage #2: With hydrogenchloride In tetrahydrofuran Further stages.;
4.37 g
With Trimethyl borate at -78℃; for 8h;
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
96%
Stage #1: 4-chloromethoxybenzene With tetrahydroxydiboron; ethanol; chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[(2-(2-aminoethyl)phenyl)]palladium(II); potassium acetate; sodium t-butanolate; XPhos at 80℃; for 18h; Inert atmosphere;
Stage #2: With hydrogenchloride; water In ethyl acetate for 0.5h; Inert atmosphere;
82%
With tetrahydroxydiboron; (chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II)); potassium acetate; XPhos In ethanol at 80℃; for 2h; Inert atmosphere;
With methanol; tetrakis(dimethylamido)diborane; chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II); potassium acetate; XPhos at 20 - 60℃; for 5.0833h; Inert atmosphere; Sealed tube;
potassium 4-(methoxy)phenyltrifluoroborate

potassium 4-(methoxy)phenyltrifluoroborate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With aluminum oxide; water at 70℃; for 0.25h; Microwave irradiation;93%
With water; silica gel at 20℃; for 1h; Inert atmosphere;83%
With iron(III) chloride; water In tetrahydrofuran at 20℃; for 0.5h;81%
With water In tetrahydrofuran at 55℃; Kinetics; Reagent/catalyst;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); N-ethyl-N,N-diisopropylamine In 2-methyltetrahydrofuran; methanol at 50℃; for 1h; Catalytic behavior; Reagent/catalyst; Concentration; Time; Inert atmosphere;92%
In methanol at 15℃; for 3h; Microwave irradiation;87%
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); tetramethyl ammonium acetate In 2-methyltetrahydrofuran; methanol; water at 40℃; for 8h; Schlenk technique; Inert atmosphere;70%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Triisopropyl borate
5419-55-6

Triisopropyl borate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-4-methoxy-benzene With n-butyllithium In tetrahydrofuran; hexane at -78 - -10℃;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃;
91%
With magnesium; iodine; hydrochloric acid In tetrahydrofuran; diethyl ether Mg and I2 heated under Ar, diethyl ether and soln. of 4-bromoanisole added, mixt. warmed to 40°C for 30 min, soln. transferred into soln.of (iso-PrO)3B in THF at -78°C, stirred overnight, warmed to roo m temp., HCl added, stirred for 1 h; extn. (aq. NH4Cl/NaOH and EtOAc), drying (MgSO4), evapn.;20%
With n-butyllithium In tetrahydrofuran; hexane
Pt(OB(C6H4OMe-4)OB(C6H4OMe-4)O)(dppe)
883153-46-6

Pt(OB(C6H4OMe-4)OB(C6H4OMe-4)O)(dppe)

trifluoroacetic acid
76-05-1

trifluoroacetic acid

Pt(CF3CO2)2(dppe)
69005-06-7

Pt(CF3CO2)2(dppe)

B

2,4,6-tris(4-methoxyphenyl)boroxine
7294-51-1

2,4,6-tris(4-methoxyphenyl)boroxine

C

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
In tetrahydrofuran under N2 or Ar; to a THF soln. of Pt-contg. compd. (0.05 mmol) was addedCF3COOH (0.1 mmol); stirring at room temp. for 2 h; addn. of hexane; the complex was filtered off and dried under vac.; elem. anal.;A 91%
B n/a
C n/a
methanol
67-56-1

methanol

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

dicyclohexylamine borane complex
131765-96-3

dicyclohexylamine borane complex

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-4-methoxy-benzene; dicyclohexylamine borane complex With magnesium In tetrahydrofuran at 70℃;
Stage #2: methanol In tetrahydrofuran at 0℃; for 1h;
Stage #3: With hydrogenchloride; water In methanol at 20℃; for 1h;
91%
water
7732-18-5

water

potassium 4-(methoxy)phenyltrifluoroborate

potassium 4-(methoxy)phenyltrifluoroborate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With montmorillonite K10 at 25℃; for 1.5h;90%
With 1H-imidazole; iron(III) chloride at 20℃; for 0.25h; Inert atmosphere;81%
With glass or Cs2CO3 In tetrahydrofuran; water Kinetics; hydrolysis at 55°C in THF/H2O in the presence of glass powder or Cs2CO3; not isolated;
para-iodoanisole
696-62-8

para-iodoanisole

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: para-iodoanisole With diisopropopylaminoborane; triethylamine; triphenylphosphine; palladium dichloride In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
89%
With tetrahydroxydiboron; (chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II)); potassium acetate; XPhos In ethanol at 80℃; for 1h; Inert atmosphere;
(p-methoxyphenyl)tri-n-butylstannane
70744-47-7

