Bismuth supplier | CasNO.7440-69-9

Name
Bismuth
EINECS 231-177-4
CAS No. 7440-69-9
Article Data615
CAS DataBase
Density 9.8 g/cm³
Solubility insoluble in water
Melting Point 271 °C(lit.)
Formula Bi
Boiling Point 1560 °C
Molecular Weight 208.98
Flash Point
Transport Information UN 3264 8/PG 3
Appearance silver-grey or reddish metal, or black powder
Safety 16-45-36/37/39-26
Risk Codes 34-11
Molecular Structure
Hazard Symbols F,C
Synonyms Bismuthelement;Bismuth-209;
PSA 0.00000
LogP 0.33750

Synthetic route

: 1304-76-3
bismuth(III) oxide

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With zinc In neat (no solvent) byproducts: ZnO; complete reduction at 500°C;;	100%
With Zn In neat (no solvent) byproducts: ZnO; complete reduction at 500°C;;	100%
With urea byproducts: H2O, CO2, N2; react. in a crucible over a low Meker flame, heating gently for 10 min; metal was extd. manually with a spatula;	71%

: bismuth(III) sulfide

: 7440-69-9
bismuth

Conditions

Conditions	Yield
In neat (no solvent) decomposition on heating above boiling temperature;; re-sulphuration on cooling down under exclusion of air; formation of Bi oxide in presence of air;;	100%
With sodium hydroxide In neat (no solvent) heating of Bi2S3 with NaOH at 400-500°C; thermodynamic calculations;;
With iron In neat (no solvent) byproducts: FeS; heating of the sulfide with Fe; formation of Bi and Bi containing dross;; addition of alkaline or earth alkaline sulfides to the reaction mixture; separation from As and Sb containing speiss;;

: 7787-58-8
bismuth(III) bromide

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With calcium reduction with Ca at 220°C;;	100%
With magnesium In diethyl ether reduction in presence of ether at 25°C;;	100%
With Mg In diethyl ether reduction in presence of ether at 25°C;;	100%

: bismuth(III) acetate oxide

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With hydrogen In acetic acid reduction at 150°C, 100 atm., 24 hours, 1,25n solution (acetic acid), 0.1n acetate;;	100%

: vanadocene

: 69162-04-5
(C6F5)3GeBi(C2H5)2

A: 7440-69-9
bismuth

B: (C5H5)2VC2H5

C: (C5H5)2VGe(C6F5)3

Conditions

Conditions	Yield
In toluene mixt. held for 5 h at 20°C; org. layer decanted; solvent evapd. (vac.); extd. (hexane); recrystd. (toluene/hexane=8/1); ESR;	A 100% B 86% C 90%

...Expand

: 603-33-8
triphenylbismuthane

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With hydrogen In xylene byproducts: C6H6; 60 atm, 124 h, 225°C;	99.4%
With hydrogen In xylene reduction of triphenyl Bi with H2 under a pressure of 60 at on heating at 250°C;;	99.4%
With hydrogen In xylene byproducts: C6H6; 60 atm, 124 h, 150°C;	6.9%

: sodium octahydrotriborate tridioxanate

: bismuth(III)

: 7440-69-9
bismuth

Conditions

Conditions	Yield
In water room temp.; X-ray diffraction, gravimetric anal.;	99%

: vanadocene

: 69202-61-5
{(C6F5)3Ge}2BiC2H5

A: 7440-69-9
bismuth

B: (C5H5)2VC2H5

C: (C5H5)2VGe(C6F5)3

Conditions

Conditions	Yield
In toluene mixt. held for 5 h at 20°C; org. layer decanted; solvent evapd. (vac.); extd. (hexane); recrystd. (toluene/hexane=8/1); ESR;	A 90% B 97% C 74%

...Expand

: 1076-43-3
benzene-d6

: 603-33-8
triphenylbismuthane

A: 7440-69-9
bismuth

B: 92-52-4
biphenyl

C: 1486-01-7
biphenyl-d10

D: 20637-23-4
2,3,4,5,6-pentadeuterio-biphenyl

Conditions

Conditions	Yield
In benzene-d6 Irradiation (UV/VIS); 40-50°C, 150 h;	A n/a B 2.5% C 2.3% D 95.2%

