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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Triphenylantimony Manufacturer/High quality/Best price/In stock

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Triphenylantimony supplier in China

Cas:603-36-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:

TriphenylantiMony

Cas:603-36-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Triphenylantimony CAS 603-36-1 Stibine, triphenyl- CAS no 603-36-1 Triphenylstibine Triphenylantimony(III) Triphenylantimony CAS 603-36-1 Stibine, triphenyl- IN Stock CAS 603-36-1 Triphenylantimony Triphenylantimony(III) Stibine, triphenyl-

Triphenylantimony CAS 603-36-1 Stibine, triphenyl- CAS no 603-36-1 Triphenylstibine Triphenylantimony(III)

Cas:603-36-1

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Triphenylantimony

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 603-36-1 with best quality

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS No.603-36-1 Triphenylantimony

Cas:603-36-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Stibine, triphenyl- 603-36-1

Cas:603-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: Triphenylantimony CAS: 603-36-1 MF: C18H15Sb MW: 353.07 EINECS: 210-037-6 Mol File: 603-36-1.mol Triphenylantimony Structure Triphenylantimony Chemical Properties Melting point 52-54 °C(lit.) Boiling point

Triphenylantimony

Cas:603-36-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Stibine, triphenyl-

Cas:603-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Triphenylantimony

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Stibine, triphenyl-

Cas:603-36-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

Triphenylantimony

Cas:603-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Triphenylantimony

Cas:603-36-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Triphenylantimony

Cas:603-36-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Triphenylantimony/High quality/Best price

Cas:603-36-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

CAS No.603-36-1 Triphenylantimony

Cas:603-36-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Triphenylantimony CAS No.:603-36-1 Molecule Formula:C18H15Sb Molecule Weight:353.07 Purity: 97% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality Triphenylantimony in stock

Cas:603-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and

Stibine, triphenyl-,cas:603-36-1

Cas:603-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

CAS No.603-36-1 Triphenylantimony

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Triphenylantimony

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

CAS No.603-36-1 Triphenylantimony

Cas:603-36-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

CAS No.603-36-1 Triphenylantimony

Cas:603-36-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hangzhou ZeErRui Chemical Co., Ltd.

Melting point 52-54 °C(lit.) Boiling point 377 °C (lit.) Density 1,434 g/cm 3 Refractive Index 1.6948 Flash Point > 230 °F Store below +30 °C. Solubility < 0.001 g/l Morphology Specif

Triphenylantimony supplier

Cas:603-36-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Triphenylantimony

Cas:603-36-1

Min.Order:1 Gram

Negotiable

Type:Other

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Wuhan Newgreat Chemical Co., Ltd

ProName:Discount price CAS 603-36-1 with best ... CasNo:603-36-1 Molecular Formula:603-36-1 Appearance:White powder Application:Chemical raw materials, pharmaceutical... DeliveryTime:Ship out within 3-7 days after paymen... PackAge:[Packaging

Triphenylantimony 603-36-1

Cas:603-36-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

CAS No.603-36-1 Triphenylantimony

Cas:603-36-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

Triphenylantimony

Cas:603-36-1

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Triphenylantimony

Cas:603-36-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

High Purity Triphenylantimony 603-36-1

Cas:603-36-1

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

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Synthetic route

tetraphenyl stibonium iodide
13903-91-8, 16894-70-5

tetraphenyl stibonium iodide

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In water Electrochem. Process; reduction;100%
diphenylfluorostibine
6651-55-4

diphenylfluorostibine

phenyltrifluorosilane
368-47-8

phenyltrifluorosilane

A

triphenylantimony
603-36-1

triphenylantimony

B

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
reflux for 3 d;A 100%
B n/a
reflux for 3 d;A 100%
B n/a
vanadocene

vanadocene

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

vanadocene monochloride

vanadocene monochloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene a soln. of vanadocene and dichlorotriphenylantimony (2:1) in toluene at room temp. for 20 h, mixt. becomes blue; solvent is removed in vac., triphenylstibine is extd. with hexane, residue consists of dark blue crystals; elem. anal.;A 98%
B 99%
vanadocene

vanadocene

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

bis(cyclopentadienyl)vanadium dichloride
12083-48-6

bis(cyclopentadienyl)vanadium dichloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene heating of vanadocene and dichlorotriphenylantimony in the ratio of 1:1 in toluene at 100°C for 5 h;; removal of solvent under vac.; the stibine was extd. with hexane;;A n/a
B 99%
NiOs3H3(1+)*C5H5(1-)*8CO*Sb(C6H5)3=(C5H5)NiOs3H3(CO)8(Sb(C6H5)3)

