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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

4-Chloroanisole Manufacturer/High quality/Best price/In stock

Cas:623-12-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality P-Chloroanisole supplier in China

Cas:623-12-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-chloroanisole

Cas:623-12-1

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Chloroanisole

Cas:623-12-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--623-12-1--4-Chloroanisole factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relatio

TIANFUCHEM--623-12-1--4-Chloroanisole factory price

Cas:623-12-1

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Chloroanisole 623-12-1

Cas:623-12-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 623-12-1 with best price

Cas:623-12-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name:4-Chloroanisole CAS No:623-12-1 Appearance:Yellow liquid Content:99% Appearance:Yellow liquid Storage:Preserve in well-closed, light-resistant and airtight containers. Package:25k

4-Chloroanisole

Cas:623-12-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

4-Chloroanisole

Cas:623-12-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Chloroanisole CAS:623-12-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat

4-Chloroanisole CAS:623-12-1

Cas:623-12-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

4-Chloroanisole CAS 623-12-1

Cas:623-12-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:623-12-1

Cas:623-12-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

4-Chloroanisole CAS: 623-12-1 Specification Item Standard Test Results Identification A.H-NMR:Comply with the structure Complies B.LC-MS:Comply with the

Factory supply 4-Chloroanisole

Cas:623-12-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

P-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Chloroanisole

Cas:623-12-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

4-Chloroanisole

Cas:623-12-1

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Organic Intermediate 1-Chloro-4-methoxybenzene CAS 623-12-1

Cas:623-12-1

Min.Order:1 Liter

FOB Price: $4.5 / 5.0

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

4-Chloroanisole

Cas:623-12-1

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

4-Chloroanisole Chemical Properties Melting point -18 °C (lit.) Boiling point 198-202 °C (lit.) density 1.164 g/mL at 25 °C (lit.) refractive index n20/D 1.535(lit.) Fp 173 °F storage temp. 2-8°C form L

4-Chloroanisole

Cas:623-12-1

Min.Order:200 Kilogram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/4-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

4-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

4-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-Chloroanisole cas no. 623-12-1 98%

Cas:623-12-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1-chloro-4-methoxybenzene

Cas:623-12-1

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

4-Chloroanisole

Cas:623-12-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

P-Chloroanisole

Cas:623-12-1

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:It is an impo

4-Chloroanisole

Cas:623-12-1

Min.Order:1 Liter

Negotiable

Type:Trading Company

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 4-Chloroanisole 500g

Cas:623-12-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4,4'-dimethoxy-diphenyliodonium chloride
50619-99-3

4,4'-dimethoxy-diphenyliodonium chloride

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
In benzene-d6 at 120℃; for 120h; Sealed tube;100%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With nickel dichloride In N,N-dimethyl-formamide at 170℃; for 0.0833333h; microwave irradiation;99%
With trans-bis(glycinato)copper(II) monohydrate; tetramethlyammonium chloride In ethanol at 100℃; for 12h; Finkelstein Reaction; Schlenk technique; Inert atmosphere;91%
With copper(I) oxide; tetramethlyammonium chloride; L-proline In ethanol at 110℃; for 18h; Inert atmosphere;80%
4-chloro-phenol
106-48-9

4-chloro-phenol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 90℃; for 16h; Product distribution; Further Variations:; Temperatures; Solvents; Pressures; reaction times; microwave irradiation;99%
With N,N'-dimethylimidazolium-2-carboxylate In acetonitrile at 160℃; for 2h; Microwave irradiation; Green chemistry;94%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0416667h; microwave irradiation;92%
potassium 4-(methoxy)phenyltrifluoroborate

potassium 4-(methoxy)phenyltrifluoroborate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With trichloroisocyanuric acid In water; ethyl acetate at 20℃; for 0.666667h; Open flask;98%
methoxybenzene
100-66-3

methoxybenzene

A

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

B

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With sodium chlorite; silica gel; manganese(III) acetylacetonate; sodium bromide In dichloromethane at 25℃; for 2h;A 97%
B 3%
With tetraethylammonium chloride; tetraethylammonium bromide Product distribution; 1.) CH2Cl2, RT, 1 h, electrolysis, 2.) CH2Cl2, RT, 24 h; other halogenating agents; other benzene derivatives and olefins;
bromochlorobenzene
106-39-8

bromochlorobenzene

sodium methylate
124-41-4

sodium methylate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With methanol; Methyl formate; copper(l) chloride at 115℃; for 2h; Autoclave; Green chemistry;97%
4-chloro-phenol
106-48-9

