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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Bismuth trichloride

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Bismuth Trichloride supplier in China

Cas:7787-60-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Bismuth Trichloride

Cas:7787-60-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Bismuth trichloride

Cas:7787-60-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: Bismuth trichloride Synonyms: BisuMuth trichloride;BisuMuth(Ⅲ) chloride;BisMuth(III) chloride, 99.999% (Metals basis);Bismuth(III) chloride anhydrous, powder, 99.999% trace metals basis;Bismuth(III) chloride reagent grade, >=98%;B

7787-60-2 Bismuth trichloride

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $300.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 7787-60-2 with best quality

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bismuthine, trichloro- 7787-60-2

Cas:7787-60-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

catalyst, Bismuth trichloride CAS:7787-60-2

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $43.0 / 48.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Bismuth trichloride CAS:7787-60-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

Bismuth trichloride CAS:7787-60-2

Cas:7787-60-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bismuthine, trichloro-

Cas:7787-60-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:7787-60-2

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Bismuth(III) chloride

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $460.0 / 500.0

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Bismuth chloride CAS: 7787-60-2 Specification Test Item Standard: USP Identification IR spectrum similar to that of RS HPLC retention time similar to that of RS Related substan

Factory supply Bismuth chloride

Cas:7787-60-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

Bismuth trichloride CAS NO.7787-60-2

Cas:7787-60-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bismuthine, trichloro-

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Bismuth Trichloride

Cas:7787-60-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

Bismuth chloride

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $30.0 / 35.0

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Bismuthtrichloride

Cas:7787-60-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Bismuth trichloride Basic information Product Name: Bismuth trichloride Synonyms: BisuMuth trichloride;BisuMuth(Ⅲ) chloride;Bismuth(III) chloride anhydrous, powder, 99.999% trace metals basis;Bismuth(III) chloride reagent grade, >=98%;Bismu

Bismuth trichloride

Cas:7787-60-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Bismuth trichloride CAS NO.7787-60-2

Cas:7787-60-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Bismuth trichloride CAS NO.7787-60-2

Cas:7787-60-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Bismuth trichloride CAS NO.7787-60-2

Cas:7787-60-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Bismuth trichloride CAS NO.7787-60-2

Cas:7787-60-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

Bismuth Chloride

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Bismuth(III) Chloride, Anhydrous

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Bismuth trichloride

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Bismuth Chloride 500g

Cas:7787-60-2

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Leshan Kairuida Photoelectric Technology Co., Ltd.

Product Introduction: Bismuth chloride (BiCl3) CAS number: 7787-60-2 Purity: 4N (99.99%), 5N (99.999%) Physical properties: White powder Overview Bismuth chloride (BiCl3) CAS number: 7787-60-2 Purity: 4N (99.99%), 5N (99.999%) Physical prope

Bismuth Chloride

Cas:7787-60-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

BisMuth(III) Chloride Anhydrous [for General Organic CheMistry]

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Bismuth Trichloride

Cas:7787-60-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

trimethylamine hydrochloride
593-81-7

trimethylamine hydrochloride

triphenylbismuthane
603-33-8

triphenylbismuthane

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);;100%
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);;100%
hydrogenchloride
7647-01-0

hydrogenchloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In acetic acid byproducts: H2O;100%
In acetic acid byproducts: H2O;100%
In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;;> 99
In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;;> 99
In perchloric acid aq. HClO4; prepn. by dissolving Bi2O3 in 6 M HCl;
disulfur dichloride
10025-67-9

disulfur dichloride

bismuth
7440-69-9

bismuth

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
heating Bi with S2Cl2 at 138.6°C, 10 hours;;100%
addition of S2Cl2 to Bi;;
addition of S2Cl2 to Bi;;
bismuth
7440-69-9

bismuth

chlorine
7782-50-5

chlorine

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;100%
tri(naphthalen-1-yl)bismuth
33397-22-7

tri(naphthalen-1-yl)bismuth

A

naphthalene
91-20-3

naphthalene

B

1-benzoylnaphthalene
642-29-5

1-benzoylnaphthalene

C

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
With aluminium trichloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:AlCl3:C6H5COOH = 1:1:1;A 34%
B 9.3%
C 99%
With iron(III) chloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:FeCl3:C6H5COOH = 1:1:1;A 44%
B 10.2%
C 96%
tri(naphthalen-1-yl)bismuth
33397-22-7