...Expand

: (4-bromobenzoylseleno)bis(4-methylphenyl)bismuth

A: 7440-69-9
bismuth

B: 5142-75-6
tri(p-tolyl)bismuth

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) 4-bromobenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);	A 1% B 95%

: 7787-60-2
bismuth(III) chloride

: 997-50-2
triethylstannane

A: 7440-69-9
bismuth

B: 994-31-0
chlorotriethylstannane

Conditions

Conditions	Yield
byproducts: H2; heating dry powdered BiCl3 with (C2H5)3SnH under reflux;;	A n/a B 93%
byproducts: H2; heating dry powdered BiCl3 with (C2H5)3SnH under reflux;;	A n/a B 93%

...Expand

: (4-methylbenzoylseleno)bis(4-methylphenyl)bismuth

A: 7440-69-9
bismuth

B: 5142-75-6
tri(p-tolyl)bismuth

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) 4-methylbenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);	A 1% B 93%

: (4-methoxybenzoylseleno)bis(4-methylphenyl)bismuth

A: 7440-69-9
bismuth

B: 33397-21-6
tris(4-methoxyphenyl)bismuth

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Se-(4-CH3C6H4)-4-methoxybenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);	A 1% B 92%

: (3-chloro-2,6-dimethoxybenzoylseleno)bis(4-methylphenyl)bismuth

A: 7440-69-9
bismuth

B: 5142-75-6
tri(p-tolyl)bismuth

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) 3-Cl-2,6-CH3Obenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);	A 1% B 92%

: bismuth(III) sulfide

: 1304-76-3
bismuth(III) oxide

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With carbon dioxide In neat (no solvent) byproducts: SO2, (BiO)2SO4; reaction in stream of CO2 under layer of salt;;	90%
With iron; pyrographite In melt melting with C in a flame- or crucible furnace; addition of Na2CO3 with formation of dross; complete reduction by addition of Fe;; removal of As and Sb as speiss;;
With pyrographite In melt melting an ore containing 25-30 % Bi with Fe oxide and C in a cupola furnace;; Bi with impurities of Sb, Pb, As and a small amount of Cu; Bi containing speiss, dross (0.2-0.6 % Bi) and further products;;

: 603-33-8
triphenylbismuthane

A: 7440-69-9
bismuth

B: 71-43-2
benzene

Conditions

Conditions	Yield
With sodium In ammonia	A n/a B 90%

: 7787-60-2
bismuth(III) chloride

: 88686-46-8
5-aza-2,2,8,8-tetramethylnonane-3,7-dione

A: 7440-69-9
bismuth

: tris(4-aza-1,7-dioxa-2,6-ditert-butylhepta-2,5-dien-1,4,7-triyl)bismuth

Conditions

Conditions	Yield
With (C2H5)3N In tetrahydrofuran byproducts: (C2H5)3NHCl; at -78 °C; extd. (pentane), crystd. from pentane at -28 °C;	A n/a B 90%

...Expand

: Yb(C4H8O)6(2+)*2(C6H5)3C(1-)=[Yb(C4H8O)6][(C6H5)3C]2

: 603-33-8
triphenylbismuthane

A: 7440-69-9
bismuth

B: 2C(C6H5)3(1-)*YbC6H5(C4H8O)3(2+)=(C(C6H5)3)2YbC6H5(C4H8O)3

Conditions

Conditions	Yield
In tetrahydrofuran Ph3Bi in THF was added to soln. of Yb-complex in THF, heated at 40-50°C for 24 h in evacuated sealed ampules; sepd. by centrifugation; elem. anal.;	A 90% B 68%

...Expand

: (benzoylseleno)bis(4-methylphenyl)bismuth

A: 7440-69-9
bismuth

B: 5142-75-6
tri(p-tolyl)bismuth

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) benzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);	A 1% B 90%

: 90-15-3
α-naphthol

: 33397-22-7
tri(naphthalen-1-yl)bismuth

: 7440-69-9
bismuth

Conditions

Conditions	Yield
130°C, 3 h;	89.1%

: bismuth(III) sulfide

A: 7440-69-9
bismuth

B: bismuth(III) sulfate

Conditions

Conditions	Yield
reaction at 800 °C;;	A 87.41% B 4.83%
reaction at 800 °C;;	A 87.41% B 4.83%
reaction at 700 °C;;	A 74.63% B 7.61%

