Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures
Cas:108-94-1
Min.Order:1 Metric Ton
FOB Price: $500.0 / 1000.0
Type:Lab/Research institutions
inquiryProduct Description Product name Cyclohexanone CAS 108-94-1 Assay 99.5% Appearance Colorless transparent liquid Capacity 20000mt/year Min.package 100gram Standard
Cas:108-94-1
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
Cas:108-94-1
Min.Order:1 Metric Ton
FOB Price: $1.0 / 3.0
Type:Manufacturers
inquiryCyclohexanone Product Name: Cyclohexanone Synonyms: Anon; caswellno270; Cicloesanone; Cykloheksanon; cykloheksanon(polish); epapesticidechemicalcode025902; Hexanon; Hytrol O; hexan-2-one; CYC
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:108-94-1
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryColorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on
Cas:108-94-1
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Manufacturers
inquiryItem Testing specifications Appearance Transparent liquid,no visible impurities Purity,%(m/m
With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu
Cas:108-94-1
Min.Order:1 Kilogram
FOB Price: $1.0 / 10.0
Type:Trading Company
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:108-94-1
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:108-94-1
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryProduct Name: Cyclohexanone Synonyms: Anon;caswellno270;Cicloesanone;Cykloheksanon;cykloheksanon(polish); epapesticidechemicalc
Cyclohexanone CAS:108-94-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate
Cas:108-94-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:108-94-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryCyclohexanone CAS:108-94-1 Specification Item Testing specifications Appearance Transparent liquid,no visible impurities Purity,%(m/m) ≥ 99.5% Acidity(as acetic acid)%(m/m) ND Density (2
Product Detail Minimum Order Qty. 10 Gram
Cas:108-94-1
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiryHebei Mojin Biological Technology Co., Ltd. is specialize in the production of chemical raw materials and reagents,located in Shijiazhuang, Hebei Province. In recent decades, under the efforts of all staff, in Shandong, Henan, Guangdong and many o
Cas:108-94-1
Min.Order:1 Kilogram
FOB Price: $20.0 / 40.0
Type:Trading Company
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:108-94-1
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryEstablished in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site
Product name: Cyclohexanone CAS No.:108-94-1 Molecule Formula:C6H10O Molecule Weight:98.15 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTIN
Cas:108-94-1
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)
Cas:108-94-1
Min.Order:1 Kilogram
FOB Price: $5.0
Type:Lab/Research institutions
inquiryGMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
108-94-1 Appearance:95%+ Package:R&D,Pilot run Application:108-94-1 Transportation:per client require Port:Express ,Air, Sea
Cas:108-94-1
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:108-94-1
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:108-94-1
Min.Order:1 Metric Ton
FOB Price: $7.0 / 8.0
Type:Trading Company
inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) iodide; diisobutylaluminium hydride In tetrahydrofuran; diethyl ether; hexane at -50℃; for 0.5h; | 100% |
With hydrogen; mer-Os(PPh3)3HBr(CO) In toluene at 100℃; under 760 Torr; for 24h; | 100% |
With diphenylsilane; zinc(II) chloride; tetrakis(triphenylphosphine) palladium(0) In chloroform for 1h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With Fe2(4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate); 1-(tert-butylsulfonyl)-2-iodosylbenzene In [D3]acetonitrile at 20℃; for 1.5h; | A 100% B 100% |
