Bismuth trichloride supplier

Name
Bismuth(III) chloride
EINECS 232-123-2
CAS No. 7787-60-2
Article Data197
CAS DataBase
Density 4.75 g/cm³
Solubility Decomposes in water
Melting Point 230-232 °C(lit.)
Formula BiCl₃
Boiling Point 447oC
Molecular Weight 315.339
Flash Point 430°C
Transport Information
Appearance White crystal and crystalline powder
Safety 26-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Bismuthchloride (BiCl3) (6CI,8CI);Bismuth chloride;Bismuthtrichloride (BiCl3);Bismuth(III) chloride;Trichlorobismuth;Trichlorobismuthine;Bismuth trchloride;
PSA 0.00000
LogP 2.06850

Synthetic route

: 593-81-7
trimethylamine hydrochloride

: 603-33-8
triphenylbismuthane

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);;	100%
byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);;	100%

: 7647-01-0
hydrogenchloride

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In acetic acid byproducts: H2O;	100%
In acetic acid byproducts: H2O;	100%
In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;;	> 99
In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;;	> 99
In perchloric acid aq. HClO4; prepn. by dissolving Bi2O3 in 6 M HCl;

: 10025-67-9
disulfur dichloride

: 7440-69-9
bismuth

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
heating Bi with S2Cl2 at 138.6°C, 10 hours;;	100%
addition of S2Cl2 to Bi;;
addition of S2Cl2 to Bi;;

: 7440-69-9
bismuth

: 7782-50-5
chlorine

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;	100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;	100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;	100%

: 33397-22-7
tri(naphthalen-1-yl)bismuth

A: 91-20-3
naphthalene

B: 642-29-5
1-benzoylnaphthalene

C: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
With aluminium trichloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:AlCl3:C6H5COOH = 1:1:1;	A 34% B 9.3% C 99%
With iron(III) chloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:FeCl3:C6H5COOH = 1:1:1;	A 44% B 10.2% C 96%

...Expand

: 33397-22-7
tri(naphthalen-1-yl)bismuth

A: 91-20-3
naphthalene

B: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
With benzoic acid In chloroform molar ratio Bi(1-C10H7)3:C6H5COOH = 1:1;	A 49.1% B 98.4%
With AlCl3 or FeCl3 In chloroform reflux;	A 36-46 B >97

: 13453-32-2
thallium (III) chloride

: 93690-72-3
tri(isopropenyl)bismuthane

A: (CH2C(CH3))TlCl

B: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In diethyl ether at -40°C;	A 98% B n/a

...Expand

: bismuth(III) sulfide

: copper(l) chloride

: copper(I) sulfide

B: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In ethanol High Pressure; mixing Bi2S3 and CuCl in ethanol, heating at 120°C for 2 d in autoclave, cooling to room temp.; filtration, washing with dild. HCl, water, ammonia, ethanol, drying in vac.;	A 82% B n/a

...Expand

: 7647-01-0
hydrogenchloride

: 7440-69-9
bismuth

: 10241-05-1
molybdenum(V) chloride

A: (H3O)2(octa-μ3-chloro-hexachloro-octahedrohexamolybdate)*6(water)

B: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) ampule with MoCl5 and Bi was heated to 230°C (2 h), to 350°C (2 h) and kept at 350°C for 12 h, cooled, homogenized and heated to 350°C (3 h) , reoriented and heated at 350°C for 24 h, cooled, treated with 12 M HCl; recrystn.; X-ray diffraction;	A 80% B n/a
In neat (no solvent) ampule with MoCl5 and Bi in the end reaction chamber was heated to 230°C over 2 h and to 350°C over 2 h, ampule wasrepositioned toremove BiCl3 by sublimation and heated at 350°C for 24 h, cooled , treated with 12 M HCl and heated; recrystn.; X-ray diffraction;	A 58% B n/a

...Expand

: 7440-69-9
bismuth

: 7790-99-0
Iodine monochloride

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In melt ardent reaction of powdered Bi with molten ICl;;	60%
In melt ardent reaction of powdered Bi with molten ICl;;	60%
In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;;
In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;;

: 603-33-8
triphenylbismuthane

: 28719-54-2, 507233-69-4, 594-30-9
triphenylbismuth dichloride

B: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In chloroform byproducts: iodobenzene; 4.5 h;	A 59% B 32%
In chloroform byproducts: iodobenzene; 4.5 h;	A 59% B 32%

