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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result MoCl5 ≥99.60 99.73 Mo ≥34.9780 35.018

High quality 10241-05-1 Molybdenum(V) chlorid

Cas:10241-05-1

Min.Order:1 Kilogram

FOB Price: $1300.0 / 1600.0

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Molybdenum(V) chloride

Cas:10241-05-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Molybdenum pentachloride

Cas:10241-05-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Molybdenum(V) chloride

Cas:10241-05-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Molybdenum chloride(MoCl5)

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Molybdenum Pentachloride CAS No.:10241-05-1 Molecule Formula:Cl5Mo Molecule Weight:273.21 Purity: 99.0% Package: 25kg/drum Description:Black crystalline powder Manufacture Standards:Enterprise Standard

Best Quality Molybdenum Pentachloride

Cas:10241-05-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

MOLYBDENUM(V) CHLORIDE CAS NO.: 10241-05-1

Cas:10241-05-1

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Molybdenum(V) chloride

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Molybdenum chloride(MoCl5)

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 10241-05-1 with competitive price

Cas:10241-05-1

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Molybdenum chloride(MoCl5)

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in or

Molybdenum (V) Chloride

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

10241-05-1

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Trading Company

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Phentex Corporation

Formula: MoCl5Molecular Weight : 273.20 Synonyms: Molybdenumpentachloride;Molybdenum(V) chloride;Pentachloromolybdenum; EINECS: 233-575-3Density: 2.928 g/mL at 25 °C(lit.)Melting Point:Boiling Point: 268 °C(lit.) Application:Catalysi

Molybdenum(V) chloride

Cas:10241-05-1

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Changsha Huajing Powdery Material Technological Co., Ltd.

Specification:Purity≥99%-99.99%,industrialgrade Property:TheappearanceofMoC15varieswiththephysic Appearance:dark crystal Storage:in shade,dark environment Package:10Kg/drum Application:Used as the component of chloridizing catalyst and fire-resi

Molybdenum pentachloride

Cas:10241-05-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Molybdinium Pentachloride

Cas:10241-05-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hebei Ruishun Trade Co.,Ltd

Hebei ruishun trade co.,ltd, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,seek development by credit reputation.our products have a large price advanta

Molybdenum(V) chloride CAS NO:10241-05-1

Cas:10241-05-1

Min.Order:10 Gram

FOB Price: $0.9 / 1.2

Type:Trading Company

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Shanghai Yingrui Biopharma Co., Ltd

1. factory price 2. high purity 3.DMF files 4. in stock 5. good service 6. we also provide the custom synthesis service 7. fast delivery SHANGHAI YINGRUI CHEMICAL TECHNOLOGY CO.,LTD. was established in 2009 ,is a research and developmen

10241-05-1 intermediates factory

Cas:10241-05-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Molybdenum chloride

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Other

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Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

MolybdenuM(V) chloride, 99.6% (Metals b

Cas:10241-05-1

Min.Order:1 Gram

Negotiable

Type:Other

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AOPHARM

Aopharm is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in modes of tran

MOLYBDENUM(V) CHLORIDE

Cas:10241-05-1

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Molybdenum chloride(MoCl5)

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Strem Chemicals, Inc.

1.High Quality Specialty Chemicals2.Expertise and Experience in Manufacturing High Purity, High Quality Chemicals3.Long Term Focus in Inorganics, Organometallics and Metals4.ISO 9001 CertifiedAppearance:dark blue xtl.

Molybdenum(V) chloride, anhydrous, 99.6%

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Other

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Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

MOLYBDENUM(V) CHLORIDE

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Trading Company

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Jiangxi shengwei chemical technology co. LTD

Jiangxi Shengwei Chemical Technology Co., Ltd.supplies scientific research products as below:1.High-purity organic chemical reagents;2.Analytical reagents; 3.Biochemical reagents;4.Chemical raw materials;5.Experimental instruments;6.Experimental cons

Molybdenum(V) chloride

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:please email us, thanks

MOLYBDENUM(V) CHLORIDE

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Other

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Skyrun Industrial Co.,Ltd

Purity, Prompt shipment, Price Application:surface active agent

CSR160805-25694

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical, ch

Molybdenum(V) chloride

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sparrow Chemical Co.,Ltd

Our company provides the best service for our customers. Under the premise of ensuring quality and delivery date, give customers the best price. The company is more willing to meet our customers. If you want to visit our factories and warehouses, we