With 3-chloro-benzenecarboperoxoic acid; [Ni2(L2H2)(OAc)2] at 20℃; for 1h; | A 7% B 93% |
With 3-chloro-benzenecarboperoxoic acid; (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride In dichloromethane; acetonitrile for 1h; Product distribution; Ambient temperature; other catalysts; kinetic isotope effect; | A 2% B 89% |
Conditions | Yield |
---|---|
With sodium bromite In acetic acid for 5h; Ambient temperature; | 100% |
With potassium permanganate; Sucrose-ethyleneoxide adducts In toluene at 20℃; for 24h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis;; | 100% |
With 4 A molecular sieve; tetrabutylammonium periodite; sodium ruthenate(VI) In dichloromethane at 20℃; for 24h; Oxidation; | 100% |
Conditions | Yield |
---|---|
With Geotrichum candidum CCT 1205 whole cells In aq. phosphate buffer at 28℃; for 24h; pH=6.5; Enzymatic reaction; | A 100% B n/a |
With hydrogen; In methanol at 30℃; under 735.5 Torr; for 5h; | A 0.8% B 98.2% |
With C8H13O2S2(3-)*Na(1+)*Rh(1+)*H(1+); hydrogen In water; toluene at 60℃; under 15001.5 Torr; for 4h; Inert atmosphere; Schlenk technique; Autoclave; | A 90% B 9% |
Conditions | Yield |
---|---|
With copper(II) sulfate In tetrahydrofuran; methanol; water for 3h; Heating; | 100% |
With bis(1-CH2Ph-3,5,7-3N-1-N(1+)tricyclo[3.3.1.13,7]decaneS2O8 In acetonitrile for 0.333333h; Oxidation; Heating; | 100% |
With Co1.4Cu1.6[Co(CN)6]2; oxygen In ethanol; water at 100℃; under 3750.38 Torr; for 3h; Reagent/catalyst; Time; Solvent; | 100% |
Conditions | Yield |
---|---|
With copper(II) sulfate In tetrahydrofuran; methanol; water for 2h; Heating; | 100% |
2-methyl-1,5-dioxaspiro<5.5>undecane
cyclohexanone
Conditions | Yield |
---|---|
With 4-phenyl-2,2,5,5-tetramethyl-3-imidazolin-1-yloxy-3-oxide; 15-crown-5; KCrO5Cl In acetonitrile at 60℃; for 7h; Product distribution; Further Variations:; Reagents; | 100% |
diethyl ether
A
(1S,3aR,5S,5'S,6R,6a'R)-2,2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0.]heptane-6,6'-furo[2,3-d][1,3]dioxole]
B
cyclohexanone
Conditions | Yield |
---|---|
With copper(II) bis(trifluoromethanesulfonate); benzene Inert atmosphere; Irradiation; | A 65% B 100% |
cyclohexenone
A
hexahydro-2H-oxepin-2-one
B
cyclohexanone
C
cyclohexanol
Conditions | Yield |
---|---|
With Geotrichum candidum CCT 1205 whole cells In aq. phosphate buffer at 28℃; for 24h; pH=6.5; Baeyer-Villiger Ketone Oxidation; Enzymatic reaction; | A n/a B 100% C n/a |
14,15-dioxa-7-aza-dispiro[5.1.5.2]pentadecane
A
caprolactam
B
11-cyanoundecanoic acid
C
cyclohexanone
Conditions | Yield |
---|---|
With cerium(IV) oxide; 2,2'-azobis(isobutyronitrile) at 50℃; for 12h; Reagent/catalyst; Temperature; Inert atmosphere; | A n/a B 99.2% C n/a |
Conditions | Yield |
---|---|
With [Ru(η(3):η(3)-C10H16)Cl(O2CCH3)] In aq. phosphate buffer at 50℃; for 10h; pH=7; Sealed tube; Inert atmosphere; | 99% |
With perchloric acid; acetaldehyde; acetone; sodium chloride In water at 25℃; Rate constant; Equilibrium constant; Irradiation; | |
With sulfuric acid In water at 25℃; Rate constant; Equilibrium constant; | |
In water at 25℃; Equilibrium constant; ionic strength: 0.01 M; | |
at 19.9 - 59.9℃; Equilibrium constant; Thermodynamic data; keto-enol-tautomerism, keto-enol-association; ΔH; |
Conditions | Yield |
---|---|
With water at 80℃; for 0.25h; microwave irradiation; | 99% |
With silica gel; iron(III) chloride at 20℃; for 0.0833333h; | 97% |
With water; Nafion-H In acetone for 0.5h; | 95% |
