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inquiryProduct Name: Bismuth trichloride Synonyms: BisuMuth trichloride;BisuMuth(Ⅲ) chloride;BisMuth(III) chloride, 99.999% (Metals basis);Bismuth(III) chloride anhydrous, powder, 99.999% trace metals basis;Bismuth(III) chloride reagent grade, >=98%;B
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inquiryBismuth chloride CAS: 7787-60-2 Specification Test Item Standard: USP Identification IR spectrum similar to that of RS HPLC retention time similar to that of RS Related substan
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Bismuth trichloride Basic information Product Name: Bismuth trichloride Synonyms: BisuMuth trichloride;BisuMuth(Ⅲ) chloride;Bismuth(III) chloride anhydrous, powder, 99.999% trace metals basis;Bismuth(III) chloride reagent grade, >=98%;Bismu
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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inquiryProduct Introduction: Bismuth chloride (BiCl3) CAS number: 7787-60-2 Purity: 4N (99.99%), 5N (99.999%) Physical properties: White powder Overview Bismuth chloride (BiCl3) CAS number: 7787-60-2 Purity: 4N (99.99%), 5N (99.999%) Physical prope
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inquiryOur clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Conditions | Yield |
---|---|
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);; | 100% |
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);; | 100% |
Conditions | Yield |
---|---|
In acetic acid byproducts: H2O; | 100% |
In acetic acid byproducts: H2O; | 100% |
In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;; | > 99 |
In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;; | > 99 |
In perchloric acid aq. HClO4; prepn. by dissolving Bi2O3 in 6 M HCl; |
Conditions | Yield |
---|---|
heating Bi with S2Cl2 at 138.6°C, 10 hours;; | 100% |
addition of S2Cl2 to Bi;; | |
addition of S2Cl2 to Bi;; |
Conditions | Yield |
---|---|
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;; | 100% |
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;; | 100% |
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;; | 100% |
tri(naphthalen-1-yl)bismuth
A
naphthalene
B
1-benzoylnaphthalene
C
bismuth(III) chloride
Conditions | Yield |
---|---|
With aluminium trichloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:AlCl3:C6H5COOH = 1:1:1; | A 34% B 9.3% C 99% |
With iron(III) chloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:FeCl3:C6H5COOH = 1:1:1; | A 44% B 10.2% C 96% |
Conditions | Yield |
---|---|
With benzoic acid In chloroform molar ratio Bi(1-C10H7)3:C6H5COOH = 1:1; | A 49.1% B 98.4% |
With AlCl3 or FeCl3 In chloroform reflux; | A 36-46 B >97 |
thallium (III) chloride
tri(isopropenyl)bismuthane
B
bismuth(III) chloride
Conditions | Yield |
---|---|
In diethyl ether at -40°C; | A 98% B n/a |
Conditions | Yield |
---|---|
In ethanol High Pressure; mixing Bi2S3 and CuCl in ethanol, heating at 120°C for 2 d in autoclave, cooling to room temp.; filtration, washing with dild. HCl, water, ammonia, ethanol, drying in vac.; | A 82% B n/a |
hydrogenchloride
bismuth
molybdenum(V) chloride
B
bismuth(III) chloride
Conditions | Yield |
---|---|
In neat (no solvent) ampule with MoCl5 and Bi was heated to 230°C (2 h), to 350°C (2 h) and kept at 350°C for 12 h, cooled, homogenized and heated to 350°C (3 h) , reoriented and heated at 350°C for 24 h, cooled, treated with 12 M HCl; recrystn.; X-ray diffraction; | A 80% B n/a |
In neat (no solvent) ampule with MoCl5 and Bi in the end reaction chamber was heated to 230°C over 2 h and to 350°C over 2 h, ampule wasrepositioned toremove BiCl3 by sublimation and heated at 350°C for 24 h, cooled , treated with 12 M HCl and heated; recrystn.; X-ray diffraction; | A 58% B n/a |
Conditions | Yield |
---|---|
In melt ardent reaction of powdered Bi with molten ICl;; | 60% |
In melt ardent reaction of powdered Bi with molten ICl;; | 60% |
