As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t
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TIANFUCHEM--1745-81-9--2-Allylphenol factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relation
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryProduct name:2-Allylphenol CAS No:1745-81-9 Appearance: Content:98% Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application: Pharmaceuti
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inquiry2-Allylphenol CAS:1745-81-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
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inquiry1745-81-9 2-AllylphenolAppearance:white powder Storage:RT Package:according to customers' requirements Application:pharma Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or CNF ect...)or according to your demand. Port:A
Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
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2-Allylphenol Basic information Product Name: 2-Allylphenol Synonyms: 1-ALLYL,2-HYDROXY-BENZENE;2LP;2-prop-2-enylphenol;InChI=1/C9H10O/c1-2-5-8-6-3-4-7-9(8)10/h2-4,6-7,10H,1,5H;2-AL;2-(2-propenyl)-pheno;o-allyl-pheno;Phenol, o-allyl- CAS: 1
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:1745-81-9
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inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:1745-81-9
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inquiryHangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
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inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
Conditions | Yield |
---|---|
In toluene at 250℃; for 1.75h; Claisen rearrangement; microwave irradiation; | 100% |
In chlorobenzene at 250℃; for 1.75h; Claisen rearrangement; microwave irradiation; | 100% |
In N,N-dimethyl-aniline at 250℃; for 1h; Claisen Rearrangement; Inert atmosphere; Microwave irradiation; Sealed tube; | 100% |
2-allyl-1-(trimethylsiloxy)benzene
2-Allylphenol
Conditions | Yield |
---|---|
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0666667h; Green chemistry; | 98% |
With methanol at 20℃; for 0.333333h; | 85% |
2-(iodomethyl)-2,3-dihydro-1-benzofuran
2-Allylphenol
Conditions | Yield |
---|---|
With dimethylboron bromide; tetra-(n-butyl)ammonium iodide; triethylamine In dichloromethane at 0℃; for 12h; | 92% |
Conditions | Yield |
---|---|
In water | 87% |
N-(2-allyloxybenzylidene)-2-phenylthiobenzenamine
A
biphenyl
B
2-(benzothiazol-2-yl)phenol
C
2-Allylphenol
Conditions | Yield |
---|---|
at 150 - 650℃; under 0.013 Torr; for 0.25h; Pyrolysis; | A 2% B 84% C 9% |
Conditions | Yield |
---|---|
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h; | 82% |
3-bromochroman
2-Allylphenol
Conditions | Yield |
---|---|
In acetonitrile Product distribution; electrochemical reductions of derivatives; 0.1 M Et4NClO4, -2.05 V; | 80% |
In acetonitrile electrochemical reduction, 0.1M Et4NClO4, -2.05 V; | 80% |
Conditions | Yield |
---|---|
With [Ir(1,5-cyclooctadiene)2]PF6 In octane at 120℃; for 20h; | A 80% B 8% |
1-tert-butyldimethylsilyloxy-2-(2-propenyl)benzene
2-Allylphenol
Conditions | Yield |
---|---|
With copper(ll) bromide In acetonitrile at 20℃; for 3h; | 77% |
1-allyl-2-(benzyloxy)benzene
2-Allylphenol
Conditions | Yield |
---|---|
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h; | 68% |
Conditions | Yield |
---|---|
With copper; copper(II) perchlorate In diethyl ether | 65% |