tri(naphthalen-1-yl)bismuth

A

naphthalene
91-20-3

naphthalene

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
With benzoic acid In chloroform molar ratio Bi(1-C10H7)3:C6H5COOH = 1:1;A 49.1%
B 98.4%
With AlCl3 or FeCl3 In chloroform reflux;A 36-46
B >97
thallium (III) chloride
13453-32-2

thallium (III) chloride

tri(isopropenyl)bismuthane
93690-72-3

tri(isopropenyl)bismuthane

A

(CH2C(CH3))TlCl

(CH2C(CH3))TlCl

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In diethyl ether at -40°C;A 98%
B n/a
bismuth(III) sulfide

bismuth(III) sulfide

copper(l) chloride

copper(l) chloride

copper(I) sulfide

copper(I) sulfide

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In ethanol High Pressure; mixing Bi2S3 and CuCl in ethanol, heating at 120°C for 2 d in autoclave, cooling to room temp.; filtration, washing with dild. HCl, water, ammonia, ethanol, drying in vac.;A 82%
B n/a
hydrogenchloride
7647-01-0

hydrogenchloride

bismuth
7440-69-9

bismuth

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

A

(H3O)2(octa-μ3-chloro-hexachloro-octahedrohexamolybdate)*6(water)

(H3O)2(octa-μ3-chloro-hexachloro-octahedrohexamolybdate)*6(water)

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) ampule with MoCl5 and Bi was heated to 230°C (2 h), to 350°C (2 h) and kept at 350°C for 12 h, cooled, homogenized and heated to 350°C (3 h) , reoriented and heated at 350°C for 24 h, cooled, treated with 12 M HCl; recrystn.; X-ray diffraction;A 80%
B n/a
In neat (no solvent) ampule with MoCl5 and Bi in the end reaction chamber was heated to 230°C over 2 h and to 350°C over 2 h, ampule wasrepositioned toremove BiCl3 by sublimation and heated at 350°C for 24 h, cooled , treated with 12 M HCl and heated; recrystn.; X-ray diffraction;A 58%
B n/a
bismuth
7440-69-9

bismuth

Iodine monochloride
7790-99-0

Iodine monochloride

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In melt ardent reaction of powdered Bi with molten ICl;;60%
In melt ardent reaction of powdered Bi with molten ICl;;60%
In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;;
In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;;
triphenylbismuthane
603-33-8

triphenylbismuthane

triphenylbismuth dichloride
28719-54-2, 507233-69-4, 594-30-9

triphenylbismuth dichloride

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In chloroform byproducts: iodobenzene; 4.5 h;A 59%
B 32%
In chloroform byproducts: iodobenzene; 4.5 h;A 59%
B 32%
ammonium chloride

ammonium chloride

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
With sulphidic ore In neat (no solvent) addition of a small excess of NH4Cl to dry grinded sulphidic ore and heating at 300-400°C under 0.1-10 atm overpressure;; removing the gaseous reaction products constantly; purification by fractionated distillation under reduced pressure;;
With sulphidic ore In neat (no solvent) addition of a small excess of NH4Cl to dry grinded sulphidic ore and heating at 300-400°C under 0.1-10 atm overpressure;; removing the gaseous reaction products constantly; purification by fractionated distillation under reduced pressure;;
trimethylamine hydrochloride
593-81-7

trimethylamine hydrochloride

triphenylbismuthane
603-33-8

triphenylbismuthane

A

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) 130°C;A >99
B >99
In ethanolA >99
B >99
phosgene
75-44-5

phosgene

bismuth(III) sulfide

bismuth(III) sulfide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: COS; heating at 350 °C;;
In neat (no solvent) byproducts: COS; passing stream of COCl2 over Bi2S3 at 350 °C;;
In neat (no solvent) byproducts: COS; heating at 350 °C;;
hydrogenchloride
7647-01-0

