Conditions | Yield |
---|---|
With phosgene In acetone at 20℃; for 0.25h; Reagent/catalyst; | 100% |
With Fe3+-montmorillonite; propionic acid at 25℃; for 6h; | |
With propionic acid; K 10-montmorillonite; FeCl3; mixture of, dried at 120 degrees C, grounded at 25℃; for 6h; |
Conditions | Yield |
---|---|
Kinetics; Irradiation (UV/VIS); in glass vessel or uviol vessel, wavelenght higher than 2540Å;; | A 100% B 100% |
Kinetics; Irradiation (UV/VIS); at room temperature, in quartz vessel; equilibrium; wavelenght lower than 2540Å;; | A 92.3% B 92.3% |
995 °C; part of a Mg-S-I water splitting cycle; | A 31% B 31% |
Conditions | Yield |
---|---|
In liquid sulphur dioxide under Ar; recrystn. (SO2), elem. anal.; | A 99% B n/a |
B
iodine
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) vac.; equimolar ratio, heating (200°C 20 d, 800°C 30 d); XRD; | A n/a B 98.5% C n/a |
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) byproducts: pyridine; heated at 130°C; washed with acetone-water (5:1), dried in vac.; elem. anal.; | A 94% B 96.5% |
Conditions | Yield |
---|---|
With hydrogenchloride byproducts: H2O, H2S, SO2; in presence of KI; | A 90% B n/a |
With HCl byproducts: H2O, H2S, SO2; in presence of KI; | A 90% B n/a |
{Pt(2)Br2}
B
iodine
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) byproducts: pyridine; heated at 120°C; washed with acetone-water (5:1), dried in vac.; elem. anal.; | A 85% B 72.7% |
iodide
iodine
Conditions | Yield |
---|---|
With ammonium peroxosulfate; iron(III) In hydrogenchloride byproducts: SO4(2-); Irradiation (UV/VIS); at 22°C with UV irradiation for 15 min; subsequent stirring in daylight for 20 min; mechanism discussed;; | 80.2% |
With ammonium peroxosulfate; iron(III) In hydrogenchloride byproducts: SO4(2-); at 22°C in daylight for 35 min;; | 73.9% |
With ammonium peroxosulfate; iron(III) In hydrogenchloride byproducts: SO4(2-); at 22°C in the dark for 15 min; subsequent stirring in daylight for 20 min;; | 69.6% |
Conditions | Yield |
---|---|
With HNO3 or I2O5 or H5IO6 In water High Pressure; mixt. of Bi compd., HIO3, HNO3 (or I2O5 or H5IO6) and H2O was sealed in autoclave; heated to 215°C; held for 5 d; cooled at rate 10°C/h to room temp.; decanted; washed (EtOH, H2O); air-dried; | A 75% B n/a |
Conditions | Yield |
---|---|
With triethylamine In ethanol for 4h; | 74% |
iodine pentoxide
B
iodine
Conditions | Yield |
---|---|
In water High Pressure; UO2, I2O5, KCl, and water were heated in autoclave at 10°C/min to425°C, after 72 h autoclave was cooled over 24 h to 23°C; washed with MeOH and dried; | A 73% B n/a |
Conditions | Yield |
---|---|
In not given in acidic soln.; | 70% |
In not given in acidic soln.; | 70% |
Conditions | Yield |
---|---|
Stage #1: N-trifluoroacetic-3-nitroaniline With sodium hydride In tetrahydrofuran at 0℃; for 1h; Stage #2: methyl iodide In tetrahydrofuran at 20℃; | 66% |
Conditions | Yield |
---|---|
In water High Pressure; UO2, I2O5, KCl, and water were heated in autoclave to 180°C, after 72 h autoclave was cooled at 9°C/h to 23°C; washed with MeOH and dried; | A n/a B 60% C n/a |
1,2-Diiodobenzene
boron triiodide
A
iodine
B
5,10-diiodo-5,10-dihydroboranthrene
Conditions | Yield |
---|---|
stirring mixt. of educts at 180°C for 5 h; I2 removed by sublimation at 60°C/0.1 Torr, sublimation of products; | A n/a B 56% |
Conditions | Yield |
---|---|
In neat (no solvent) at room temp.; | 38% |
iodine
Conditions | Yield |
---|---|
in presence of O3 at room temp.; | 2.8% |
in presence of O3 at room temp.; | 2.8% |
With manganese(IV) oxide at 370°C; |
Conditions | Yield |
---|---|
potassium polymanganite(IV) In solid byproducts: O2; mixt. of KIO3 and potassium polymanganate heated (400-600°C, 2h, air); X-ray diffraction; | A 1% B n/a |
2-(iodomethyl)isoindoline-1,3-dione
iodine
Conditions | Yield |
---|---|
Zerstzung bei Raumtemperatur; |
2,4-dichloro-6-diiodomethyl-[1,3,5]triazine
iodine
Conditions | Yield |
---|---|
at 25℃; |
8-iodo-3,7-dihydro-purine-2,6-dione
iodine
Conditions | Yield |
---|---|
at 200℃; Abspaltung; |
Conditions | Yield |
---|---|
at 130℃; Zersetzung; |