In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;; | |
In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;; |
triphenylbismuthane
triphenylbismuth dichloride
B
bismuth(III) chloride
Conditions | Yield |
---|---|
In chloroform byproducts: iodobenzene; 4.5 h; | A 59% B 32% |
In chloroform byproducts: iodobenzene; 4.5 h; | A 59% B 32% |
bismuth(III) chloride
Conditions | Yield |
---|---|
With sulphidic ore In neat (no solvent) addition of a small excess of NH4Cl to dry grinded sulphidic ore and heating at 300-400°C under 0.1-10 atm overpressure;; removing the gaseous reaction products constantly; purification by fractionated distillation under reduced pressure;; | |
With sulphidic ore In neat (no solvent) addition of a small excess of NH4Cl to dry grinded sulphidic ore and heating at 300-400°C under 0.1-10 atm overpressure;; removing the gaseous reaction products constantly; purification by fractionated distillation under reduced pressure;; |
trimethylamine hydrochloride
triphenylbismuthane
A
bismuth(III) chloride
B
benzene
Conditions | Yield |
---|---|
In neat (no solvent) 130°C; | A >99 B >99 |
In ethanol | A >99 B >99 |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: COS; heating at 350 °C;; | |
In neat (no solvent) byproducts: COS; passing stream of COCl2 over Bi2S3 at 350 °C;; | |
In neat (no solvent) byproducts: COS; heating at 350 °C;; |
Conditions | Yield |
---|---|
With oxygen; catalyst:NO(x) In hydrogenchloride Kinetics; byproducts: H2SO4, S; oxidation of Bi2S3 by O2 in aq. HCl/MgCl2/KI/HNO2, catalyst: nitrogen oxides, react. temp. 295-313 K; react. monitored potentiometric and by atomic absorption analysis and IR; |
Conditions | Yield |
---|---|
In neat (no solvent) at light read heat;; | |
In neat (no solvent) heated to red heat;; | |
In neat (no solvent) at light read heat;; | |
In neat (no solvent) heated to red heat;; |
Conditions | Yield |
---|---|
With thionyl chloride In neat (no solvent) byproducts: SO2; reaction between 150 and 200 °C;; | |
With thionyl chloride In neat (no solvent) byproducts: SO2; in the cold;; | 0% |
sulfur dioxide
bismuth(III) oxide
chlorine
D
bismuth(III) chloride
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; heating Bi2O3 in flow of SO2 and Cl2 (equimolar mixt. or excess Cl2) for30-120 min at 300-750°C; X-ray diffraction, thermogravimetry of products; product ratio dependingon reaction conditions; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: SO2; heated at 150-200 °C;; | |
In neat (no solvent) byproducts: SO2; heated at 150-200 °C;; | |
In neat (no solvent) 150°C;; |
bismuth(III) oxide
diselenium dichloride
A
selenium
B
selenium oxychloride
C
bismuth(III) chloride
bismuth(III) oxide
phosphorus trichloride
bismuth(III) chloride
Conditions | Yield |
---|---|
In neat (no solvent) formed in small yields;; | |
In neat (no solvent) formed in small yields;; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: AlOCl; heating a mixture of Bi2O3 and AlCl3 in vacuum at 300°C for 2 days;; | |
In neat (no solvent) byproducts: AlOCl; heating a mixture of Bi2O3 and AlCl3 in vacuum at 300°C for 2 days;; |
disulfur dichloride
bismuth(III) oxide
A
sulfur dioxide
B
bismuth(III) chloride
C
sulfur
Conditions | Yield |
---|---|
In neat (no solvent) heating starting material;; |
Conditions | Yield |
---|---|
In neat (no solvent) heating in a bomb at 138°C;; | |
addition of S2Cl2 to Bi2O3;; | |
In neat (no solvent) |
tetrachlorosilane
bismuth(III) oxide
bismuth(III) chloride
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: SiO2; 44 h heating in a closed tube at 270-280 °C gives no complete reaction;; | |
In neat (no solvent) byproducts: SiO2; heating in a tube at 370-380 °C;; | |
In neat (no solvent) heating;; | |
In neat (no solvent) byproducts: SiO2; heating in a tube at 370-380 °C;; | |
In neat (no solvent) heating;; |
Conditions | Yield |
---|---|