With 1.) K; zinc(II) chloride 1.) xylene, 3 h, reflux, 2.) 13 h, reflux; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With C6H10BBr3 In dichloromethane at 20℃; for 0.0833333h; Claisen rearrangement; Inert atmosphere; | A 61% B 12% |
With aluminium(III) iodide In carbon disulfide at -70℃; for 3.5h; | A 26% B 4.5% |
at 200℃; for 4h; Claisen rearrangement; neat (no solvent); | |
With tetrabutylammomium bromide at 245℃; for 0.5h; Claisen Rearrangement; Microwave irradiation; |
allyl phenyl ether
A
2-methyl-2,3-dihydro-1-benzofuran
B
2-Allylphenol
Conditions | Yield |
---|---|
With silica gel at 60℃; for 5h; | A 60% B 33% |
With silica gel at 60℃; for 5h; | A 60% B 33% |
With silica gel at 60℃; for 5h; Product distribution; other allylaryl ethers; variation of reaction time, also in benzene (reflux); | A 60% B 33% |
Conditions | Yield |
---|---|
Stage #1: 2-amino-phenol With hydrogenchloride; water; isopentyl nitrite Stage #2: 3-chloroprop-1-ene With ferrous(II) sulfate heptahydrate; dimethyl sulfoxide In water for 0.416667h; | A 54% B n/a |
allyl phenyl ether
A
4-(prop-2-enyl)phenol
B
2-Allylphenol
C
phenol
Conditions | Yield |
---|---|
With β‐cyclodextrin In water at 25℃; for 0.5h; Irradiation; | A 21.9% B 40.2% C 2.1% |
With β‐cyclodextrin In water at 25℃; for 0.5h; Quantum yield; Irradiation; without β-CD, in nitrogen or oxygen atmosphere; | A 21.9% B 40.2% C 2.1% |
In methanol Product distribution; Kinetics; Quantum yield; Further Variations:; Solvents; Reagents; photo-Claisen rearrangement; Irradiation; | |
In butan-1-ol at 35℃; for 0.0833333h; Temperature; Time; Concentration; Claisen Rearrangement; Flow reactor; UV-irradiation; |
N-(2-allyloxybenzylidene)-2-phenoxybenzenamine
A
2-phenylbenzo[d]oxazole
B
2-(2-Hydroxyphenyl)benzoxazole
C
2-Allylphenol
Conditions | Yield |
---|---|
at 130 - 650℃; under 0.01 Torr; for 0.416667h; Pyrolysis; | A 14% B 36% C 6% |
3-chloroprop-1-ene
phenol
A
allyl phenyl ether
B
allyl 2-allylphenyl ether
C
1-allyl-4-(allyloxy)benzene
D
2-Allylphenol
Conditions | Yield |
---|---|
With potassium hydroxide; phthalocyanine VII at 180℃; for 2h; Alkylation; Further byproducts given; | A 35% B 10% C 5% D 20% |
With potassium hydroxide; phthalocyanine III at 180℃; for 2h; Alkylation; | A 20% B 11% C 4% D 15% |
N-(2-allyloxybenzylidene)-2-methylbenzenamine
A
2-(1H-indol-2-yl)phenol
B
N-salicylidene-o-methylaniline
C
2-Allylphenol
Conditions | Yield |
---|---|
at 120 - 650℃; under 0.02 Torr; for 0.333333h; Pyrolysis; | A 35% B 7% C 5% |
2-Allylphenol
Conditions | Yield |
---|---|
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h; | 31% |
N-nitroso-N-cyclopropylurea
phenol
C
allyl phenyl ether
D
2-Allylphenol
Conditions | Yield |
---|---|
With caesium carbonate In dichloromethane at 5 - 8℃; for 0.833333h; Further byproducts given; | A 17% B 12% C 5.5% D 6% |
Conditions | Yield |
---|---|
With hydroquinone In various solvent(s) at 200℃; for 24h; Addition; | A 10% B 3.3% C 7% D 0.3% |
Conditions | Yield |
---|---|
at 190℃; Kinetics; |
Conditions | Yield |
---|---|
at 200℃; Kinetics; |
2-allyl-phenylamine
2-Allylphenol
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite anschliessend Erwaermen; |
2-allyloxybenzoic acid
2-Allylphenol
Conditions | Yield |
---|---|
With 2,3-Dimethylaniline |
2-allyloxybenzoic acid
A
2-Hydroxy-3-(2-propenyl)-benzoesaeure
B
2-Allylphenol
Conditions | Yield |
---|---|
at 170 - 235℃; | |
at 180℃; |
2-Hydroxy-3-(2-propenyl)-benzoesaeure
2-Allylphenol
Conditions | Yield |
---|---|
With 2,3-Dimethylaniline | |
at 300℃; |
4-hydroxy-3-allyl-benzoic acid
2-Allylphenol
Conditions | Yield |
---|---|
