Product description: Product name Allyl bromide CAS number 106-95-6 Assay ≥99% Appearance Colorless transparent liquid Capacity 1000mt/year Application Dye, spice, pesticide
Cas:106-95-6
Min.Order:1 Kilogram
FOB Price: $12.0
Type:Lab/Research institutions
inquiryAllyl bromide CAS: 106-95-6 Specification Product name Allyl bromide CAS number 106-95-6 Assay ≥99% Appearance Colorless transparent liquid Capacity 1000mt/year Applicat
low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China
Cas:106-95-6
Min.Order:0
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inquiry1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:106-95-6
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryProductName:Allylbromide Synonyms:1-Bromo-2-propene;1-Propene,3-bromo-;3-bromo-1-propen;3-bromo-prop-1-ene;3-bromo-propen;3-Brompropen;Allylbro… Appearance:clear liquid Storage:store at RT Package:250kg drums Application:organic synthesis i
Conditions | Yield |
---|---|
With CO In decane (CO); heating (6 h, 140°C), cooling; chromy. (silica gel, ether); | A 97% B n/a |
With CO In decane (CO); heating (2 h, 140°C), cooling; chromy. (silica gel, ether); | A 48% B n/a |
Conditions | Yield |
---|---|
With CO In decane (CO); heating (2 h, 140°C), cooling; chromy. (silica gel, ether); | A 96% B n/a |
With CO In decane (CO); heating (2 h, 120°C), cooling; chromy. (silica gel, ether); | A 45% B n/a |
With carbon monoxide In diethylene glycol heating in diglime under CO atm.;; | A 70-80 B 50-70 |
Conditions | Yield |
---|---|
(N2); heating (16 h, 140°C), cooling; concn., chromy. (silica gel, MeOH); elem. anal.; | A 94% B n/a |
Conditions | Yield |
---|---|
With para-bromotoluene; oxalic acid at 65℃; for 1.33333h; Temperature; Reflux; | 93% |
Conditions | Yield |
---|---|
With piperazine; hydrogen In ethanol at 80℃; under 4500.45 Torr; for 24h; | 92% |
With piperazine; hydrogen In ethanol at 100℃; under 4500.45 Torr; for 24h; Green chemistry; | |
With hydrogen In ethanol at 100℃; under 4500.45 Torr; for 24h; chemoselective reaction; | 89 %Chromat. |
With hydrogen In ethanol at 30℃; under 3750.38 Torr; for 2h; chemoselective reaction; |
Conditions | Yield |
---|---|
With silica bromide In dichloromethane at 20℃; for 0.0833333h; | 91% |
With Silphos; bromine In acetonitrile for 0.166667h; Heating; | 84% |
With tetradecafluorohexane; phosphorus tribromide In diethyl ether at 20℃; for 12h; | 75% |
Conditions | Yield |
---|---|
With hexaethylphosphoric triamide In benzene for 24h; Ambient temperature; Yields of byproduct given; | A 89.9% B n/a |
6,7-dihydropyrido[3,2,1-ij]quinazoline-1,3 (2H,5H)-dione
A
2-allyl-6,7-dihydro-5H-pyrido[3,2,1-ij]quinazoline-1,3-dione
B
allyl bromide
Conditions | Yield |
---|---|
A n/a B 89% |
C17H19BrO2Te
A
dibromo-bis-(4-methoxy-phenyl)-λ4-tellane
B
allyl bromide
Conditions | Yield |
---|---|
With bromine at 0℃; for 4h; | A 80% B n/a |
3-chloroprop-1-ene
A
1,2-Dibromopropane
B
1-bromo-2-chloropropane
C
2-bromo-1-chloropropane
D
allyl bromide
Conditions | Yield |
---|---|
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.5h; | A 79% B 16% C 2% D 2% |
3-thiophene carboxaldehyde
benzyl bromide
4-methoxy-benzaldehyde
A
allyl bromide
B
3-((Z)-2-Benzylsulfanyl-vinyl)-5-(4-methoxy-phenyl)-2,5-dihydro-furan-2-ol
Conditions | Yield |
---|---|
With samarium; 1,2-Diiodoethane In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 27h; Ambient temperature; | A 22% B 63% |
bromocyane
allyldiphenyltelluronium bromide
A
C13H10BrNTe
B
allyl bromide
Conditions | Yield |
---|---|
at 25℃; for 8h; | A 62% B n/a |