: 34422-57-6
tris(pentafluorophenyl)bismuth

A: 7440-69-9
bismuth

B: bismuth hydroxide

C: 363-72-4
Pentafluorobenzene

D: 434-90-2
decafluorobiphenyl

Conditions

Conditions	Yield
With water	A 0% B n/a C 87% D 0%
With H2O	A 0% B n/a C 87% D 0%
With water	A 0% B n/a C n/a D 0%

...Expand

: 7732-18-5
water

: 7787-60-2
bismuth(III) chloride

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With Zn; HCl In water BiCl3 added to water with stirring, Zn powder added, stirred at room temp. for 2-4 h, mixture added to diluted aq. HCl for several min; ppt. filtered, washed (water), dried (vac., 60°C, 4 h); elem. anal.;	80%

: 617-86-7
triethylsilane

: 7787-60-2
bismuth(III) chloride

A: 7440-69-9
bismuth

B: 994-30-9
triethylsilyl chloride

Conditions

Conditions	Yield
byproducts: H2; heating dry powdered BiCl3 with triethyl silane under reflux;;	A n/a B 79%
byproducts: H2; heating dry powdered BiCl3 with triethyl silane under reflux;;	A n/a B 79%

...Expand

: bismuth(III) 2-ethylhexanoate

: 7440-69-9
bismuth

Conditions

Conditions	Yield
With 1-dodecylthiol In tetrahydrofuran-d8 byproducts: 2-ethylhexanoic acid, CH3(CH2)11SS(CH2)11CH3; Irradiation (UV/VIS); (N2); addn. of thiol deriv. to soln. of bismuth compd. in THF-d8, exposure to 365 nm light for 4 d at power of 7mW/cm**2; NMR monitoring;	75%
With 1-dodecylthiol In tetrahydrofuran byproducts: 2-ethylhexanoic acid, CH3(CH2)11SS(CH2)11CH3; Irradiation (UV/VIS); (N2); addn. of 3 equiv. of thiol deriv. to soln. of bismuth compd. in dry THF, exposure to ambient light at room temp. for 24 h or 2 wks; exposure to air, cenrifugation for 2 min at 9000 rpm, removing supernatant, suspending in THF, centrifugation, drying at room temp. in vac.;

: 33397-22-7
tri(naphthalen-1-yl)bismuth

: 87-66-1
2-hydroxyresorcinol

: 7440-69-9
bismuth

Conditions

Conditions	Yield
130°C, 4 h;	70.5%
130°C, 3 h;	64.9%
130°C, 2 h;	49.9%
130°C, 1 h;	17.5%

: praseodymium

bis[tris(pentafluorophenyl)germyl]mercury: bis[tris(pentafluorophenyl)germyl]mercury

: 69202-61-5
{(C6F5)3Ge}2BiC2H5

A: 7440-69-9
bismuth

B: praseodymium heptakis[tris(pentafluorophenyl)germanyl]dimercurate*3(dimethoxyethane)

C: mercury

Conditions

Conditions	Yield
In 1,2-dimethoxyethane fivefold excess of compound I in evacuated ampul shaken for 5 h at 20°C; centrifugated, decanted, solvent removed (vac.), ppt. washed (toluene);dried (vac.);	A 70% B 263.6 % C 22.5%

...Expand

: 5153-28-6
diphenylbismuth(III) chloride

A: 7440-69-9
bismuth

B: Bi(3+)*C6H5(1-)

C: Bi(3+)*2C6H5(1-)

Conditions

Conditions	Yield
other Radiation; on neutron radiation;	A 56.5% B 16.4% C 2.4%
other Radiation; on neutron radiation;	A 56.5% B 16.4% C 2.4%

...Expand

: Et2BiTeEt

A: 7440-69-9
bismuth

: Bi2Te

Conditions

Conditions	Yield
With (Z)-9-octadecen-1-amine at 100℃; for 14h; Inert atmosphere; Schlenk technique;	A n/a B 55.4%

: Li[Al(perfluoro-tertbutoxide)4]

: Bi5(3+)*3AsF6(1-)*SO2=[Bi5](AsF6)3*SO2

: 87-85-4
Hexamethylbenzene

A: 7440-69-9
bismuth

B: 874445-84-8
[(C6Me6)H][Al(OC(CF3)3)4]