In further solvent(s) byproducts: C6H5COOH; solution of Bi2O3 in C6H5COCl with formation of BiCl3;; | |
In further solvent(s) byproducts: C6H5COOH; solution of Bi2O3 in C6H5COCl with formation of BiCl3;; |
Conditions | Yield |
---|---|
In melt byproducts: AlOCl; heating a mixture of Bi2O3 and gaseous Al2Cl6 in a closed tube at 300°C for 2 days;; evaporation of BiCl3/Al2Cl6 (separation from AlOCl);; | |
In melt byproducts: AlOCl; heating a mixture of Bi2O3 and gaseous Al2Cl6 in a closed tube at 300°C for 2 days;; evaporation of BiCl3/Al2Cl6 (separation from AlOCl);; |
Conditions | Yield |
---|---|
In melt byproducts: pyridine, H2O; solution in molten C5H5N*HCl with formation of BiCl3;; | |
In melt byproducts: pyridine, H2O; solution in molten C5H5N*HCl with formation of BiCl3;; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: Bi3O2Cl3; heating in dry Cl-stream;; | |
In neat (no solvent) byproducts: O2; prepn. by flow method; Bi2O3 placed to a heated tubular reactor with inert gas passing through it; after achieving a given temp. inert gas flow replaced by flow of Cl2; linear gas speed was 0.02-0.05 m/s; temp. was 550-750°C; volatiles trapped in cooled traps; monitored by X-ray diffraction and chem. analysis; | |
In neat (no solvent) byproducts: Bi3O2Cl3; heating in dry Cl-stream;; |
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; at 25-460°C; |
bismuth(III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In hydrogenchloride formation of BiCl4(1-) in aq. HCl solution at 25°C; various HCl- and BiCl3 concentrations;; | 100% |
With hydrogenchloride In hydrogenchloride solution of BiCl3 in aq. HCl (ionic strength 1 or 2); formation of 3 chloro complexes besides BiCl4(1-);; | |
With hydrogenchloride In hydrogenchloride formation of BiCl4(1-) in aq. HCl solution, stabilized by H(1+) and Cl(1-);; |
bismuth(III) chloride
triphenylbismuthane
diphenylbismuth(III) chloride
Conditions | Yield |
---|---|
In diethyl ether 20°C; | 100% |
In diethyl ether 20°C; | 100% |
In toluene; xylene 30 min reflux; | 97% |
Conditions | Yield |
---|---|
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;; | 100% |
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;; | 100% |
bismuth-tri(diethylphosphoro dithioate)
bismuth(III) chloride
monochlorobismuth(III) bis(diethyldithiophosphate)
Conditions | Yield |
---|---|
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.; | 100% |
bismuth(III) chloride
monochlorobismuth(III) bis(diisobutyldithiophosphate)
Conditions | Yield |
---|---|
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran Ar atm.; equimolar ratio LiCl:BiCl3, stirring (30 min); concn., layering (Et2O), cooling (-7°C, 12 h); | 100% |
Conditions | Yield |
---|---|
In chloroform reflux under CO2; | 99% |
In chloroform reflux under CO2; | 99% |
tetrahydrofuran
bismuth(III) chloride
bismuth trichloride, tetrahydrofuran adduct
Conditions | Yield |
---|---|
In tetrahydrofuran absence of O2 and moisture; dissoln. of Bi-salt in mimimum THF; filtration, layering with hexanes, crystn. (-30°C, several d); | 99% |
2-aminocyclopent-1-ene-1-carbodithioic acid
bismuth(III) chloride
Bi(C5H6CSSNH2)3
Conditions | Yield |
---|---|
In ethanol reactn. of soln. of BiCl3 with soln. of ligand (room temp.), pptn.; filtration, washed (ethanol), dried (air); | 99% |
In benzene byproducts: NaCl; A soln. of BiCl3 is added to a suspn. of sodium salt of aminocyclopentene compd. with constant stirring, refluxed for 2 h, NaCl is filtered; Filtrate is concentrated, recrystd. from benzene-hexane, elem. anal.; | 95% |
1,1-dibutyl-2,5-bis(methylene)stannolane
bismuth(III) chloride
1-chloro-2,5-bis(methylene)bismolane
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: n-Bu2SnCl2; THF soln. of BiCl3 was added to the stannolane at 0°C; solvent was removed under vac. at 0°C, residue was washed with pentane, dissolved in THF, filtered, evapd. at 0°C; | 99% |