(p-methoxyphenyl)tri-n-butylstannane

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With borane; water In tetrahydrofuran for 1h; Heating;88%
4-methoxyphenyl triflate
66107-29-7

4-methoxyphenyl triflate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-methoxyphenyl triflate With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; diisopropopylaminoborane; triethylamine; triphenylphosphine In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
87%
With tetrahydroxydiboron; (chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II)); potassium acetate; XPhos In ethanol at 80℃; for 2h; Inert atmosphere;
With methanol; tetrakis(dimethylamido)diborane; chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II); potassium acetate; XPhos at 20 - 60℃; for 6.5833h; Inert atmosphere; Sealed tube;
methanol
67-56-1

methanol

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

diisopropylamine borane
55124-35-1

diisopropylamine borane

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane With magnesium; phenylmagnesium bromide In tetrahydrofuran at 20℃; for 0.166667h;
Stage #2: 1-bromo-4-methoxy-benzene In tetrahydrofuran at 70℃;
Stage #3: methanol Reagent/catalyst; Further stages;
87%
triethyl borate
150-46-9

triethyl borate

p-methoxyphenyllithium
14774-77-7

p-methoxyphenyllithium

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
In tetrahydrofuran addn. of B-compd. to org. compd. in THF, stirring (-78°C, 1.5 h); addn. of satd. soln. of aq. NH4Cl (-78°C), warming (room temp.),DDN: OF H2O, shaking with ether, washing of ether extracts (satd. aq. NaHCO3 and satd. brine), drying (Na2SO4), filtration, evapn. (vac.), crystn. (H2O);86%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-methoxy-aniline With hydrogenchloride; sodium nitrite In methanol; water at 0 - 5℃; for 0.5h;
Stage #2: With tetrahydroxydiboron In methanol; water at 20℃; for 1h;
86%
Multi-step reaction with 2 steps
1.1: water / 0.03 h / 20 °C
1.2: 0.25 h / 0 °C
2.1: N,N-dimethyl-formamide / 0.25 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: tetrafluoroboric acid; sodium nitrite / water / 1 h / 0 °C
1.2: 0 - 20 °C
2.1: methanol / 17 h / 20 °C / Irradiation; Inert atmosphere; Schlenk technique
View Scheme
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

water
7732-18-5

water

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With NaOC(CH3)3; 2,4,6-(i-Pr)3C6H2C6H4[2-P(cyclo-C6H11)2]; KOAc In ethanol mixt. B2(OH)4, hexane wash, Pd-complex, (iPr)3C6H2C6H4-2-P(cyclo-C6H11),NaOBu-t and excess KOAc in EtOH at 80°C for 18 h;82%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-methoxy-N,N,N-trimethylbenzenaminium iodide
17310-99-5

4-methoxy-N,N,N-trimethylbenzenaminium iodide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
In methanol at 15℃; for 3h; Microwave irradiation;82%
2,5-bis-(4-methoxyphenyl)-4,4-dimethyl-[1,3,2]dioxaborolane

2,5-bis-(4-methoxyphenyl)-4,4-dimethyl-[1,3,2]dioxaborolane

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water at 20℃; for 24h;80%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-methoxy-aniline
104-94-9

4-methoxy-aniline

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-methoxy-aniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h;
77%
Stage #1: 4-methoxy-aniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With potassium carbonate In water at 20℃; for 0.333333h; Reagent/catalyst; Solvent;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Trimethyl borate
121-43-7

Trimethyl borate

water
7732-18-5

water

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-4-methoxy-benzene With magnesium In tetrahydrofuran at 20℃; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at -78 - 20℃; for 4h; Inert atmosphere;
Stage #3: water With hydrogenchloride
77%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Trimethyl borate
121-43-7