(1R)-3-bromo-1,8,8-trimethyl-3-aza-bicyclo[3.2.1]octane-2,4-dione
hydrogen iodide
iodine
hydrogen iodide
iodine
Conditions | Yield |
---|---|
at 150℃; |
sulfur dioxide
water
iodine
A
sulfuric acid
B
hydrogen iodide
Conditions | Yield |
---|---|
0 - 25 °C; part of a Mg-S-I water splitting cycle; | A 100% B 100% |
Conditions | Yield |
---|---|
In gas | 100% |
In solid | 100% |
In further solvent(s) with I2 dissolved in organic solvents; | 100% |
Conditions | Yield |
---|---|
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;; | 100% |
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;; | 100% |
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;; | 100% |
Conditions | Yield |
---|---|
In neat (no solvent) in vac., for 0% excess Tl at 540°C, for 1% excess Tl at 500, 540°C, for 2, 5, 10, 20% excess Tl at 450, 500, 540°C; sublimed, elem. anal., IR, XRD; | 100% |
In neat (no solvent) in vac., for 20% excess Tl at 400°C; sublimed, elem. anal., IR, XRD; | 99.1% |
In neat (no solvent) in vac., for 0% excess Tl at 500°C; sublimed, elem. anal., IR, XRD; | 98.9% |
Conditions | Yield |
---|---|
Kinetics; byproducts: H2, LiI; Interaction of initial cryst. materials in molar ratio LiBH4:I2 = 1.50 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 100% |
byproducts: H2, LiI; Interaction of initial cryst. materials in molar ratio LiBH4:I2 = 1.35 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 99.5% |
Kinetics; byproducts: H2, LiI; Interaction of initial cryst. materials in molar ratio LiBH4:I2 = 2.0 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 99.8% |
Kinetics; byproducts: H2, LiI; Interaction of initial cryst. materials in molar ratio LiBH4:I2 = 2.5 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 95.4% |
byproducts: H2, HI; Grinding of initial materials (molar ratio = 1) while being cooled withliq. N2, thorough mixing, transferring of mixt. to a thermographic ampoule and heating in vac. or N2.; Sepn. of gas mixt. by fractional condensation. Detn. of composition after the thermography by gas volumetric anal.; |
Conditions | Yield |
---|---|
byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 1.35 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 100% |
byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 1.5 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 97.7% |
Kinetics; byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 2.5 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 94% |
Kinetics; byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 2.0 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.; | 88.7% |
byproducts: H2, HI; Grinding of initial materials (molar ratio = 1) while being cooled withliq. N2, thorough mixing, transferring of mixt. to a thermographic ampoule and heating in vac. or N2.; Sepn. of gas mixt. by fractional condensation. Detn. of composition after the thermography by gas volumetric anal.; |
iodine
tungsten(VI) chloride
Conditions | Yield |
---|---|
In neat (no solvent) Ar atmosphere, sealed ampoule, formation of black melt at 300°C, tube furnace (150°C), crystn. (3 months); | 100% |
Conditions | Yield |
---|---|
In dichloromethane first at -30°c, than at room temp. for 10min stirring, reducing of the soln., adding Et2O/pentane; drying at 25°C (vacuo), elem. anal.; | 100% |
Conditions | Yield |
---|---|
In tetrachloromethane Kinetics; Irradiation (UV/VIS); Kinetics of the reaction of Co(H2CC6H5)2(bipy)2ClO4 with I2 under irradiation with light at 517 nm is investigated.; PhCh2I and Co(H2CC6H5)I(bipy)2ClO4 are the main products.; | A n/a B 100% |
Conditions | Yield |
---|---|
In tetrachloromethane Irradiation (UV/VIS); Irradiation at 509 nm in CCl4; Estimation of the quantum yield of the photochemical reaction. Yield of the products estimated by g.l.c.; | A 0.02% B <1 C 100% |
Conditions | Yield |
---|---|
In tetrachloromethane Kinetics; byproducts: C2H6, CH4; Irradiation (UV/VIS); Kinetics of the reaction of Co(CH3)2(H3CCNOHC(CH3)NC3H6NC(CH3)CNOCH3) with I2 under irradiation with light at 517 nm is investigated.; MeI and Co(CH3)I(H3CCNOHC(CH3)NC3H6NC(CH3)CNOCH3) are the main products, C2H6 and CH4 are byproducts.; | A n/a B 100% |
