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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sal

4-Chlorobromobenzene

Cas:106-39-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Bromochlorobenzene supplier in China

Cas:106-39-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

4-bromochlorobenzene

Cas:106-39-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-bromo-4-chlorobenzene

Cas:106-39-8

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:1 Gram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

4-bromochlorobenzene

Cas:106-39-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product Description Name 4-Bromochlorobenzene CAS 106-39-8 Assay 99% Appearance

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

4-Chlorobromobenzene

Cas:106-39-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

High Purity CAS 106-39-8 with competitive price

Cas:106-39-8

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-bromochlorobenzene CAS106-39-8

Cas:106-39-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

4-bromochlorobenzene Identification Product name: 4-bromochlorobenzene Product name: 4-bromochlorob

4-bromochlorobenzene

Cas:106-39-8

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Bromochlorobenzene 106-39-8

Cas:106-39-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

4-Bromochlorobenzene with CAS: 106-39-8

Cas:106-39-8

Min.Order:1 Kilogram

FOB Price: $24.0 / 30.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Bromochlorobenzene CAS:106-39-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

4-Bromochlorobenzene CAS:106-39-8

Cas:106-39-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

4-Bromochlorobenzene/ LIDE PHARMA- Factory supply / Best price

Cas:106-39-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

4-Bromochlorobenzene CAS 106-39-8

Cas:106-39-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

4-Chlorobromobenzene CAS: 106-39-8 Specification mp 64-67 °c(lit.) bp 196 °c(lit.) density 1.651 refractive index 1,496-1,498 fp 196°c storage temp. 2-8°c

Factory supply 4-Chlorobromobenzene

Cas:106-39-8

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Bromochlorobenzene

Cas:106-39-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

4-BROMOCHLOROBENZENE

Cas:106-39-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

p-Bromochlorobenzene

Cas:106-39-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Chlorobromobenzene

Cas:106-39-8

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

106-39-8 factory best price 4-Bromochlorobenzene P-chlorobromobenzene is an important organic chemical raw material, which is mainly used as a solvent and also used in organic synthesis. The traditional method for synthesis of p-chlorobromobenzene h

106-39-8 factory best price 4-Bromochlorobenzene

Cas:106-39-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Bromochlorobenzene

Cas:106-39-8

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-bromochlorobenzene CAS NO.106-39-8

Cas:106-39-8

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-bromochlorobenzene

Cas:106-39-8

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Synthetic route

p-chlorobenzenediazonium tetrafluoroborate
673-41-6

p-chlorobenzenediazonium tetrafluoroborate

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With dibenzo-18-crown-6; potassium bromide; copper(ll) bromide; 1,10-Phenanthroline; copper(I) bromide In acetonitrile at 20℃; for 0.333333h; Sandmeyer bromination;99%
With N-Bromosuccinimide; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction;52%
chlorobenzene
108-90-7

chlorobenzene

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With sulfuric acid; tetramethylammonium bromide at 120℃; for 3h; Product distribution; Further Variations:; Reagents;98%
With sulfuric acid; potassium bromide at 60℃; for 2h;95%
With Oxone; sodium bromide In water at 20℃; for 3h; regioselective reaction;90%
p-Toluolsulfonylnitrit
66021-66-7

p-Toluolsulfonylnitrit

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

N,N'-bis(p-toluenesulfonyl)hydroxylamine
56410-24-3

N,N'-bis(p-toluenesulfonyl)hydroxylamine

Conditions
ConditionsYield
With 4-bromo-aniline; copper dichloride In acetonitrile at 25℃; for 1h;A 93%
B 83%
4-bromo-aniline
106-40-1

4-bromo-aniline

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

N,N'-bis(p-toluenesulfonyl)hydroxylamine
56410-24-3

N,N'-bis(p-toluenesulfonyl)hydroxylamine

Conditions
ConditionsYield
With p-toluenesulfonyl nitrite; copper dichloride In acetonitrile for 0.75h;A 93%
B n/a
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With sodium nitrite In acetonitrile at 80℃; for 1h; Sealed tube;93%
With N-Bromosuccinimide In acetonitrile at 81℃; for 8h;65%
4-bromo-benzenediazonium; tetrachloro cuprate(II)