C: [Bi5(hexamethylbenzene)4][Al(OC(CF3)3)4]3

D: [Bi4OF2Cl6(hexamethylbenzene)4][Al(OC(CF3)3)4]2*hexamethylbenzene

Conditions

Conditions	Yield
In dichloromethane byproducts: LiAsF6; under N2, 1 equiv. of Li-compd., 1 equiv. of Bi-compd. and 2 equiv. of C6Me6 were stirred in CH2Cl2 for 4 h, 5 °C; soln. was concd., held at -24 °C for 2 d, crystals were sepd., another crop was given after 2 d at this temp., elem. anal.; keeping the mother liq. for 2 weeks, Bi, the Bi4OF2Cl6(2+) and C6Me6H(1+)-cation con tg. compds. were formed.;	A n/a B n/a C 55% D n/a

...Expand

: 7440-69-9
bismuth

aqueous H2 O2: aqueous H2 O2

: 7664-93-9
sulfuric acid

: 7440-44-0
pyrographite

: 68283-19-2
2-butyl-5-hydroxymethyl-1H-imidazole

: 7440-06-4
platinum

: 68282-49-5
2-butyl-1H-imidazole-5-carboxaldehyde

Conditions

Conditions	Yield
With sodium hydroxide In water	100%
With sodium hydroxide In water	98.2%
With sodium hydroxide In methanol; water	94.5%

...Expand

: 7440-69-9
bismuth

: 7553-56-2
iodine

: 7787-64-6
bismuth(III) iodide

Conditions

Conditions	Yield
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;	100%
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;	100%
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;	100%

: 7440-69-9
bismuth

: 7726-95-6
bromine

: 7787-58-8
bismuth(III) bromide

Conditions

Conditions	Yield
In melt passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;	100%
In melt passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;	100%
In melt passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;	100%

: 7440-69-9
bismuth

: 7727-37-9
nitrogen

: bismuth nitride

Conditions

Conditions	Yield
In neat (no solvent) Electrochem. Process; cothodic pulverization within 10 hours of Bi under pure N2 (0.1 - 0.3 Torr), glow-discharge at 1000-1500 V; anode Fe; description of the aparatus given;; 359.8 mg BiN; deposition of 12.1 weight % on cathode, of 45.4 weight % on anode, 25.2 weight % on glass parts of the aparatus, 17.3 weight % on Fe- (or Al-) protecting ring of the aparatus;;	100%
In further solvent(s) Electric Arc; between Bi-cathode and Cu-anode in a liquid mixture of argon and nitrogen;;
In further solvent(s) Electric Arc; between Bi-cathode and Cu-anode in a liquid mixture of argon and nitrogen;;
In neat (no solvent) cathodic pulverization of Bi during glow discharge under N2 (0.1 - 0.3 torr);;

: 7440-69-9
bismuth

: 7440-23-5
sodium

: sodium bismuthide

Conditions

Conditions	Yield
In neat (no solvent) heating a mixture of Na and Bi (molar ratio 3 : 1) at 775°C under Ar;;	100%
determined by thermal analysis;;
determined by chemical methods;;

: 7440-69-9
bismuth

: 7704-34-9
sulfur

: bismuth(III) sulfide

Conditions

Conditions	Yield
In neat (no solvent) under dry N2 atm. in vac. glovebox; mixt. of Bi and S was transferred inquartz tube, with was flame sealed under vac.; tube was heated to 650.d egree.C for 48 h; stayed at 650°C for 2 ds; cooled to 50°Cin 10 h; ground into powder;	100%
In melt by melting at possible min. temp.;
In melt addition of S to molten Bi at 600-700°C;; Bi content 1 - 2 %;;

: 10025-67-9
disulfur dichloride

: 7440-69-9
bismuth

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
heating Bi with S2Cl2 at 138.6°C, 10 hours;;	100%
addition of S2Cl2 to Bi;;
addition of S2Cl2 to Bi;;

: 7440-69-9
bismuth

: 7782-50-5
chlorine

: 7787-60-2
bismuth(III) chloride

Conditions

Conditions	Yield
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;	100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;	100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;	100%