With quinoline beim Erhitzen bis zum Sieden; |
Conditions | Yield |
---|---|
With hydrazine hydrate In ethanol for 14h; Solvent; Reflux; | 100% |
With ethanol; lithium; nickel dichloride; 4,4'-di-tert-butylbiphenyl In tetrahydrofuran at 20℃; for 12h; | 99% |
With hydrogen; NiCl2-Li-[poly(2-vinyl-naphthalene)-co-(divinylbenzene)] In tetrahydrofuran at 20℃; under 760.051 Torr; for 1.5h; | 98% |
Conditions | Yield |
---|---|
tris(triphenylphosphine)ruthenium(II) chloride at 100℃; for 1h; | 100% |
With potassium tert-butylate In tetrahydrofuran at 20℃; for 12h; | 94% |
With [1,3-Mes2-(N2C3H5)]Cl2(PCy3)Ru=CHPh In methanol at 60℃; for 3h; | 92% |
tert-butyldimethylsilyl chloride
2-Allylphenol
1-tert-butyldimethylsilyloxy-2-(2-propenyl)benzene
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 23℃; | 100% |
With 1H-imidazole In dichloromethane at 20℃; for 18h; Inert atmosphere; | 99% |
With 1H-imidazole In dichloromethane at 20℃; Schlenk technique; | 99% |
2-Allylphenol
epichlorohydrin
1-(2-allyl-phenoxy)-3-chloro-propan-2-ol
Conditions | Yield |
---|---|
With pyridine In chloroform; water; phenol | 100% |
With piperidine Heating; |
(2S)-glycidyl-3-nitrobenzenesulfonate
2-Allylphenol
(S)1-(2’-allylphenoxy)-2,3-epoxypropane
Conditions | Yield |
---|---|
Stage #1: o-Allylphenol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; for 0.5h; Inert atmosphere; Stage #2: (2S)-glycidyl-3-nitrobenzenesulfonate In N,N-dimethyl-formamide; mineral oil at 60℃; | 100% |
Conditions | Yield |
---|---|
With sodium hydroxide In tetrahydrofuran; water at 0 - 20℃; for 2h; Reagent/catalyst; Green chemistry; | 100% |
With 1,4-diaza-bicyclo[2.2.2]octane In dichloromethane |
2-Allylphenol
Conditions | Yield |
---|---|
With tellurium tetrachloride In dichloromethane at 39 - 40℃; for 3h; Reflux; | 100% |
With tellurium tetrachloride In tetrachloromethane for 6h; Reflux; | 90% |
2-Allylphenol
Conditions | Yield |
---|---|
With tellurium(IV) tetrabromide In acetonitrile at 20 - 25℃; for 20h; | 100% |
With tellurium(IV) tetrabromide In acetonitrile at 20 - 25℃; for 20h; | 100% |
With tellurium(IV) tetrabromide In acetonitrile at 20℃; for 24h; | 100% |
Conditions | Yield |
---|---|
With iodine at 25℃; for 0.0166667h; | 99% |
With triethylamine at 20℃; for 25h; | 99% |
With dmap In dichloromethane at 20℃; for 2.5h; | 96% |
Conditions | Yield |
---|---|
With zeolite BEA/37.5 at 39.84℃; for 1h; Catalytic behavior; Reagent/catalyst; Time; Temperature; | 99% |
With [Nd(acetonitrile)9][AlCl4]3*acetonitrile In chloroform at 65℃; for 24h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique; regioselective reaction; | 97% |
With aluminium(III) triflate In nitromethane at 101℃; for 3h; | 93% |
ethyl bromoacetate
2-Allylphenol
2-(prop-2-enylphenoxy)-ethanoic acid ethyl ester
Conditions | Yield |
---|---|
With potassium carbonate; potassium iodide In acetone for 16h; Heating; | 99% |
With sodium hydride 1.) DMF; Yield given. Multistep reaction; | |
With caesium carbonate In N,N-dimethyl-formamide |
Conditions | Yield |
---|---|
Stage #1: o-Allylphenol With sodium hexamethyldisilazane In tetrahydrofuran for 0.5h; Stage #2: 3-chloro-2-fluoropropene In N,N-dimethyl-formamide at 20℃; for 12h; | 99% |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; for 18h; | 99% |
2-Allylphenol
3-(2-hydroxyphenyl)propane-1,2-diol
Conditions | Yield |
---|---|
With osmium(VIII) oxide; N-methyl-2-indolinone In water; acetone at 20℃; | 99% |