: ammonium chloride

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
With sulphidic ore In neat (no solvent) addition of a small excess of NH4Cl to dry grinded sulphidic ore and heating at 300-400°C under 0.1-10 atm overpressure;; removing the gaseous reaction products constantly; purification by fractionated distillation under reduced pressure;;
With sulphidic ore In neat (no solvent) addition of a small excess of NH4Cl to dry grinded sulphidic ore and heating at 300-400°C under 0.1-10 atm overpressure;; removing the gaseous reaction products constantly; purification by fractionated distillation under reduced pressure;;

: 593-81-7
trimethylamine hydrochloride

: 603-33-8
triphenylbismuthane

A: 7787-60-2
bismuth(III) chloride

B: 71-43-2
benzene

Conditions

Conditions	Yield
In neat (no solvent) 130°C;	A >99 B >99
In ethanol	A >99 B >99

...Expand

: 75-44-5
phosgene

: bismuth(III) sulfide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: COS; heating at 350 °C;;
In neat (no solvent) byproducts: COS; passing stream of COCl2 over Bi2S3 at 350 °C;;
In neat (no solvent) byproducts: COS; heating at 350 °C;;

: 7647-01-0
hydrogenchloride

: bismuth(III) sulfide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
With oxygen; catalyst:NO(x) In hydrogenchloride Kinetics; byproducts: H2SO4, S; oxidation of Bi2S3 by O2 in aq. HCl/MgCl2/KI/HNO2, catalyst: nitrogen oxides, react. temp. 295-313 K; react. monitored potentiometric and by atomic absorption analysis and IR;

: bismuth(III) sulfide

: 7782-50-5
chlorine

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) at light read heat;;
In neat (no solvent) heated to red heat;;
In neat (no solvent) at light read heat;;
In neat (no solvent) heated to red heat;;

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
With thionyl chloride In neat (no solvent) byproducts: SO2; reaction between 150 and 200 °C;;
With thionyl chloride In neat (no solvent) byproducts: SO2; in the cold;;	0%

: 7446-09-5
sulfur dioxide

: 1304-76-3
bismuth(III) oxide

: 7782-50-5
chlorine

A: bismuth (III) oxychloride

B: bismuth(III) sulfate

C: bismuth(III) sulfide

D: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; heating Bi2O3 in flow of SO2 and Cl2 (equimolar mixt. or excess Cl2) for30-120 min at 300-750°C; X-ray diffraction, thermogravimetry of products; product ratio dependingon reaction conditions;

...Expand

: 7719-09-7
thionyl chloride

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SO2; heated at 150-200 °C;;
In neat (no solvent) byproducts: SO2; heated at 150-200 °C;;
In neat (no solvent) 150°C;;

: 1304-76-3
bismuth(III) oxide

: 10025-68-0
diselenium dichloride

A: 7782-49-2
selenium

B: 7791-23-3
selenium oxychloride

C: 7787-60-2
bismuth(III) chloride

...Expand

: 1304-76-3
bismuth(III) oxide

: 7719-12-2, 52843-90-0
phosphorus trichloride

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) formed in small yields;;
In neat (no solvent) formed in small yields;;

: 7446-70-0
aluminium trichloride

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: AlOCl; heating a mixture of Bi2O3 and AlCl3 in vacuum at 300°C for 2 days;;
In neat (no solvent) byproducts: AlOCl; heating a mixture of Bi2O3 and AlCl3 in vacuum at 300°C for 2 days;;

: 10025-67-9
disulfur dichloride

: 1304-76-3
bismuth(III) oxide

A: 7446-09-5
sulfur dioxide

B: 7787-60-2
bismuth(III) chloride

C: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent) heating starting material;;

...Expand

: 10025-67-9
disulfur dichloride

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) heating in a bomb at 138°C;;
addition of S2Cl2 to Bi2O3;;
In neat (no solvent)

: 10026-04-7, 53609-55-5
tetrachlorosilane

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SiO2; 44 h heating in a closed tube at 270-280 °C gives no complete reaction;;
In neat (no solvent) byproducts: SiO2; heating in a tube at 370-380 °C;;
In neat (no solvent) heating;;
In neat (no solvent) byproducts: SiO2; heating in a tube at 370-380 °C;;
In neat (no solvent) heating;;

: 1304-76-3
bismuth(III) oxide

: 98-88-4
benzoyl chloride

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In further solvent(s) byproducts: C6H5COOH; solution of Bi2O3 in C6H5COCl with formation of BiCl3;;
In further solvent(s) byproducts: C6H5COOH; solution of Bi2O3 in C6H5COCl with formation of BiCl3;;