hydrogenchloride

bismuth(III) sulfide

bismuth(III) sulfide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
With oxygen; catalyst:NO(x) In hydrogenchloride Kinetics; byproducts: H2SO4, S; oxidation of Bi2S3 by O2 in aq. HCl/MgCl2/KI/HNO2, catalyst: nitrogen oxides, react. temp. 295-313 K; react. monitored potentiometric and by atomic absorption analysis and IR;
bismuth(III) sulfide

bismuth(III) sulfide

chlorine
7782-50-5

chlorine

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) at light read heat;;
In neat (no solvent) heated to red heat;;
In neat (no solvent) at light read heat;;
In neat (no solvent) heated to red heat;;
bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
With thionyl chloride In neat (no solvent) byproducts: SO2; reaction between 150 and 200 °C;;
With thionyl chloride In neat (no solvent) byproducts: SO2; in the cold;;0%
sulfur dioxide
7446-09-5

sulfur dioxide

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

chlorine
7782-50-5

chlorine

A

bismuth (III) oxychloride

bismuth (III) oxychloride

B

bismuth(III) sulfate

bismuth(III) sulfate

C

bismuth(III) sulfide

bismuth(III) sulfide

D

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; heating Bi2O3 in flow of SO2 and Cl2 (equimolar mixt. or excess Cl2) for30-120 min at 300-750°C; X-ray diffraction, thermogravimetry of products; product ratio dependingon reaction conditions;
thionyl chloride
7719-09-7

thionyl chloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: SO2; heated at 150-200 °C;;
In neat (no solvent) byproducts: SO2; heated at 150-200 °C;;
In neat (no solvent) 150°C;;
bismuth(III) oxide
1304-76-3

bismuth(III) oxide

diselenium dichloride
10025-68-0

diselenium dichloride

A

selenium
7782-49-2

selenium

B

selenium oxychloride
7791-23-3

selenium oxychloride

C

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) formed in small yields;;
In neat (no solvent) formed in small yields;;
aluminium trichloride
7446-70-0

aluminium trichloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: AlOCl; heating a mixture of Bi2O3 and AlCl3 in vacuum at 300°C for 2 days;;
In neat (no solvent) byproducts: AlOCl; heating a mixture of Bi2O3 and AlCl3 in vacuum at 300°C for 2 days;;
disulfur dichloride
10025-67-9

disulfur dichloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

A

sulfur dioxide
7446-09-5

sulfur dioxide

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

C

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
In neat (no solvent) heating starting material;;
disulfur dichloride
10025-67-9

disulfur dichloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating in a bomb at 138°C;;
addition of S2Cl2 to Bi2O3;;
In neat (no solvent)
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: SiO2; 44 h heating in a closed tube at 270-280 °C gives no complete reaction;;
In neat (no solvent) byproducts: SiO2; heating in a tube at 370-380 °C;;
In neat (no solvent) heating;;
In neat (no solvent) byproducts: SiO2; heating in a tube at 370-380 °C;;
In neat (no solvent) heating;;
bismuth(III) oxide
1304-76-3

bismuth(III) oxide

benzoyl chloride
98-88-4

benzoyl chloride

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In further solvent(s) byproducts: C6H5COOH; solution of Bi2O3 in C6H5COCl with formation of BiCl3;;
In further solvent(s) byproducts: C6H5COOH; solution of Bi2O3 in C6H5COCl with formation of BiCl3;;
aluminium chloride dimer

aluminium chloride dimer

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In melt byproducts: AlOCl; heating a mixture of Bi2O3 and gaseous Al2Cl6 in a closed tube at 300°C for 2 days;; evaporation of BiCl3/Al2Cl6 (separation from AlOCl);;
In melt byproducts: AlOCl; heating a mixture of Bi2O3 and gaseous Al2Cl6 in a closed tube at 300°C for 2 days;; evaporation of BiCl3/Al2Cl6 (separation from AlOCl);;
pyridine hydrochloride
628-13-7

pyridine hydrochloride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In melt byproducts: pyridine, H2O; solution in molten C5H5N*HCl with formation of BiCl3;;
In melt byproducts: pyridine, H2O; solution in molten C5H5N*HCl with formation of BiCl3;;
bismuth(III) oxide
1304-76-3