4-bromo-benzenediazonium; tetrachloro cuprate(II)

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
In dimethyl sulfoxide Ambient temperature;92%
4-bromo-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate
1203709-75-4

4-bromo-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With copper(l) chloride In acetonitrile at 80℃; for 2h;89%
(4-chlorophenyl)(mesityl)iodonium trifluoromethanesulfonate
1204518-00-2

(4-chlorophenyl)(mesityl)iodonium trifluoromethanesulfonate

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With copper(I) bromide In acetonitrile at 80℃; for 2h;85%
4-bromo-aniline
106-40-1

4-bromo-aniline

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With N-chloro-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 6h;83%
With tert.-butylnitrite; N-benzyl-N,N,N-triethylammonium chloride; copper dichloride; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Time; Solvent;43%
1-(p-chlorophenyl)-3,3-dimethyl-1-triazene
7203-90-9

1-(p-chlorophenyl)-3,3-dimethyl-1-triazene

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With methanesulfonic acid; tetrabutyl-ammonium chloride; copper In acetonitrile at 40℃; for 0.25h;82%
potassium 4-bromophenyltrifluoroborate
374564-35-9

potassium 4-bromophenyltrifluoroborate

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With trichloroisocyanuric acid In water; ethyl acetate at 20℃; for 1h; Open flask;81%
4-chloro-aniline
106-47-8

4-chloro-aniline

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

N,N'-bis(p-toluenesulfonyl)hydroxylamine
56410-24-3

N,N'-bis(p-toluenesulfonyl)hydroxylamine

Conditions
ConditionsYield
With p-toluenesulfonyl nitrite; copper(ll) bromide In acetonitrile at 25℃; for 0.0166667h;A 79%
B n/a
4-bromo-phenol
106-41-2

4-bromo-phenol

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With phenylphosphorus tetrachloride at 160℃;78%
4-(chloro)benzenediazonium benzo[d][1,3,2]dithiazol-2-ide-1,1,3,3-tetraoxide

4-(chloro)benzenediazonium benzo[d][1,3,2]dithiazol-2-ide-1,1,3,3-tetraoxide

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;75%
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;73%
Multi-step reaction with 2 steps
1: 90 percent / aq. NaOH / 0.5 h / 0 - 5 °C
2: 82 percent / Bu4N(+)Cl(-); MeSO3H; Cu / acetonitrile / 0.25 h / 40 °C
View Scheme
4-Bromobenzenediazonium o-benzenedisulfonimide

4-Bromobenzenediazonium o-benzenedisulfonimide

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 20℃; Substitution;74%
4-chlorophenylhydrazine hydrochloride
1073-70-7

4-chlorophenylhydrazine hydrochloride

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With boron tribromide; dimethyl sulfoxide at 80℃; for 1h;72%
4-chlorophenyldiazonium salt
17333-85-6

4-chlorophenyldiazonium salt

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With tin(II); chloride; copper(II) nitrate In water for 0.5h; Ambient temperature;70%
With copper(I) bromide
4-chloro-aniline
106-47-8

4-chloro-aniline

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 6h;68%
With tert.-butylnitrite; tetrabutylammomium bromide; copper(I) bromide; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Reagent/catalyst; Time; Solvent;61%
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide In acetonitrile at 20℃; for 23h;58%
2-methylenesuccinic acid
97-65-4

2-methylenesuccinic acid

(4-bromophenyl)diazonium chloride
2028-85-5

(4-bromophenyl)diazonium chloride

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

C11H10BrClO4
1427331-03-0

C11H10BrClO4

Conditions
ConditionsYield
With copper(II) choride dihydrate In [(2)H6]acetone; water at 25℃; for 2.5h; Meerwein Arylation;A n/a
B 62%
chlorobenzene
108-90-7

chlorobenzene

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; iron(III) chloride In acetonitrile for 2h;A 57%
B 38%
With potassium bromate In sulfuric acid; acetic acid for 1h; Heating; Yields of byproduct given;A 52%
B n/a
With potassium bromate In sulfuric acid; acetic acid for 1h; Heating; Yield given;A 52%
B n/a
bromobenzene
108-86-1

bromobenzene

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With lead(IV) acetate; tin(IV) chloride In dichloromethane for 20h;56%
With thallium chloride at 100℃; durch Chlorierung;
With iron(III) chloride
1-(4-chlorophenyl)silatrane
29025-67-0