Multi-step reaction with 3 steps 1: 92 percent / pyridine / 2 h / 100 °C 2: 73 percent / m-chloroperbenzoic acid / CH2Cl2 / 18 h / 20 °C 3: 70 percent / aq. sodium hydroxide / 0.5 h / Heating View Scheme |
Conditions | Yield |
---|---|
With formic acid; palladium diacetate; triphenylphosphine In 1,3,5-trimethyl-benzene at 90℃; for 16h; | 99% |
1-iodo-butane
carbon monoxide
2-Allylphenol
Valeriansaeure-<2-allyl-phenylester>
Conditions | Yield |
---|---|
With rhodium(III) chloride; 1,3-bis-(diphenylphosphino)propane; sodium carbonate; sodium bromide In 1,4-dioxane at 120℃; under 750.075 Torr; for 24h; Inert atmosphere; chemoselective reaction; | 99% |
Conditions | Yield |
---|---|
Stage #1: resorcinol diglycidyl ether; o-Allylphenol With potassium methanolate at 110℃; for 1.7h; Inert atmosphere; Stage #2: 1,2-epoxytetradecane at 120℃; for 21.4333h; Inert atmosphere; | 98.1% |
1,1,1,3,3,3-hexamethyl-disilazane
2-Allylphenol
2-allyl-1-(trimethylsiloxy)benzene
Conditions | Yield |
---|---|
With 3-methyl-1-sulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0333333h; Neat (no solvent); | 98% |
With 1,3-disulfonic acid imidazolium hydrogen sulfate In neat (no solvent) at 20℃; for 0.0333333h; Green chemistry; | 98% |
With succinimide-N-sulfonic acid In acetonitrile at 20℃; for 0.0333333h; chemoselective reaction; | 95% |
diphenyl diselenide
2-Allylphenol
2,3-dihydro-2-<(phenylseleno)methyl>benzofuran
Conditions | Yield |
---|---|
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile In acetonitrile at 20℃; for 2h; Irradiation; Green chemistry; | 98% |
With ammonium persulfate In acetonitrile at 70℃; for 12h; | 77% |
With tetrabutylammonium perchlorate In acetonitrile at 20℃; for 1.5h; Electrochemical reaction; Green chemistry; | 55% |
thianthrene cation radical perchlorate
2-Allylphenol
A
thianthrene-5-oxide
B
5-(4-hydroxy-3-allylphenyl)thianthreniumyl perchlorate
C
Thianthrene
Conditions | Yield |
---|---|
In acetonitrile | A 5.4% B 98% C 40% |
2-Allylphenol
2-(prop-2-en-1-yl)cyclohexan-1-ol
Conditions | Yield |
---|---|
With nickel(II) oxide; hydrogen; palladium In hexane at 100℃; under 22502.3 Torr; for 16h; | 98% |
Conditions | Yield |
---|---|
With triethylamine In ethyl acetate at 0 - 20℃; for 0.166667h; Green chemistry; | 98% |
With pyridine In dichloromethane | 52.6 mg |
Conditions | Yield |
---|---|
With N,N'-dimethylpiperazine In 1,4-dioxane at 80℃; Inert atmosphere; Schlenk technique; | 98% |
With 1,4-diaza-bicyclo[2.2.2]octane; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In acetonitrile at 20℃; for 12h; Reagent/catalyst; Solvent; Schlenk technique; Irradiation; Inert atmosphere; | 90% |
With 1,4-diaza-bicyclo[2.2.2]octane; tris[2-phenylpyridinato-C2,N]iridium(III) In acetonitrile at 25℃; for 12h; Schlenk technique; Irradiation; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With dmap In dichloromethane at 0 - 20℃; for 0.333333h; | 98% |
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile at 80℃; for 18h; | 98% |
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; potassium carbonate; triphenylphosphine In water at 85 - 105℃; for 16h; Inert atmosphere; | 98% |
With 5%-palladium/activated carbon; potassium carbonate; triphenylphosphine In water at 85 - 105℃; for 4h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With benzo[de]benzo[4,5]imidazo[2,1-a]isoquinolin-7-one In cyclohexane at 20℃; for 1h; Inert atmosphere; Sealed tube; Irradiation; | 98% |
Conditions | Yield |
---|---|
With potassium methanolate at 110 - 123℃; for 18.3h; Inert atmosphere; | 97.1% |
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