: aluminium chloride dimer

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In melt byproducts: AlOCl; heating a mixture of Bi2O3 and gaseous Al2Cl6 in a closed tube at 300°C for 2 days;; evaporation of BiCl3/Al2Cl6 (separation from AlOCl);;
In melt byproducts: AlOCl; heating a mixture of Bi2O3 and gaseous Al2Cl6 in a closed tube at 300°C for 2 days;; evaporation of BiCl3/Al2Cl6 (separation from AlOCl);;

: 628-13-7
pyridine hydrochloride

: 1304-76-3
bismuth(III) oxide

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In melt byproducts: pyridine, H2O; solution in molten C5H5N*HCl with formation of BiCl3;;
In melt byproducts: pyridine, H2O; solution in molten C5H5N*HCl with formation of BiCl3;;

: 1304-76-3
bismuth(III) oxide

: 7782-50-5
chlorine

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Bi3O2Cl3; heating in dry Cl-stream;;
In neat (no solvent) byproducts: O2; prepn. by flow method; Bi2O3 placed to a heated tubular reactor with inert gas passing through it; after achieving a given temp. inert gas flow replaced by flow of Cl2; linear gas speed was 0.02-0.05 m/s; temp. was 550-750°C; volatiles trapped in cooled traps; monitored by X-ray diffraction and chem. analysis;
In neat (no solvent) byproducts: Bi3O2Cl3; heating in dry Cl-stream;;

: 1304-76-3
bismuth(III) oxide

: 7782-50-5
chlorine

A: bismuth (III) oxychloride

B: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; at 25-460°C;

...Expand

: 7787-60-2
bismuth(III) chloride

: tetrachlorobismuth (1-)

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride formation of BiCl4(1-) in aq. HCl solution at 25°C; various HCl- and BiCl3 concentrations;;	100%
With hydrogenchloride In hydrogenchloride solution of BiCl3 in aq. HCl (ionic strength 1 or 2); formation of 3 chloro complexes besides BiCl4(1-);;
With hydrogenchloride In hydrogenchloride formation of BiCl4(1-) in aq. HCl solution, stabilized by H(1+) and Cl(1-);;

: 7787-60-2
bismuth(III) chloride

: 603-33-8
triphenylbismuthane

: 5153-28-6
diphenylbismuth(III) chloride

Conditions

Conditions	Yield
In diethyl ether 20°C;	100%
In diethyl ether 20°C;	100%
In toluene; xylene 30 min reflux;	97%

: 507-02-8
acetyl iodide

: 7787-60-2
bismuth(III) chloride

: 7787-64-6
bismuth(III) iodide

Conditions

Conditions	Yield
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;	100%
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;	100%

: 3911-04-4, 21312-75-4
bismuth-tri(diethylphosphoro dithioate)

: 7787-60-2
bismuth(III) chloride

: 89928-33-6, 1010422-09-9
monochlorobismuth(III) bis(diethyldithiophosphate)

Conditions

Conditions	Yield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.;	100%

: bismuth(III) tris(diisobutyldithiophosphate)

: 7787-60-2
bismuth(III) chloride

: 89928-37-0
monochlorobismuth(III) bis(diisobutyldithiophosphate)

Conditions

Conditions	Yield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.;	100%

: 109-99-9
tetrahydrofuran

: 7787-60-2
bismuth(III) chloride

: lithium chloride

: bis[tetrakis(tetrahydrofuran-O)lithium(I)] diμ-chloro-bis[trichloro(tetrahydrofuran-O)bismuthate(III)]

Conditions

Conditions	Yield
In tetrahydrofuran Ar atm.; equimolar ratio LiCl:BiCl3, stirring (30 min); concn., layering (Et2O), cooling (-7°C, 12 h);	100%

...Expand

: 603-36-1
triphenylantimony

: 7787-60-2
bismuth(III) chloride

: 2629-47-2
diphenylantimony(III) chloride

Conditions

Conditions	Yield
In chloroform reflux under CO2;	99%
In chloroform reflux under CO2;	99%

: 109-99-9
tetrahydrofuran

: 7787-60-2
bismuth(III) chloride

: 70650-04-3
bismuth trichloride, tetrahydrofuran adduct

Conditions

Conditions	Yield
In tetrahydrofuran absence of O2 and moisture; dissoln. of Bi-salt in mimimum THF; filtration, layering with hexanes, crystn. (-30°C, several d);	99%

: 20735-33-5
2-aminocyclopent-1-ene-1-carbodithioic acid

: 7787-60-2
bismuth(III) chloride

: 107556-45-6
Bi(C5H6CSSNH2)3

Conditions

Conditions	Yield
In ethanol reactn. of soln. of BiCl3 with soln. of ligand (room temp.), pptn.; filtration, washed (ethanol), dried (air);	99%
In benzene byproducts: NaCl; A soln. of BiCl3 is added to a suspn. of sodium salt of aminocyclopentene compd. with constant stirring, refluxed for 2 h, NaCl is filtered; Filtrate is concentrated, recrystd. from benzene-hexane, elem. anal.;	95%