4-chloro-phenol

dimethyl sulfate
77-78-1

dimethyl sulfate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide; potassium carbonate for 0.00694444h; Irradiation; microwave;89%
With sodium hydroxide at 100℃;
With alkaline solution
With potassium carbonate In acetone
With lithium hydroxide In tetrahydrofuran for 1h; Ambient temperature; Yield given;
2-bromo-1-chloro-4-methoxybenzene
2732-80-1

2-bromo-1-chloro-4-methoxybenzene

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With methanol; gold; hydrogen; caesium carbonate at 100℃; under 3800.26 Torr; for 71h;89%
(4-methoxyphenyl)(mesityl)iodonium trifluoromethanesulfonate
1330681-27-0

(4-methoxyphenyl)(mesityl)iodonium trifluoromethanesulfonate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With copper(l) chloride In acetonitrile at 80℃; for 2h;87%
N-chloro-N-(4-methylphenyl)acetamide
14596-60-2

N-chloro-N-(4-methylphenyl)acetamide

methoxybenzene
100-66-3

methoxybenzene

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

2-Chloroanisole
766-51-8

2-Chloroanisole

C

N-(2-chloro-4-methylphenyl)acetamide
18931-78-7

N-(2-chloro-4-methylphenyl)acetamide

D

4-Methylacetanilide
103-89-9

4-Methylacetanilide

Conditions
ConditionsYield
at 110℃; for 12h; Mechanism; Orton Haloaniline Rearrangement; Inert atmosphere; Darkness;A 82%
B n/a
C n/a
D 87%
phenyltrimethylammonium chloride
138-24-9

phenyltrimethylammonium chloride

4-chloro-phenol
106-48-9

4-chloro-phenol

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

Conditions
ConditionsYield
With caesium carbonate In toluene for 6h; Heating;A 85%
B n/a
4-chloro-phenol
106-48-9

4-chloro-phenol

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

Conditions
ConditionsYield
With boron trifluoride In diethyl ether for 0.05h; microwave irradiation;85%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-bromo-4-chloroanisole
60633-25-2

2-bromo-4-chloroanisole

Conditions
ConditionsYield
With (CH3)4Br In liquid sulphur dioxide at -23℃; Rate constant;100%
With (CH3)4Br In liquid sulphur dioxide at -23℃;100%
With iron(III) chloride; N-Bromosuccinimide; 1-butyl-3-methylimidazolium trifluoromethanesulfonimide In toluene regioselective reaction;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-chloro-phenol
106-48-9

4-chloro-phenol

Conditions
ConditionsYield
With sodium; diphenyldisulfane In 1-methyl-pyrrolidin-2-one for 0.5h; Heating;100%
With calcium hydride; diphenyldisulfane In 1-methyl-pyrrolidin-2-one at 220℃; for 0.5h;99%
With copper(I) oxide; sodium methylate In methanol at 185℃; for 12h; Autoclave;96%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

Conditions
ConditionsYield
With 2-(dicyclohexylphosphino)-4'-(N,N-dimethylamino)-1,1'-biphenyl at 100℃; Suzuki-Miyaura coupling;100%
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate In tetrahydrofuran at 50℃; for 24h; Suzuki coupling; Inert atmosphere;100%
With 1,2-di-(N-2-methoxyethylbenzimidazoliummethyl)-benzene dichloride; potassium tert-butylate; palladium diacetate In water; N,N-dimethyl-formamide at 50℃; for 3h; Reagent/catalyst; Suzuki Coupling;100%
morpholine
110-91-8

morpholine

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

N-(4-methoxyphenyl)morpholine
27347-14-4

N-(4-methoxyphenyl)morpholine

Conditions
ConditionsYield
With (55)Pd068(44)Ni032; potassium carbonate In water at 80℃; for 8h; Catalytic behavior; Buchwald-Hartwig Coupling;100%
With 2-dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl; sodium t-butanolate In tetrahydrofuran at 80℃; for 2.5h; Reagent/catalyst;100%
With potassium tert-butylate; [(IPr)Pd(acac)Cl] In 1,2-dimethoxyethane at 50℃; for 4h; Buchwald-Hartwig coupling;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-Fluorobenzenesulfonyl chloride
349-88-2

