1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualified
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryGOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation
Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:121-71-1
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:121-71-1
Min.Order:1 Kilogram
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Type:Manufacturers
inquiryProduct Name 3'-Hydroxyacetophenone Synonyms m-Hydroxyacetophenone; 3-Acetylphenol
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Other
inquiryProduct Description Product website: http://www.finerchem.com Product Name 3'-Hydroxyacetophenone CAS No. 121-71-1 Appearance White crystalline powder
Cas:121-71-1
Min.Order:1 Gram
FOB Price: $8.0
Type:Lab/Research institutions
inquiryhigh quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Cas:121-71-1
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryCangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap
Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu
Cas:121-71-1
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Manufacturers
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:121-71-1
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen
Cas:121-71-1
Min.Order:1 Kilogram
FOB Price: $2.0 / 6.0
Type:Trading Company
inquiry3'-Hydroxyacetophenone Basic information Product Name: 3'-Hydroxyacetophenone Synonyms: m-Acetylphenol;Ethanone, 1-(3-hydroxyphenyl)-;m-Hydroxyacetophenonel;3'-Hydroxyacetoph
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:121-71-1
Min.Order:1 Gram
FOB Price: $12.0 / 15.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:121-71-1
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:121-71-1
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryAdvantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&
Cas:121-71-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryName 3'-Hydroxyacetophenone Synonyms m-Hydroxyacetophenone; 3-Acetylphenol Molecular Formula C8H8O2 Molecular Weight 1
Cas:121-71-1
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Other
inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Beige-brown Crystalline Powder Storage:Store in sealed
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryWe are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery
Cas:121-71-1
Min.Order:10 Gram
FOB Price: $3.5
Type:Trading Company
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:121-71-1
Min.Order:1 Kilogram
FOB Price: $21.7 / 28.1
Type:Trading Company
inquiry3'-Hydroxyacetophenone CAS:121-71-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic
Cas:121-71-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHebei Mojin Biotechnology Co., Ltd,Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all em
Cas:121-71-1
Min.Order:1 Gram
FOB Price: $40.0
Type:Trading Company
inquiryOur Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiry3'-Hydroxyacetophenone(3-HAP) CAS:121-71-1 Specification Description: Off-white to Beige to brown crystalline powder Off-white to Beige crystalline powder Solubility Soluble in ether, alcohol, slightly soluble in wa
Cas:121-71-1
Min.Order:1 Kilogram
Negotiable
Type:Other
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
3-hydroxy phenylacetylene
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With gold(III) tribromide; water at 200℃; for 0.333333h; microwave irradiation; | 100% |
With tropylium tetrafluoroborate; water; acetic acid at 130℃; for 1h; Catalytic behavior; Temperature; Microwave irradiation; Inert atmosphere; | 92% |
With trifluorormethanesulfonic acid; water In 2,2,2-trifluoroethanol at 25℃; for 24h; Sealed tube; regioselective reaction; | 87% |
With water at 60℃; for 20h; Sealed tube; | 63% |
With methanesulfonic acid; iron(II) chloride tetrahydrate In 1,2-dichloro-ethane at 60℃; for 2h; Inert atmosphere; | 49% |