allyloxytrimethylsilane
allyl bromide
Conditions | Yield |
---|---|
With Tri-n-butylfluorphosphoniumbromid In dichloromethane at 20℃; for 24h; | 61% |
trans-{Me2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)}
benzyl bromide
A
1,1'-(1,2-ethanediyl)bisbenzene
B
allyl bromide
C
toluene
Conditions | Yield |
---|---|
In [D3]acetonitrile Kinetics; Irradiation (UV/VIS); Degasses condition, 298 K, 33 h;; detected by NMR-spectroscopy;; | A 22% B n/a C 55% |
{EtCobis(dimethylglyoximato)(pyridine)}
benzyl bromide
A
allyl bromide
B
toluene
Conditions | Yield |
---|---|
In [D3]acetonitrile Kinetics; Irradiation (UV/VIS); Degasses condition, 298 K, 14 h;; detected by NMR-spectroscopy;; | A n/a B 33% |
Conditions | Yield |
---|---|
With sodium hydroxide; cetylpyridinium bromide at 130℃; for 2h; | 20% |
With silver(l) oxide | |
With Hexamethylphosphorous triamide |
{MeCobis(dimethylglyoximato)(pyridine)}
benzyl bromide
A
allyl bromide
B
toluene
Conditions | Yield |
---|---|
In [D3]acetonitrile Kinetics; Irradiation (UV/VIS); Degasses condition, 298 K, 71 h;; detected by NMR-spectroscopy;; | A n/a B 6.4% |
propene
allyl bromide
Conditions | Yield |
---|---|
With bromine at 300 - 315℃; | |
With N-Bromosuccinimide; toluene-4-sulfonic acid In tetrahydrofuran at 100℃; for 4h; Inert atmosphere; Schlenk technique; | |
With bromine at 525℃; |
bromocyane
N-allyl-N-benzylaniline
A
N-benzyl-N-phenylcyanamide
B
allyl bromide
Conditions | Yield |
---|---|
With hydrogen bromide; zinc Darst.; |
Conditions | Yield |
---|---|
With triphenyl phosphite at 140℃; |
1,4-dibromo-butane
methane
vinyl cation
A
propene
B
1,2-propanediene
C
propyl bromide
D
allyl bromide
Conditions | Yield |
---|---|
at 100℃; under 60 - 720 Torr; Product distribution; Kinetics; Thermodynamic data; labelled with tritium; -ΔH; |
1,4-dibromo-butane
1,2-propanediene
A
2-bromoprop-1-ene
B
allyl bromide
Conditions | Yield |
---|---|
With water; hydrogen; oxygen at 37℃; under 150 Torr; Product distribution; Irradiation; variation of system composition and initial pressure; |
Conditions | Yield |
---|---|
Mechanism; Irradiation; |
allyl radical
allyl bromide
Conditions | Yield |
---|---|
With bromine under 1 Torr; Rate constant; concentration dependence; reaction of allyl radicals with NO2; | |
With bromine at 24.9 - 258.9℃; Kinetics; Irradiation; carrier gas, He, the role of resonance stabilization; |
Conditions | Yield |
---|---|
With pyridine; tributyltin bromide at 50℃; Thermodynamic data; Equilibrium constant; Δ G; | 20 % Chromat. |
With bismuth(III) bromide In 1,2-dichloro-ethane for 1.75h; Heating; Yield given; |
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 24h; Heating; | 100% |
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water at 25℃; for 4h; | 84% |
With potassium carbonate In ethanol at 70℃; for 10h; regioselective reaction; | 84% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 5h; Heating; | 100% |
Stage #1: 7-hydroxy-2H-chromen-2-one With potassium carbonate In acetone at 20℃; for 0.0833333h; Stage #2: allyl bromide In acetone for 3h; Reflux; | 100% |
With potassium carbonate In acetone at 70℃; for 12h; | 98.6% |
7-hydroxy-4-methyl-chromen-2-one
allyl bromide
7-allyloxy-4-methyl-2H-chromen-2-one
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 60℃; for 1h; regioselective reaction; | 100% |
With potassium carbonate In acetone for 16h; Reflux; | 90% |
With potassium carbonate In acetone for 12h; Reflux; | 90% |
Conditions | Yield |
---|---|
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In various solvent(s) for 2.5h; Ambient temperature; | 100% |
