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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Triphenylamine Manufacturer/High quality/Best price/In stock

Cas:603-34-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Triphenylamine WITH HIGH PURITY

Cas:603-34-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min -----------------------------------------------------------------------------------------------

High purity Various Specifications Triphenylamine CAS:603-34-9

Cas:603-34-9

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:shanghai

Triphenylamine

Cas:603-34-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Triphenylamine

Cas:603-34-9

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 603-34-9 Triphenylamine Manufacturer

Cas:603-34-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Shanghai Hohance Chemical Co., ltd

1)Entity factory, can batch production 2)Sample service 3)the most competitive price with good quality: we do this products so many years with Skilled craft can control the cost. so we can provide the most competitive price for our cust

Triphenylamine

Cas:603-34-9

Min.Order:1 Kilogram

FOB Price: $10.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Triphenylamine

Cas:603-34-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/1450.html Product Name Triphenylamine CAS No. 603-34-9

Triphenylamine

Cas:603-34-9

Min.Order:1 Gram

FOB Price: $11.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Triphenylamine Basic information Product Name: Triphenylamine Synonyms: amine,triphenyl;N,N,N-Triphenylamine;n,n-diphenyl-benzenamin;Triphenylamin;N,N-DIPHENYLANILINE;N,N-diphenylbenzena

TIANFU-CHEM CAS:603-34-9 Triphenylamine

Cas:603-34-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

Triphenylamine N, N-Diphenylbenzenamine 603-34-9

Cas:603-34-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 603-34-9 with best quality

Cas:603-34-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Triphenylamine CAS No: 603-34-9 Assay: >98% Appearance: light yellow to off-white powder Application: OLED material interm Product Name: Triphenylamine Synonyms: amine,triphenyl;N,N,N-Triphenylamine;n,n-diphenyl-benzenamin;Triphen

Triphenylamine

Cas:603-34-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

amine,triphenylCAS NO.:603-34-9

Cas:603-34-9

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Triphenylamine 603-34-9

Cas:603-34-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Organic Synthesis, Triphenylamine CAS:603-34-9

Cas:603-34-9

Min.Order:1 Kilogram

FOB Price: $39.6 / 45.1

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Triphenylamine CAS:603-34-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate

Triphenylamine CAS:603-34-9

Cas:603-34-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Triphenylamine

Cas:603-34-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Kemi-Works Chemical Co., Ltd

1.Product name: Triphenylamine 2.CAS No. 603-34-9 3.MF: C18H15N 4.Assay:99.0%min ISO9001 Storage:Store in dry and cool place with good seal Package: 25kg/drum, or as per your request. Application:Pharmaceutical Intermediates ect. Transportati

Triphenylamine

Cas:603-34-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Triumph International Development Limilted

Appearance:White or off-white Solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Se

Triphenylamine

Cas:603-34-9

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Triphenylamine

Cas:603-34-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Triphenylamine

Cas:603-34-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

Triphenylamine

Cas:603-34-9

Min.Order:0

Negotiable

Type:Trading Company

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Triphenylamine

Cas:603-34-9

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Triphenylamine

Cas:603-34-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity Various Specifications Triphenylamine

Cas:603-34-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

603-34-9 High purity TriphenylaMine in stock

Cas:603-34-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:off-white solid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transportation:BY

Triphenylamine

Cas:603-34-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Triphenylamine

Cas:603-34-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Triphenylamine

Cas:603-34-9

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Synthetic route

bromobenzene
108-86-1

bromobenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 20℃; for 1h;99%
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 24h; Catalytic behavior; Reagent/catalyst; Time; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Reagent/catalyst; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
aniline
62-53-3

aniline

chlorobenzene
108-90-7

chlorobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Reagent/catalyst; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
With potassium tert-butylate In toluene at 135℃; for 36h;78%
With copper chromium oxide; potassium hydroxide In toluene for 18h; Ullmann Condensation; Inert atmosphere; Reflux; Green chemistry;43%
With bis-triphenylphosphine-palladium(II) chloride; (E)-2-(((2,5-bis(trifluoromethyl)phenyl)imino)methyl)phenol; sodium t-butanolate In o-xylene at 145℃; for 12h; Schlenk technique; Inert atmosphere;
diphenylamine
122-39-4