4-Fluorobenzenesulfonyl chloride

4-Chloro-2-(4-fluoro-benzenesulfonyl)-1-methoxy-benzene

4-Chloro-2-(4-fluoro-benzenesulfonyl)-1-methoxy-benzene

Conditions
ConditionsYield
With indium(III) chloride; trifluorormethanesulfonic acid In trifluoroacetic acid at 70℃; for 1.5h;100%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

(2,6-dimethoxyphenyl)zinc chloride

(2,6-dimethoxyphenyl)zinc chloride

2,4’,6-trimethoxybiphenyl
54960-98-4

2,4’,6-trimethoxybiphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); ruphos In tetrahydrofuran at 70℃; Negishi coupling;100%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

(2,4,6-triisopropylphenyl)zinc chloride

(2,4,6-triisopropylphenyl)zinc chloride

4-methoxy-2',4',6'-tri-isopropylbiphenyl

4-methoxy-2',4',6'-tri-isopropylbiphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); ruphos In tetrahydrofuran at 70℃; for 15h; Negishi coupling;100%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-Methoxypropiophenone
121-97-1

4-Methoxypropiophenone

1,2-bis-(4-methoxy-phenyl)-propan-1-one
35258-41-4

1,2-bis-(4-methoxy-phenyl)-propan-1-one

Conditions
ConditionsYield
With 2-methoxy-6-(N-methyl-N-phenyl-amino)phenyl(dicyclohexyl)phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 18h; Schlenk technique; Inert atmosphere;100%
With PdCl2(C3H3N2(CH3))(C3H2N2(C6H3(C3H7)2)2); potassium tert-butylate In toluene at 80℃; for 6h; Inert atmosphere;89%
With C40H44ClN3Pd; sodium t-butanolate In toluene at 80℃; for 3h; Inert atmosphere;87%
bromobenzene
108-86-1

bromobenzene

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

Conditions
ConditionsYield
Stage #1: bromobenzene With lithium
Stage #2: With zinc(II) chloride
Stage #3: 4-chloromethoxybenzene; nickel phosphine amido pincer complex In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 12h; Negishi cross-coupling; Further stages.;
99.2%
Stage #1: bromobenzene With iodine; magnesium In diethyl ether at 50℃; for 1h; Inert atmosphere;
Stage #2: 4-chloromethoxybenzene With magnesium In diethyl ether at 45 - 50℃; for 2h; Inert atmosphere;
90%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4,4'-Dimethoxybiphenyl
2132-80-1

4,4'-Dimethoxybiphenyl

Conditions
ConditionsYield
With cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane99%
With cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane99%
With tetrabutylammomium bromide; sodium methylate In water at 80℃; for 20h; Ullmann reaction;97%
pyrrolidine

pyrrolidine

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

N-(4-methoxyphenyl)pyrrolidine

N-(4-methoxyphenyl)pyrrolidine

Conditions
ConditionsYield
With [IPr*·H][Pd(η3-cin)Cl2]; potassium tert-butylate at 60 - 80℃; for 2h; Buchwald-Hartwig Coupling; Sealed tube;99%
With potassium hydroxide; johnphos; 2-(di-t-butylphosphino)biphenyl palladium In toluene at 90℃; for 20h;94%
With [Pd(2-aminobiphenyl)(PiPr2ArXyl2)](OMs); sodium t-butanolate In tetrahydrofuran at 80℃; for 19h; Reagent/catalyst; Inert atmosphere; Schlenk technique;94%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

o-toluidine

o-toluidine

N-(4-methoxyphenyl)-2-methylbenzenamine

N-(4-methoxyphenyl)-2-methylbenzenamine

Conditions
ConditionsYield
With [IPr*·H][Pd(η3-cin)Cl2]; potassium tert-butylate at 60 - 80℃; for 2h; Buchwald-Hartwig Coupling; Sealed tube;99%
With (2-phenyl-1H-inden-3-yl)-dicyclohexylphosphinium tetrafluoroborate; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 1,2-dimethoxyethane at 20 - 120℃; Buchwald-Hartwig amination; Inert atmosphere;91%
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate In toluene at 100℃; for 15h;88%
With bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1.5h; Inert atmosphere;50%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