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane for 3h; Product distribution; Ambient temperature; other solvent; | 90% |
87% | |
With sodium hydroxide; tetrabutylammomium bromide In toluene | 62% |
With copper; sodium carbonate; benzene |
Conditions | Yield |
---|---|
With ammonium acetate; zinc In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere; | 100% |
zinc In N,N-dimethyl-formamide for 2h; Product distribution; Ambient temperature; other solvents : N,N-dimethylacetoamide, N-methyl-2-pyrrolidone, 2-pyrrolidone, 2-methyloxazoline; | 99% |
With zinc In N,N-dimethyl-formamide for 2h; Ambient temperature; other solvents : N,N-dimethylacetoamide, N-methyl-2-pyrrolidone, 2-pyrrolidone, 2-methyloxazoline; | 99% |
Conditions | Yield |
---|---|
With caesium carbonate In water; N,N-dimethyl-formamide at 20℃; for 12h; | 100% |
With potassium carbonate In acetone at 20℃; for 24h; | 99% |
With potassium carbonate In acetone at 20℃; for 20h; Reflux; | 98% |
Conditions | Yield |
---|---|
With zinc In tetrahydrofuran at 20℃; for 1h; Alkylation; Barbier allylation; | 100% |
With potassium fluoride; antimony In water for 16h; allylation; | 100% |
With hydrogenchloride; antimony In water for 16h; Product distribution; Further Variations:; Reagents; times; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 65℃; | 100% |
With tetra-(n-butyl)ammonium iodide; potassium carbonate In N,N-dimethyl-formamide at 20℃; for 6h; | 100% |
With tetra-(n-butyl)ammonium iodide; potassium carbonate In N,N-dimethyl-formamide at 20℃; for 6h; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 9h; Reflux; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 1h; | 100% |
3-methoxy-2-hydroxybenzaldehyde
allyl bromide
2-allyloxy-3-methoxy-benzaldehyde
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 50℃; Williamson Ether Synthesis; | 100% |
With sodium hydroxide; benzyltri(n-butyl)ammonium chloride In dichloromethane Ambient temperature; | 98% |
With potassium carbonate In acetonitrile for 4h; Inert atmosphere; Reflux; | 98% |
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 20℃; | 100% |
With silica gel In water at 20℃; for 1h; | 95% |
With potassium fluoride on Celite In acetonitrile at 83℃; for 2h; | 95% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 18h; Heating; | 100% |
With potassium carbonate; sodium iodide In ethanol for 3h; Reflux; | 100% |
With potassium carbonate In ethanol for 3h; Reflux; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In butanone for 12h; Heating; | 100% |
With potassium carbonate In acetone at 20℃; Reflux; | 100% |
With potassium carbonate In acetone Reflux; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; Reflux; | 100% |
With potassium carbonate; potassium iodide In acetone for 18h; Reflux; | 100% |
With potassium carbonate | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 65℃; for 20h; | 100% |
With potassium carbonate In dimethyl sulfoxide at 20℃; for 8h; | 99% |
With potassium carbonate In acetone Heating; | 89% |
Conditions | Yield |
---|---|
In ethanol at 95℃; for 48h; | 100% |
for 2h; Reflux; | 92% |
Conditions | Yield |
---|---|
With ammonium acetate; zinc In tetrahydrofuran at 0℃; for 0.0166667h; Barbier reaction; | 100% |
With manganese; chloro-trimethyl-silane; indium In tetrahydrofuran at 20℃; for 4h; Alkylation; | 98% |
With manganese; chloro-trimethyl-silane; indium In tetrahydrofuran at 20℃; for 4h; Barbier allylation; | 98% |
Conditions | Yield |
---|---|
With ammonium chloride; zinc In tetrahydrofuran for 1h; Ambient temperature; | 100% |