: 108036-01-7
1,1-dibutyl-2,5-bis(methylene)stannolane

: 7787-60-2
bismuth(III) chloride

: 108036-02-8
1-chloro-2,5-bis(methylene)bismolane

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: n-Bu2SnCl2; THF soln. of BiCl3 was added to the stannolane at 0°C; solvent was removed under vac. at 0°C, residue was washed with pentane, dissolved in THF, filtered, evapd. at 0°C;	99%

: 42294-79-1
bismuth(III) tris(diisopropyldithiophosphate)

: 7787-60-2
bismuth(III) chloride

: 1010422-10-2, 89928-31-4
monochlorobismuth(III) bis(diisopropyldithiophosphate)

Conditions

Conditions	Yield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 1:2), heating (1 h, 50-60°C); removal of solvent; elem. anal.;	99%

: 30488-04-1
trimethylsilyldimesylamine

: 7787-60-2
bismuth(III) chloride

: bismuth(III)-bis(dimesylamide)chloride

Conditions

Conditions	Yield
In dichloromethane; ethyl acetate byproducts: Me3SiCl; inert atm.; refluxing (2 h); filtn., drying (vac.); elem. anal.;	99%
In dichloromethane; ethyl acetate inert atm.; 16 h, 20°C, molar ratio BiCl3:silylamine 1.5:1;
In dichloromethane; ethyl acetate inert atm.; molar ratio BiCl3:silylamine 1:3, 2 d 20°C, refluxng (10 h);
In ethyl acetate inert atm.; refluxing (3 h), molar ratio BiCl3:silylamine 1:1;

: 34281-26-0
2-ethylamino-1-cyclopentene-1-dithiocarboxylic acid

: 7787-60-2
bismuth(III) chloride

: 107556-46-7
tris{2-(ethylamino)cyclopent-1-ene-1-dithiocarboxylato}bismuth(III)

Conditions

Conditions	Yield
In ethanol reactn. of soln. of BiCl3 with soln. of ligand (room temp.), pptn.; filtration, washed (ethanol), dried (air);	98%
In benzene byproducts: NaCl; A soln. of BiCl3 is added to a suspn. of sodium salt of aminocyclopentene compd. with constant stirring, refluxed for 2 h, NaCl is filtered; Filtrate is concentrated, recrystd. from benzene-hexane, elem. anal.;	96%

: bismuth(III) tris(diisobutyldithiophosphate)

: 7787-60-2
bismuth(III) chloride

: 89928-38-1
dichlorobismuth(III) diisobutyldithiophosphate

Conditions

Conditions	Yield
In benzene addn. of Bi-complex to soln. of BiCl3 (ratio BiCl3/Bi-complex 2:1), heating (1 h, 50-60°C); removal of solvent; elem. anal.;	98%

: potassium tetraisopropoxyaluminate

: 7787-60-2
bismuth(III) chloride

: 394219-44-4
Bi(Al(OC3H7)4)3

Conditions

Conditions	Yield
In benzene byproducts: KCl; to suspn. of BiCl3 in benzene was added KAl-complex, stirred at room temp. for 8 h; filtered, volatiles were removed under reduced pressure; elem. anal.;	98%

: 33902-86-2
3,5,7-tris(morpholinomethyl)tropolone

: 7787-60-2
bismuth(III) chloride

: tris(3,5,7-tris(morpholinomethyl)tropolonato)bismuth(III)

Conditions

Conditions	Yield
With morpholine In ethanol addn. of BiCl3 soln. to refluxing soln. of tropolone compound and morpholine, reflux (10 min); centrifugation of hot soln., decantation, filtration, reflux of filtrate(3 min), crystn. on slow cooling to room temp., filtration, washing (et hanol), drying (vacuum over P4O10); elem. anal.;	98%

: 7647-01-0
hydrogenchloride

: 67-56-1
methanol

: 7732-18-5
water

: 7787-60-2
bismuth(III) chloride

: (MeNC5H4C5H4NMe)3[Bi4(chloride)18]*1.7(water)

Conditions

Conditions	Yield
In methanol High Pressure; mixing BiCl3, N compd., addn. of methanol and HCl (36 %), heating in autoclave (6 h, from 25 to 150°C, then 13 h at 150°C), cooling over 10 h to 25°C; filtration, washing with methanol, XRD;	98%