Conditions | Yield |
---|---|
With water at 80℃; for 0.25h; microwave irradiation; | 99% |
With water; acetone; mesoporous aluminosilicate at 55℃; for 2h; | 85% |
With aluminium(III) iodide In acetonitrile; benzene for 0.166667h; Ambient temperature; | 90 % Chromat. |
With erbium(III) triflate In nitromethane for 0.5h; Product distribution; Further Variations:; Solvents; reaction time; |
Conditions | Yield |
---|---|
Fe/W/Zr oxide catalyst of example 3 In acetone at 70℃; Product distribution / selectivity; | A 99% B 99% |
With sulfuric acid In decane; nitromethane Product distribution / selectivity; | A 99.56 %Chromat. B 99.47 %Chromat. |
sulfuric acid In decane; nitromethane at 53℃; Product distribution / selectivity; |
2,2,3,3-tetramethyl-1,4-dioxaspiro<4.5>decane
cyclohexanone
Conditions | Yield |
---|---|
With iron(III) chloride hexahydrate; acetaldehyde In dichloromethane for 1h; Reflux; | 99% |
Conditions | Yield |
---|---|
With Pd nanoparticles and TiO2; hydrogen; hydrazine hydrate In water at 80℃; under 450.045 Torr; for 10h; Catalytic behavior; Kinetics; Mechanism; Reagent/catalyst; | 98.9% |
With hydrogen at 160 - 200℃; under 1125.11 Torr; for 1h; Reagent/catalyst; Autoclave; | 96.3% |
With 2 mol-% Pd/C; hydrogen; potassium formate In water at 90℃; for 6h; Temperature; Reagent/catalyst; | 94% |
Conditions | Yield |
---|---|
With methyltrifluoromethyldioxirane In dichloromethane at -22℃; for 0.3h; | 98% |
With hydrogenchloride; FeH6Mo6O24(3-)*3H3N*3H(1+)*7H2O; tetrabutylammomium bromide; dihydrogen peroxide In 1,4-dioxane; water at 85℃; for 24h; Catalytic behavior; Solvent; Temperature; Reagent/catalyst; | 98% |
With dihydrogen peroxide at 49.84℃; for 3h; Catalytic behavior; Temperature; Reagent/catalyst; | 93.1% |
Conditions | Yield |
---|---|
With 1,1,1-trifluoro-2-propanone; methyltrifluoromethyldioxirane In dichloromethane at 0℃; for 2h; also dimethyldioxirane efficiently afford cleavage of acetals and ketals to carbonyl products under mild, neutral conditions through α-CH insertion, also react dialkyl ethers and cyclic ethers to alcohols, aldehydes, carboxylic axids or to lactones; | 98% |
With 1,1,1-trifluoro-2-propanone; methyltrifluoromethyldioxirane In dichloromethane at 0℃; for 2h; | 98% |
With iron(III) chloride In dichloromethane for 0.25h; Ambient temperature; | 96% |
Conditions | Yield |
---|---|
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; dihydrogen peroxide In water; acetonitrile at 20℃; for 0.75h; | 98% |
With acetic acid at 20℃; for 6h; | 82% |
With dihydrogen peroxide; iodine; sodium dodecyl-sulfate In water at 20℃; for 3h; Micellar solution; | 75% |
N'-cyclohexylidene-N,N-dimethyl-hydrazine
cyclohexanone
Conditions | Yield |
---|---|
With baker's yeast; phosphate buffer In ethanol at 37℃; for 12h; | 98% |
With triethylene diamine nickel thiosulfate; water In chloroform at 20℃; for 0.0833333h; Hydrolysis; | 94% |
With chloro-trimethyl-silane; sodium iodide In water; acetonitrile for 0.05h; deprotection; | 92% |
cyclohexane-1,1-diylbis(phenylsulfane)
cyclohexanone
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 20 - 25℃; for 2h; Irradiation; | 98% |
Conditions | Yield |
---|---|
With [Ru(η(5)-C5,κ-P-Cp(P))(CH3CN)2]PF6 In tetrahydrofuran-d8 at 60℃; for 5h; Inert atmosphere; | 97% |
With tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate; potassium carbonate In acetonitrile for 1h; Inert atmosphere; Reflux; | 96% |
With bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (1,3,5-triaza-7-phosphaadamantane); isopropyl alcohol In water at 100℃; for 1h; Reagent/catalyst; | 95.5% |