With silica gel; ammonium chloride; zinc for 16h; Product distribution; Mechanism; Ambient temperature; other carbonyl compounds; other allyl halides; var. solid or liquid phases; var. reaction time; | 98% |
With chloro-trimethyl-silane; Piperonyl butoxide; tetrabutylammomium bromide In N,N-dimethyl-formamide for 2h; Ambient temperature; | 98% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h; Alkylation; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 60℃; | 99% |
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 0.833333h; | 99% |
Conditions | Yield |
---|---|
With 2,6-di-tert-butyl-4-methyl-phenol at 115℃; for 16h; | 100% |
for 16h; Heating; | 95% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; Reflux; | 100% |
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetone for 1h; Reflux; Inert atmosphere; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 24h; | 99% |
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 2h; Inert atmosphere; | 99% |
2-Methoxy-4-methylphenol
allyl bromide
1-(allyloxy)-2-methoxy-4-methylbenzene
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 12h; Heating; | 100% |
With potassium carbonate; sodium iodide In acetone for 15h; Reflux; Inert atmosphere; | 96% |
With potassium carbonate In acetone for 6h; Heating; | 95% |
5,6,7,8-Tetrahydronaphthalen-1-ol
allyl bromide
5-(allyloxy)-1,2,3,4-tetrahydronaphthalene
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide at 25℃; for 2h; Inert atmosphere; | 100% |
With methanol; sodium methylate | |
With sodium; toluene at 70 - 80℃; | |
With potassium carbonate; acetone |
2-methoxy-4-nitrophenol
allyl bromide
1-(allyloxy)-2-methoxy-4-nitrobenzene
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 55℃; for 12h; | 100% |
With potassium carbonate; acetone | |
at 70℃; for 6h; |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; sodium hydroxide In 2-methyltetrahydrofuran; water for 0.5h; Reflux; | 100% |
With potassium carbonate In acetone for 1h; Reflux; | 98% |
Stage #1: allyl bromide With sodium hydride In N,N-dimethyl-formamide; oil at -10℃; for 0.166667h; Stage #2: p-Iodophenol In N,N-dimethyl-formamide; oil for 0.75h; | 96% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 6h; Heating / reflux; | 100% |
With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h; | 99% |
With potassium carbonate In N,N-dimethyl-formamide at 60℃; Schlenk technique; | 99% |
Conditions | Yield |
---|---|
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane for 1.5h; Ambient temperature; | 100% |
With sodium hydroxide In water for 2h; | 70% |
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dichloromethane; water for 1h; Schlenk technique; Inert atmosphere; | 63% |
With lithium methanolate |
2-bromo-6-methylphenol
allyl bromide
2-(allyloxy)-1-bromo-3-methylbenzene
Conditions | Yield |
---|---|
Stage #1: 2-bromo-6-methylphenol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.0833333h; Stage #2: allyl bromide In N,N-dimethyl-formamide; mineral oil at 20℃; | 100% |
With potassium carbonate; acetone | |
Stage #1: 2-bromo-6-methylphenol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Stage #2: allyl bromide In N,N-dimethyl-formamide; mineral oil at 0 - 25℃; Stage #3: With water In N,N-dimethyl-formamide; mineral oil |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; Reflux; | 100% |
With potassium carbonate In acetone for 8h; Heating; | 95% |
With potassium carbonate In ethanol for 3h; Reflux; Inert atmosphere; | 93% |
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