: 7440-69-9
bismuth

: 7782-49-2
selenium

: bismuth(III) selenide

Conditions

Conditions	Yield
In neat (no solvent) under dry N2 atm. in vac. glovebox; mixt. of Bi and Se was transferred in quartz tube, with was flame sealed under vac.; tube was heated to 600°C for 48 h; stayed at 600°C for 2 ds; cooled to 50°C in 10 h; ground into powder;	100%
high pressure at 420°C;
on Al plate at 47-180°C; tempering under m.p. of Se; no reaction at 130°C without tempering;

: 7440-69-9
bismuth

: 7789-33-5
iodine(I) bromide

: 7787-58-8
bismuth(III) bromide

Conditions

Conditions	Yield
In melt	100%
In melt	100%
In melt addition of Bi powder to molten IBr;; extraction with CCl4;;
In melt addition of Bi powder to molten IBr;; extraction with CCl4;;

: 7440-69-9
bismuth

: tellurium

bismuth telluride: bismuth telluride

Conditions

Conditions	Yield
In neat (no solvent) Bi and Te ground, pressed at 650 K, homogenizing calcination (570 K, 400h) in evacuated quartz ampoules; single phase (X-ray- and electron-microprobe analyses);	100%

: 7440-69-9
bismuth

: 7782-49-2
selenium

: tellurium

Bi(x)(Te0.9Se0.1)3 x:1.96-2.04;: Bi(x)(Te0.9Se0.1)3 x:1.96-2.04;

Conditions

Conditions	Yield
In neat (no solvent) Bi, Se and Te ground, pressed at 650 K, homogenizing calcination (570 K, 400h) in evacuated quartz ampoules; single phase (X-ray- and electron-microprobe analyses);	100%

...Expand

: 7440-69-9
bismuth

: 7782-49-2
selenium

: tellurium

Bi(x)(Te0.8Se0.2)3 x:1.8-2.2;: Bi(x)(Te0.8Se0.2)3 x:1.8-2.2;

Conditions

Conditions	Yield
In neat (no solvent) Bi, Se and Te ground, pressed at 650 K, homogenizing calcination (730 K, 400h) in evacuated quartz ampoules; single phase (X-ray- and electron-microprobe analyses);	100%

...Expand

: 7440-69-9
bismuth

: potassium sulfide

: bismuth(III) sulfide

: Bi2K8S7

Conditions

Conditions	Yield
differential thermal anal.;	100%

...Expand

: 7440-69-9
bismuth

: 7440-09-7
potassium

: 7704-34-9
sulfur

: potassium metathiobismuthite

Conditions

Conditions	Yield
In neat (no solvent)	100%
differential thermal anal.;	100%

...Expand

: 7440-69-9
bismuth

: silver perchlorate

: bismuth(III) perchlorate

Conditions

Conditions	Yield
In acetonitrile Electrolysis; electrolysis of AgClO4 in acetonitrile, Bi anode;; not isolated;;	100%

: 7440-69-9
bismuth

: potassium sulfide

: bismuth(III) sulfide

: K2Bi4S7

Conditions

Conditions	Yield
differential thermal anal.;	100%

...Expand

: 7440-69-9
bismuth

: bismuth(III) sulfide

: potassium metathiobismuthite

: Bi3KS5, low temperature

Conditions

Conditions	Yield
annealing at 650°C; differential thermal anal.;	100%

...Expand

: 7440-69-9
bismuth

: bismuth(III) sulfide

: potassium metathiobismuthite

: Bi3KS5, high temperature

Conditions

Conditions	Yield
quenching from 830°C; differential thermal anal.;	100%

...Expand

: 7440-69-9
bismuth

: europium

: Eu4Bi3

Conditions

Conditions	Yield
In neat (no solvent) Ar atm.; stoichiometric ratio, heating (1100°C, 24-48 h);	100%
In neat (no solvent) induction heating at 1400°C of stoich. amounts of elements in a sealed tungsten crucible; XRD;
In neat (no solvent, solid phase) Electric Arc; Bi and Eu were arc-melted under Ar in silica ampules, heated to 700°C for 6 h, at 1050°C for 6 h, quenched to room temp., reheatedat 1100°C for 36 h, cooled to room temp. at 3°C/h;

: 7440-69-9
bismuth

: 7439-96-5
manganese

: Yb

: Yb14MnBi11

Conditions

Conditions	Yield
Stage #1: bismuth; manganese; Yb for 1h; Milling; Inert atmosphere; Stage #2: at 1125 - 1225℃; for 96h; Inert atmosphere; Sealed tube;	100%