1-(4-chlorophenyl)silatrane

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane for 8h; Ambient temperature;52%
Trichloroethylene
79-01-6

Trichloroethylene

(4-bromophenyl)diazonium chloride
2028-85-5

(4-bromophenyl)diazonium chloride

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

1-Brom-4-<1,2,2,2-tetrachlor-ethyl>-benzol
4714-31-2

1-Brom-4-<1,2,2,2-tetrachlor-ethyl>-benzol

Conditions
ConditionsYield
With potassium chloride; copper dichloride In water; acetoneA n/a
B 52%
(4-bromophenyl)diazonium chloride
2028-85-5

(4-bromophenyl)diazonium chloride

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

1-Brom-4-<1,2,2,2-tetrachlor-ethyl>-benzol
4714-31-2

1-Brom-4-<1,2,2,2-tetrachlor-ethyl>-benzol

Conditions
ConditionsYield
With Trichloroethylene; potassium chloride; copper dichloride In water; acetoneA n/a
B 52%
C7H6ClN7
93680-29-6

C7H6ClN7

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; trifluoroacetic acid In acetonitrile at 70 - 80℃;40%
p-chlorobenzenediazonium tetrafluoroborate
673-41-6

p-chlorobenzenediazonium tetrafluoroborate

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

1-Chloro-4-fluorobenzene
352-33-0

1-Chloro-4-fluorobenzene

C

chlorobenzene
108-90-7

chlorobenzene

Conditions
ConditionsYield
With trimethylsilyl bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; copper(I) bromide at 70℃; Schiemann reaction;A 4%
B 61 % Chromat.
C 35%
2-nitro-aniline
88-74-4

2-nitro-aniline

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With tert-Butyl thionitrate; Bromoform for 0.5h; Heating;25%
chlorobenzene
108-90-7

chlorobenzene

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

Conditions
ConditionsYield
With bromine trifluoride; bromine at 0 - 10℃;A 25%
B 5%
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

bromochlorobenzene
106-39-8

bromochlorobenzene

Conditions
ConditionsYield
With bromine; mercury(II) oxide In nitrobenzene at 180 - 185℃; for 2h;22%
bromochlorobenzene
106-39-8

bromochlorobenzene

4,4'-dichlorobiphenyl
2050-68-2

4,4'-dichlorobiphenyl

Conditions
ConditionsYield
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium carbonate In 1-methyl-pyrrolidin-2-one at 130℃; for 3h; Microwave irradiation; chemoselective reaction;100%
Stage #1: bromochlorobenzene With tert.-butyl lithium In diethyl ether at -78℃;
Stage #2: In diethyl ether
Stage #3: With Duroquinone In diethyl ether
96%
With potassium carbonate In N,N-dimethyl-formamide for 0.666667h;96%
bromochlorobenzene
106-39-8

bromochlorobenzene

benzene
71-43-2

benzene

Conditions
ConditionsYield
With potassium hydroxide; hydrogen; palladium on activated charcoal; Aliquat 336 In water at 50℃; for 0.833333h;100%
With di-tert-butyl peroxide; caesium carbonate; isopropyl alcohol at 120℃; for 3h; Inert atmosphere;93 %Chromat.
With ammonium formate In methanol at 20℃; for 16h;
bromochlorobenzene
106-39-8

bromochlorobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

Conditions
ConditionsYield
With potassium carbonate In ethanol at 80℃; for 36h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With C28H38Cl2N2O6PdS2(2-)*2Na(1+); tetrabutylammomium bromide; potassium carbonate In water at 75℃; Suzuki coupling; Inert atmosphere;99%
With Br(1-)*C28H29BrN5O2Pd(1+); potassium carbonate In methanol; water at 100℃; for 3h; Suzuki-Miyaura coupling;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