MOLYBDENUM(V)CHLORIDE

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Trading Company

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Beantown Chemical

in stock Application:10241-05-1

Molybdenum(V) chloride, 99.5% trace metals basis

Cas:10241-05-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

chlorine
7782-50-5

chlorine

molybdenum
7439-98-7

molybdenum

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
dry chlorine was passed over finely divided molebdenum at 300°C; sublimation;88%
at elevated temp.;
exotermic; reversible react. in zone at 1400 °C;
perfluoropropylene
116-15-4

perfluoropropylene

molybdenum(VI) oxide

molybdenum(VI) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
by heating;
by heating;
sulfur dichloride
10545-99-0

sulfur dichloride

molybdenum(VI) oxide

molybdenum(VI) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
reduced pressure, 160-180°C, 10h;
molybdenum(VI) oxide

molybdenum(VI) oxide

A

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

B

molybdenum(VI) tetrachloride oxide
55171-05-6, 13814-75-0

molybdenum(VI) tetrachloride oxide

C

dioxomolybdenum(VI) dichloride
13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
With chlorine in presence of C (C:MoO3=3:1), start at 80°C: 190-600°C;
molybdenum(VI) oxide

molybdenum(VI) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With chlorine in presence of C; above 600°C (>18 l/h); C:MoO3 = 4:1;
With tetrachloromethane at 400°C;
With chlorine in presence of C (C:MoO3=3:1), start at 80°C: above 600°C;
With tetrachloromethane at 400°C;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

molybdenum(VI) oxide

molybdenum(VI) oxide

A

molybdenum(VI) oxide chloride

molybdenum(VI) oxide chloride

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

C

dioxomolybdenum(VI) dichloride
13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cl2; heating of SiCl4 and MoO3 in a closed tube at 260-270°C;;
tetrachloromethane
56-23-5

tetrachloromethane

molybdenum(VI) oxide

molybdenum(VI) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) passing steam of CCl4 over MoO3 at 510 °C;;
In neat (no solvent) heating of MoO3 with CCl4 at about 280°C in a closed tube for 3 hours;;
In neat (no solvent) react. of MoO3 with CCl4 vapor at 510°C in absence of air;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

molybdenum(VI) oxide

molybdenum(VI) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) heating of a mixt. of MoO3 and PCl5 in CO2-atm.; vigorous react. with formation of white and brown vapors;;
hydrogenchloride
7647-01-0

hydrogenchloride

molybdenum(VI) oxide

molybdenum(VI) oxide

A

oxomolybdenum(V) chloride
13814-74-9

oxomolybdenum(V) chloride

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

C

chlorine
7782-50-5

chlorine

D

molybdenum(VI) tetrachloride oxide
55171-05-6, 13814-75-0

molybdenum(VI) tetrachloride oxide

E

dioxomolybdenum(VI) dichloride
13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
In solid byproducts: H2O; thermal decomposition of mixt. of MoO3 with poly(vinylchloride) or cerechlor 70 with different mole ratios in air, the heating rate of 10 deg/min at 20-850°C;
chlorine
7782-50-5

chlorine

molybdenum(VI) oxide

molybdenum(VI) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In tetrachloromethane heating of MoO3 with a dry soln. of Cl2 in CCl4 at 240°C in a closed tube for 3 hours;; crystn.; washing with CCl4 in CO2-atm.; sucking off; drying in vac.;;>99
In tetrachloromethane heating of MoO3 with a dry soln. of Cl2 in CCl4 at 240°C in a closed tube for 3 hours;; crystn.; washing with CCl4 in CO2-atm.; sucking off; drying in vac.;;>99
oxygen
80937-33-3

oxygen

chlorine
7782-50-5

chlorine

molybdenum
7439-98-7

molybdenum

A

molybdenum(VI) oxychloride

molybdenum(VI) oxychloride

B

molybdenum(VI) oxide chloride

molybdenum(VI) oxide chloride

C

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

chlorine
7782-50-5

chlorine

molybdenum
7439-98-7

molybdenum

A

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

B

molybdenum(IV) chloride
13320-71-3

molybdenum(IV) chloride

Conditions
ConditionsYield
In neat (no solvent) introduction of Cl2-gas (8-9 Torr/20 min/1.8 l/h) through purified (90min/H2 stream/1000°C) Mo powder (860 - 1160°C);; extraction of MoCl5 (CCl4); extraction MoCl4 (diethylether or water); further extraction (ethanol or water);;A n/a
B 0-10
molybdenum(IV) oxide

