Triphenylantimony supplier

Name
Triphenylantimony
EINECS 210-037-6
CAS No. 603-36-1
Article Data121
CAS DataBase
Density 1.434 g/cm³
Solubility insoluble in water
Melting Point 52-55 °C
Formula C₁₈H₁₅Sb
Boiling Point 377 °C
Molecular Weight 353.067
Flash Point 109 °C
Transport Information UN 3467
Appearance off-white powder
Safety 61
Risk Codes 20/22-51/53
Molecular Structure
Hazard Symbols Xn,N
Synonyms NSC 2844;Triphenylantimony;Triphenylstibane;Triphenylstibine;BRN 3608108;CCRIS 1300;Trifenylstibin;
PSA 0.00000
LogP 4.46040

Synthetic route

: 13903-91-8, 16894-70-5
tetraphenyl stibonium iodide

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In water Electrochem. Process; reduction;	100%

: 6651-55-4
diphenylfluorostibine

: 368-47-8
phenyltrifluorosilane

A: 603-36-1
triphenylantimony

B: 7783-61-1
silicon tetrafluoride

Conditions

Conditions	Yield
reflux for 3 d;	A 100% B n/a
reflux for 3 d;	A 100% B n/a

...Expand

: vanadocene

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

A: vanadocene monochloride

B: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In toluene a soln. of vanadocene and dichlorotriphenylantimony (2:1) in toluene at room temp. for 20 h, mixt. becomes blue; solvent is removed in vac., triphenylstibine is extd. with hexane, residue consists of dark blue crystals; elem. anal.;	A 98% B 99%

...Expand

: vanadocene

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

A: 12083-48-6
bis(cyclopentadienyl)vanadium dichloride

B: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In toluene heating of vanadocene and dichlorotriphenylantimony in the ratio of 1:1 in toluene at 100°C for 5 h;; removal of solvent under vac.; the stibine was extd. with hexane;;	A n/a B 99%

...Expand

: NiOs3H3(1+)*C5H5(1-)*8CO*Sb(C6H5)3=(C5H5)NiOs3H3(CO)8(Sb(C6H5)3)

: 603-35-0
triphenylphosphine

A: NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

B: NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

C: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In hexane The complex and a slight excess of Pp are refluxed in hexane for 5 min (N2). Some decompn. was observed.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;	A 99% B n/a C n/a

...Expand

: (C6H5)4SbSC6H5*0.06CHCl3

A: 92-52-4
biphenyl

B: 139-66-2
diphenyl sulfide

C: 603-36-1
triphenylantimony

D: 882-33-7
diphenyldisulfane

E: 71-43-2
benzene

Conditions

Conditions	Yield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;	A 21% B 69% C 99% D 30% E 6%

...Expand

: 10025-91-9
antimony(III) chloride

: 108-90-7
chlorobenzene

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
Stage #1: chlorobenzene With cis-Octadecenoic acid; sodium In toluene at 30 - 40℃; for 2h; Inert atmosphere; Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;	98.1%

: (C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A: 696-63-9
4-Methoxybenzenethiol

B: H3COC6H4SCCl3

C: 5335-87-5
4,4'-dimethoxyphenyl disulfide

D: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In tetrachloromethane Kinetics; at 34°C; not isolated, GLC;	A 47% B 5% C 48% D 98%
In chloroform-d1 Kinetics; at 34°C; not isolated, GLC;	A 35% B 5% C 64% D 95%

...Expand

: (C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A: 696-63-9
4-Methoxybenzenethiol

B: 92-52-4
biphenyl

C: 5335-87-5
4,4'-dimethoxyphenyl disulfide

D: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In neat (no solvent) 130°C; not isolated, GLC;	A 69% B 17% C 28% D 98%
In cyclohexene reflux; not isolated, GLC;	A 80% B 12% C 18% D 98%
In benzene reflux; not isolated, GLC;	A 86% B 4% C 8% D 95%
In chloroform reflux; not isolated, GLC;	A 70% B 4% C 19% D 95%