diphenylamine
122-39-4

diphenylamine

(p-chlorophenyl)diphenylamine
4316-56-7

(p-chlorophenyl)diphenylamine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;100%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 80℃;90.7%
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In toluene at 100℃; for 24h; Buchwald-Hartwig Coupling; Sealed tube; Inert atmosphere;79%
bromochlorobenzene
106-39-8

bromochlorobenzene

tert-butyl 1,4-diazepine-1-carboxylate
112275-50-0

tert-butyl 1,4-diazepine-1-carboxylate

tert-butyl 4-(4-chlorophenyl)-1,4-diazepane-1-carboxylate
868063-67-6

tert-butyl 4-(4-chlorophenyl)-1,4-diazepane-1-carboxylate

Conditions
ConditionsYield
With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 23h; Heating / reflux;100%
With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 23h; Heating / reflux;100%
bromochlorobenzene
106-39-8

bromochlorobenzene

potassium 3-aminothiophene-2-carboxylate
1210469-45-6

potassium 3-aminothiophene-2-carboxylate

3-amino-2-(4-chlorophenyl)thiophene
183676-87-1

3-amino-2-(4-chlorophenyl)thiophene

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tetrabutylammomium bromide; palladium dichloride In 1-methyl-pyrrolidin-2-one at 100℃; Inert atmosphere;100%
With 1,1'-bis-(diphenylphosphino)ferrocene; tetrabutylammomium bromide; palladium dichloride In 1-methyl-pyrrolidin-2-one; N,N-dimethyl-formamide at 80℃; for 16h; Inert atmosphere;77%
4-tributylstannanyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester
208465-07-0

4-tributylstannanyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

bromochlorobenzene
106-39-8

bromochlorobenzene

4-(4-Chloro-phenyl)-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester
138647-50-4

4-(4-Chloro-phenyl)-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In toluene at 120℃; for 17h;100%
bromochlorobenzene
106-39-8

bromochlorobenzene

tert-butyl (3aR,6aS)-5-methylene-1,3,3a,4,6,6a-hexahydrocyclopenta[c]pyrrole-2-carboxylate
139228-12-9

tert-butyl (3aR,6aS)-5-methylene-1,3,3a,4,6,6a-hexahydrocyclopenta[c]pyrrole-2-carboxylate

(3aR,6aS)-tert-butyl 5-(4-chlorobenzyl)hexahydrocyclopenta[c]pyrrole-2(1H)-carboxylate

(3aR,6aS)-tert-butyl 5-(4-chlorobenzyl)hexahydrocyclopenta[c]pyrrole-2(1H)-carboxylate

Conditions
ConditionsYield
Stage #1: tert-butyl (3aR,6aS)-5-methylene-1,3,3a,4,6,6a-hexahydrocyclopenta[c]pyrrole-2-carboxylate With 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 65℃; for 1h;
Stage #2: bromochlorobenzene With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In tetrahydrofuran; 1,4-dioxane; water at 65℃; for 48h;
100%
bromochlorobenzene
106-39-8

bromochlorobenzene

A

4,4'-dichlorobiphenyl
2050-68-2

4,4'-dichlorobiphenyl

B

chlorobenzene
108-90-7

chlorobenzene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 57h; Inert atmosphere;A 0.8%
B 99.2%
In 1,2-dimethoxyethane at 85℃; Product distribution; var. solvents; var. times; Ni from NiI2 or NiBr2;
With nickel In 1,2-dimethoxyethane at 85℃; for 20h;A 61 % Chromat.
B 32 % Chromat.
bromochlorobenzene
106-39-8

bromochlorobenzene

allyl bromide
106-95-6

allyl bromide

1-allyl-4-chlorobenzene
1745-18-2

1-allyl-4-chlorobenzene

Conditions
ConditionsYield
Stage #1: bromochlorobenzene With iodine; magnesium In diethyl ether Inert atmosphere; Reflux;
Stage #2: allyl bromide In diethyl ether at 0 - 20℃; for 2.08333h; Inert atmosphere;
99%
(i) Mg, Et2O, (ii) /BRN= 605308/; Multistep reaction;
Stage #1: bromochlorobenzene With iodine; magnesium In diethyl ether for 2h; Reflux; Inert atmosphere;
Stage #2: allyl bromide In diethyl ether at 20℃; Cooling with ice; Inert atmosphere;
bromochlorobenzene
106-39-8