NiOs3H3(1+)*C5H5(1-)*8CO*Sb(C6H5)3=(C5H5)NiOs3H3(CO)8(Sb(C6H5)3)

triphenylphosphine
603-35-0

triphenylphosphine

A

NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

B

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In hexane The complex and a slight excess of Pp are refluxed in hexane for 5 min (N2). Some decompn. was observed.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;A 99%
B n/a
C n/a
(C6H5)4SbSC6H5*0.06CHCl3

(C6H5)4SbSC6H5*0.06CHCl3

A

biphenyl
92-52-4

biphenyl

B

diphenyl sulfide
139-66-2

diphenyl sulfide

C

triphenylantimony
603-36-1

triphenylantimony

D

diphenyldisulfane
882-33-7

diphenyldisulfane

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 21%
B 69%
C 99%
D 30%
E 6%
antimony(III) chloride
10025-91-9

antimony(III) chloride

chlorobenzene
108-90-7

chlorobenzene

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
Stage #1: chlorobenzene With cis-Octadecenoic acid; sodium In toluene at 30 - 40℃; for 2h; Inert atmosphere;
Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;
98.1%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

H3COC6H4SCCl3

H3COC6H4SCCl3

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In tetrachloromethane Kinetics; at 34°C; not isolated, GLC;A 47%
B 5%
C 48%
D 98%
In chloroform-d1 Kinetics; at 34°C; not isolated, GLC;A 35%
B 5%
C 64%
D 95%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

biphenyl
92-52-4

biphenyl

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) 130°C; not isolated, GLC;A 69%
B 17%
C 28%
D 98%
In cyclohexene reflux; not isolated, GLC;A 80%
B 12%
C 18%
D 98%
In benzene reflux; not isolated, GLC;A 86%
B 4%
C 8%
D 95%
In chloroform reflux; not isolated, GLC;A 70%
B 4%
C 19%
D 95%
(C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4SbSC6H4OCH3*0.11CHCl3

A

biphenyl
92-52-4

biphenyl

B

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

C

1-methoxy-4-(phenylsulfanyl)benzene
5633-57-8

1-methoxy-4-(phenylsulfanyl)benzene

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 17%
B 28%
C 69%
D 98%
E 13%
triphenylantimony bis(2,4-dimethylbenzenesulfonate)

triphenylantimony bis(2,4-dimethylbenzenesulfonate)

A

zinc bis(2,4-dimethylbenzenesulfonate)

zinc bis(2,4-dimethylbenzenesulfonate)

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In acetone Sb comp. and Zn dust heated in acetone in a sealed glass ampule at 90°C for 2 h; solvent removed, residue treated with hexane and then with alcohol; products detected by IR spectra;A 98%
B 95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

lithium
7439-93-2

lithium

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
With bromobenzene In diethyl ether with 20% excess of Li at 0°C then reflux for 2 h;97%
(2,6-dimethylphenoxy)tetraphenylantimony
209054-80-8

(2,6-dimethylphenoxy)tetraphenylantimony

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) byproducts: 2,6,2',6'-tetramethyldiphenoquinone; heated for 1 h at 220°C in a glass evacuated ampoule; sepd. by chromy. on silica gel; eluted with petroleum ether;97%
cobaltocene
1277-43-6

cobaltocene

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

cobalticenium chloride

cobalticenium chloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene a mixt. of cobaltocene and dichlorotriphenylstibine in toluene is heated at 100°C for 3 h, decolorization of soln. and formation of a light-green ppt. is observed,; ppt. is extd. with toluene and toluene is driven off to give triphenylstibine, the residual light-green powder is chlorodicyclopentadienylcobalt;A 96%
B 97%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In benzene-d6 reflux; not isolated, GLC;A 86%
B 7%
C 97%
(C6H5)4SbSC6H4OCH3*0.5CHCl3

(C6H5)4SbSC6H4OCH3*0.5CHCl3

A

biphenyl
92-52-4

biphenyl

B

bis(2-methoxyphenyl)disulfide
13920-94-0

bis(2-methoxyphenyl)disulfide

C

1-methoxy-2-(phenylthio)benzene
14065-22-6

1-methoxy-2-(phenylthio)benzene

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 6%
B 5%
C 92%
D 97%
E 4%
(C6H5)4SbSC6H4Br*0.12CHCl3