molybdenum(IV) oxide

A

molybdenum(II) chloride

molybdenum(II) chloride

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent)
With coal In neat (no solvent)
tetrachloromethane
56-23-5

tetrachloromethane

molybdenum(IV) oxide

molybdenum(IV) oxide

A

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

B

molybdenum(IV) chloride
13320-71-3

molybdenum(IV) chloride

Conditions
ConditionsYield
With pyrographite mass ratio MoO2:C = 5:1; mixt. heated at 300°C in a flow of N2 loaded with CCl4; absence of moisture and oxygen; further by-product: Mo oxide chloride; removal of MoCl5 and Mo oxide chloride by vac. distn.;A <1
B n/a
molybdenum(IV) oxide

molybdenum(IV) oxide

chlorine
7782-50-5

chlorine

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) passing dry air-free Cl2 over a mixt. of MoO2 and coal at very high temp.;;
With coal In neat (no solvent) passing dry air-free Cl2 over a mixt. of MoO2 and coal at very high temp.;;
molybdenum(VI) fluoride
7783-77-9

molybdenum(VI) fluoride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

C

trifluorophosphane
7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In not given react. of an excess of PCl3 with MoF6 forming PF3, MoCl5, Cl2; further react. of an excess of PCl3 with Cl2 forming PCl5;;
In not given react. of an excess of PCl3 with MoF6 forming PF3, MoCl5, Cl2; further react. of an excess of PCl3 with Cl2 forming PCl5;;
MoCl5*POCl3
31438-02-5

MoCl5*POCl3

A

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) decompn. on heating at about 170°C;;
In neat (no solvent) decompn. on heating at about 170°C;;
tetrachloromethane
56-23-5

tetrachloromethane

Mo3O8

Mo3O8

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) react. of Mo3O8 and CCl4 at 240°C;;
In neat (no solvent) react. of Mo3O8 and CCl4 at 240°C;;
molybdenite

molybdenite

chlorine
7782-50-5

chlorine

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) react. of MoS2 and Cl2 at high temp.;;
In neat (no solvent) react. of MoS2 and Cl2 at high temp.;;
tetrachloromethane
56-23-5

tetrachloromethane

molybdenum(IV) oxide

molybdenum(IV) oxide

molybdenum(IV) chloride
13320-71-3

molybdenum(IV) chloride

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With C In neat (no solvent) byproducts: Mo-oxychloride; heating of MoO2 and carbon in N2-stream satd. with CCl4 (<300°C); sublimation off of MoCl5 (vac., 100°C);
With C In neat (no solvent) heating of MoO2 and carbon in N2-stream satd. with CCl4 (300°C, 2h); sublimation off of MoCl5 (vac., 100°C); elem. anal.;
molybdenum(V) oxide

molybdenum(V) oxide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With hydrogenchloride 200°C;
With HCl 200°C;
thionyl chloride
7719-09-7

thionyl chloride

molybdenum acid

molybdenum acid

nonachlorodimolybdenum(V) heptachlorodioxodimolybdate(V)

nonachlorodimolybdenum(V) heptachlorodioxodimolybdate(V)

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

C

dioxomolybdenum(VI) dichloride
13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
In neat (no solvent) reflux for 96 h; removal of excess thionyl chloride, vacuum sublimation;
trans-(Et2O)2MoCl4
30411-56-4

trans-(Et2O)2MoCl4

A

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

B

molybdenum(III) chloride
13478-18-7

molybdenum(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating under vac. above 140°C;
molybdenum (IV) sulfide

molybdenum (IV) sulfide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) chemical transport reaction (900 to 800°C);;
molybdenum(IV) chloride
13320-71-3

molybdenum(IV) chloride

A

molybdenum(II) chloride

molybdenum(II) chloride

B

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

C

molybdenum(III) chloride
13478-18-7

molybdenum(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating of MoCl4 in a closed tube;;
In neat (no solvent) heating of MoCl4 in a closed tube;;
molybdenum(IV) chloride
13320-71-3