bromochlorobenzene

triethyl phosphite
122-52-1

triethyl phosphite

diethyl (4-chlorophenyl)phosphonate
2373-43-5

diethyl (4-chlorophenyl)phosphonate

Conditions
ConditionsYield
With tri-n-propylamine; tetrabutylammomium bromide; palladium dichloride In water at 100℃; for 4h; Green chemistry; chemoselective reaction;99%
With triethylamine In water at 100℃; for 5h; Green chemistry;92%
With triethylamine In water at 100℃; for 5h; Arbuzov Reaction; Green chemistry;91%
bromochlorobenzene
106-39-8

bromochlorobenzene

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

butyl p-chlorocinnamate
123248-22-6, 42175-12-2

butyl p-chlorocinnamate

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; tetrabutylammomium bromide; triethylamine In N,N-dimethyl-formamide at 140℃; for 20h; Reagent/catalyst; Heck Reaction; Sealed tube; Inert atmosphere; Schlenk technique;99%
With potassium carbonate at 120℃; for 2.25h; Catalytic behavior; Heck Reaction;98%
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 3h; Catalytic behavior; Heck Reaction;97%
bromochlorobenzene
106-39-8

bromochlorobenzene

2-(6-bromo-pyridin-2-yl)-4-methylpyrimidine
122918-19-8

2-(6-bromo-pyridin-2-yl)-4-methylpyrimidine

2-[6-(4-chloro-phenyl)-pyridin-2-yl]-4-methyl-pyrimidine

2-[6-(4-chloro-phenyl)-pyridin-2-yl]-4-methyl-pyrimidine

Conditions
ConditionsYield
Stage #1: bromochlorobenzene With n-butyllithium In tetrahydrofuran Dehalogenation;
Stage #2: With zinc(II) chloride In diethyl ether at 20℃; Metallation;
Stage #3: 2-(6-bromo-pyridin-2-yl)-4-methylpyrimidine; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; diethyl ether for 2h; Substitution; Heating;
99%
styrene
292638-84-7

styrene

bromochlorobenzene
106-39-8

bromochlorobenzene

A

(E)-1-(4-chlorophenyl)-2-phenylethene
1657-50-7

(E)-1-(4-chlorophenyl)-2-phenylethene

B

1-(4-chlorophenyl)-1-phenylethene
18218-20-7

1-(4-chlorophenyl)-1-phenylethene

Conditions
ConditionsYield
With sodium carbonate; Pd-montmorillonite In 1-methyl-pyrrolidin-2-one at 150℃; for 2h; Heck reaction;A 99%
B n/a
With 1-methyl-pyrrolidin-2-one; sodium acetate; palladium diacetate at 135℃; for 15h; Heck reaction;
With sodium acetate; PdCl2[2-[(1-MeS-S)-3-[(Ph2P-P)oxy]propyl]-N,N-Me2-aniline] In N,N-dimethyl-formamide at 130℃; for 24h; Heck reaction; Title compound not separated from byproducts;
With tetrabutyl-ammonium chloride; sodium carbonate; Pd-MCM-41 In 1-methyl-pyrrolidin-2-one at 150℃; for 6h; Heck coupling; Title compound not separated from byproducts;
bromochlorobenzene
106-39-8

bromochlorobenzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

Conditions
ConditionsYield
With potassium carbonate In water at 50℃; for 0.333333h; Suzuki Coupling;99%
With sodium carbonate at 80℃; for 0.333333h; Green chemistry;98%
With potassium carbonate at 100℃; for 1h; Catalytic behavior;97%
1H-imidazole
288-32-4