...Expand

: (C6H5)4SbSC6H4OCH3*0.11CHCl3

A: 92-52-4
biphenyl

B: 5335-87-5
4,4'-dimethoxyphenyl disulfide

C: 5633-57-8
1-methoxy-4-(phenylsulfanyl)benzene

D: 603-36-1
triphenylantimony

E: 71-43-2
benzene

Conditions

Conditions	Yield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;	A 17% B 28% C 69% D 98% E 13%

...Expand

: triphenylantimony bis(2,4-dimethylbenzenesulfonate)

: 7440-66-6
zinc

A: zinc bis(2,4-dimethylbenzenesulfonate)

B: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In acetone Sb comp. and Zn dust heated in acetone in a sealed glass ampule at 90°C for 2 h; solvent removed, residue treated with hexane and then with alcohol; products detected by IR spectra;	A 98% B 95%

...Expand

: 10025-91-9
antimony(III) chloride

: 7439-93-2
lithium

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
With bromobenzene In diethyl ether with 20% excess of Li at 0°C then reflux for 2 h;	97%

: 209054-80-8
(2,6-dimethylphenoxy)tetraphenylantimony

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In neat (no solvent) byproducts: 2,6,2',6'-tetramethyldiphenoquinone; heated for 1 h at 220°C in a glass evacuated ampoule; sepd. by chromy. on silica gel; eluted with petroleum ether;	97%

: 1277-43-6
cobaltocene

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

A: cobalticenium chloride

B: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In toluene a mixt. of cobaltocene and dichlorotriphenylstibine in toluene is heated at 100°C for 3 h, decolorization of soln. and formation of a light-green ppt. is observed,; ppt. is extd. with toluene and toluene is driven off to give triphenylstibine, the residual light-green powder is chlorodicyclopentadienylcobalt;	A 96% B 97%

...Expand

: (C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A: 696-63-9
4-Methoxybenzenethiol

B: 5335-87-5
4,4'-dimethoxyphenyl disulfide

C: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In benzene-d6 reflux; not isolated, GLC;	A 86% B 7% C 97%

...Expand

: (C6H5)4SbSC6H4OCH3*0.5CHCl3

A: 92-52-4
biphenyl

B: 13920-94-0
bis(2-methoxyphenyl)disulfide

C: 14065-22-6
1-methoxy-2-(phenylthio)benzene

D: 603-36-1
triphenylantimony

E: 71-43-2
benzene

Conditions

Conditions	Yield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;	A 6% B 5% C 92% D 97% E 4%

...Expand

: (C6H5)4SbSC6H4Br*0.12CHCl3

A: 92-52-4
biphenyl

B: 5335-84-2
bis(4-bromophenyl)disulfide

C: 65662-88-6
phenyl(4-bromophenyl)sulfide

D: 603-36-1
triphenylantimony

E: 71-43-2
benzene

Conditions

Conditions	Yield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;	A 3% B 3% C 97% D 96% E 3%

...Expand

: 329747-31-1
(3,5-di-tert-butylphenoxy)tetraphenylantimony

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In neat (no solvent) byproducts: PhOC6H3(tert-bu)2; heating for 1 h at 220°C in a glass evacuated ampoule; recrystd. from EtOH;	97%

: 108-86-1
bromobenzene

: 10025-91-9
antimony(III) chloride

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
Stage #1: bromobenzene With sodium; stearic acid In toluene at 40℃; for 1h; Inert atmosphere; Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Inert atmosphere;	96.5%

: 6264-93-3
2-aminotropone

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
With potassium tert-butylate; 2-hydroxy-2-phenylacetophenone In benzene byproducts: benzil; under N2; t-BuOK added to stirred soln. of Ph3SbCl2 and H2NC7H5O (molar ratio 2:1:1) in dry benzene; stirred at room temp. for 30 min; benzoin (1 equiv.) added; heated under reflux for 1.5 h; solvent evapd.; sepd. by column chromy. (SiO2, CH2Cl2); further sepd. byTLC (SiO2, hexane-ethyl acetate);	96%
With potassium tert-butylate In benzene byproducts: benzophenone; under N2; t-BuOK added to stirred soln. of Ph3SbCl2 and H2NC7H5O (molar ratio 2:1:1) in dry benzene; stirred at room temp. for 30 min; benzopinacol (1 equiv.) added; stirred at room temp. for 2 h; solvent evapd.; sepd. by column chromy. (SiO2, CH2Cl2); further sepd. byTLC (SiO2, hexane-ethyl acetate);	92%