bismuth(III) oxide

chlorine
7782-50-5

chlorine

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Bi3O2Cl3; heating in dry Cl-stream;;
In neat (no solvent) byproducts: O2; prepn. by flow method; Bi2O3 placed to a heated tubular reactor with inert gas passing through it; after achieving a given temp. inert gas flow replaced by flow of Cl2; linear gas speed was 0.02-0.05 m/s; temp. was 550-750°C; volatiles trapped in cooled traps; monitored by X-ray diffraction and chem. analysis;
In neat (no solvent) byproducts: Bi3O2Cl3; heating in dry Cl-stream;;
bismuth(III) oxide
1304-76-3

bismuth(III) oxide

chlorine
7782-50-5

chlorine

A

bismuth (III) oxychloride

bismuth (III) oxychloride

B

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; at 25-460°C;
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

tetrachlorobismuth (1-)

tetrachlorobismuth (1-)

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride formation of BiCl4(1-) in aq. HCl solution at 25°C; various HCl- and BiCl3 concentrations;;100%
With hydrogenchloride In hydrogenchloride solution of BiCl3 in aq. HCl (ionic strength 1 or 2); formation of 3 chloro complexes besides BiCl4(1-);;
With hydrogenchloride In hydrogenchloride formation of BiCl4(1-) in aq. HCl solution, stabilized by H(1+) and Cl(1-);;
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

triphenylbismuthane
603-33-8

triphenylbismuthane

diphenylbismuth(III) chloride
5153-28-6

diphenylbismuth(III) chloride

Conditions
ConditionsYield
In diethyl ether 20°C;100%
In diethyl ether 20°C;100%
In toluene; xylene 30 min reflux;97%
acetyl iodide
507-02-8

acetyl iodide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

bismuth(III) iodide
7787-64-6

bismuth(III) iodide

Conditions
ConditionsYield
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;100%
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;100%
bismuth-tri(diethylphosphoro dithioate)
3911-04-4, 21312-75-4

bismuth-tri(diethylphosphoro dithioate)

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

monochlorobismuth(III) bis(diethyldithiophosphate)
89928-33-6, 1010422-09-9

monochlorobismuth(III) bis(diethyldithiophosphate)

Conditions
ConditionsYield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.;100%
bismuth(III) tris(diisobutyldithiophosphate)

bismuth(III) tris(diisobutyldithiophosphate)

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

monochlorobismuth(III) bis(diisobutyldithiophosphate)
89928-37-0

monochlorobismuth(III) bis(diisobutyldithiophosphate)

Conditions
ConditionsYield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

lithium chloride

lithium chloride

bis[tetrakis(tetrahydrofuran-O)lithium(I)] diμ-chloro-bis[trichloro(tetrahydrofuran-O)bismuthate(III)]

bis[tetrakis(tetrahydrofuran-O)lithium(I)] diμ-chloro-bis[trichloro(tetrahydrofuran-O)bismuthate(III)]

Conditions
ConditionsYield
In tetrahydrofuran Ar atm.; equimolar ratio LiCl:BiCl3, stirring (30 min); concn., layering (Et2O), cooling (-7°C, 12 h);100%
triphenylantimony
603-36-1

triphenylantimony

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

diphenylantimony(III) chloride
2629-47-2

diphenylantimony(III) chloride

Conditions
ConditionsYield
In chloroform reflux under CO2;99%
In chloroform reflux under CO2;99%
tetrahydrofuran
109-99-9

tetrahydrofuran

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

bismuth trichloride, tetrahydrofuran adduct
70650-04-3

bismuth trichloride, tetrahydrofuran adduct

Conditions
ConditionsYield
In tetrahydrofuran absence of O2 and moisture; dissoln. of Bi-salt in mimimum THF; filtration, layering with hexanes, crystn. (-30°C, several d);99%
2-aminocyclopent-1-ene-1-carbodithioic acid
20735-33-5