Trimethyl borate

sulfuric acid
7664-93-9

sulfuric acid

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With magnesium In tetrahydrofuran74%
borane
13283-31-3

borane

4-methoxyphenyl magnesium bromide
13139-86-1

4-methoxyphenyl magnesium bromide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With water In tetrahydrofuran slow addn. of 10 mmol of the Grignard reagent to a stirred soln. of borane in THF (40 mmol); the mixt. was poured into ice-water and acidified with 10% HCl;; extn. into ether three-times; the combined extracts were dried over NaSO4; removal of solvent under reduced pressure; trituration with petroleum ether; recrystn. from H2O;;73%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

diisopropylamine borane
55124-35-1

diisopropylamine borane

para-bromotoluene
106-38-7

para-bromotoluene

water
7732-18-5

water

A

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

B

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

C

B-(4-methoxyphenyl)-B-(4-methylphenyl)borinic acid

B-(4-methoxyphenyl)-B-(4-methylphenyl)borinic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane; para-bromotoluene With magnesium In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;
Stage #2: 1-bromo-4-methoxy-benzene In tetrahydrofuran at 40℃; for 14h; Inert atmosphere;
Stage #3: water In tetrahydrofuran Temperature; Inert atmosphere;
A 9%
B 12%
C 73%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

para-iodoanisole
696-62-8

para-iodoanisole

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

Conditions
ConditionsYield
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); tetramethyl ammonium acetate In 2-methyltetrahydrofuran; methanol; water at 40℃; for 6.5h; Catalytic behavior; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere;70%
With fac-tris(2-phenylpyridinato-N,C2')iridium(III); tributyl-amine; water In acetonitrile at 25℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;40%
In methanol; water at -5℃; for 0.166667h; UV-irradiation; Flow reactor; chemoselective reaction;100 %Spectr.
With [{Pd(μ-Cl){κ2-P,C-P(iPr)2(OC6H3-2-Ph)}}2]; sodium acetate In dichloromethane; water at 40℃; for 6h; Inert atmosphere;
o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

methyl 4'-methoxybiphenyl-2-carboxylate
17103-25-2

methyl 4'-methoxybiphenyl-2-carboxylate

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate In water; acetonitrile at 60℃; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With bis(triphenylphosphine)palladium(II) dichloride; sodium carbonate In tetrahydrofuran; water at 80℃; for 14h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; Sealed tube;95%
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In toluene for 18h; Heating;80%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane at 20℃; for 0.166667h;100%
With N-Bromosuccinimide In acetonitrile at 80℃; for 12h;96%
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; Sealed tube;85%
bromobenzene
108-86-1

bromobenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; p-tolylboronic pinacol ester In 1,4-dioxane; water at 70℃; for 1h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; chemoselective reaction;100%
With potassium carbonate In ethanol; water at 50℃; for 0.5h; Catalytic behavior; Suzuki-Miyaura Coupling;100%
With potassium carbonate; palladium dichloride In pyridine for 4h; Suzuki cross-coupling; Heating;99%
iodobenzene
591-50-4

iodobenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

Conditions
ConditionsYield
With sodium carbonate In ethanol; water at 80℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;100%
With SIPr-PdCl2-Py; sodium t-butanolate In tetrahydrofuran at 70℃; for 12h; Suzuki-Miyaura Coupling;100%
With caesium carbonate; 1,4-diaza-bicyclo[2.2.2]octane; copper(l) iodide In N,N-dimethyl-formamide at 125 - 130℃; for 19h; Suzuki-Miyaura cross-coupling reaction;99%
para-chlorotoluene
106-43-4

para-chlorotoluene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 3-butyl-1-methyl-5-[9-(3-methyl-1H-imidazol-3-ium-1-yl)nonyl]-3H-1,2,3-triazol-1-ium diiodide; caesium carbonate In 1,4-dioxane Suzuki-Miyaura reaction; Inert atmosphere; Heating;100%
With tris(dibenzylideneacetone)dipalladium (0); C3H3N2(C9H11)2*HCl; caesium carbonate In 1,4-dioxane at 80℃; for 1.5h;99%
Stage #1: 4-methoxyphenylboronic acid With allyl(1,3-bis(2,6-diisopropyl-4-(3-((3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)oxy)propyl)phenyl)-imidazol-2-ylidene)palladium(II) chloride; potassium tert-butylate In ethanol at 30℃; for 0.5h; Inert atmosphere;
Stage #2: para-chlorotoluene In ethanol at 30℃; for 4h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Suzuki Coupling; Inert atmosphere;
99%
4-tolyl iodide
624-31-7

4-tolyl iodide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 80℃; for 0.166667h; Suzuki Coupling;100%
With sodium carbonate In ethanol; water at 80℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;100%
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;99%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4-(4'-methoxyphenyl)benzaldehyde
52988-34-8