...Expand

: 75-15-0
carbon disulfide

: 7787-60-2
bismuth(III) chloride

: 111-92-2
dibutylamine

: tris(di-n-butyldithiocarbamato)-bismuth(III)

Conditions

Conditions	Yield
With sodium In ethanol; water Addn. of Na to ethanol at 263 K, dropwise addn. of amine and CS2, slow addn. of BiCl3; yellow solid pptd., filtered and dried in vacuo, diisolved in hot acetone and crystn.;	97%

...Expand

: 87-85-4
Hexamethylbenzene

: 7787-60-2
bismuth(III) chloride

: 103349-18-4
((hexamethylbenzene)bis[trichlorobismuth(III)])n

Conditions

Conditions	Yield
In toluene under dry N2, soln. of BiCl3 and C6Me6 in toluene is heated until boiling; slowly cooling; elem. anal.;	97%
In toluene BiCl3 is added to soln. of C6(CH3)6 in toluene and heated to 60°C; filtn.;	92%

: potassium tetraisopropoxyaluminate

: 6831-82-9
potassium isopropoxide

: 7787-60-2
bismuth(III) chloride

: Bi(3+)*2Al(OC3H7)4(1-)*OC3H7(1-)=Bi(Al(OC3H7)4)2(OC3H7)

Conditions

Conditions	Yield
In benzene byproducts: KCl; to suspn. of BiCl3 in benzene was added KAl-complex and KOiPr, stirred at room temp. for 8 h; filtered, volatiles were removed under reduced pressure; elem. anal.;	97%

...Expand

: 7787-60-2
bismuth(III) chloride

: 13242-44-9
2-(N,N-dimethylamino)ethylthiol hydrochloride

: Bi(3+)*3Cl(1-)*SC2H4NH(CH3)2=BiCl3SC2H4NH(CH3)2

Conditions

Conditions	Yield
In tetrahydrofuran; ethanol pptn.; recrystn. (water); elem. anal.;	97%

: 86901-19-1
magnesium-anthracene-(THF)3

: 7787-60-2
bismuth(III) chloride

: Mg1.51BiCl0.11C0.8H1.5

Conditions

Conditions	Yield
In tetrahydrofuran; toluene byproducts: MgCl2, anthracene, THF; Ar atmosphere, stirring of suspn. of Mg compound in toluene at room temp. (24 h), decantation of solvent, addn. of THF, addn. of BiCl3, stirring(room temp., 48 h); filtration, washing (THF, pentane), drying (0.1-0.2 mbar); elem. anal.;	97%

: 7787-60-2
bismuth(III) chloride

: 13242-44-9
2-(N,N-dimethylamino)ethylthiol hydrochloride

: 200342-37-6
BiCl3(SCH2CH2N(CH3)2H)

Conditions

Conditions	Yield
In tetrahydrofuran; ethanol (N2); elem. anal.;	97%

Bismuth trichloride Specification

The Bismuthine, trichloro-, with the CAS registry number 7787-60-2 and EINECS registry number 232-123-2, has the systematic name of bismuth(+3) trihydride cation trichloride. It is a kind of white crystal and crystalline powder, and belongs to the following product categories: Inorganics; Bismuth Salts; BismuthMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Crystal Grade Inorganics; Salts; Bismuth SaltsEssential Chemicals; Reagent Grade; Routine Reagents. And the molecular formula of the chemical is BiCl₃.

The characteristics of Bismuthine, trichloro- are as followings: (1)H-Bond Donor 0; (2)H-Bond Acceptor 0 ; (3)Rotatable Bond Count 0; (4)Exact Mass 313.886941; (5)MonoIsotopic Mass 313.886941; (6)Topological Polar Surface Area 0; (7)Heavy Atom Count 4; (8)Formal Charge 0; (9)Complexity 8; (10)Isotope Atom Count 0; (11)Defined Atom StereoCenter Count 0; (12)Undefined Atom StereoCenter Count 0; (13)Defined Bond StereoCenter Count 0; (14)Undefined Bond StereoCenter Count ; (15)Covalently-Bonded Unit Count 1.

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective gloves and eye/face protection, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: [Cl-].[Cl-].[Cl-].[BiH3+3]
(2InChI: InChI=1/Bi.3ClH.3H/h;3*1H;;;/q+3;;;;;;/p-3/rBiH3.3ClH/h1H3;3*1H/q+3;;;/p-3
(3)InChIKey: QJWNFCZARGUHFM-YRLNYOAXAG

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	2250mg/kg (2250mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986.
rat	LD50	oral	3334mg/kg (3334mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986.

Product Name

Bismuth(III) chloride

Synthetic route

Bismuth trichloride Specification

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