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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Triphenylbismuth Manufacturer/High quality/Best price/In stock

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Triphenylbismuth supplier in China

Cas:603-33-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Manufacturer supply Triphenylbismuth CAS 603-33-8 with best price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed add

Manufacturer supply Triphenylbismuth CAS 603-33-8 with best price

Cas:603-33-8

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

TriphenylbisMuthine

Cas:603-33-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:

TriphenylbisMuthine

Cas:603-33-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Triphenylbismuth

Cas:603-33-8

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 603-33-8 Triphenylbismuth Manufacturer

Cas:603-33-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant production

Triphenylbismuth

Cas:603-33-8

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Triphenylbismuth CAS 603-33-8 Bismuthine, triphenyl- CAS no 603-33-8 BISMUTH TRIPHENYL TRIPHENYLBISMUTHINE Triphenylbismuth CAS 603-33-8 Bismuthine, triphenyl- IN Stock CAS 603-33-8 Bismuthine, triphenyl- Triphenylbismuth COA TDS price MSDS

Triphenylbismuth CAS 603-33-8 Bismuthine, triphenyl- CAS no 603-33-8 BISMUTH TRIPHENYL TRIPHENYLBISMUTHINE

Cas:603-33-8

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

inquiry

LIDE PHARMACEUTICALS LIMITED

LIDE PHARMACEUTICALS LIMITED is a professional chemicals and APIs leading manufacturer in China. Our core business line covers APIs, Intermediates, Herb extract, etc. We are specialized in chemical synthesis, process development of pharmaceu

Triphenylbismuth

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $0.9 / 1.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Triphenyl bismuth

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM Triphenylbismuth

Cas:603-33-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 603-33-8 with best quality

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

TriphenylbismuthCAS603-33-8

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod

Bismuthine, triphenyl-

Cas:603-33-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

CAS No. 603-33-8 Other Names TPB MF C18H15Bi EINECS No. 210-033-4 Type Pharmaceutical Intermediates Appearance:White crystal Stora

Triphenyl bismuth

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

BISMUTH TRIPHENYLCAS NO.:603-33-8

Cas:603-33-8

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bismuthine, triphenyl- 603-33-8

Cas:603-33-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

catalyst , Triphenylbismuth CAS:603-33-8

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $81.0 / 85.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Triphenylbismuth CAS:603-33-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

Triphenylbismuth CAS:603-33-8

Cas:603-33-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

payment methods: bitcoin,western union,USDT,ETH,Monero,wire transfer shipping methods: DHL,UPS,TNT,EMS,FedEx Email Us: admin07@hsnm.com.cn Quick details of Triphenyl bismuth(TPB white crystal Product par

Triphenyl bismuth

Cas:603-33-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Triphenylbismuth

Cas:603-33-8

Min.Order:1 Kilogram

FOB Price: $100.0 / 120.0

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 603-33-8 Triphenylbismuth

Cas:603-33-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Triphenyl bismuth

Cas:603-33-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

TRIPHENYLBISMUTH

Cas:603-33-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Triphenylbismuth

Cas:603-33-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Triphenylbismuth/High quality/Best price

Cas:603-33-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Triphenylbismuth

Cas:603-33-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Triphenylbismuth Manufacturer/High quality/Best price/In stock

Cas:603-33-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

bismuth(III) bromide
7787-58-8

bismuth(III) bromide

diphenylmercury(II)
587-85-9

diphenylmercury(II)

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In diethyl ether byproducts: C6H5HgBr; 12h; distillation of ether phase;100%
BiO2SC6H5

BiO2SC6H5

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In not given byproducts: SO2; 4h at 216°C under 1E-2 - 1E-3 Torr;100%
dibromotriphenylbismuth
28719-55-3, 7065-17-0

dibromotriphenylbismuth

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In ethanol 1h reflux;100%
With potassium hydroxide In water 5h reflux or shaking;
With ammonia In ethanol byproducts: sulfur;
With NH3 In ethanol byproducts: sulfur;
triphenylbismuth difluoride
2023-48-5, 28719-53-1

triphenylbismuth difluoride

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In ethanol 1h reflux;100%
in alkaline medium;
in alkaline medium;
triphenylbismuth dichloride
28719-54-2, 507233-69-4, 594-30-9

triphenylbismuth dichloride

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In ethanol 1h reflux;100%
With sodium hydrogensulfite In acetone at 0°C;80%
With potassium hydroxide In ethanol 5h reflux or shaking;
tetraphenylbismuth chloride
42967-53-3

tetraphenylbismuth chloride

A

triphenylbismuthane
603-33-8

triphenylbismuthane

B

chlorobenzene
108-90-7

chlorobenzene

Conditions
ConditionsYield
In not given decomposition at room temp.;A 100%
B 100%
C6H5Bi(O2SC6H5)2