Conditions | Yield |
---|---|
In tetrachloromethane Kinetics; Irradiation (UV/VIS); Kinetics of the reaction of Co(CH3)(H3CCNOHONCCH3)2(C5H5N) with I2 under irradiation with light at 517 nm is investigated.; MeI and CoI(H3CCNOHONCCH3)2(C5H5N) are the products.; | A n/a B 100% |
Conditions | Yield |
---|---|
In tetrachloromethane Kinetics; Irradiation (UV/VIS); Kinetics of the reaction of Co(C2H5)(H3CCNOHONCCH3)2(C5H5N) with I2 under irradiation with light at 517 nm is investigated.; MeI and CoI(H3CCNOHONCCH3)2(C5H5N) are the products.; | A n/a B 100% |
iodine
Conditions | Yield |
---|---|
With sodium thiosulfate In acetone addn. of iodine to a soln. of Co-compd., stirring at room temp. for 1 h, change of colour from brown-red to red on addn. of aq. Na2S2O3; extg. the aq. layer with CH2Cl2, drying over Na2SO4, filtration, evapn., chromy. (Al2O3, ethyl acetate), elem. anal.; | 100% |
Conditions | Yield |
---|---|
In not given react. (N2, CO or Ar); elem. anal.; | 100% |
Conditions | Yield |
---|---|
In dichloromethane elem. anal.; | 100% |
selenium
arsenic pentafluoride
fluorosulfonylchloride
sulfur dioxide
iodine
Conditions | Yield |
---|---|
byproducts: AsF3; SO2 and AsF5 were condensed into Se and I2; after 16 h no insoluble material was observed; condensed SO2ClF into the soln.; react. time 3 h; slowly (ca.20 h) condension; cooling; crystn.; washing; removed volatile materials by evacuation; subjected to vac. for <0.2 h; elem. anal.; | 100% |
byproducts: AsF3; SO2 and AsF5 were condensed onto Se and I2; after 16 h no insoluble material was observed; condensation of SO2ClF onto the soln.; react. time 7 h; slowly (ca.20 h) condensation of solvent; cooling; crystn.; washing; removal of volatile material by evacuation; elem. anal.; | 104 % |
Conditions | Yield |
---|---|
AsF5 was condensed onto a mixture of Se and I2 in liq. SO2; react. time 4 h; slowly (ca.20 h) condensation of solvent; crystn.; after 16 h removal of volatile material by evacuation; elem. anal.; X-ray diffraction; | 100% |
AsF5 was condensed onto a mixture of Se and I2 in liq. SO2; react. time 6 h; slowly (ca.20 h) condensation; crystn.; after 16 h removal of volatile materials by evacuation; elem. anal.; X-ray diffraction; | 106 % |
anti-2-norbornene-7-yl-trimethyl tin
iodine
trimethylstannyl iodide
Conditions | Yield |
---|---|
In methanol | 100% |
In methanol | 100% |
In dimethyl sulfoxide | 88% |
iodine
methyl 3-(tri-n-butylstannyl)propionate
Conditions | Yield |
---|---|
In tetrachloromethane byproducts: CH3(CH2)3I; | 100% |
benzimidazolin-2-ylidene(chloro)gold
iodine
Conditions | Yield |
---|---|
In dichloromethane protective gas: argon; stirring mixture (20 h/room temp.);; pptn.; filtration; washing (CH2Cl2); drying; elem. anal.;; | 100% |
Conditions | Yield |
---|---|
In not given | 100% |
iodine
Conditions | Yield |
---|---|
In nitromethane-d3 not isolated, monitored by NMR; | 100% |
iodine
bis[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]distilbene
[((Si(CH3)3)2CH)3C6H2]SbI2
Conditions | Yield |
---|---|
In tetrachloromethane room temp.; | 100% |
iodine
Conditions | Yield |
---|---|
In further solvent(s) excess of I2, stirring in chloronaphthalene (60-70°C, 1 h); cooling, collection (filtration), washing (EtOH), drying (vac.); elem. anal.; | 100% |
Conditions | Yield |
---|---|
In pentane Ar-atmosphere; stirring (40°C, 3 h); detd. by NMR spectroscopy; | 100% |
In pentane all manipulations with exclusion of air and moisture; soln. of compds. heated at 40°C for 3 h; controlled by NMR; volatiles evapd. by oil pump; elem. anal.; |
Conditions | Yield |
---|---|
In acetonitrile soln. of iodine addn. to soln. of Tl-compd., mixing, standing (dark, 220h, room temperature), evacuation (under Ar, room temperature, then wate r bath, distillation of I-compd.), product remaining in solid residue; | A 99% B 100% |
Conditions | Yield |
---|---|
In neat (no solvent) Ar atm.; molar ratio Te:I2:AlI3 1:2:1, heating (150-200°C, several hours); | 100% |
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