(C6H5)4SbSC6H4Br*0.12CHCl3

A

biphenyl
92-52-4

biphenyl

B

bis(4-bromophenyl)disulfide
5335-84-2

bis(4-bromophenyl)disulfide

C

phenyl(4-bromophenyl)sulfide
65662-88-6

phenyl(4-bromophenyl)sulfide

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 3%
B 3%
C 97%
D 96%
E 3%
(3,5-di-tert-butylphenoxy)tetraphenylantimony
329747-31-1

(3,5-di-tert-butylphenoxy)tetraphenylantimony

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) byproducts: PhOC6H3(tert-bu)2; heating for 1 h at 220°C in a glass evacuated ampoule; recrystd. from EtOH;97%
bromobenzene
108-86-1

bromobenzene

antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
Stage #1: bromobenzene With sodium; stearic acid In toluene at 40℃; for 1h; Inert atmosphere;
Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Inert atmosphere;
96.5%
2-aminotropone
6264-93-3

2-aminotropone

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
With potassium tert-butylate; 2-hydroxy-2-phenylacetophenone In benzene byproducts: benzil; under N2; t-BuOK added to stirred soln. of Ph3SbCl2 and H2NC7H5O (molar ratio 2:1:1) in dry benzene; stirred at room temp. for 30 min; benzoin (1 equiv.) added; heated under reflux for 1.5 h; solvent evapd.; sepd. by column chromy. (SiO2, CH2Cl2); further sepd. byTLC (SiO2, hexane-ethyl acetate);96%
With potassium tert-butylate In benzene byproducts: benzophenone; under N2; t-BuOK added to stirred soln. of Ph3SbCl2 and H2NC7H5O (molar ratio 2:1:1) in dry benzene; stirred at room temp. for 30 min; benzopinacol (1 equiv.) added; stirred at room temp. for 2 h; solvent evapd.; sepd. by column chromy. (SiO2, CH2Cl2); further sepd. byTLC (SiO2, hexane-ethyl acetate);92%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

H3COC6H4SCCl3

H3COC6H4SCCl3

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

triphenylantimony
603-36-1

triphenylantimony

E

chlorobenzene
108-90-7

chlorobenzene

Conditions
ConditionsYield
In tetrachloromethane byproducts: biphenyl; reflux; not isolated, GLC;A 36%
B 40%
C 22%
D 96%
E 33%
dibromogermane dioxane

dibromogermane dioxane

triphenylantimony dibromide
20265-30-9

triphenylantimony dibromide

A

germanium tetrabromide
13450-92-5

germanium tetrabromide

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene byproducts: dioxane; standing (room temperature, 24 h); liquid chromy.;A 93%
B 95%
vanadocene monochloride

vanadocene monochloride

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

bis(cyclopentadienyl)vanadium dichloride
12083-48-6

bis(cyclopentadienyl)vanadium dichloride

B

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In toluene a soln. of Cp2VCl and Ph3SbCl2 (2:1) at 100°C for 3 h;A 95%
B 95%
(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

(C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A

4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

B

biphenyl
92-52-4

biphenyl

C

4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

D

4-methoxyphenyl cyclohexyl sulfide
59693-94-6

4-methoxyphenyl cyclohexyl sulfide

E

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In cyclohexane reflux; not isolated, GLC;A 62%
B 3%
C 5%
D 31%
E 95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
With phenylmagnesium bromide In tetrahydrofuran; benzene N2 atmosphere; addn. of SbCl3 to PhMgBr soln. (over 1.5-2 h, 85°C), heating (70-85°C, 1 h); ware addn., sepn. of org. layer, solvent removal, fractioning (vac., 200-205°C), crystn. (ethanol); elem. anal.;94%
With bromobenzene; sodium In toluene; benzene reflux for 5 to 6 h, SbCl3:C6H5BrNa in 0.5:1.5:4.35 rate; distn.;71.7%
With aniline; zinc In ethyl acetate treating diazotated aniline and SbCl3 with zinc powder;52%
Cr(CO)3{Sb(C6H5)3}3
79542-59-9

Cr(CO)3{Sb(C6H5)3}3

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cr, Cr(CO)6, CO; in vacuo or under inert gas, heated at 230°C for 5 h; washed (benzene); TLC;94%
germanium(II) chloride dioxane

germanium(II) chloride dioxane

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

A

triphenylantimony
603-36-1

triphenylantimony

B

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

Conditions
ConditionsYield
In toluene byproducts: dioxane; standing (room temperature, 24 h); liquid chromy.;A 93%
B 91%
(C6H5)4SbSC6H4CH3*0.25CHCl3