4-(4'-methoxyphenyl)benzaldehyde

Conditions
ConditionsYield
With sodium carbonate In ethanol at 75℃; for 2h; Suzuki-Miyaura cross coupling;100%
With palladium 10% on activated carbon; caesium carbonate at 100℃; for 24h; Suzuki-Miyaura coupling; Neat (no solvent);100%
With potassium tert-butylate In ethanol; water at 25℃; for 2h; Suzuki-Miyaura Coupling;100%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

N,N-dimethyl 2-iodo-3-(trans-2-methoxycarbonylethenyl)-4-trimethylsilyl-1H-pyrrole-1-sulfonamide
284663-47-4

N,N-dimethyl 2-iodo-3-(trans-2-methoxycarbonylethenyl)-4-trimethylsilyl-1H-pyrrole-1-sulfonamide

N,N-dimethyl 2-(p-methoxyphenyl)-3-(trans-2-methoxycarbonylethenyl)-4-trimethylsilyl-1H-pyrrole-1-sulfonamide
284663-48-5

N,N-dimethyl 2-(p-methoxyphenyl)-3-(trans-2-methoxycarbonylethenyl)-4-trimethylsilyl-1H-pyrrole-1-sulfonamide

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium sulfate In methanol; toluene at 90 - 100℃; for 2h; Phenylation;100%
para-bromotoluene
106-38-7

para-bromotoluene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In pyridine for 4h; Suzuki cross-coupling; Heating;100%
With C21H26Cl2N2Pd; potassium carbonate In toluene at 110℃; for 18h; Suzuki Coupling; Inert atmosphere; Sealed tube;100%
With tetrabutylammomium bromide; sodium carbonate; palladium contaminants present in sodium carbonate In water at 150℃; for 0.0833333h; Suzuki coupling; microwave irradiation;99%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4'-methoxy-2-methylbiphenyl
92495-54-0

4'-methoxy-2-methylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; palladium-incarcerated polystyrene-based copolymer; tris(o-methoxyphenyl)phosphine In water; toluene for 2h; Suzuki-Miyaura coupling; Heating;100%
With potassium phosphate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 20℃; for 6h; Suzuki cross-coupling;98%
With potassium fluoride; tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 2h; Suzuki cross-coupling;98%
p-tolyl triflate
29540-83-8

p-tolyl triflate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 3-butyl-1-methyl-5-[9-(3-methyl-1H-imidazol-3-ium-1-yl)nonyl]-3H-1,2,3-triazol-1-ium diiodide; caesium carbonate In 1,4-dioxane Suzuki-Miyaura reaction; Inert atmosphere; Heating;100%
With potassium fluoride; palladium diacetate; tricyclohexylphosphine In tetrahydrofuran at 20℃; for 4h; Suzuki cross-coupling;95%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1-(4'-methoxy-biphenyl-4-yl)-ethanone
13021-18-6

1-(4'-methoxy-biphenyl-4-yl)-ethanone

Conditions
ConditionsYield
With sodium phosphate; palladium on activated charcoal In water; isopropyl alcohol at 20℃; for 2h; Suzuki-Miyaura reaction;100%
With potassium carbonate In water at 80℃; for 5h; Suzuki Coupling;100%
With potassium carbonate In methanol at 25℃; for 1h; Wavelength; Suzuki-Miyaura Coupling; Inert atmosphere; Irradiation;100%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

p-aminoiodobenzene
540-37-4

p-aminoiodobenzene

4-(4-methoxyphenyl)aniline
1137-77-5

4-(4-methoxyphenyl)aniline

Conditions
ConditionsYield
With sodium carbonate In ethanol; water at 80℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;100%
With potassium carbonate In ethanol at 78℃; for 1h; Suzuki-Miyaura coupling; Air atmosphere;96%
With potassium carbonate In methanol; water at 40 - 45℃; for 1.5h; Suzuki Coupling;92%
3-Bromopyridine
626-55-1

3-Bromopyridine

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

3-(4-methoxyphenyl)pyridine
5958-02-1

3-(4-methoxyphenyl)pyridine

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 120℃; for 5h; Suzuki Coupling;100%
With potassium carbonate In isopropyl alcohol at 85 - 90℃; for 24h; Suzuki-Miyaura Coupling;99%
With sodium phosphate; palladium on activated charcoal In isopropyl alcohol at 80℃; for 6h; Suzuki-Miyaura coupling reaction;98%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