2-aminocyclopent-1-ene-1-carbodithioic acid

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Bi(C5H6CSSNH2)3
107556-45-6

Bi(C5H6CSSNH2)3

Conditions
ConditionsYield
In ethanol reactn. of soln. of BiCl3 with soln. of ligand (room temp.), pptn.; filtration, washed (ethanol), dried (air);99%
In benzene byproducts: NaCl; A soln. of BiCl3 is added to a suspn. of sodium salt of aminocyclopentene compd. with constant stirring, refluxed for 2 h, NaCl is filtered; Filtrate is concentrated, recrystd. from benzene-hexane, elem. anal.;95%
1,1-dibutyl-2,5-bis(methylene)stannolane
108036-01-7

1,1-dibutyl-2,5-bis(methylene)stannolane

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

1-chloro-2,5-bis(methylene)bismolane
108036-02-8

1-chloro-2,5-bis(methylene)bismolane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: n-Bu2SnCl2; THF soln. of BiCl3 was added to the stannolane at 0°C; solvent was removed under vac. at 0°C, residue was washed with pentane, dissolved in THF, filtered, evapd. at 0°C;99%
bismuth(III) tris(diisopropyldithiophosphate)
42294-79-1

bismuth(III) tris(diisopropyldithiophosphate)

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

monochlorobismuth(III) bis(diisopropyldithiophosphate)
1010422-10-2, 89928-31-4

monochlorobismuth(III) bis(diisopropyldithiophosphate)

Conditions
ConditionsYield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.;99%
trimethylsilyldimesylamine
30488-04-1

trimethylsilyldimesylamine

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

bismuth(III)-bis(dimesylamide)chloride

bismuth(III)-bis(dimesylamide)chloride

Conditions
ConditionsYield
In dichloromethane; ethyl acetate byproducts: Me3SiCl; inert atm.; refluxing (2 h); filtn., drying (vac.); elem. anal.;99%
In dichloromethane; ethyl acetate inert atm.; 16 h, 20°C, molar ratio BiCl3:silylamine 1.5:1;
In dichloromethane; ethyl acetate inert atm.; molar ratio BiCl3:silylamine 1:3, 2 d 20°C, refluxng (10 h);
In ethyl acetate inert atm.; refluxing (3 h), molar ratio BiCl3:silylamine 1:1;
2-ethylamino-1-cyclopentene-1-dithiocarboxylic acid
34281-26-0

2-ethylamino-1-cyclopentene-1-dithiocarboxylic acid

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

tris{2-(ethylamino)cyclopent-1-ene-1-dithiocarboxylato}bismuth(III)
107556-46-7

tris{2-(ethylamino)cyclopent-1-ene-1-dithiocarboxylato}bismuth(III)

Conditions
ConditionsYield
In ethanol reactn. of soln. of BiCl3 with soln. of ligand (room temp.), pptn.; filtration, washed (ethanol), dried (air);98%
In benzene byproducts: NaCl; A soln. of BiCl3 is added to a suspn. of sodium salt of aminocyclopentene compd. with constant stirring, refluxed for 2 h, NaCl is filtered; Filtrate is concentrated, recrystd. from benzene-hexane, elem. anal.;96%
bismuth(III) tris(diisobutyldithiophosphate)

bismuth(III) tris(diisobutyldithiophosphate)

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

dichlorobismuth(III) diisobutyldithiophosphate
89928-38-1

dichlorobismuth(III) diisobutyldithiophosphate

Conditions
ConditionsYield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 2:1), heating (1 h, 50-60°C); removal of solvent; elem. anal.;98%
potassium tetraisopropoxyaluminate

potassium tetraisopropoxyaluminate

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Bi(Al(OC3H7)4)3
394219-44-4

Bi(Al(OC3H7)4)3

Conditions
ConditionsYield
In benzene byproducts: KCl; to suspn. of BiCl3 in benzene was added KAl-complex, stirred at room temp. for 8 h; filtered, volatiles were removed under reduced pressure; elem. anal.;98%
3,5,7-tris(morpholinomethyl)tropolone
33902-86-2

3,5,7-tris(morpholinomethyl)tropolone

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

tris(3,5,7-tris(morpholinomethyl)tropolonato)bismuth(III)

tris(3,5,7-tris(morpholinomethyl)tropolonato)bismuth(III)