C6H5Bi(O2SC6H5)2

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In not given byproducts: SO2; 4h at 190°C under 1E-2 - 1E-3 Torr;100%
pentaphenylbismuth
3049-07-8

pentaphenylbismuth

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
With isopropyl alcohol In not given byproducts: C6H6, acetone; at 20°C;100%
In pyridine byproducts: benzene, arine=arin(germ.); decomposition in pyridine;100%
With phenol In not given byproducts: C6H6, C6H5OH, diphenylether;90%
2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

A

methanol
67-56-1

methanol

B

Dimethyl ether
115-10-6

Dimethyl ether

C

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

D

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
With H2O In chloroform-d1 water was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and mixt. was allowed to stand at room temp. for 33 h; detn. by NMR;A 30%
B 16%
C 100%
D 100%
2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

isopropyl alcohol
67-63-0

isopropyl alcohol

A

isopropyl methyl ether
598-53-8

isopropyl methyl ether

B

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

C

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;A 82%
B 100%
C 100%
2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

benzyl alcohol
100-51-6

benzyl alcohol

A

benzyl methyl ether
538-86-3

benzyl methyl ether

B

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

C

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 Kinetics; alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;A 95%
B 100%
C 100%
methanol
67-56-1

methanol

2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

A

Dimethyl ether
115-10-6

Dimethyl ether

B

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

C

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;A 69%
B 100%
C 100%
2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

ethanol
64-17-5

ethanol

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

A

ethyl methyl ether
540-67-0

ethyl methyl ether

B

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

C

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;A 74%
B 100%
C 100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

triphenylphosphine
603-35-0

triphenylphosphine

A

triphenyl-methylphosphonium tetrafluoroborate

triphenyl-methylphosphonium tetrafluoroborate

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 react. (Ph3BiMe)(BF4) and PPh3 in CDCl3 at room temp.; detn. by 1H NMR;A 100%
B 100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

triphenylbismuthane
603-33-8

triphenylbismuthane

B

1-methoxy-N,N-dimethylmethyleneiminium tetrafluoroborate

1-methoxy-N,N-dimethylmethyleneiminium tetrafluoroborate

Conditions
ConditionsYield
In chloroform-d1 mixt. (Ph3BiMe)(BF4), DMF, and CDCl3 was allowed to stand at room temp.for 1 h; detn. by NMR;A 100%
B 100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

triphenyl-arsane
603-32-7

triphenyl-arsane

A

triphenylbismuthane
603-33-8

triphenylbismuthane

B

methyltriphenylarsonium tetrafluoroborate

methyltriphenylarsonium tetrafluoroborate

Conditions
ConditionsYield
In chloroform-d1 react. (Ph3BiMe)(BF4) and AsPh3 in CDCl3 at room temp.; detn. by 1H NMR;A 100%
B 100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

triphenylantimony
603-36-1

triphenylantimony

A

methyltriphenylstibonium tetrafluoroborate
3802-09-3

methyltriphenylstibonium tetrafluoroborate

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 react. (Ph3BiMe)(BF4) and SbPh3 in CDCl3 at room temp.; detn. by 1H NMR;A 100%
B 100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

thioacetamide
62-55-5

thioacetamide

A

1-(methylthio)ethyleneiminium tetrafluoroborate
277306-39-5

1-(methylthio)ethyleneiminium tetrafluoroborate

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 mixt. (Ph3BiMe)(BF4), thioacetamide, and CDCl3 was allowed to react at room temp. for 1 min; detn. by NMR;A 100%
B 100%
2-(isopropoxycarbonyl)ethyl(triphenyl)bismuthonium trifluoromethanesulfonate