Conditions | Yield |
---|---|
With ammonium chlorochromate on aluminum oxide In diethyl ether for 0.5h; Heating; various conditions; | 97% |
With zirconium hydrogen sulfate; silica gel In hexane at 20℃; for 0.3h; | 92% |
With water; silica gel; tetrabromosilane In tetrachloromethane at 20℃; for 0.233333h; | 90% |
Conditions | Yield |
---|---|
triethylamine In dichloromethane at 20 - 25℃; for 16h; | A 97% B n/a |
Conditions | Yield |
---|---|
With baker's yeast; phosphate buffer In ethanol at 37℃; for 11h; | 97% |
With caro's acid; silica gel for 0.05h; Oxidation; Irradiation; | 94% |
With iron(II) sulfate In chloroform at 20℃; for 0.75h; Hydrolysis; | 90% |
Conditions | Yield |
---|---|
With sodium bromate; ammonium cerium(IV) nitrate In acetonitrile at 80℃; for 0.333333h; | A 97% B 95% |
Conditions | Yield |
---|---|
With C53H46ClN3P2Ru; potassium tert-butylate; acetone at 56℃; under 750.075 Torr; for 0.666667h; Oppenauer Oxidation; | 97% |
Cyclohexanone oxime
acetaldehyde
A
Acetaldehyde oxime
B
cyclohexanone
Conditions | Yield |
---|---|
With sulfuric acid at 4 - 10℃; for 2h; | A 97% B 97% |
Conditions | Yield |
---|---|
In toluene for 18h; Molecular sieve; Dean-Stark trap; Heating / reflux; | 100% |
With sulfuric acid In toluene Dean-Stark; Reflux; | 99% |
With K-10 Montmorillonite clay In toluene for 2.5h; Heating; | 95% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol for 0.025h; microwave irradiation; | 100% |
With sodium hydroxide In ethanol; water at 20℃; for 24h; Inert atmosphere; Green chemistry; | 99% |
aluminum oxide for 0.0416667h; microwave irradiation; | 98% |
Conditions | Yield |
---|---|
With trimethyl orthoformate at 40℃; under 6000480 Torr; for 8h; | 100% |
With chloranil In acetonitrile for 0.5h; Irradiation; | 99% |
With trimethyl orthoformate at 20℃; for 0.5h; | 98% |
diethoxyphosphoryl-acetic acid ethyl ester
cyclohexanone
ethyl cyclohexylideneacetate
Conditions | Yield |
---|---|
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran; mineral oil for 1h; Stage #2: cyclohexanone In tetrahydrofuran; mineral oil for 18h; | 100% |
With sodium hydride In tetrahydrofuran for 8h; | 98% |
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With 15-crown-5; sodium hydride In tetrahydrofuran; mineral oil at 0℃; Stage #2: cyclohexanone In tetrahydrofuran; mineral oil at -40 - 20℃; | 97% |
Pentaerythritol
cyclohexanone
7,11,18,21-tetraoxa-trispiro[5.2.2.5.2.2]heneicosane
Conditions | Yield |
---|---|
With sulfuric acid at 80℃; | 100% |
With pyrographite In toluene for 8h; Heating; | 94% |
peroxodisulfate ion; zirconium(IV) oxide In toluene for 4h; Heating; | 94% |
1.3-butanediol
cyclohexanone
2-methyl-1,5-dioxaspiro<5.5>undecane
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In benzene for 8.5h; Heating; | 100% |
With pyridine; toluene-4-sulfonic acid In benzene Condensation; Heating; | 100% |
With toluene-4-sulfonic acid In benzene Heating; | 81% |
With MOR zeolite supported Bronsted acidic ionic liquid at 50℃; for 2h; | 68.1% |
With toluene-4-sulfonic acid; benzene |
cyclohexanone
cyclopenta-1,3-diene
cyclopenta-2,4-dien-1-ylidenecyclohexane
Conditions | Yield |
---|---|
Stage #1: cyclohexanone; cyclopenta-1,3-diene With pyrrolidine In methanol at 20℃; Inert atmosphere; Stage #2: With acetic acid In methanol for 0.15h; | 100% |
In methanol for 0.416667h; Ambient temperature; new method; | 96% |
With pyrrolidine In methanol for 0.416667h; Ambient temperature; | 96% |
Conditions | Yield |
---|---|
Stage #1: cyclohexanone With sodium hydroxide In ethanol; water at 0 - 5℃; Stage #2: benzaldehyde In ethanol; water | 100% |