molybdenum(IV) chloride

A

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

B

molybdenum(III) chloride
13478-18-7

molybdenum(III) chloride

Conditions
ConditionsYield
In ethanol decompn. of MoCl4 on solving in alc.;;
In diethyl ether decompn. of MoCl4 on solving in ether;;
In neat (no solvent) thermal decomposition of MoCl4 in vac. or under Ar in a sealed ampoule;
molybdenite

molybdenite

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) passing Cl2 over heated MoS2;;
With chlorine In neat (no solvent) react. of MoS2 in a stream of chlorine;;
With Cl2 In neat (no solvent) react. of MoS2 in a stream of chlorine;;
With Cl2 In neat (no solvent) passing Cl2 over heated MoS2;;
sodium azide

sodium azide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

molybdenum nitride

molybdenum nitride

Conditions
ConditionsYield
In neat (no solvent) High Pressure; all manipulations carried out in a dry glove box with Ar flowing; MoCl5 and NaN3 placed into a stainless steel autoclave; sealed and heated for 12 h at the temp. of 450, 500, and 550°C, respectively, followed by cooling to room temp. on standing; product washed with dilute absolute ethanolic dilute HCl and distilled water for several times; vacuum-dried at 60°C for 4 h;100%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

[MoCl4(NSCl)OPCl3]
87142-29-8

[MoCl4(NSCl)OPCl3]

Conditions
ConditionsYield
With thiazyl chloride In neat (no solvent) MoCl5 is dissolved in POCl3. The resulting soln. is added within 0.5 h to a soln. of S3N3Cl3 under stirring and cooling with an ice bath (underdry conditions).; After 2 h POCl3 is pumped off in vacuo for 5 h; elem. anal.;100%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

diphenyl acetylene
501-65-5

diphenyl acetylene

{MoCl4(PhCCPh)}2

{MoCl4(PhCCPh)}2

Conditions
ConditionsYield
In dichloromethane under exclusion of O2 and moisture in pure Ar; to a suspn. of MoCl5 in CH2Cl2 is added diphenylacetylene under stirring (2 d, room temp.); filtn., washed with CH2Cl2, dried in vacuum, elem. anal.;99%
With C2Cl4
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

MoOCl3(NC5H5)3
79803-20-6

MoOCl3(NC5H5)3

Conditions
ConditionsYield
With pyridine In pyridine 6 h stirring; filtration, elem. anal.;99%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

molybdenum
7439-98-7

molybdenum

Conditions
ConditionsYield
With magnesium hydride In toluene byproducts: H2; (argon); grinding MoCl5 and MgH2 in a mill, addn. of toluene, heating toreflux temp. under further grinding (9 h); washing (toluene), drying (vac.);97.6%
With hydrogen
on annealing single crystal tungsten wire, in MoCl5-WCl6 gas mixt. normal mixed crystal formation;
Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

molybdenum oxide trichloride

molybdenum oxide trichloride

Conditions
ConditionsYield
In dichloromethane byproducts: Me3SiCl; under inert atm.; soln. of Si-compd. added dropwise to a stirred suspension of Mo-compd. at room temp. , mixt. stirred at room temp. for 2h, dark brown solid and colorless soln.; supernatant decanted, solid collected, washed (light petroleum), dried (vac.); elem. anal.;97.5%
1,4-diphenyl-1,3-butadiyne
886-66-8

1,4-diphenyl-1,3-butadiyne

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

{MoCl4(C6H5CCCCC6H5)}2

{MoCl4(C6H5CCCCC6H5)}2

Conditions
ConditionsYield
In tetrachloromethane byproducts: PhC4Cl2Ph; to a suspn. of MoCl5 in CCl4 is added a soln. of PhCCCCPh in CCl4 with stirring, soln. is stirred for 6 d; ppt. is filtered, washed with CCl4 and dried in vac., elem. anal.;97%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

[Cl2OMo(μ-OC2H5)2(μHOC2H5)MoOCl2]

[Cl2OMo(μ-OC2H5)2(μHOC2H5)MoOCl2]

Conditions
ConditionsYield
With C2H5OH In ethanol; chloroform under N2; a mixt. of CHCl3 and EtOH is added to MoCl5, stirred; the volatiles are evapd. in vac., the ppt. is washed, elem. anal.;97%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

acetonitrile
75-05-8

acetonitrile

bis(acetonitrile)tetrachloromolybdenum(IV)
56613-96-8, 77210-60-7, 15584-93-7, 19187-82-7

bis(acetonitrile)tetrachloromolybdenum(IV)