: (C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A: 696-63-9
4-Methoxybenzenethiol

B: H3COC6H4SCCl3

C: 5335-87-5
4,4'-dimethoxyphenyl disulfide

D: 603-36-1
triphenylantimony

E: 108-90-7
chlorobenzene

Conditions

Conditions	Yield
In tetrachloromethane byproducts: biphenyl; reflux; not isolated, GLC;	A 36% B 40% C 22% D 96% E 33%

...Expand

: dibromogermane dioxane

: 20265-30-9
triphenylantimony dibromide

A: 13450-92-5
germanium tetrabromide

B: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In toluene byproducts: dioxane; standing (room temperature, 24 h); liquid chromy.;	A 93% B 95%

...Expand

: vanadocene monochloride

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

A: 12083-48-6
bis(cyclopentadienyl)vanadium dichloride

B: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In toluene a soln. of Cp2VCl and Ph3SbCl2 (2:1) at 100°C for 3 h;	A 95% B 95%

...Expand

: (C6H5)4Sb(1+)*H3COC6H4S(1-)*0.11CHCl3 = (C6H5)4SbSC6H4OCH3*0.11CHCl3

A: 696-63-9
4-Methoxybenzenethiol

B: 92-52-4
biphenyl

C: 5335-87-5
4,4'-dimethoxyphenyl disulfide

D: 59693-94-6
4-methoxyphenyl cyclohexyl sulfide

E: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In cyclohexane reflux; not isolated, GLC;	A 62% B 3% C 5% D 31% E 95%

...Expand

: 10025-91-9
antimony(III) chloride

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
With phenylmagnesium bromide In tetrahydrofuran; benzene N2 atmosphere; addn. of SbCl3 to PhMgBr soln. (over 1.5-2 h, 85°C), heating (70-85°C, 1 h); ware addn., sepn. of org. layer, solvent removal, fractioning (vac., 200-205°C), crystn. (ethanol); elem. anal.;	94%
With bromobenzene; sodium In toluene; benzene reflux for 5 to 6 h, SbCl3:C6H5BrNa in 0.5:1.5:4.35 rate; distn.;	71.7%
With aniline; zinc In ethyl acetate treating diazotated aniline and SbCl3 with zinc powder;	52%

: 79542-59-9
Cr(CO)3{Sb(C6H5)3}3

: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cr, Cr(CO)6, CO; in vacuo or under inert gas, heated at 230°C for 5 h; washed (benzene); TLC;	94%

: germanium(II) chloride dioxane

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

A: 603-36-1
triphenylantimony

B: 10038-98-9
germaniumtetrachloride

Conditions

Conditions	Yield
In toluene byproducts: dioxane; standing (room temperature, 24 h); liquid chromy.;	A 93% B 91%

...Expand

: (C6H5)4SbSC6H4CH3*0.25CHCl3

A: 92-52-4
biphenyl

B: 103-19-5
di(p-tolyl) disulfide

C: 3699-01-2
4-tolyl phenyl sulfide

D: 603-36-1
triphenylantimony

E: 71-43-2
benzene

Conditions

Conditions	Yield
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;	A 4% B 40% C 50% D 93% E 15%

...Expand

: 727679-11-0
bis(phenylethynyl)ytterbium(II) tetrahydrofuranate

: 16894-70-5
iodotetraphenyl-λ5-stibane

A: 106316-57-8, 166943-06-2
tetrakis(tetrahydrofurane)diiodidoytterbium(II)

B: 925457-74-5
phenylethynylytterbium(II) iodide tetrahydrofuranate

C: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In tetrahydrofuran Sb-compound in THF added to Yb-complex in THF, kept at room temp. for 24h under vac.; washed with hexane, dried in vac., solvent removed; elem. anal.;	A 29% B 71% C 92.5%

...Expand

: 727679-11-0
bis(phenylethynyl)ytterbium(II) tetrahydrofuranate

: 16894-68-1
tetraphenylchloroantimony(V)