(C6H5)4SbSC6H4CH3*0.25CHCl3

A

biphenyl
92-52-4

biphenyl

B

di(p-tolyl) disulfide
103-19-5

di(p-tolyl) disulfide

C

4-tolyl phenyl sulfide
3699-01-2

4-tolyl phenyl sulfide

D

triphenylantimony
603-36-1

triphenylantimony

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;A 4%
B 40%
C 50%
D 93%
E 15%
bis(phenylethynyl)ytterbium(II) tetrahydrofuranate
727679-11-0

bis(phenylethynyl)ytterbium(II) tetrahydrofuranate

iodotetraphenyl-λ5-stibane
16894-70-5

iodotetraphenyl-λ5-stibane

A

tetrakis(tetrahydrofurane)diiodidoytterbium(II)
106316-57-8, 166943-06-2

tetrakis(tetrahydrofurane)diiodidoytterbium(II)

B

phenylethynylytterbium(II) iodide tetrahydrofuranate
925457-74-5

phenylethynylytterbium(II) iodide tetrahydrofuranate

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In tetrahydrofuran Sb-compound in THF added to Yb-complex in THF, kept at room temp. for 24h under vac.; washed with hexane, dried in vac., solvent removed; elem. anal.;A 29%
B 71%
C 92.5%
bis(phenylethynyl)ytterbium(II) tetrahydrofuranate
727679-11-0

bis(phenylethynyl)ytterbium(II) tetrahydrofuranate

tetraphenylchloroantimony(V)
16894-68-1

tetraphenylchloroantimony(V)

A

YbCl2(C4H8O)4
925457-75-6

YbCl2(C4H8O)4

B

YbCl(C4H8O)4(C6H5C2)
925457-71-2

YbCl(C4H8O)4(C6H5C2)

C

triphenylantimony
603-36-1

triphenylantimony

Conditions
ConditionsYield
In tetrahydrofuran Sb-compound in THF added to Yb-complex in THF, kept at room temp. for 24h under vac.; washed with hexane, dried in vac., solvent removed; elem. anal.;A 25%
B 70%
C 91.5%
antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

diphenylantimony(III) chloride
2629-47-2

diphenylantimony(III) chloride

Conditions
ConditionsYield
In neat (no solvent) for 72h;100%
In neat (no solvent) for 3h;100%
Stage #1: antimony(III) chloride; triphenylantimony at 20℃; for 72h; Inert atmosphere;
Stage #2: for 336h; Cooling;
95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

triphenylantimony
603-36-1

triphenylantimony

dichlorophenylstibine
5035-52-9

dichlorophenylstibine

Conditions
ConditionsYield
In neat (no solvent) for 72h;100%
In neat (no solvent) for 3h;100%
In neat (no solvent) for 3h; Schlenk technique; Inert atmosphere;100%
triphenylantimony
603-36-1

triphenylantimony

thiophenol
108-98-5

thiophenol

(C6H5)2SbSC6H5
28609-59-8

(C6H5)2SbSC6H5

Conditions
ConditionsYield
In benzene threefold excess of C6H5SH used, heating at 50°C for 15 h; with and without addn. of t-butyl hyponitrite: radical mechanism postulated;100%
In benzene threefold excess of C6H5SH used, heating at 50°C for 15 h; with and without addn. of t-butyl hyponitrite: radical mechanism postulated;100%
In benzene Kinetics; mole ratio 3:1, 15 h;>99
In benzene Kinetics; mole ratio 3:1, 15 h;>99
triphenylantimony
603-36-1

triphenylantimony

thallium (III) chloride
13453-32-2

thallium (III) chloride

triphenylantimony dichloride
594-31-0, 34716-91-1, 20265-29-6

triphenylantimony dichloride

Conditions
ConditionsYield
In ethanol; toluene100%
In ethanol; toluene100%
chloro(1,5-cyclooctadiene)rhodium(I) dimer

chloro(1,5-cyclooctadiene)rhodium(I) dimer

dichloromethane
75-09-2

dichloromethane

triphenylantimony
603-36-1

triphenylantimony

Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Conditions
ConditionsYield
In ethanol (under Ar, Schlenk); Rh-complex added to refluxing soln. of Sb(C6H5)3 inEtOH; ppt. filtered, washed with CH2Cl2/hexane, dried in vacuo; elem. anal.;100%
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