1-(3-{[tert-butyl(dimethyl)silyl]oxy}phenyl)ethanone
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With lithium acetate In water; N,N-dimethyl-formamide at 25℃; for 7h; Inert atmosphere; | 99% |
With dichloro bis(acetonitrile) palladium(II) In water; acetone at 75℃; for 16h; | 88% |
With KF-Al2O3 (acidic) In acetonitrile for 48h; Ambient temperature; | 82% |
Conditions | Yield |
---|---|
With copper acetylacetonate; N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water In water; dimethyl sulfoxide at 80℃; for 24h; Schlenk technique; Inert atmosphere; | 99% |
With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0); tert-butyl XPhos In 1,4-dioxane; water at 80℃; for 14h; | 96% |
With bis(η3-allyl-μ-chloropalladium(II)); t-BuBrettPhos; p-methylbenzaldehyde oxime; caesium carbonate In N,N-dimethyl-formamide at 90℃; for 5h; Catalytic behavior; Solvent; Reagent/catalyst; Inert atmosphere; | 90% |
With tris(6,6'-diamino-2,2'-bipyridine); 4,4-diphenyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene; Br2Ni*3H2O; water; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide; acetonitrile at 20℃; for 24h; Glovebox; Irradiation; Inert atmosphere; | 88% |
With dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; boric acid; palladium diacetate; caesium carbonate In 1-methyl-pyrrolidin-2-one at 80℃; for 24h; Schlenk technique; Inert atmosphere; | 72% |
1-(3-ethoxyphenyl)ethan-1-one
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With 1-n-butyl-3-methylimidazolim bromide at 200 - 220℃; for 0.5h; Microwave irradiation; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With water; sodium acetate In ethanol for 5h; Reflux; | 98% |
With potassium hydrogensulfate; silica gel In methanol at 20℃; for 1h; | 94% |
With sodium hydroxide |
3'-iodoacetophenone
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With copper acetylacetonate; N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; potassium hydroxide In water; dimethyl sulfoxide at 60℃; for 24h; Schlenk technique; Inert atmosphere; | 98% |
With water; ethylene glycol; potassium hydroxide; copper dichloride In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere; | 95% |
With copper(I) oxide; water; potassium carbonate; Sucrose at 140℃; for 6h; Sealed tube; Inert atmosphere; | 90% |
3-acetyl phenyltrifluoromethanesulfonate
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With tetraethylammonium hydroxide In 1,4-dioxane at 20℃; for 1h; | 97% |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With potassium hydroxide In toluene; tert-butyl alcohol at 100℃; for 0.5h; Inert atmosphere; | 97% |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With water; caesium carbonate; hydrazine hydrate at 80℃; for 48h; | 95% |
With oxygen; triethylamine In 2-methyltetrahydrofuran at 20℃; under 760.051 Torr; for 24h; Green chemistry; | 68% |
With recombinant phenylacetone monooxygenase from Thermobifida fusca, M446G mutant; NADPH In dimethyl sulfoxide at 25℃; pH=9; Kinetics; Tris/HCl buffer; Enzymatic reaction; chemoselective reaction; | |
Multi-step reaction with 2 steps 1: tetrahydrofuran / 40 °C / Reduced pressure 2: recombinant phenylacetone monooxygenase from Thermobifida fusca; NADPH / dimethyl sulfoxide / 25 °C / pH 9 / Tris/HCl buffer; Enzymatic reaction View Scheme | |
With oxygen; N-ethyl-N,N-diisopropylamine; [5,6]fullerene-C70 In chloroform; toluene at 20℃; for 12h; Irradiation; |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; | 95% |
methyllithium
3-Carboxyphenol
A
3-Hydroxyacetophenone
B
meta-hydroxy-α,α-dimethylbenzyl alcohol
Conditions | Yield |
---|---|
With chloro-trimethyl-silane In tetrahydrofuran; diethyl ether at 0℃; for 2h; Yields of byproduct given; | A 94% B n/a |
With chloro-trimethyl-silane In tetrahydrofuran; diethyl ether at 0℃; for 2h; Yield given; | A 94% B n/a |
Conditions | Yield |
---|---|