A: 925457-75-6
YbCl2(C4H8O)4

B: 925457-71-2
YbCl(C4H8O)4(C6H5C2)

C: 603-36-1
triphenylantimony

Conditions

Conditions	Yield
In tetrahydrofuran Sb-compound in THF added to Yb-complex in THF, kept at room temp. for 24h under vac.; washed with hexane, dried in vac., solvent removed; elem. anal.;	A 25% B 70% C 91.5%

...Expand

: 10025-91-9
antimony(III) chloride

: 603-36-1
triphenylantimony

: 2629-47-2
diphenylantimony(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) for 72h;	100%
In neat (no solvent) for 3h;	100%
Stage #1: antimony(III) chloride; triphenylantimony at 20℃; for 72h; Inert atmosphere; Stage #2: for 336h; Cooling;	95%

: 10025-91-9
antimony(III) chloride

: 603-36-1
triphenylantimony

: 5035-52-9
dichlorophenylstibine

Conditions

Conditions	Yield
In neat (no solvent) for 72h;	100%
In neat (no solvent) for 3h;	100%
In neat (no solvent) for 3h; Schlenk technique; Inert atmosphere;	100%

: 603-36-1
triphenylantimony

: 108-98-5
thiophenol

: 28609-59-8
(C6H5)2SbSC6H5

Conditions

Conditions	Yield
In benzene threefold excess of C6H5SH used, heating at 50°C for 15 h; with and without addn. of t-butyl hyponitrite: radical mechanism postulated;	100%
In benzene threefold excess of C6H5SH used, heating at 50°C for 15 h; with and without addn. of t-butyl hyponitrite: radical mechanism postulated;	100%
In benzene Kinetics; mole ratio 3:1, 15 h;	>99
In benzene Kinetics; mole ratio 3:1, 15 h;	>99

: 603-36-1
triphenylantimony

: 13453-32-2
thallium (III) chloride

: 594-31-0, 34716-91-1, 20265-29-6
triphenylantimony dichloride

Conditions

Conditions	Yield
In ethanol; toluene	100%
In ethanol; toluene	100%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 75-09-2
dichloromethane

: 603-36-1
triphenylantimony

: Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Conditions

Conditions	Yield
In ethanol (under Ar, Schlenk); Rh-complex added to refluxing soln. of Sb(C6H5)3 inEtOH; ppt. filtered, washed with CH2Cl2/hexane, dried in vacuo; elem. anal.;	100%

...Expand

: di(rhodium)tetracarbonyl dichloride

: 603-36-1
triphenylantimony

: 17967-63-4
Rh(Sb(C6H5)3)2(CO)Cl

Conditions

Conditions	Yield
In dichloromethane (under Ar or N2, Schlenk); Rh-complex and Sb(C6H5)3 dissolved in CH2Cl2,stirred for 2 h; reduced to dryness, residue stirred in hexane, ppt. filtered, dried in vacuo; elem. anal.;	100%

: 278172-59-1
methyltriphenylbismuthonium tetrafluoroborate

: 603-36-1
triphenylantimony

A: 3802-09-3
methyltriphenylstibonium tetrafluoroborate

B: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In chloroform-d1 react. (Ph3BiMe)(BF4) and SbPh3 in CDCl3 at room temp.; detn. by 1H NMR;	A 100% B 100%

...Expand

: trans-diiodo(N-pyridine)[1-methyl-3-benzylimidazol-2-ylidene]platinum(II)

: 603-36-1
triphenylantimony

: C47H42IN2PtSb2(1+)*I(1-)

Conditions

Conditions	Yield
In ethanol at 55℃; Inert atmosphere; Schlenk technique;	100%

: 603-36-1
triphenylantimony

: 55681-99-7
tri-tert-butyl gallium

: C30H42GaSb

Conditions

Conditions	Yield
In chloroform at -30℃; for 120h; Inert atmosphere; Glovebox; Schlenk technique;	100%