triphenylantimony
603-36-1

triphenylantimony

Rh(Sb(C6H5)3)2(CO)Cl
17967-63-4

Rh(Sb(C6H5)3)2(CO)Cl

Conditions
ConditionsYield
In dichloromethane (under Ar or N2, Schlenk); Rh-complex and Sb(C6H5)3 dissolved in CH2Cl2,stirred for 2 h; reduced to dryness, residue stirred in hexane, ppt. filtered, dried in vacuo; elem. anal.;100%
methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

triphenylantimony
603-36-1

triphenylantimony

A

methyltriphenylstibonium tetrafluoroborate
3802-09-3

methyltriphenylstibonium tetrafluoroborate

B

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 react. (Ph3BiMe)(BF4) and SbPh3 in CDCl3 at room temp.; detn. by 1H NMR;A 100%
B 100%
trans-diiodo(N-pyridine)[1-methyl-3-benzylimidazol-2-ylidene]platinum(II)

trans-diiodo(N-pyridine)[1-methyl-3-benzylimidazol-2-ylidene]platinum(II)

triphenylantimony
603-36-1

triphenylantimony

C47H42IN2PtSb2(1+)*I(1-)

C47H42IN2PtSb2(1+)*I(1-)

Conditions
ConditionsYield
In ethanol at 55℃; Inert atmosphere; Schlenk technique;100%
triphenylantimony
603-36-1

triphenylantimony

tri-tert-butyl gallium
55681-99-7

tri-tert-butyl gallium

C30H42GaSb

C30H42GaSb

Conditions
ConditionsYield
In chloroform at -30℃; for 120h; Inert atmosphere; Glovebox; Schlenk technique;100%
potassium (3-(benzyloxy)phenyl)trifluoroborate

potassium (3-(benzyloxy)phenyl)trifluoroborate

triphenylantimony
603-36-1

triphenylantimony

3-(benzyloxy)-1,1’-biphenyl
123689-52-1

3-(benzyloxy)-1,1’-biphenyl

Conditions
ConditionsYield
With ferrocenium hexafluorophosphate; bis(tri-t-butylphosphine)palladium(0); cesium fluoride In tetrahydrofuran at 60℃; Inert atmosphere; Schlenk technique; Glovebox;100%
triphenylantimony
603-36-1

triphenylantimony

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With cyclododecane; palladium diacetate In chloroform at 70℃; for 14h; other solvents, other temp., other times;99%
With triethylamine; palladium diacetate In tetrahydrofuran at 65℃; for 1.5h;97%
With 2-thioxo-3H-1,3-benzothiazole; copper diacetate; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere;11 %Chromat.
triphenylantimony
603-36-1

triphenylantimony

acetic acid
64-19-7

acetic acid

triphenylantimony(V) diacetate
1538-62-1, 34716-94-4

triphenylantimony(V) diacetate

Conditions
ConditionsYield
With dihydrogen peroxide In acetic acid H2O2 added to soln. of (C6H5)3Sb in CH3CO2H; washed with hexane, dried;99%
With tert.-butylhydroperoxide In diethyl ether byproducts: t-BuOH, H2O; t-BuOOH was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O, kept in the dark for 24 h at room temp.; solvent was distilled off under reduced pressure, recrystd. from CHCl3/hexane;90%
With dihydrogen peroxide In diethyl ether; isopropyl alcohol H2O2 was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O and i-PrOH, kept in the dark for 3 h at room temp.; filtered, washed with i-PrOH, recrystd. from CHCl3/hexane;85%
copper diacetate In pyridine; toluene byproducts: C6H6; mixt. of starting materials and catalyst in soln. sealed in an ampul without evacuation, heated (8h, 110. degree.C); liquid portion distd. at reduced pressure;
triphenylantimony
603-36-1

triphenylantimony

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

diphenylantimony(III) chloride
2629-47-2

diphenylantimony(III) chloride

Conditions
ConditionsYield
In chloroform reflux under CO2;99%
In chloroform reflux under CO2;99%
2-furanoic acid
88-14-2

2-furanoic acid

triphenylantimony
603-36-1

triphenylantimony

triphenylantimony bis(2-furoinate)
126117-45-1

triphenylantimony bis(2-furoinate)