Conditions
ConditionsYield
at 20℃; for 14h; Inert atmosphere; Schlenk technique;96%
at 20℃; for 20.3333h; Inert atmosphere;93%
In acetonitrile solid MoCl5 added to MeCN, stirred for 3 h at ambient temp.; filtered, washed with MeCN, dried in vac.;87%
dimethylbis(phenylethynyl)silane
2170-08-3

dimethylbis(phenylethynyl)silane

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

2Mo(4+)*8Cl(1-)*C6H5CCSi(CH3)2CCC6H5=[Mo2Cl8(C6H5CCSi(CH3)2CC(C6H5))]

2Mo(4+)*8Cl(1-)*C6H5CCSi(CH3)2CCC6H5=[Mo2Cl8(C6H5CCSi(CH3)2CC(C6H5))]

Conditions
ConditionsYield
In tetrachloromethane byproducts: PhC2Cl2SiMe2C2Cl2; under Ar; adding slowly dropwise a soln. of PhCCSiMe2CCPh to a suspn. of MoCl5, stirring (2 d, room temp.); filtering, washing (CCl4), drying (high vac.); elem. anal.;96%
bis(trichlorophosphine)iminium chloride

bis(trichlorophosphine)iminium chloride

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

bis(trichlorophosphine)iminium hexachloromolybdate(V)
116591-43-6

bis(trichlorophosphine)iminium hexachloromolybdate(V)

Conditions
ConditionsYield
In dichloromethane exclusion of moisture, stirred for 12 h at room temp.; pptd. with CCl4, filtered, washed with CCl4, dried in vac.; elem. anal.;95%
N-trimethylsilyl(triphenylphosphoranylidene)amine
13892-06-3

N-trimethylsilyl(triphenylphosphoranylidene)amine

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

{MoCl4(NP(C6H5)3)}2*CH2Cl2

{MoCl4(NP(C6H5)3)}2*CH2Cl2

Conditions
ConditionsYield
With CH2Cl2 In dichloromethane byproducts: ClSi(CH3)3; slow addn. of phosphorane soln. to MoCl5 suspension with stirring, excluding moisture; refluxing, 3h; cooling; pptn.; filtration; washing (CH2Cl2); drying (vac.) for a short period of time; elem. anal.;95%
Di-n-butyl selenide
14835-66-6

Di-n-butyl selenide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

acetonitrile
75-05-8

acetonitrile

trans-[MoCl4(nBu2Se)2]

trans-[MoCl4(nBu2Se)2]

Conditions
ConditionsYield
Stage #1: molybdenum(V) chloride; acetonitrile for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: Di-n-butyl selenide In dichloromethane for 0.25h; Inert atmosphere; Schlenk technique;
94%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

2-aminobenzothiazole hydrochloride
94787-08-3

2-aminobenzothiazole hydrochloride

2C7H7N2S(1+)*MoOCl5(2-)=(C7H7N2S)2{MoOCl5}

2C7H7N2S(1+)*MoOCl5(2-)=(C7H7N2S)2{MoOCl5}

Conditions
ConditionsYield
In hydrogenchloride Addn. of ligand to soln. of MoCl5.; Concg., cooling in ice, passing a stream of HCl through the soln., green crystals ppt., washing (ether, thionyl chloride), drying over KOH, elem. anal.;92%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

MoOCl3(CH3OCH2CH2OCH3)
14523-42-3, 141778-40-7

MoOCl3(CH3OCH2CH2OCH3)

Conditions
ConditionsYield
In dichloromethane addn. of Me3SiOSiMe3 to a soln. of W-complex in CH2Cl2 and 1,2-dimethoxyethane, stirring for a short period; filtn., elem. anal.;91%
P(C6H5)4(1+)*MoNCl4(1-) = P(C6H5)4MoNCl4
89087-28-5, 94930-25-3