...Expand

: 7440-69-9
bismuth

: 7782-49-2
selenium

: caesium selenide

: 7440-43-9
cadmium

: Cs1.13Cd1.13Bi2.87Se6

Conditions

Conditions	Yield
In neat (no solvent) at 750℃; for 48h; Inert atmosphere;	100%

...Expand

: 7440-69-9
bismuth

: 7440-31-5
tin

: lithium sulfide

: 7704-34-9
sulfur

: Li0.97Sn2.06Bi4.97S10

Conditions

Conditions	Yield
Stage #1: bismuth; tin; lithium sulfide; sulfur at 800℃; under 0.00150015 Torr; for 10h; Inert atmosphere; Glovebox; Sealed tube; Stage #2: at 800℃; for 26h;	100%

...Expand

: 7440-69-9
bismuth

: 7664-93-9
sulfuric acid

: bismuth(III) sulfate

Conditions

Conditions	Yield
In further solvent(s) H2SO4 was added to Bi in HNO3 with stirring and heating; more H2SO4 wasadded and suspn. was heated for 40 h; heated in a muffle furnace at 648K; elem. anal.;	99.8%
In sulfuric acid byproducts: SO2; by dissolving in boiling concd. H2SO4;;
In sulfuric acid byproducts: SO2; very weak reaction with diluted H2SO4.;;
In nitric acid Bi dissolved in HNO3 and treated with H2SO4, heated for several hours at 380 °C;;

Bismuth Consensus Reports

Reported in EPA TSCA Inventory.

Bismuth Specification

The Bismuth, with the cas registry number 7440-69-9, is a kind of silver white or tiny red metal. This chemical is soluble in hot sulfuric acid, nutirc acid and aqua regia while insoluble in water. Besides, being stable chemically, it is incompatible with strong acids, strong oxidizing agents, nitrosyl fluoride, fused ammonium nitrate, interhalogen compounds, chlorine. This chemical could be produced from using zone melting method to refine bismuth metal.

Its product categories are including Industrial/Fine Chemicals; Inorganics; FUNGICIDE; Bismuth; Metal and Ceramic Science; Metals; BismuthMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; AAS; AAS CRMsAlphabetic; AASSpectroscopy; Application CRMs; B; BI - BZSpectroscopy; Matrix Selection; Nitrate; Spectroscopy.

The characteristics of this chemical are as follows: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 0; (5)Exact Mass: 208.980383; (6)MonoIsotopic Mass: 208.980383; (7)Heavy Atom Count: 1; (8)Covalently-Bonded Unit Count: 1; (9)Melting point: 271 °C; (10)Boiling Point: 1560 °C; (11)Density: 9.8 g/mL at 25 °C; (12)Vapor Pressure: <0.1 mm Hg ( 20 °C).

As to its usage, it is widely applied in many ways. It could be used in the preparation of semiconductor high purity material, high purity bismuth chemical and also as the cooling agent in the atomic reactor; It could also be used as the analysis reagent.

When you are using this chemical, you should be very cautious. For one thing, it is corrosive which may destroy living tissue on contact. For another thing, it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water.

Due to so many dangers above, you should take the different measures to deal with different cases. Wear suitable protective clothing, gloves and eye/face protection. And if in case of contact with eyes, rinse immediately with plenty of water and seek medical advice, and if in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Besides, keep it away from sources of ignition - No smoking.

Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: [Bi]
(2)InChI: InChI=1S/Bi
(3)InChIKey: JCXGWMGPZLAOME-UHFFFAOYSA-N

Below are the toxicity information of this chemical:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
man	LDLo	unreported	221mg/kg (221mg/kg)		"Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
mouse	LD50	oral	10gm/kg (10000mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986.
rabbit	LDLo	unreported	535mg/kg (535mg/kg)	BEHAVIORAL: FOOD INTAKE (ANIMAL) KIDNEY, URETER, AND BLADDER: URINE VOLUME DECREASED BEHAVIORAL: COMA	Journal of Pharmacology and Experimental Therapeutics. Vol. 28, Pg. 121, 1926.
rat	LD50	oral	5gm/kg (5000mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986.

Product Name

Bismuth

Synthetic route

Bismuth Consensus Reports

Bismuth Specification

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