With CaO modified with benzyl bromide In methanol at 65℃; under 760.051 Torr; for 3h; Reagent/catalyst; Concentration; Temperature; Time; | 95.8% |
With N,N-Dimethyltrimethylsilylamine; magnesium bromide ethyl etherate at 20℃; for 16h; Inert atmosphere; neat (no solvent); | 93% |
cyclohexanone
1-Ethynyl-1-cyclohexanol
1,2-di(1-hydroxycyclohexyl)acetylene
Conditions | Yield |
---|---|
Stage #1: 1-Ethynylcyclohexan-1-ol With ethylmagnesium bromide In tetrahydrofuran at 23 - 80℃; Stage #2: cyclohexanone In tetrahydrofuran at 23 - 25℃; Stage #3: With ammonium chloride In tetrahydrofuran; water | 100% |
With sodium hydroxide; tetrabutylammomium bromide In toluene at 70℃; for 2h; | 89% |
Stage #1: 1-Ethynylcyclohexan-1-ol With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: cyclohexanone With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In tetrahydrofuran; hexane at -78 - 20℃; for 14h; | 74% |
Conditions | Yield |
---|---|
With zeolite HSZ-360 In toluene for 3h; Heating; | 100% |
With [Al(H2O)6][MS]3 In cyclohexane for 0.833333h; Reagent/catalyst; Dean-Stark; Reflux; | 100% |
With AgOTf and (3-(3,5-bis(diphenylphosphino)phenyl)-pyridine) In toluene for 12h; Reflux; | 99% |
Conditions | Yield |
---|---|
With thionyl chloride; silica gel In toluene for 24h; Heating; | 100% |
With bentonite In toluene for 3h; Heating; | 99% |
With silica gel; iron(III) chloride In dichloromethane Ambient temperature; | 99% |
Conditions | Yield |
---|---|
With ammonium acetate; zinc In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere; | 100% |
zinc In N,N-dimethyl-formamide for 2h; Product distribution; Ambient temperature; other solvents : N,N-dimethylacetoamide, N-methyl-2-pyrrolidone, 2-pyrrolidone, 2-methyloxazoline; | 99% |
With zinc In N,N-dimethyl-formamide for 2h; Ambient temperature; other solvents : N,N-dimethylacetoamide, N-methyl-2-pyrrolidone, 2-pyrrolidone, 2-methyloxazoline; | 99% |
cyclohexanone
2-hydroxy-2-methylpropanenitrile
1-hydroxy-1-cyclohexanecarbonitrile
Conditions | Yield |
---|---|
With Hevea brasiliensis (S)-hydroxynitrile lyase pH=4.5; aq. buffer; Enzymatic reaction; | 100% |
With titanium(IV) isopropylate; dl-3-(2-hydroxy-1-naphthylidene)-imino-ε-caprolactam (Nap-ACL) In dichloromethane for 3h; Ambient temperature; | 99% |
With ytterbium(III) isopropoxide In tetrahydrofuran for 0.5h; Ambient temperature; | 94% |
cyclohexanone
ethyl 2-cyanoacetate
ethyl 2-cyano-2-cyclohexylideneacetate
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In neat liquid at 20℃; for 0.133333h; Knoevenagel Condensation; Green chemistry; | 100% |
With third generation polystyrene supported poly(amidoamine) dendrimer In ethanol at 50℃; for 0.333333h; Knoevenagel condensation; | 98% |
With ammonium acetate; acetic acid In toluene Knoevenagel Condensation; Reflux; | 97% |
cyclohexanone
2-amino-benzenethiol
3H-spiro{benzothiazole-2,1'-cyclohexane}
Conditions | Yield |
---|---|
With trifluoroacetic acid at 80℃; for 16h; Reagent/catalyst; | 100% |
In toluene Heating; | 93.8% |
With aluminum oxide In neat (no solvent) at 20℃; for 0.5h; Inert atmosphere; | 92% |
cyclohexanone
toluene-4-sulfonic acid hydrazide
N'-cyclohexylidene-4-methylbenzene-1-sulfonohydrazide
Conditions | Yield |
---|---|
In methanol at 20℃; for 3h; | 100% |
In methanol at 20℃; Inert atmosphere; | 99.5% |
With hydrogenchloride In methanol for 24h; Heating; | 97% |
Conditions | Yield |
---|---|
With formic acid; Cp*IrCl(N-(phenyl(pyridin-2-yl)methyl)methanesulfonamide)complex In ethyl acetate at 40℃; for 18h; Reagent/catalyst; Inert atmosphere; | 100% |