P(C6H5)4(1+)*MoNCl4(1-) = P(C6H5)4MoNCl4

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

2P(C6H5)4(1+)*{Mo2NCl9}2(2-) = (P(C6H5)4)2{Mo2NCl9}2

2P(C6H5)4(1+)*{Mo2NCl9}2(2-) = (P(C6H5)4)2{Mo2NCl9}2

Conditions
ConditionsYield
With POCl3; Cl2 In dichloromethane exclusion of moisture; a soln. of the Mo-complex is dropped into a suspension of MoCl5 with stirring, stirring continued for further 12 h;; filtration; washing (CH2Cl2); drying in vac.; a second crop is obtained by concn. of the filtrate; elem. anal.;90%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

2,2-dimethylpropylidynephosphine
78129-68-7

2,2-dimethylpropylidynephosphine

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

{MoCl2(C5H4NC5H4N)2(1+)}*{MoCl4(C5H4NC5H4N)(1-)}={Mo2Cl6(C5H4NC5H4N)3}

{MoCl2(C5H4NC5H4N)2(1+)}*{MoCl4(C5H4NC5H4N)(1-)}={Mo2Cl6(C5H4NC5H4N)3}

Conditions
ConditionsYield
In dichloromethane byproducts: Me3C-CC-CMe3; filtered, the filtration cooled at 5°C, filtered, elem. anal.;90%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

MoCl4(NSCl)
94017-24-0

MoCl4(NSCl)

Conditions
ConditionsYield
With thiazyl chloride In dichloromethane byproducts: Cl2; MoCl5 is suspd. in CH2Cl2, heated to 35°C and S3N3Cl3 in CH2Cl2 is added under stirring (under dry conditions). The color changes from dark red to dark violett after 0.5 h.; After 20 h filtn., washing with CH2Cl2 and drying in vavuo; elem. anal.;90%
bis(trichlorophosphine)iminium hexachlorophosphate
18828-06-3

bis(trichlorophosphine)iminium hexachlorophosphate

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

A

bis(trichlorophosphine)iminium hexachloromolybdate(V)
116591-43-6

bis(trichlorophosphine)iminium hexachloromolybdate(V)

B

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

Conditions
ConditionsYield
In not given exclusion of moisture, stirred for 12 h at room temp.; filtered, dissolved in CH2Cl2, pptd. with CCl4, filtered, washed with CCl4, dried in vac.; elem. anal.;A 89%
B n/a
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

trans-bisdinitrogenbis(1,2-diphenylphosphinoethane)molybdenum(0)

trans-bisdinitrogenbis(1,2-diphenylphosphinoethane)molybdenum(0)

Conditions
ConditionsYield
With nitrogen; 1,2-bis-(diphenylphosphino)ethane In tetrahydrofuran Electrochem. Process; MoCl5-Ph2PCH2CH2PPh2 in THF-NBu4BF4 was electrolysed under N2 (20°C, 1 atm) (E(app)=-2.4 V); mechanism discussed;; catholyte was removed, THF was removed under vac. at room temp. left a mixt. of product and NBu4BF4, soluble in CH3CN or MeOH, catholyte residue was repeated extd. with solvent, product was removed, recrystd. from Et2O-THF;89%
tetrahydrofuran
109-99-9

tetrahydrofuran

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

[MoCl4(tetrahydrofuran)2]
16998-75-7

[MoCl4(tetrahydrofuran)2]

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether under Ar; MoCl5 and Sn suspd. in Et2O at room temp., mixt. stirred for 30 min, excess Sn sepd. by transferring the gently stirred supernatant suspn. in a new flask, suspn. filtered, ppt. washed (Et2O), THF added, mixt. stirred for 3 h at room temp.; liquid decanted off, residue washed with THF and ether, dried in vac.;89%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

tert-butylamine
75-64-9

tert-butylamine

bis-t-butylamidobis-t-butylaminebis-t-butylimidotetrachlorodimolybdenum(V)*1/6C6H6

bis-t-butylamidobis-t-butylaminebis-t-butylimidotetrachlorodimolybdenum(V)*1/6C6H6