N-methylaniline
100-61-8

N-methylaniline

N-(4-methoxyphenyl)-N-methylaniline
55251-46-2

N-(4-methoxyphenyl)-N-methylaniline

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); di-tert-butylneopentylphosphonium tetrafluoroborate; sodium t-butanolate In toluene at 100℃; for 18h; Hartwig-Buchwald amination;99%
With dichloro(3-chloropyridinyl)(1,3-(diisopropylphenyl)-4,5-bis(dimethylamino)imidazol-2-ylidene)palladium(II); potassium tert-butylate In 1,4-dioxane at 80℃; for 18h; Reagent/catalyst; Solvent; Temperature; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique; Sealed tube;99%
With [IPr*·H][Pd(η3-cin)Cl2]; potassium tert-butylate at 60 - 80℃; for 2h; Buchwald-Hartwig Coupling; Sealed tube;99%
styrene
292638-84-7

styrene

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

E-1-(phenyl)-2-(4'-methoxyphenyl)ethene
1694-19-5

E-1-(phenyl)-2-(4'-methoxyphenyl)ethene

Conditions
ConditionsYield
With tetrakis[μ-1-[(3-methoxyphenyl)methyl]-2-phenyl-3-[2-oxo-2-[(2-phenolato-kO)aminokN]ethyl]-1H-imidazoliumato-kC4]tetrapalladium; tetrabutylammomium bromide; sodium acetate at 140℃; for 12h; Heck Reaction;99%
With tetrabutylammonium acetate; palladium diacetate; DavePhos In 1,4-dioxane at 80℃; for 24h; Heck reaction; Inert atmosphere; Sealed tube;95%
With C128H58Cl2O2P4Pd; potassium carbonate In methanol at 60℃; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Heck Reaction; Inert atmosphere; Schlenk technique;93%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

diphenylamine

diphenylamine

N,N-diphenyl-4-methoxyaniline

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 80℃; for 12h;99%
With bis(η3-allyl-μ-chloropalladium(II)); 2,6-bis(2,4,6-triisopropylphenyl)phenyl(dicyclohexylphosphine); sodium t-butanolate In dodecane; toluene at 100℃; for 6h; Catalytic behavior; Reagent/catalyst; Glovebox;99%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 70℃; for 16h;97%
piperidine

piperidine

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

N-(4-methoxylphenyl)piperidine
5097-25-6

N-(4-methoxylphenyl)piperidine

Conditions
ConditionsYield
With potassium tert-butylate; C50H75ClP2Pd In tetrahydrofuran at 20℃; for 6h; Schlenk technique; Inert atmosphere;99%
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In toluene at 70℃;95%
With sodium t-butanolate In toluene at 100 - 110℃; for 24h; Buchwald-Hartwig amination; Inert atmosphere; Sealed vial;94%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-methylphenylboronic acid

4-methylphenylboronic acid

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With potassium phosphate monohydrate; Ethyl 4-bromobenzoate; C52H49PRu; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere;99%
With potassium phosphate; C114H132Cl6N10Pd3 In water; isopropyl alcohol at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;99%
With C58H82Cl4N6Pd2; potassium tert-butylate In water; isopropyl alcohol at 80℃; for 4h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-fluorophenylmagnesium bromide
446-53-7

2-fluorophenylmagnesium bromide

4-methoxy-2'-fluorobiphenyl
72093-47-1

4-methoxy-2'-fluorobiphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran; 1,4-dioxane at 80℃; for 3h; Arylation;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran; 1,4-dioxane at 80℃; for 3h; Arylation;99%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;99%
With iron(II) triflate; 1,3-bis(2,4,6-trimethylphenyl)-4,5,6,7-tetrahydro-1H-1,3-diazepinium bromide; sodium t-butanolate In tetrahydrofuran at 60℃; for 16h; Kumada Cross-Coupling; Sealed tube; Inert atmosphere;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4'-methoxy-2-methylbiphenyl
92495-54-0

4'-methoxy-2-methylbiphenyl

Conditions
ConditionsYield
With potassium fluoride; monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) In toluene at 80℃; for 72h; Suzuki coupling;99%
With potassium phosphate tribasic trihydrate; PdCl2(C3H3N2(CH3))(C3H2N2(C6H3(C3H7)2)2) In tetrahydrofuran; water at 20℃; for 24h; Suzuki-Miyaura coupling reaction; Inert atmosphere;99%
With potassium phosphate; C114H132Cl6N10Pd3 In water; isopropyl alcohol at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