Conditions
ConditionsYield
With H2O2 In diethyl ether; water 42% aq. soln. of hydrogen peroxide added to reagent mixt. at 20°C, stored for 12 h; solvent evapd., recrystd. (toluene), elem. anal.;99%
triphenylantimony
603-36-1

triphenylantimony

3,4,5-trifluorobenzoic acid
121602-93-5

3,4,5-trifluorobenzoic acid

(C6H5)3Sb(OCOC6H2F3)2
460752-06-1

(C6H5)3Sb(OCOC6H2F3)2

Conditions
ConditionsYield
With dihydrogen peroxide In diethyl ether; water byproducts: H2O; react. of antimony compd. and acid with aq. H2O2 at room temp. in ether; elem. anal.;99%
triphenylantimony
603-36-1

triphenylantimony

3,4,5-trifluorobenzoic acid
121602-93-5

3,4,5-trifluorobenzoic acid

triphenylantimony bis(3,4,5-trifluorobenzoate)

triphenylantimony bis(3,4,5-trifluorobenzoate)

Conditions
ConditionsYield
With H2O2 In diethyl ether (C6F3H2)COOH and 30% aq. H2O2 added to soln. of Ph3Sb in ether; kept at 20°C for 12 h; crystals filtered off; dried; elem. anal.;99%
hydrogenchloride
7647-01-0

hydrogenchloride

[Mo3(PdCl)S4(H2O)9](3+)

[Mo3(PdCl)S4(H2O)9](3+)

water
7732-18-5

water

triphenylantimony
603-36-1

triphenylantimony

[Mo3(PdSb(C6H5)3)S4(H2O)5Cl4]

[Mo3(PdSb(C6H5)3)S4(H2O)5Cl4]

Conditions
ConditionsYield
In hydrogenchloride; methanol a soln. of Sb compd. (methanol) added to a soln. of cluster (aq. HCl), kept in open vial for 2 d; crysts. filtered, dried (vac., P2O5); elem. anal.;99%
N-chlorotriphenylphosphoraneimine
80166-23-0

N-chlorotriphenylphosphoraneimine

triphenylantimony
603-36-1

triphenylantimony

triphenylphosphinimino-triphenylstibonium chloride

triphenylphosphinimino-triphenylstibonium chloride

Conditions
ConditionsYield
In dichloromethane with exclusion of moisture, 1 equiv. of P-compd. in CH2Cl2 was added dropwise to CH2Cl2 soln. of Sb-compd.; soln. was concd. in dry N2-stream, several days at room temp., crystals were filtered off, filtrate was evapd. to dryness;99%
tris(2-methoxyphenyl)bismuthane oxide

tris(2-methoxyphenyl)bismuthane oxide

triphenylantimony
603-36-1

triphenylantimony

A

tris(2-methoxyphenyl)bismuthine
83724-41-8

tris(2-methoxyphenyl)bismuthine

B

triphenyl antimony oxide
4756-75-6

triphenyl antimony oxide

Conditions
ConditionsYield
In dichloromethane Ph3Sb (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;A 99%
B 99%
hydrogenchloride
7647-01-0

hydrogenchloride

[Mo3(NiCl)S4(H2O)9](3+)

[Mo3(NiCl)S4(H2O)9](3+)

triphenylantimony
603-36-1

triphenylantimony

[Mo3(NiSb(C6H5)3)S4(H2O)5Cl4]

[Mo3(NiSb(C6H5)3)S4(H2O)5Cl4]

Conditions
ConditionsYield
In hydrogenchloride; methanol a soln. of Sb compd. (methanol) added to a soln. of cluster (aq. HCl), kept in open vial for 2 d; crysts. filtered, dried (vac., P2O5); elem. anal.;99%
triphenylantimony
603-36-1

triphenylantimony

phenylpropyolic acid
637-44-5

phenylpropyolic acid

triphenylantimony bis(phenylpropiolate)

triphenylantimony bis(phenylpropiolate)

Conditions
ConditionsYield
With tert.-butylhydroperoxide In diethyl ether for 12h;99%
With tert.-butylhydroperoxide In diethyl ether for 12h; Heating;99%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

triphenylantimony
603-36-1

triphenylantimony

dichloro(η5-pentamethylcyclopentadienyl)(triphenylstibine)rhodium(III)
848236-31-7

dichloro(η5-pentamethylcyclopentadienyl)(triphenylstibine)rhodium(III)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;99%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

triphenylantimony
603-36-1

triphenylantimony

C28H30Cl2IrSb

C28H30Cl2IrSb

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;99%
triphenylantimony
603-36-1

triphenylantimony

phenylpropyolic acid
637-44-5

phenylpropyolic acid

triphenylantimony bis(phenylpropiolate)

triphenylantimony bis(phenylpropiolate)

Conditions
ConditionsYield
With tert.-butylhydroperoxide In water for 12h;99%

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