With 1-n-butyl-3-methylimidazolim bromide at 220℃; for 0.666667h; Inert atmosphere; Microwave irradiation; | 92% |
With calcium hydride; diphenyldisulfane In 1-methyl-pyrrolidin-2-one at 220℃; for 0.5h; | 83% |
With 1-N-ferrocenylmethyl benzimidazole tagged polymer In N,N-dimethyl-formamide Reflux; | 76% |
With sodium thioethylate In N,N-dimethyl-formamide at 80℃; for 3.5h; | 18% |
1-(3-(methoxymethoxy)phenyl)ethan-1-one
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With tin(IV) chloride In dichloromethane at 0℃; for 0.0333333h; | 92% |
acetic acid 3-aminophenyl ester
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
Stage #1: acetic acid 3-aminophenyl ester With sulfuric acid at 20℃; Cooling with ice; Stage #2: With sodium nitrite In water Reflux; | 92% |
1-(3-(allyloxy)phenyl)ethanone
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With bis(benzonitrile)palladium(II) dichloride In benzene for 20h; Heating; | 90% |
1-(3-((tetrahydro-2H-pyran-2-yl)oxy)phenyl)ethan-1-one
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With tin(IV) chloride In dichloromethane at 0℃; for 0.0333333h; | 90% |
Conditions | Yield |
---|---|
Stage #1: 1-(3-aminophenyl)ethanone With sulfuric acid In water at 45 - 50℃; for 0.5h; Stage #2: With water; urea; sodium nitrite In water at 0 - 5℃; for 0.5h; Stage #3: With sulfuric acid In 5,5-dimethyl-1,3-cyclohexadiene; water at 90℃; for 2h; | 88.3% |
Stage #1: 1-(3-aminophenyl)ethanone With sodium nitrite In water at 20℃; Milling; Green chemistry; Stage #2: With water at 80℃; for 0.5h; Neutral conditions; Green chemistry; | 80% |
With uranyl nitrate hydrate; water; trifluoroacetic acid for 48h; Irradiation; Inert atmosphere; | 58% |
With sulfuric acid; water Diazotization; |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With water In dimethyl sulfoxide at 155℃; for 0.5h; | 85% |
Conditions | Yield |
---|---|
With copper acetylacetonate; N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water In water; dimethyl sulfoxide at 130℃; for 24h; Concentration; Schlenk technique; Inert atmosphere; | 82% |
With trans-di(μ-acetato)bis[o-(di-o-tolyl-phosphino)benzyl]dipalladium(II); C29H45Pt; potassium carbonate In water; N,N-dimethyl-formamide at 115℃; for 0.5h; Inert atmosphere; Microwave irradiation; | 81% |
With tris(6,6'-diamino-2,2'-bipyridine); 4,4-diphenyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene; Br2Ni*3H2O; water; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide; acetonitrile at 20℃; for 24h; Glovebox; Irradiation; Inert atmosphere; | 54% |
1-[3-(phenylmethoxy)phenyl]ethan-1-one
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With sodium hydrogen sulfate; silica gel; methoxybenzene at 115℃; for 3h; | 81% |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With acetic acid In water at 90℃; for 4h; Reagent/catalyst; Temperature; | 77.6% |
3-acetyl-2-cyclohexen-1-one
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With tetrakis(acetonitrile)palladium(II) bis(tetrafluoroborate); 6,6'-dimethyl-2,2'-bipyridine; sodium anthraquinone-2-sulfonate; oxygen In water; dimethyl sulfoxide at 80℃; under 760.051 Torr; for 24h; | 77% |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With potassium fluoride; dihydrogen peroxide; sodium hydrogencarbonate In tetrahydrofuran; methanol at 40℃; | 76% |
5-acetyl-2-cyclohexen-1-one
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With lithium bromide; copper(ll) bromide In acetonitrile for 1h; Heating; | 75% |
tert-Butyl acrylate
4-iodoanisol
1-(3-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)ethanone
A
3-Hydroxyacetophenone
B
1,1'-(biphenyl-3,3'-diyl)bis(ethan-1-one)
C
tert-butyl (E)-3-(2-methoxyphenyl)prop-2-enoate
Conditions | Yield |
---|---|
With oxygen; palladium diacetate; sodium carbonate In N,N-dimethyl-formamide at 50℃; for 6h; Further byproducts given; | A 6% B 5% C 26% D 71% |
3-hydroxy phenylacetylene