Conditions
ConditionsYield
With benzene In benzene byproducts: Me3CNH3Cl; a soln. of the amine (43.9 mmol) in benzene is added to a suspn. of MoCl5 (7.3 mmol) in benzene and the mixt. stirred for 3 h; filtration, residue washed with benzene; filtrates combined and evapd; solid washed with petroleum ether and dried in vac.; elem. anal.;88%
trimethyl(tert-butylamino)silane
5577-67-3

trimethyl(tert-butylamino)silane

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

bis-t-butylaminebis-t-butylimidohexachlorodimolybdenum(V)*1/6C6H6

bis-t-butylaminebis-t-butylimidohexachlorodimolybdenum(V)*1/6C6H6

Conditions
ConditionsYield
With benzene In benzene a soln. of the amine (10.35 mmol) in benzene is slowly added to a suspn. of MoCl5 (5.1 mmol) in benzene cooled to ica-water temp.; mixt. stirred for 18 h; filtration, solid washed with benzene and dried in vac.; product is a mixt. of 2 isomers; elem. anal.;88%
(C6H5)3PCH3(1+)*{MoNCl4}(1-)=((C6H5)3PCH3){MoNCl4}
85361-08-6

(C6H5)3PCH3(1+)*{MoNCl4}(1-)=((C6H5)3PCH3){MoNCl4}

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

(C6H5)3PCH3(1+)*{Mo2NCl9}(1-)=((C6H5)3PCH3){Mo2NCl9}

(C6H5)3PCH3(1+)*{Mo2NCl9}(1-)=((C6H5)3PCH3){Mo2NCl9}

Conditions
ConditionsYield
In dichloromethane stirring, room temp., 2h; pptn.; filtration; washing (CH2Cl2); drying (vac.); elem. anal.;88%
In dichloromethane; benzene addn. of Mo complex soln. (CH2Cl2) to MoCl5 soln. (benzene); pptn. of oil; crystn. within one day; filtration; washing (CH2Cl2); drying (vac.); elem. anal.;
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

silicon tetraiodide
13465-84-4

silicon tetraiodide

MoI3

MoI3

Conditions
ConditionsYield
at 150℃; for 16h; Inert atmosphere; Schlenk technique;88%
at 120℃; for 16h;
hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

molybdenum tetrabromide
13520-59-7

molybdenum tetrabromide

Conditions
ConditionsYield
In further solvent(s) cooling MoCl5 in C2H5Br (red-brown soln.) to about -50°C; connecting to a vac. line and to a cylinder of HBr; introduction of HBr (colorless soln. after 10min, pptn.); repeating 5times vac./HBr operation, 2h; stirring, room temp., 15h;; filtration of black solid; washing with heptane; drying in vac.; elem. anal.;;87%
hexamethyldisilathiane
3385-94-2

hexamethyldisilathiane

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

molybdenum(V) sulphide trichloride

molybdenum(V) sulphide trichloride

Conditions
ConditionsYield
In dichloromethane byproducts: Me3SiCl; under inert atm.; suspension of Mo-compd. cooled in a dry-ice/acetone slush bath, treated dropwise over a period of 15 min with soln. of Si-compd. chilled to -30°C, pptn., mixt. allowed to warm to room temp., stirred for 2h; supernatant decanted, solid collected, washed (petroleum ether), dried (vac.); elem. anal.;87%
2,2-dimethylpropylidynephosphine
78129-68-7

2,2-dimethylpropylidynephosphine

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

methyltriphenylphosphonium chloride
1031-15-8

methyltriphenylphosphonium chloride

A

2((C6H5)3PCH3)(1+)*{MoCl6(2-)}=((C6H5)3PCH3)2{(MoCl6)}

2((C6H5)3PCH3)(1+)*{MoCl6(2-)}=((C6H5)3PCH3)2{(MoCl6)}

B

3((C6H5)3PCH3)(1+)*{(Mo2Cl9)(3-)}=((C6H5)3PCH3)3{(Mo2Cl9)}

3((C6H5)3PCH3)(1+)*{(Mo2Cl9)(3-)}=((C6H5)3PCH3)3{(Mo2Cl9)}

Conditions
ConditionsYield
In dichloromethane byproducts: Me3C-CC-CMe3; filtered, washed with CH2Cl2, CCl4 added to filtrate, pptd., elem. anal.;A 13%
B 87%
phosgene
75-44-5

phosgene

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

tetramethylurea
632-22-4

tetramethylurea

3(N(CH3)2)2CCl(1+)*MoCl8(3-) = [(N(CH3)2)2CCl]3(MoCl8)

3(N(CH3)2)2CCl(1+)*MoCl8(3-) = [(N(CH3)2)2CCl]3(MoCl8)

Conditions
ConditionsYield
In toluene (N2); stirring (0°C); ppt. washing (CHCl3, Et2O), drying (vac.); elem. anal.;87%

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