: potassium (3-(benzyloxy)phenyl)trifluoroborate

: 603-36-1
triphenylantimony

: 123689-52-1
3-(benzyloxy)-1,1’-biphenyl

Conditions

Conditions	Yield
With ferrocenium hexafluorophosphate; bis(tri-t-butylphosphine)palladium(0); cesium fluoride In tetrahydrofuran at 60℃; Inert atmosphere; Schlenk technique; Glovebox;	100%

: 603-36-1
triphenylantimony

: 92-52-4
biphenyl

Conditions

Conditions	Yield
With cyclododecane; palladium diacetate In chloroform at 70℃; for 14h; other solvents, other temp., other times;	99%
With triethylamine; palladium diacetate In tetrahydrofuran at 65℃; for 1.5h;	97%
With 2-thioxo-3H-1,3-benzothiazole; copper diacetate; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere;	11 %Chromat.

: 603-36-1
triphenylantimony

: 64-19-7
acetic acid

: 1538-62-1, 34716-94-4
triphenylantimony(V) diacetate

Conditions

Conditions	Yield
With dihydrogen peroxide In acetic acid H2O2 added to soln. of (C6H5)3Sb in CH3CO2H; washed with hexane, dried;	99%
With tert.-butylhydroperoxide In diethyl ether byproducts: t-BuOH, H2O; t-BuOOH was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O, kept in the dark for 24 h at room temp.; solvent was distilled off under reduced pressure, recrystd. from CHCl3/hexane;	90%
With dihydrogen peroxide In diethyl ether; isopropyl alcohol H2O2 was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O and i-PrOH, kept in the dark for 3 h at room temp.; filtered, washed with i-PrOH, recrystd. from CHCl3/hexane;	85%
copper diacetate In pyridine; toluene byproducts: C6H6; mixt. of starting materials and catalyst in soln. sealed in an ampul without evacuation, heated (8h, 110. degree.C); liquid portion distd. at reduced pressure;

: 603-36-1
triphenylantimony

: 7787-60-2
bismuth(III) chloride

: 2629-47-2
diphenylantimony(III) chloride

Conditions

Conditions	Yield
In chloroform reflux under CO2;	99%
In chloroform reflux under CO2;	99%

: 88-14-2
2-furanoic acid

: 603-36-1
triphenylantimony

: 126117-45-1
triphenylantimony bis(2-furoinate)

Conditions

Conditions	Yield
With H2O2 In diethyl ether; water 42% aq. soln. of hydrogen peroxide added to reagent mixt. at 20°C, stored for 12 h; solvent evapd., recrystd. (toluene), elem. anal.;	99%

: 603-36-1
triphenylantimony

: 121602-93-5
3,4,5-trifluorobenzoic acid

: 460752-06-1
(C6H5)3Sb(OCOC6H2F3)2

Conditions

Conditions	Yield
With dihydrogen peroxide In diethyl ether; water byproducts: H2O; react. of antimony compd. and acid with aq. H2O2 at room temp. in ether; elem. anal.;	99%

: 603-36-1
triphenylantimony

: 121602-93-5
3,4,5-trifluorobenzoic acid

: triphenylantimony bis(3,4,5-trifluorobenzoate)

Conditions

Conditions	Yield
With H2O2 In diethyl ether (C6F3H2)COOH and 30% aq. H2O2 added to soln. of Ph3Sb in ether; kept at 20°C for 12 h; crystals filtered off; dried; elem. anal.;	99%

: 7647-01-0
hydrogenchloride

: [Mo3(PdCl)S4(H2O)9](3+)

: 7732-18-5
water

: 603-36-1
triphenylantimony

: [Mo3(PdSb(C6H5)3)S4(H2O)5Cl4]

Conditions

Conditions	Yield
In hydrogenchloride; methanol a soln. of Sb compd. (methanol) added to a soln. of cluster (aq. HCl), kept in open vial for 2 d; crysts. filtered, dried (vac., P2O5); elem. anal.;	99%

...Expand

: 80166-23-0
N-chlorotriphenylphosphoraneimine

: 603-36-1
triphenylantimony

: triphenylphosphinimino-triphenylstibonium chloride

Conditions

Conditions	Yield
In dichloromethane with exclusion of moisture, 1 equiv. of P-compd. in CH2Cl2 was added dropwise to CH2Cl2 soln. of Sb-compd.; soln. was concd. in dry N2-stream, several days at room temp., crystals were filtered off, filtrate was evapd. to dryness;	99%