bismuth(III) tris(diisopropyldithiophosphate)
bismuth(III) chloride
monochlorobismuth(III) bis(diisopropyldithiophosphate)
Conditions | Yield |
---|---|
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.; | 99% |
trimethylsilyldimesylamine
bismuth(III) chloride
Conditions | Yield |
---|---|
In dichloromethane; ethyl acetate byproducts: Me3SiCl; inert atm.; refluxing (2 h); filtn., drying (vac.); elem. anal.; | 99% |
In dichloromethane; ethyl acetate inert atm.; 16 h, 20°C, molar ratio BiCl3:silylamine 1.5:1; | |
In dichloromethane; ethyl acetate inert atm.; molar ratio BiCl3:silylamine 1:3, 2 d 20°C, refluxng (10 h); | |
In ethyl acetate inert atm.; refluxing (3 h), molar ratio BiCl3:silylamine 1:1; |
2-ethylamino-1-cyclopentene-1-dithiocarboxylic acid
bismuth(III) chloride
tris{2-(ethylamino)cyclopent-1-ene-1-dithiocarboxylato}bismuth(III)
Conditions | Yield |
---|---|
In ethanol reactn. of soln. of BiCl3 with soln. of ligand (room temp.), pptn.; filtration, washed (ethanol), dried (air); | 98% |
In benzene byproducts: NaCl; A soln. of BiCl3 is added to a suspn. of sodium salt of aminocyclopentene compd. with constant stirring, refluxed for 2 h, NaCl is filtered; Filtrate is concentrated, recrystd. from benzene-hexane, elem. anal.; | 96% |
bismuth(III) chloride
dichlorobismuth(III) diisobutyldithiophosphate
Conditions | Yield |
---|---|
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 2:1), heating (1 h, 50-60°C); removal of solvent; elem. anal.; | 98% |
Conditions | Yield |
---|---|
In benzene byproducts: KCl; to suspn. of BiCl3 in benzene was added KAl-complex, stirred at room temp. for 8 h; filtered, volatiles were removed under reduced pressure; elem. anal.; | 98% |
3,5,7-tris(morpholinomethyl)tropolone
bismuth(III) chloride
Conditions | Yield |
---|---|
With morpholine In ethanol addn. of BiCl3 soln. to refluxing soln. of tropolone compound and morpholine, reflux (10 min); centrifugation of hot soln., decantation, filtration, reflux of filtrate(3 min), crystn. on slow cooling to room temp., filtration, washing (et hanol), drying (vacuum over P4O10); elem. anal.; | 98% |
Conditions | Yield |
---|---|
In methanol High Pressure; mixing BiCl3, N compd., addn. of methanol and HCl (36 %), heating in autoclave (6 h, from 25 to 150°C, then 13 h at 150°C), cooling over 10 h to 25°C; filtration, washing with methanol, XRD; | 98% |
Conditions | Yield |
---|---|
With sodium In ethanol; water Addn. of Na to ethanol at 263 K, dropwise addn. of amine and CS2, slow addn. of BiCl3; yellow solid pptd., filtered and dried in vacuo, diisolved in hot acetone and crystn.; | 97% |
Hexamethylbenzene
bismuth(III) chloride
((hexamethylbenzene)bis[trichlorobismuth(III)])n
Conditions | Yield |
---|---|
In toluene under dry N2, soln. of BiCl3 and C6Me6 in toluene is heated until boiling; slowly cooling; elem. anal.; | 97% |
In toluene BiCl3 is added to soln. of C6(CH3)6 in toluene and heated to 60°C; filtn.; | 92% |
Conditions | Yield |
---|---|
In benzene byproducts: KCl; to suspn. of BiCl3 in benzene was added KAl-complex and KOiPr, stirred at room temp. for 8 h; filtered, volatiles were removed under reduced pressure; elem. anal.; | 97% |
bismuth(III) chloride
2-(N,N-dimethylamino)ethylthiol hydrochloride
Conditions | Yield |
---|---|
In tetrahydrofuran; ethanol pptn.; recrystn. (water); elem. anal.; | 97% |
Conditions | Yield |
---|---|
In tetrahydrofuran; toluene byproducts: MgCl2, anthracene, THF; Ar atmosphere, stirring of suspn. of Mg compound in toluene at room temp. (24 h), decantation of solvent, addn. of THF, addn. of BiCl3, stirring(room temp., 48 h); filtration, washing (THF, pentane), drying (0.1-0.2 mbar); elem. anal.; | 97% |
bismuth(III) chloride
2-(N,N-dimethylamino)ethylthiol hydrochloride
BiCl3(SCH2CH2N(CH3)2H)
Conditions | Yield |
---|---|
In tetrahydrofuran; ethanol (N2); elem. anal.; | 97% |
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