acetic acid
A
3-Hydroxyacetophenone
B
3-acetylphenyl acetate
Conditions | Yield |
---|---|
With iron(III) sulfate hydrate at 95℃; for 24h; Schlenk technique; | A 71% B 6% |
Conditions | Yield |
---|---|
With iodine; hydrazine hydrate; dimethyl sulfoxide In water; acetonitrile at 80℃; for 7.5h; | 64.7% |
With chromium(VI) oxide |
Conditions | Yield |
---|---|
With Candida albicans CCT 0776 In water at 30℃; for 144h; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A 42% B 42% |
With immobilized Candida albicans CCT 0776 cells in calcium alginate beads In water at 30℃; for 16h; Reagent/catalyst; | A n/a B n/a |
acetophenone
A
3-Hydroxyacetophenone
B
o-hydroxyacetophenone
C
4-Hydroxyacetophenone
Conditions | Yield |
---|---|
With (difluoroboryl)dimethylglyoximatocobalt(II) bis(acetonitrile); water; 3-cyano-1-methylquinolinium cation In acetonitrile at 20℃; for 5h; Inert atmosphere; Irradiation; Green chemistry; | A 6% B 38% C 14% |
With hydroxyl radical; potassium hexacyanoferrate(III) Rate constant; Ambient temperature; also without K3Fe(CN)6; | |
With air; carbon monoxide; sodium acetate; palladium on activated charcoal; phosphovanadomolybdic acid In water; acetic acid at 120℃; under 15200 Torr; for 4h; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide | 100% |
With NaH In N,N-dimethyl-formamide | 98% |
With sodium ethanolate |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; Reflux; | 100% |
With potassium carbonate In acetone for 8h; Heating; | 95% |
With potassium carbonate In ethanol for 3h; Reflux; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
Stage #1: 3-Hydroxyacetophenone With sodium tetrahydroborate at 60℃; for 0.5h; Ball milling; neat (no solvent); Stage #2: With water regiospecific reaction; | 100% |
With formic acid; C18H24ClIrN3 In water at 80℃; for 4h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 99% |
With sodium tetrahydroborate; nickel(II) phthalocyanine In PEG-400 at 20℃; for 0.416667h; chemoselective reaction; | 86% |
Conditions | Yield |
---|---|
With sodium hydride In benzene for 0.5h; | 100% |
3-Hydroxyacetophenone
benzyl bromide
1-[3-(phenylmethoxy)phenyl]ethan-1-one
Conditions | Yield |
---|---|
With potassium carbonate In acetone Reflux; Inert atmosphere; | 100% |
With potassium carbonate; potassium iodide In acetone for 24h; Heating / reflux; | 98% |
In N,N-dimethyl-formamide; mineral oil | 97% |
3-Hydroxyacetophenone
3,4-dimethoxy-benzaldehyde
(E)-1-(3,4-dimethoxyphenyl)-3-(3-hydroxyphenyl)prop-2-en-1-one
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol at 0 - 20℃; for 16h; | 100% |
With potassium hydroxide In ethanol; water at 0 - 20℃; | 92% |
With potassium hydroxide In ethanol at 20℃; for 16h; Condensation; | 91% |
Conditions | Yield |
---|---|
With sodium ethanolate In tetrahydrofuran at 25℃; for 0.00277778h; microwave irradiation; | 100% |
With potassium tert-butylate In tetrahydrofuran at 20℃; Claisen Condensation; | 88% |
3-Hydroxyacetophenone
tert-butyldimethylsilyl chloride
1-(3-{[tert-butyl(dimethyl)silyl]oxy}phenyl)ethanone
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 100% |
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 12h; | 93% |
With dmap; triethylamine In DMF (N,N-dimethyl-formamide) at 20℃; for 2.5h; | 91% |
N-ethyl-N-methylcarbamoyl chloride
3-Hydroxyacetophenone
1-(N-ethyl-N-methylaminocarbonyloxy)-3-acetylbenzene
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20 - 55℃; for 5h; Product distribution / selectivity; Heating / reflux; | 100% |
With potassium carbonate In acetone for 4h; Reflux; | 100% |
With potassium carbonate In acetone at 60℃; for 0.4h; Reagent/catalyst; Temperature; Solvent; | 100% |
3-Hydroxyacetophenone
3-Chloro-2-methylpropene
1-[3-(2-methylallyloxy)phenyl]ethanone
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide; potassium carbonate In N,N-dimethyl-formamide at 20 - 80℃; | 100% |