5-chloro-4-methoxy-2-methyl-2H-pyridazin-3-one
77541-59-4

5-chloro-4-methoxy-2-methyl-2H-pyridazin-3-one

4-methoxy-5-(4-methoxyphenyl)-2-methyl-3(2H)-pyridazinone
335349-24-1

4-methoxy-5-(4-methoxyphenyl)-2-methyl-3(2H)-pyridazinone

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 120℃; Suzuki cross-coupling;100%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

5-chloro-4-methoxy-2-phenyl-3(2H)-pyridazinone
76929-42-5

5-chloro-4-methoxy-2-phenyl-3(2H)-pyridazinone

4-methoxy-5-(4-methoxyphenyl)-2-phenyl-3(2H)-pyridazinone
335349-29-6

4-methoxy-5-(4-methoxyphenyl)-2-phenyl-3(2H)-pyridazinone

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 120℃; Suzuki cross-coupling;100%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-methoxy-phenol
150-76-5

4-methoxy-phenol

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In ethanol at 20℃; for 8h; Reagent/catalyst; Irradiation; Sonication;100%
With solid poly(N-vinylpyrrolidone)-hydrogen peroxide complex (PVD-H2O2 complex) In dichloromethane at 20℃; regioselective reaction;99%
With menadione; sodium hydrogencarbonate; sodium L-ascorbate In ethanol; water at 20℃; under 760.051 Torr; for 24h; pH=8.5; Darkness; Green chemistry;99%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-chloro-5-methoxy-2-methyl-2H-pyridazin-3-one
14628-57-0

4-chloro-5-methoxy-2-methyl-2H-pyridazin-3-one

5-methoxy-4-(4-methoxyphenyl)-2-methyl-3(2H)-pyridazinone

5-methoxy-4-(4-methoxyphenyl)-2-methyl-3(2H)-pyridazinone

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 120℃; Suzuki cross-coupling;100%
4-(trifluormethanesulfonyloxy)benzaldehyde
17763-69-8

4-(trifluormethanesulfonyloxy)benzaldehyde

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-(4'-methoxyphenyl)benzaldehyde
52988-34-8

4-(4'-methoxyphenyl)benzaldehyde

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; lithium chloride In ethanol; toluene Suzuki coupling; Heating;100%
With potassium phosphate; C18H9F5NOP(2-)*Pd(2+)*C3H7NO In ethanol at 20℃; for 12h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;78%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4,4'-Dimethoxybiphenyl
2132-80-1

4,4'-Dimethoxybiphenyl

Conditions
ConditionsYield
With air; potassium carbonate; [Pd(Cl)κ2N,C,-CH2C6H2(4,6-Me)2CH=NC6H3(2,6-iPr)2]2 In ethanol for 2h; Suzuki-Miyaura coupling reaction; Heating;100%
With sodium carbonate; palladium on activated charcoal In ethanol at 20℃; for 5h; Suzuki-Miyaura cross-coupling;100%
With potassium carbonate In water at 50℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;100%
2,3-Dichloro-1,4-naphthoquinone
117-80-6

2,3-Dichloro-1,4-naphthoquinone

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

2,3-bis(4-methoxyphenyl)naphthalene-1,4-dione
50982-55-3

2,3-bis(4-methoxyphenyl)naphthalene-1,4-dione

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; benzene for 4h; Suzuki coupling; Heating;100%
para-iodoanisole
696-62-8

para-iodoanisole

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4,4'-Dimethoxybiphenyl
2132-80-1

4,4'-Dimethoxybiphenyl

Conditions
ConditionsYield
With potassium phosphate monohydrate; 4,4'-di-tBu-2,2'-dipyridylpalladium(II) dichloride In methanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;100%
With potassium carbonate In water at 80℃; for 2h; Suzuki Coupling;100%
With sodium carbonate In ethanol; water at 80℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;100%
p-trifluoromethylphenyl bromide
402-43-7

p-trifluoromethylphenyl bromide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

1-(4-methoxyphenyl)-4-(trifluoromethyl)benzene
10355-12-1

1-(4-methoxyphenyl)-4-(trifluoromethyl)benzene

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 120℃; for 5h; Suzuki Coupling;100%
With sodium carbonate; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; palladium diacetate In water at 60℃; for 1h; Suzuki coupling;99%
With potassium phosphate; [5-(3-butylbenzimidazol-2-yliden-1-yl)-25,26,27,28-tetrapropyloxy calix[4]arene] (pyridine) palladium(II) dibromide In 1,4-dioxane at 100℃; for 24h; Inert atmosphere;99%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-chloro-6-iodo-quinoline
40107-07-1