1H-imidazole

bromochlorobenzene
106-39-8

bromochlorobenzene

1-(4-chlorophenyl)imidazole
51581-54-5

1-(4-chlorophenyl)imidazole

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; heptakis(6-amino-6-deoxy)-β-cyclodextrin In dimethyl sulfoxide at 110℃; for 24h; Sealed tube;99%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 8h; chemoselective reaction;98%
With copper(I) oxide; potassium phosphate; N1,N2-bis(furan-2-ylmethyl)oxalamide In dimethyl sulfoxide at 120℃; for 24h;97%
bromochlorobenzene
106-39-8

bromochlorobenzene

ortho-nitrobenzoic acid
552-16-9

ortho-nitrobenzoic acid

4'-chloro-2-nitrobiphenyl
6271-80-3

4'-chloro-2-nitrobiphenyl

Conditions
ConditionsYield
Stage #1: ortho-nitrobenzoic acid With potassium carbonate In various solvent(s) at 120℃; for 0.5h;
Stage #2: bromochlorobenzene With 1,10-Phenanthroline; copper(l) iodide In various solvent(s) at 160℃; for 24h; Further stages.;
99%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; N,N-dimethyl-aniline; silver carbonate; palladium dichloride at 150℃; for 2h;35%
Stage #1: ortho-nitrobenzoic acid; copper(II) carbonate In 1-methyl-pyrrolidin-2-one
Stage #2: bromochlorobenzene; bis(acetylacetonato)palladium(II); triphenylphosphine In 1-methyl-pyrrolidin-2-one at 120℃; for 24h; Product distribution / selectivity;
9 %Chromat.
bromochlorobenzene
106-39-8

bromochlorobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-chloro-4'-methylbiphenyl
19482-11-2

4-chloro-4'-methylbiphenyl

Conditions
ConditionsYield
With 2C60H80NaO12*Cl6Pd2; potassium carbonate In methanol; water at 20℃; for 0.166667h; Suzuki coupling;99%
With sodium hydroxide In ethanol; water at 25℃; for 4.5h; Suzuki Coupling;98%
With sodium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 10h; Suzuki-Miyaura Coupling; Inert atmosphere;98%
bromochlorobenzene
106-39-8

bromochlorobenzene

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

methyl 3-(4-chlorophenyl)propenoate
20754-21-6

methyl 3-(4-chlorophenyl)propenoate

B

methyl 2-(4-chlorophenyl)acrylate
50415-59-3

methyl 2-(4-chlorophenyl)acrylate

Conditions
ConditionsYield
With sodium carbonate; Pd-montmorillonite In 1-methyl-pyrrolidin-2-one at 150℃; for 2h; Heck reaction;A 99%
B n/a
bromochlorobenzene
106-39-8

bromochlorobenzene

potassium 4-tolyltriolborate

potassium 4-tolyltriolborate

4-chloro-4'-methylbiphenyl
19482-11-2

4-chloro-4'-methylbiphenyl

Conditions
ConditionsYield
palladium diacetate In water; N,N-dimethyl-formamide at 20℃; for 5h;99%
With C24H25Cl3FeN3PPd*C3H6O In ethanol; water at 80℃; for 3h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; Sealed tube;89%
bromochlorobenzene
106-39-8

bromochlorobenzene

phenol
108-95-2

phenol

4-chlorodiphenyl ether
7005-72-3

4-chlorodiphenyl ether

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 12h;99%
With potassium carbonate In N,N-dimethyl-formamide at 110℃;97%
With copper(l) iodide; iron(III)-acetylacetonate; potassium carbonate In N,N-dimethyl-formamide at 135℃; for 12h; Inert atmosphere;93%
bromochlorobenzene
106-39-8

bromochlorobenzene

C17H20N2O4S
1207202-14-9

C17H20N2O4S

1-[1-(4-chlorophenyl)-2-methoxyvinyl]-4-methoxybenzene
1207201-99-7

1-[1-(4-chlorophenyl)-2-methoxyvinyl]-4-methoxybenzene

Conditions
ConditionsYield
Stage #1: C17H20N2O4S With tris(dibenzylideneacetone)dipalladium (0); lithium tert-butoxide; XPhos In 1,4-dioxane for 0.0166667h; Inert atmosphere;
Stage #2: bromochlorobenzene In 1,4-dioxane at 90℃; for 14h; Inert atmosphere;
99%
bromochlorobenzene
106-39-8

bromochlorobenzene

thiophenol
108-98-5

thiophenol

1,4-bis(phenylthio)benzene
3459-94-7

1,4-bis(phenylthio)benzene

Conditions
ConditionsYield
With 1,2,3,4-tetrahydroquinolin-8-ol; caesium carbonate; copper(I) bromide In N,N-dimethyl-formamide at 130℃; for 48h; Inert atmosphere; chemoselective reaction;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