2-(isopropoxycarbonyl)ethyl(triphenyl)bismuthonium trifluoromethanesulfonate

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 Kinetics; byproducts: i-PrOC(O)C2H4OSO2CF3; sample soln. decompn. at 25°C; (1)H-NMR monitoring;100%
Nitrosobenzene
586-96-9

Nitrosobenzene

(3,3-dimethyl-2-oxobutyl)triphenylbismuthonium tetrafluoroborate

(3,3-dimethyl-2-oxobutyl)triphenylbismuthonium tetrafluoroborate

A

triphenylbismuthane
603-33-8

triphenylbismuthane

B

(E)-2,2,7,7-Tetramethyl-oct-4-ene-3,6-dione
10507-31-0

(E)-2,2,7,7-Tetramethyl-oct-4-ene-3,6-dione

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at -78℃;A 99%
B 87%
triphenlbismuth dibromide

triphenlbismuth dibromide

pentaphenylbismuth
3049-07-8

pentaphenylbismuth

A

bromobenzene
108-86-1

bromobenzene

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In toluene solvent removing, crystals washing and drying;A n/a
B 99%
pentaphenylphosphorus
2588-88-7

pentaphenylphosphorus

triphenyl bismuth (2+); dichloride
507233-69-4, 594-30-9, 28719-54-2

triphenyl bismuth (2+); dichloride

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In toluene byproducts: tetraphenylphosphorus chloride; mixt. of Ph5P and Ph3BiCl2 in toluene heated at 100°C for 1 h in evacuated glass ampoule; cooling, removal of solvent, treatment with petroleum ether, evapn. of etheral extracts;98%
potassium tert-butylate
865-47-4

potassium tert-butylate

3-oxo-3-phenylpropyl(triphenyl)bismuthonium tetrafluoroborate

3-oxo-3-phenylpropyl(triphenyl)bismuthonium tetrafluoroborate

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In N,N-dimethyl-formamide byproducts: C6H5C(O)CHCH2; K-compd. addn. to Bi-compd. suspn. at -78°C, mixt. allowing to warm to room temp., solvent removal under reduced pressure, residue extn. (Et2O), extract evapn.; residue chromy. on silica gel (hexane, EtOAc 100:o to 80:20);98%
hydrazinium hydroxide

hydrazinium hydroxide

triphenylbismuth difluoride
2023-48-5, 28719-53-1

triphenylbismuth difluoride

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In ethanol room temp., 1 h;98%
In ethanol room temp., 1 h;98%
sodium benzoate
532-32-1

sodium benzoate

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In N,N-dimethyl-formamide mixt. (Ph3BiMe)(BF4), sodium benzoate, and DMF was stirred at room temp. for 2 h; water and Et2O was added and stirred, organic phase was separated and dried over MgSO4 and evapd.;A 30%
B 97%
pentaphenylphosphorus
2588-88-7

pentaphenylphosphorus

triphenylbismuth dibromide
28719-55-3, 7065-17-0

triphenylbismuth dibromide

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In toluene byproducts: tetraphenylphosphorus bromide; mixt. of Ph5P and Ph3BiBr2 in toluene heated at 100°C for 1 h in evacuated glass ampoule; cooling, removal of solvent, treatment with petroleum ether, evapn. of etheral extracts;96%
pentaphenylphosphorus
2588-88-7

pentaphenylphosphorus

triphenylbismuth(V) difluoride
2023-48-5, 28719-53-1

triphenylbismuth(V) difluoride

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In toluene byproducts: tetraphenylphosphorus fluoride; mixt. of Ph5P and Ph3BiF2 in toluene heated at 100°C for 1 h in evacuated glass ampoule; cooling, removal of solvent, treatment with petroleum ether, evapn. of etheral extracts;96%
triphenylantmony dibromide

triphenylantmony dibromide

pentaphenylbismuth
3049-07-8

pentaphenylbismuth

A

bromobenzene
108-86-1

bromobenzene

B

triphenylbismuthane
603-33-8

triphenylbismuthane

C

tetraphenylantimony(V) bromide
16894-69-2

tetraphenylantimony(V) bromide

Conditions
ConditionsYield
In toluene 0.5 h, 20°C; solvent and bromobenzene removing, crystals washing (petroleum ether) and drying, Ph4SbBr in residue, Ph3Bi in petroleum ether soln.;A n/a
B 96%
C 86%
3,5-Di-tert-butylphenol
1138-52-9