4-chloro-6-iodo-quinoline

4-chloro-6-(4-methoxyphenyl)quinoline
500127-41-3

4-chloro-6-(4-methoxyphenyl)quinoline

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 64℃; for 15h; Product distribution; Further Variations:; Catalysts; Reaction partners; Reagents; Solvents; temperatures, reaction times; Suzuki reaction;100%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water for 15h; Product distribution; Further Variations:; Catalysts; Heating;100%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-methoxy-4'-nitrobiphenyl
2143-90-0

4-methoxy-4'-nitrobiphenyl

Conditions
ConditionsYield
With sodium carbonate In ethanol; water at 80℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;100%
With palladium diacetate; 4-Ph2P-C6H4-2-N-glucosamine; sodium carbonate In tetrahydrofuran; ethanol; water at 60℃; for 18h;99%
With polyhydroxylated phosphine; sodium carbonate; palladium diacetate In ethanol; water; toluene at 60℃; for 18h;99%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

4-methoxy-4'-nitrobiphenyl
2143-90-0

4-methoxy-4'-nitrobiphenyl

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 150℃; for 36h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With C12H10N3OPol; tetrabutylammomium bromide; palladium diacetate; potassium carbonate In water at 100℃; for 15h; Suzuki-Miyaura reaction;99%
With sodium tetrachloropalladate(II); 5-[3-(4-carboxy-2,6-dimethylphenyl)-2-thioxoimidazolidin-1-yl]benzene-1,2,3-tricarboxylic acid; tetrabutylammomium bromide; potassium hydroxide In water at 100℃; for 10h; Temperature; Suzuki-Miyaura Coupling; Sealed tube;99%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

9,15-bis(trifluoromethylsulfonyloxy)<212,13><5.2>metacyclophane
135019-26-0

9,15-bis(trifluoromethylsulfonyloxy)<212,13><5.2>metacyclophane

C35H36O2

C35H36O2

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 110 - 120℃; for 24h; Suzuki coupling reaction;100%
cyclopent-2-enone
930-30-3

cyclopent-2-enone

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

(R)-3-(4-methoxyphenyl)cyclopentan-1-one
155325-51-2

(R)-3-(4-methoxyphenyl)cyclopentan-1-one

Conditions
ConditionsYield
With potassium hydroxide; (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene; bis(ethylene)rhodium(I) chloride dimer In 1,4-dioxane; water at 50℃; for 1h;100%
With chlorobis(ethylene)rhodium(I) dimer; C22H20N2O4; potassium hydroxide In ethanol at 30℃; for 1h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;98%
With chlorobis(ethylene)rhodium(I) dimer; (R)-6,6'-dimethoxy-P2,P2,P2',P2'-tetrakis-[4-(trifluoromethyl)phenyl]-biphenyl-2,2'-bisphosphine; potassium hydroxide In water; toluene at 20℃; for 6.5h; Inert atmosphere; optical yield given as %ee; stereoselective reaction;96%
3-Bromothianaphthene
7342-82-7

3-Bromothianaphthene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

3-(4-methoxy-phenyl)-benzo[b]thiophene
24257-23-6

3-(4-methoxy-phenyl)-benzo[b]thiophene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 6h; Reflux; Inert atmosphere;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 6h; Inert atmosphere; Reflux;100%
With di-1-adamantyl(4-sulfonatobenzyl)phosphonium; palladium diacetate; sodium carbonate In water; acetonitrile at 50℃; Reagent/catalyst; Suzuki Coupling; Inert atmosphere; Glovebox;76%
With di-1-adamantyl(4-sulfonatobenzyl)phosphonium; palladium diacetate; sodium carbonate In water; acetonitrile at 50℃; Reagent/catalyst; Suzuki Coupling; Inert atmosphere; Glovebox;76%
tetrakis(triphenylphosphine) palladium(0) Suzuki-Miyaura reaction;52%
diphenyl diselenide
1666-13-3

diphenyl diselenide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

p-methoxyphenyl phenyl selenide
80448-01-7

p-methoxyphenyl phenyl selenide

Conditions
ConditionsYield
With Cu NPs/Ac In dimethyl sulfoxide at 20 - 100℃; for 3h; Sealed tube; Sonication;100%
With indium tribromide In dimethyl sulfoxide at 130℃; for 20h;98%
With Oxone In ethanol at 60℃; for 2h; Solvent; Temperature; Schlenk technique;98%
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