Stage #1: cyclohexanone; benzylamine With formic acid; chlorido(8-quinolinolato-k2N,O)(η5-pentamethylcyclopentadienyl)iridium(III) In ethyl acetate at 0 - 40℃; Inert atmosphere; Schlenk tube; Cooling with ice; Stage #2: With sodium hydrogencarbonate In water; ethyl acetate Product distribution / selectivity; | 98% |
With 4 A molecular sieve; borane pyridine complex In methanol for 16h; | 96% |
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In diethyl ether for 3h; Heating; | 100% |
With hydrogenchloride In diethyl ether at 20℃; for 0.15h; | 98% |
bis(acetylacetonato)dioxidomolybdenum(VI) In acetonitrile at 20℃; for 3.5h; | 96% |
Conditions | Yield |
---|---|
hydrotalcite structure integrating fluoride ions In DMF (N,N-dimethyl-formamide) at 25℃; for 2h; Conversion of starting material; Knoevenagel Condensation; | 100% |
With 1-butyl-1,4-diazabicyclo[2.2.2]octanylium hydrotetrafluoroborate In water at 20℃; for 0.0333333h; Knoevenagel condensation; | 100% |
Ru(+)Cp*(NCCHCO2Et)(-)*(PPh3)2 In tetrahydrofuran at 25℃; for 5h; Condensation; Aldol reaction; | 99% |
Conditions | Yield |
---|---|
With Fe(AAEMA)3; oxygen; isobutyraldehyde In 1,2-dichloro-ethane under 760 Torr; for 36h; Ambient temperature; | 100% |
With borax; dihydrogen peroxide; N-benzyl-N,N,N-triethylammonium chloride In water; benzene at 55℃; for 24h; | 100% |
With bismuth(lll) trifluoromethanesulfonate In dichloromethane at 20℃; for 0.5h; Baeyer-Villiger oxidation; | 100% |
cyclohexanone
2-bromocyclohexanone
Conditions | Yield |
---|---|
With N-Bromosuccinimide; toluene-4-sulfonic acid In dichloromethane; cyclohexanone at 0℃; for 4h; Reflux; | 100% |
With N-Bromosuccinimide; toluene-4-sulfonic acid In dichloromethane at 0℃; for 4h; Reflux; | 98% |
With Cl(CF2)4SO2Br In tetrachloromethane at 10℃; for 0.166667h; | 95% |
Conditions | Yield |
---|---|
With sodium nitrite In trifluoroacetic acid | 100% |
With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity; | 100% |
With dihydrogen peroxide; ortho-tungstic acid In water at 90℃; for 20h; Product distribution / selectivity; | 99% |
Conditions | Yield |
---|---|
Stage #1: cyclohexanone With potassium peroxomonosulfate In water at 20℃; Baeyer-Villiger oxidation; Stage #2: With water at 20℃; Solvolysis; Further stages.; | 100% |
With dihydrogen peroxide; n-butylstannoic acid; acetic acid at 70℃; for 8h; | 87% |
With Oxone In hexane; water at 40℃; for 6h; Baeyer-Villiger oxidation; | 77% |
Conditions | Yield |
---|---|
With N,O-bis(trimethylsilyl)hydroxylamine; potassium hydride In tetrahydrofuran for 1.5h; Ambient temperature; - 78 deg C to room temp.; | 100% |
With acetic acid; acetone oxime at 120℃; for 1h; | 100% |
With ammonium chloride; Amberlyst A-21 In ethanol for 1h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With iodine; mercury dichloride In dichloromethane for 0.5h; Ambient temperature; | 100% |
With N-chloro-succinimide In dimethyl sulfoxide at 20℃; for 0.166667h; | 92% |
With N-chloro-succinimide In various solvent(s) at 20℃; for 0.416667h; | 90% |
Conditions | Yield |
---|---|
With hydrogen; 5 percent Rh/MgO; magnesium oxide In water at 323℃; under 15001.2 Torr; Product distribution; | 100% |
With Triethoxysilane; benzoic acid ethyl ester; cesium fluoride at 25℃; for 0.0166667h; | 100% |
With zinc(II) tetrahydroborate In acetonitrile for 0.166667h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With trimethyl orthoformate at 60℃; under 6000480 Torr; for 8h; | 100% |
With orthoformic acid triethyl ester at 20℃; for 1h; | 96% |
iodine for 1h; | 90% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View