3,5-Di-tert-butylphenol

4-nitrophenoxytetraphenylbismuth
105071-86-1

4-nitrophenoxytetraphenylbismuth

A

4-nitrophenyl phenyl ether
620-88-2

4-nitrophenyl phenyl ether

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
With 1,1-Diphenylethylene In toluene stirring mixt. in toluene for 5 h under Ar under reflux; removal of solvent, column chromy. of residue (hexane);A 96%
B 70%
In toluene stirring mixt. in toluene for 5 h under Ar under reflux; removal of solvent, column chromy. of residue (hexane);A 95%
B 79%
diphenylbismuth 4-methylbenzenesulfonate
108858-14-6

diphenylbismuth 4-methylbenzenesulfonate

pentaphenylantimony
2170-05-0

pentaphenylantimony

A

tetraphenylantimony 4-methylbenzenesulfonate
104316-53-2, 481073-75-0

tetraphenylantimony 4-methylbenzenesulfonate

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In diethyl ether mixt. of Ph5Sb and Bi sulfonate in ether kept for 48 h at 20°C; ppt. filtered, washed (hexane), dried; ethereal and hexane soln. evapd.,recrystd. from EtOH;A 93%
B 96%
triphenylbismuthane
603-33-8

triphenylbismuthane

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With triethylamine; palladium diacetate In N,N,N,N,N,N-hexamethylphosphoric triamide at 65℃; for 0.166667h;100%
With para-bromotoluene; C22H25ClNPPdS; potassium carbonate In 1,4-dioxane at 100℃; for 6h; Inert atmosphere; Schlenk technique;48%
With 2-thioxo-3H-1,3-benzothiazole; copper diacetate; bis(dibenzylideneacetone)-palladium(0) In 1,2-dichloro-ethane at 80℃; for 24h; Inert atmosphere;19 %Chromat.
N-ethylbenzimidazolinone
10045-45-1

N-ethylbenzimidazolinone

triphenylbismuthane
603-33-8

triphenylbismuthane

1-ethyl-3-phenyl-1,3-dihydro-2H-benzo[d]imidazol-2-one

1-ethyl-3-phenyl-1,3-dihydro-2H-benzo[d]imidazol-2-one

Conditions
ConditionsYield
With copper diacetate; triethylamine In dichloromethane for 23h; Ambient temperature;100%
triphenylbismuthane
603-33-8

triphenylbismuthane

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

rel-(1S,4R)-2-phenyl-2-azabicyclo[2.2.1]hept-5-en-3-one
186586-76-5

rel-(1S,4R)-2-phenyl-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With copper diacetate; triethylamine In dichloromethane for 24h; Ambient temperature;100%
triphenylbismuthane
603-33-8

triphenylbismuthane

tri-tert-butyl hydrazine-1,1,2-tricarboxylate
185456-26-2

tri-tert-butyl hydrazine-1,1,2-tricarboxylate

1,1,2-tris(tert-butoxycarbonyl)-2-phenylhydrazine
312934-60-4

1,1,2-tris(tert-butoxycarbonyl)-2-phenylhydrazine

Conditions
ConditionsYield
With copper diacetate; triethylamine In dichloromethane at 20℃; for 23h; Arylation;100%
triphenylbismuthane
603-33-8

triphenylbismuthane

tert-butyl 2-(4-nitrophenyl)diazenecarboxylate
92722-14-0

tert-butyl 2-(4-nitrophenyl)diazenecarboxylate

tert-butyl 2-(4-nitrophenyl)-2-phenylhydrazinecarboxylate

tert-butyl 2-(4-nitrophenyl)-2-phenylhydrazinecarboxylate

Conditions
ConditionsYield
With methanol; copper diacetate In acetonitrile at 70℃; for 0.0833333h;100%
tert-butyl 2-(4-methylphenyl)azocarboxylate
773893-07-5