benzaldehyde
100-52-7

benzaldehyde

(S)-4-chlorobenzhydrol
101402-04-4

(S)-4-chlorobenzhydrol

Conditions
ConditionsYield
With triisopropoxytitanium(IV) chloride; phenyllithium In diethyl ether; cyclohexane at -78 - 20℃; for 0.25h; Inert atmosphere; enantioselective reaction;99%
Stage #1: bromochlorobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: With titanium(IV) isopropylate; magnesium bromide In tetrahydrofuran; diethyl ether; hexane for 0.5h; Inert atmosphere;
Stage #3: benzaldehyde With titanium(IV) isopropylate; (R)-3-(3,5-diphenylphenyl)-2,2'-dihydroxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl In diethyl ether; dichloromethane at 0℃; for 3h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
80%
Multi-step reaction with 2 steps
1.1: C36H31F2N2(1+)*BF4(1-); copper(l) chloride; sodium trimethylsilanolate / toluene / 0.42 h / 25 °C / Inert atmosphere; Sealed tube
1.2: 3 h / 60 °C / Inert atmosphere; Sealed tube
2.1: tetrabutyl ammonium fluoride / Inert atmosphere
View Scheme
benzoxazole
273-53-0

benzoxazole

bromochlorobenzene
106-39-8

bromochlorobenzene

2-(4-chlorophenyl)benzoxazole
1141-35-1

2-(4-chlorophenyl)benzoxazole

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; nixantphos In N,N-dimethyl-formamide at 24℃; for 12h; Heck Reaction; Inert atmosphere;99%
With [(N,N'-bis-(2,6-di(isopropyl)phenyl)imidazolidin-2-ylidene)Pd(allyl)]2(μ2-trans-4,4'-bipyridylethylene)(BF4)2; lithium tert-butoxide In 1,2-dimethoxyethane at 10℃; for 12h; Catalytic behavior; Reagent/catalyst; Sealed tube;94%
With palladium diacetate; copper(II) acetate monohydrate; potassium carbonate; triphenylphosphine In toluene for 3h; Reflux; under air;87%
With n-butyllithium; palladium diacetate; C45H35P2(1+)*CF3O3S(1-); caesium carbonate In dimethyl sulfoxide at 50℃; for 14h; Inert atmosphere;85%
bromochlorobenzene
106-39-8

bromochlorobenzene

ethanolamine
141-43-5

ethanolamine

2-(4-chlorophenylamino)ethanol
2933-81-5

2-(4-chlorophenylamino)ethanol

Conditions
ConditionsYield
With copper(l) chloride; potassium hydroxide at 90℃; for 8h; Neat (no solvent);99%
bromochlorobenzene
106-39-8

bromochlorobenzene

benzaldehyde
100-52-7

benzaldehyde

4-chlorobenzophenone
134-85-0

4-chlorobenzophenone

Conditions
ConditionsYield
With palladium diacetate; N-picolinoylcyclohexylamine; potassium hydrogencarbonate In tert-Amyl alcohol at 150℃; for 24h;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

3-(methylsulphinyl)thiophene
133361-97-4

3-(methylsulphinyl)thiophene

2,5-bis(4-chlorophenyl)-3-(methylsulfinyl)thiophene

2,5-bis(4-chlorophenyl)-3-(methylsulfinyl)thiophene

Conditions
ConditionsYield
With di(1-adamantyl)-n-butylphosphine; cesium acetate; bis(dibenzylideneacetone)-palladium(0) at 100℃; for 12h; Inert atmosphere; regioselective reaction;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

4,5-dimethyl-9-phenyl-9H-fluoren-9-ol

4,5-dimethyl-9-phenyl-9H-fluoren-9-ol

C27H21ClO

C27H21ClO

Conditions
ConditionsYield
With chloro(2’-amino-1,1’-biphenyl-2-yl)palladium(II) dimer; C60H54NO5P; sodium hydride In toluene at 80℃; for 12h; Inert atmosphere; enantioselective reaction;99%

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