: tris(2-methoxyphenyl)bismuthane oxide

: 603-36-1
triphenylantimony

A: 83724-41-8
tris(2-methoxyphenyl)bismuthine

B: 4756-75-6
triphenyl antimony oxide

Conditions

Conditions	Yield
In dichloromethane Ph3Sb (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;	A 99% B 99%

...Expand

: 7647-01-0
hydrogenchloride

: [Mo3(NiCl)S4(H2O)9](3+)

: 603-36-1
triphenylantimony

: [Mo3(NiSb(C6H5)3)S4(H2O)5Cl4]

Conditions

Conditions	Yield
In hydrogenchloride; methanol a soln. of Sb compd. (methanol) added to a soln. of cluster (aq. HCl), kept in open vial for 2 d; crysts. filtered, dried (vac., P2O5); elem. anal.;	99%

...Expand

: 603-36-1
triphenylantimony

: 637-44-5
phenylpropyolic acid

: triphenylantimony bis(phenylpropiolate)

Conditions

Conditions	Yield
With tert.-butylhydroperoxide In diethyl ether for 12h;	99%
With tert.-butylhydroperoxide In diethyl ether for 12h; Heating;	99%

: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

: 603-36-1
triphenylantimony

: 848236-31-7
dichloro(η5-pentamethylcyclopentadienyl)(triphenylstibine)rhodium(III)

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 2h;	99%

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 603-36-1
triphenylantimony

: C28H30Cl2IrSb

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 2h;	99%

: 603-36-1
triphenylantimony

: 637-44-5
phenylpropyolic acid

: triphenylantimony bis(phenylpropiolate)

Conditions

Conditions	Yield
With tert.-butylhydroperoxide In water for 12h;	99%

Triphenylantimony Consensus Reports

Triphenylstibane （603-36-1）and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Triphenylantimony Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Sb)/m³
ACGIH TLV: TWA 0.5 mg(Sb)/m³
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m³

Triphenylantimony Specification

The Triphenyl stibine with CAS registry number of 603-36-1 is also known as Stibine, triphenyl-. The IUPAC name is Triphenylstibane. It belongs to product categories of Classes of Metal Compounds; Sb (Antimony) Compounds; Semimetal Compounds. Its EINECS registry number is 210-037-6. In addition, the formula is C₁₈H₁₅Sb and the molecular weight is 353.08. This chemical is a off-white powder and should be stored in sealed containers.

Physical properties about Triphenyl stibine are: (1)Rotatable Bond Count: 3; (2)Exact Mass: 352.021193; (3)MonoIsotopic Mass: 352.021193; (4)Topological Polar Surface Area: 0; (5)Heavy Atom Count: 19; (6)Formal Charge: 0; (7)Complexity: 202.

Uses of Triphenyl stibine: it is used as catalyst for reaction of changing leukotriene into aromatic and hydrogenated aromatic. This chemical is also used as inhibitors for polymerization, lubricant additives and used in dechlorination.

When you are using this chemical, please be cautious about it. As a chemical, it is harmful by inhalation and if swallowed. What's more, it is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. During using it, avoid release to the environment refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
1. SMILES: c3c([Sb](c1ccccc1)c2ccccc2)cccc3
2. InChI: InChI=1/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;/rC18H15Sb/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
3. InChIKey: HVYVMSPIJIWUNA-KWOBPOEBAA
4. Std. InChI: InChI=1S/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;
5. Std. InChIKey: HVYVMSPIJIWUNA-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD50	oral	650mg/kg (650mg/kg)	Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,
mouse	LDLo	intraperitoneal	500mg/kg (500mg/kg)	"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 6, Pg. 229, 1954.
rat	LD50	intraperitoneal	168mg/kg (168mg/kg)	Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,
rat	LD50	oral	183mg/kg (183mg/kg)	"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1280, 1986.

Product Name

Triphenylantimony

Synthetic route

Triphenylantimony Consensus Reports

Triphenylantimony Standards and Recommendations

Triphenylantimony Specification

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