tert-butyl 2-(4-methylphenyl)azocarboxylate

triphenylbismuthane
603-33-8

triphenylbismuthane

N'-phenyl-N'-p-tolyl-hydrazinecarboxylic acid tert-butyl ester

N'-phenyl-N'-p-tolyl-hydrazinecarboxylic acid tert-butyl ester

Conditions
ConditionsYield
With methanol; copper diacetate In acetonitrile at 70℃; for 0.0833333h;100%
di-tert-butyl-diazodicarboxylate
870-50-8

di-tert-butyl-diazodicarboxylate

triphenylbismuthane
603-33-8

triphenylbismuthane

di-tert-butyl 1-phenylhydrazine-1,2-dicarboxylate
65578-58-7

di-tert-butyl 1-phenylhydrazine-1,2-dicarboxylate

Conditions
ConditionsYield
With copper diacetate; 1,1,1,3',3',3'-hexafluoro-propanol In acetonitrile at 75℃; for 0.25h;100%
trimethylamine hydrochloride
593-81-7

trimethylamine hydrochloride

triphenylbismuthane
603-33-8

triphenylbismuthane

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);;100%
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);;100%
Iodine monochloride
7790-99-0

Iodine monochloride

triphenylbismuthane
603-33-8

triphenylbismuthane

diphenylbismuth(III) chloride
5153-28-6

diphenylbismuth(III) chloride

Conditions
ConditionsYield
In diethyl ether byproducts: C6H5I;100%
In diethyl ether byproducts: C6H5I;100%
byproducts: C6H5I;
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

triphenylbismuthane
603-33-8

triphenylbismuthane

diphenylbismuth(III) chloride
5153-28-6

diphenylbismuth(III) chloride

Conditions
ConditionsYield
In diethyl ether 20°C;100%
In diethyl ether 20°C;100%
In toluene; xylene 30 min reflux;97%
N,N,N,N,N,N-hexamethylphosphoric triamide
680-31-9

N,N,N,N,N,N-hexamethylphosphoric triamide

trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

triphenylbismuthane
603-33-8

triphenylbismuthane

diphenylbismuth triflate - (hexamethylphosphoric triamide)2 complex

diphenylbismuth triflate - (hexamethylphosphoric triamide)2 complex

Conditions
ConditionsYield
In methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane Ar-atmosphere; mixing BiAr3, 2 equivs. of HMPA and 1 equiv. of Me3SiOTf at 0°C, stirring for 0.5-2 h at room temp.; evapn.; elem. anal.;100%
1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione
22767-90-4

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione

triphenylbismuthane
603-33-8

triphenylbismuthane

Bi(3+)*3F3CCOCHCOC(CH3)3(1-)=Bi(F3CCOCHCOC(CH3)3)3

Bi(3+)*3F3CCOCHCOC(CH3)3(1-)=Bi(F3CCOCHCOC(CH3)3)3

Conditions
ConditionsYield
In neat (no solvent) byproducts: C6H6; Distn.; Evapn. in vac., vac. sublimation, elem. anal.;100%
triphenylbismuthane
603-33-8

triphenylbismuthane

triphenylbismuth oxalate
97068-77-4

triphenylbismuth oxalate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; oxalic acid In diethyl ether byproducts: (CH3)3COH, H2O; molar ratio Bi(C6H5)3:C4H9OOH:acid = 1:1:1; stirred at room temp. for one day; liquid part distd. off at a reduced pressure, product recrystd. from ethyl acetate; elem. anal.;100%
triphenylbismuthane
603-33-8

triphenylbismuthane

triphenylbismuth(V) diacetate
28899-97-0

triphenylbismuth(V) diacetate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; acetic acid In diethyl ether byproducts: (CH3)3COH, H2O; molar ratio Bi(C6H5)3:(CH3)3COOH:CH3COOH = 1:1:2; stirred at room temp.for one day; liquid distd. off at a reduced pressure, product recrystd. from ethyl acetate, elem. anal.;100%
Multi-step reaction with 2 steps
1: Chloramin T / acetonitrile
2: CH3COOH
View Scheme
With ozone; ethyl acetate In ethyl acetate ethyl acetate satd. with ozone at -78°C; warmed to ambient temp.; BiPh3 added; soln. evapd. in vac.; quant. recovery of unchanged BiPh3;0%

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