With potassium carbonate In acetonitrile for 17h; Reflux; |
3-Hydroxyacetophenone
propargyl bromide
1-(3-(prop-2-yn-1-yloxy)phenyl)ethan-1-one
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide; toluene at 25℃; for 24h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; | |
Stage #1: 3-Hydroxyacetophenone With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.5h; Stage #2: propargyl bromide In N,N-dimethyl-formamide at 0 - 25℃; for 16h; |
Conditions | Yield |
---|---|
With iodine at 140℃; for 3h; | 100% |
With iodine at 140℃; for 3h; | 100% |
With iodine at 140℃; for 3h; | 100% |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With C38H46ClIrN2P; hydrogen; sodium t-butanolate In ethanol at 0 - 50℃; under 1500.15 - 75007.5 Torr; Reagent/catalyst; Solvent; Inert atmosphere; Autoclave; | 100% |
With 1,1,1,3',3',3'-hexafluoro-propanol; C32H39BrMnN2O2P; potassium tert-butylate; hydrogen In methanol at 20℃; under 22502.3 Torr; for 16h; Glovebox; Autoclave; enantioselective reaction; | 99% |
With formic acid; triethylamine; [Ru(η6-p-cymene)(HNC(Ph)C(Ph)NTs)] In ethanol at 60 - 70℃; for 5h; Product distribution / selectivity; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
Stage #1: 3-Hydroxyacetophenone With potassium carbonate In acetone for 0.166667h; Stage #2: dimethyl sulfate In acetone at 45℃; for 2h; | 99.73% |
With potassium carbonate In acetone at 45℃; for 2h; Large scale reaction; | 95% |
Stage #1: 3-Hydroxyacetophenone With sodium hydroxide In water for 0.5h; Large scale; Stage #2: dimethyl sulfate In water at 30 - 38℃; for 9.15h; pH=> 13; Temperature; pH-value; Microwave irradiation; Large scale; | 91.1% |
Conditions | Yield |
---|---|
With magnesium(II) perchlorate at 20℃; for 1h; | 99% |
With sodium hydroxide In water at 0℃; for 1.5h; pH=7 - 8; | 94% |
copper(II) bis(tetrafluoroborate) at 20℃; for 0.5h; | 92% |
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 4h; Inert atmosphere; | 99% |
trifluoromethylsulfonic anhydride
3-Hydroxyacetophenone
3-acetyl phenyltrifluoromethanesulfonate
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine; dmap In dichloromethane for 2h; Ambient temperature; | 99% |
With pyridine In dichloromethane at 0 - 20℃; | 96% |
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With Triisopropoxymethan; cerium triflate In hexane at 25℃; for 1h; | 99% |
With zeolite HSZ-360 In toluene for 11h; Heating; | 88% |
With toluene-4-sulfonic acid In benzene Heating / reflux; | 36% |
3-Hydroxyacetophenone
p-toluenesulfonyl chloride
3-acetylphenyl p-toluenesulfonate
Conditions | Yield |
---|---|
With potassium carbonate In tetrahydrofuran; water at 0 - 20℃; for 2h; Green chemistry; | 99% |
With 1,4-diaza-bicyclo[2.2.2]octane In dichloromethane at 0 - 20℃; Inert atmosphere; | 91% |
With dmap; triethylamine In dichloromethane |
Conditions | Yield |
---|---|
With magnesium(II) perchlorate at 40℃; for 4.5h; | 99% |
n-propanesulfonyl chloride
3-Hydroxyacetophenone
3-acetylphenyl propane-1-sulfonate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; for 5h; | 99% |
Conditions | Yield |
---|---|
With copper diacetate; triethylamine In dichloromethane at 50℃; for 3h; Reagent/catalyst; Time; Sealed tube; | 99% |
triisopropylsilyl chloride
3-Hydroxyacetophenone
1-(3-((triisopropylsilyl)oxy)phenyl)ethanone
Conditions | Yield |
---|---|
With 1H-imidazole In dichloromethane at 20℃; for 6h; | 99% |
3-Hydroxyacetophenone
Conditions | Yield |
---|---|
With triethanolamine; N-benzyl-N,N,N-triethylammonium chloride; sodium iodide In acetone at 25℃; | 99% |
Conditions | Yield |
---|---|
With dmap In toluene at 130℃; for 1h; Microwave irradiation; Sealed tube; | 99% |
3-Hydroxyacetophenone
4-Hydrazino-5,6-tetramethylenethieno<2,3-d>pyrimidine
Conditions | Yield |
---|---|
In ethanol for 24h; Reflux; | 99% |
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