Conditions
ConditionsYield
With morpholine In ethanol addn. of BiCl3 soln. to refluxing soln. of tropolone compound and morpholine, reflux (10 min); centrifugation of hot soln., decantation, filtration, reflux of filtrate(3 min), crystn. on slow cooling to room temp., filtration, washing (et hanol), drying (vacuum over P4O10); elem. anal.;98%
hydrogenchloride
7647-01-0

hydrogenchloride

methanol
67-56-1

methanol

water
7732-18-5

water

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

(MeNC5H4C5H4NMe)3[Bi4(chloride)18]*1.7(water)

(MeNC5H4C5H4NMe)3[Bi4(chloride)18]*1.7(water)

Conditions
ConditionsYield
In methanol High Pressure; mixing BiCl3, N compd., addn. of methanol and HCl (36 %), heating in autoclave (6 h, from 25 to 150°C, then 13 h at 150°C), cooling over 10 h to 25°C; filtration, washing with methanol, XRD;98%
carbon disulfide
75-15-0

carbon disulfide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

dibutylamine
111-92-2

dibutylamine

tris(di-n-butyldithiocarbamato)-bismuth(III)

tris(di-n-butyldithiocarbamato)-bismuth(III)

Conditions
ConditionsYield
With sodium In ethanol; water Addn. of Na to ethanol at 263 K, dropwise addn. of amine and CS2, slow addn. of BiCl3; yellow solid pptd., filtered and dried in vacuo, diisolved in hot acetone and crystn.;97%
Hexamethylbenzene
87-85-4

Hexamethylbenzene

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

((hexamethylbenzene)bis[trichlorobismuth(III)])n
103349-18-4

((hexamethylbenzene)bis[trichlorobismuth(III)])n

Conditions
ConditionsYield
In toluene under dry N2, soln. of BiCl3 and C6Me6 in toluene is heated until boiling; slowly cooling; elem. anal.;97%
In toluene BiCl3 is added to soln. of C6(CH3)6 in toluene and heated to 60°C; filtn.;92%
potassium tetraisopropoxyaluminate

potassium tetraisopropoxyaluminate

potassium isopropoxide
6831-82-9

potassium isopropoxide

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Bi(3+)*2Al(OC3H7)4(1-)*OC3H7(1-)=Bi(Al(OC3H7)4)2(OC3H7)

Bi(3+)*2Al(OC3H7)4(1-)*OC3H7(1-)=Bi(Al(OC3H7)4)2(OC3H7)

Conditions
ConditionsYield
In benzene byproducts: KCl; to suspn. of BiCl3 in benzene was added KAl-complex and KOiPr, stirred at room temp. for 8 h; filtered, volatiles were removed under reduced pressure; elem. anal.;97%
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

2-(N,N-dimethylamino)ethylthiol hydrochloride
13242-44-9

2-(N,N-dimethylamino)ethylthiol hydrochloride

Bi(3+)*3Cl(1-)*SC2H4NH(CH3)2=BiCl3SC2H4NH(CH3)2

Bi(3+)*3Cl(1-)*SC2H4NH(CH3)2=BiCl3SC2H4NH(CH3)2

Conditions
ConditionsYield
In tetrahydrofuran; ethanol pptn.; recrystn. (water); elem. anal.;97%
magnesium-anthracene-(THF)3
86901-19-1

magnesium-anthracene-(THF)3

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Mg1.51BiCl0.11C0.8H1.5

Mg1.51BiCl0.11C0.8H1.5

Conditions
ConditionsYield
In tetrahydrofuran; toluene byproducts: MgCl2, anthracene, THF; Ar atmosphere, stirring of suspn. of Mg compound in toluene at room temp. (24 h), decantation of solvent, addn. of THF, addn. of BiCl3, stirring(room temp., 48 h); filtration, washing (THF, pentane), drying (0.1-0.2 mbar); elem. anal.;97%
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

2-(N,N-dimethylamino)ethylthiol hydrochloride
13242-44-9

2-(N,N-dimethylamino)ethylthiol hydrochloride

BiCl3(SCH2CH2N(CH3)2H)
200342-37-6

BiCl3(SCH2CH2N(CH3)2H)

Conditions
ConditionsYield
In tetrahydrofuran; ethanol (N2); elem. anal.;97%

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