Conditions
ConditionsYield
Stage #1: 4-chloromethoxybenzene With nickel(II) acetylacetonate; bis(1-adamantyl)phosphine oxide In tetrahydrofuran at 20℃; for 0.0833333h;
Stage #2: phenylmagnesium chloride In tetrahydrofuran at 20℃; Kumada cross-coupling;
99%
With [{C4H2N-2,5-(CH2PPh2)2-κ3PNP}NiCl] In tetrahydrofuran; toluene at 23℃; for 12h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique;89%
With C61H78ClN4Ni2 In tetrahydrofuran at 20℃; for 18h; Reagent/catalyst; Kumada Cross-Coupling; Schlenk technique;85%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4,4'-Dimethoxybiphenyl
2132-80-1

4,4'-Dimethoxybiphenyl

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); bis(2,4-dimethoxyphenyl)phosphine oxide; cesium fluoride at 100℃; for 12h;99%
With potassium carbonate; palladium dichloride In various solvent(s) at 20℃; for 5h; Suzuki-Miyaura cross-coupling;98%
With potassium phosphate; 4-dicyclohexylphosphino-12-(2',6'-dimethoxy)phenyl-[2.2]paracyclophane; palladium diacetate In 1,4-dioxane at 80℃; for 12h; Suzuki-Miyaura coupling; Inert atmosphere;93%
Benzophenone imine
1013-88-3

Benzophenone imine

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

N-(4-methoxyphenyl)-1,1-diphenylmethanimine
42834-19-5

N-(4-methoxyphenyl)-1,1-diphenylmethanimine

Conditions
ConditionsYield
With potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0); 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In 1,4-dioxane at 100℃; for 6h;99%
With sodium t-butanolate In toluene at 100 - 110℃; for 48h; Buchwald-Hartwig amination; Inert atmosphere; Sealed vial;80%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

aniline
62-53-3

aniline

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

Conditions
ConditionsYield
With [Pd(2-aminobiphenyl)(PCyp2ArXyl2)](OMs); sodium t-butanolate In tetrahydrofuran at 80℃; for 19h; Reagent/catalyst; Inert atmosphere; Schlenk technique;99%
With sodium t-butanolate; XPhos palladium(II) phenethylamine chloride In 1,4-dioxane at 100℃; for 0.166667h;98%
With C40H42NP; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 1,4-dioxane; water at 20℃; for 0.5h; Inert atmosphere; Sealed tube; Reflux;98%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

1-[(1,1-dimethylethyl)thio]-4-methoxybenzene
7205-64-3

1-[(1,1-dimethylethyl)thio]-4-methoxybenzene

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate In 1,4-dioxane at 100℃; for 18h;99%
1-indoline
496-15-1

1-indoline

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

1-(4-methoxyphenyl)-1H-indole
172887-18-2

1-(4-methoxyphenyl)-1H-indole

Conditions
ConditionsYield
With [Pd(2-aminobiphenyl)(PCyp2ArXyl2)](OMs); sodium t-butanolate In tetrahydrofuran at 80℃; for 19h; Reagent/catalyst; Inert atmosphere; Schlenk technique;99%
With tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate; 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane In toluene for 24h; Inert atmosphere; Reflux;72%
In 1,4-dioxane for 5h;
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2,4'-dimethoxybiphenyl
49602-47-3

2,4'-dimethoxybiphenyl

Conditions
ConditionsYield
With potassium phosphate; C46H52Cl3N3O2Pd In tetrahydrofuran; water at 60℃; for 4h; Suzuki-Miyaura Coupling;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; water; palladium diacetate In tetrahydrofuran at 20℃; for 3h; Suzuki-Miyaura reaction;98%
With potassium phosphate; N,N'-bis-[2,4,6-tri(3,3,3-trifluoropropyl)phenyl]-4,5-dihydroimidazolium chloride; palladium diacetate In tetrahydrofuran; water at 20℃; for 12h; Suzuki-Miyaura cross-coupling; Inert atmosphere;95%
With [(N,N′-bis-(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)PdCl2(pyrazole)]; sodium hydroxide In ethanol at 20℃; for 6h; Reagent/catalyst; Suzuki-Miyaura Coupling; Sealed tube;85%
With potassium phosphate; C28H31ClN2Ni; triphenylphosphine In tert-Amyl alcohol; toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;81%

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