diphenylamine

chlorobenzene
108-90-7

chlorobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With C30H41ClPPd; sodium t-butanolate In toluene at 100℃; for 2h; Buchwald-Hartwig Coupling; Inert atmosphere;99%
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; for 21h;98%
2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

aniline
62-53-3

aniline

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 25℃; for 72h;98%
With cesium fluoride In acetonitrile at 20℃; for 72h;98%
iodobenzene
591-50-4

iodobenzene

aniline
62-53-3

aniline

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With potassium tert-butylate; 1,2-bis(2,6-diisopropylphenylimino)ethane; copper(l) iodide In toluene at 120℃; for 48h;97%
With potassium tert-butylate In toluene at 120℃; for 12h; Ullmann coupling; Inert atmosphere;95%
With copper chromium oxide; potassium hydroxide In toluene for 6h; Catalytic behavior; Reagent/catalyst; Solvent; Ullmann Condensation; Inert atmosphere; Reflux; Green chemistry;95%
bromobenzene
108-86-1

bromobenzene

N-(trimethylsilyl)-diphenylamine
17425-91-1

N-(trimethylsilyl)-diphenylamine

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 1h; Inert atmosphere;97%
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 1h; Time; Inert atmosphere;97%
4-(diphenylamino)phenyl boronic acid
201802-67-7

4-(diphenylamino)phenyl boronic acid

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With silver nitrate; triethylamine In ethanol; water at 80℃; for 0.166667h; Solvent; Reagent/catalyst;97%
With copper(ll) sulfate pentahydrate; oxygen; diisopropylamine In ethanol; water at 80℃; for 1.5h; Catalytic behavior; Reagent/catalyst; Green chemistry;96%
iodobenzene
591-50-4

iodobenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With bis(triphenylphosphine)nickel(II) chloride; ethylmagnesium bromide; triphenylphosphine In tetrahydrofuran at 80℃; for 3h;96%
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium hydroxide In dimethyl sulfoxide at 120℃; for 0.666667h;96%
With potassium tert-butylate In toluene at 120℃; for 12h;95%
2-((4-diphenylamino)phenyl)[1,3,2]dioxaborolane
402488-98-6

2-((4-diphenylamino)phenyl)[1,3,2]dioxaborolane

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With silver nitrate; triethylamine In ethanol; water at 80℃; for 0.233333h;96%
cyclohexanone
108-94-1

cyclohexanone

nitrobenzene
98-95-3

nitrobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With N/O-doped porous carbon (on base of polypyrrole) supported nanopalladium In toluene at 160℃; for 36h; Reagent/catalyst; Inert atmosphere; Sealed tube;96%
chlorobenzene
108-90-7

chlorobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With potassium tert-butylate; urea; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane at 100℃; for 46h;95%
With ammonia; sodium; Petroleum ether
Multi-step reaction with 2 steps
1: sodium t-butanolate; (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl / neat (no solvent) / 12 h / 110 °C / Inert atmosphere; Green chemistry
2: sodium t-butanolate; (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl / neat (no solvent) / 12 h / 110 °C / Inert atmosphere; Green chemistry
View Scheme
iodobenzene
591-50-4

iodobenzene

aniline
62-53-3

aniline

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With [2,2]bipyridinyl; potassium tert-butylate; copper(l) iodide In toluene at 115℃; for 3.5h; Product distribution; Further Variations:; Reagents;A 95%
B 2%
With copper at 180℃; for 12h;A 46%
B 31%
With copper(l) iodide; cesium fluoride In dimethyl sulfoxide at 130℃; for 24h; Ullmann Condensation; Inert atmosphere; Glovebox;A 12%
B 39 %Chromat.
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 110℃; for 3.5h; Product distribution; Further Variations:; Catalysts; high pressure;
iodobenzene
591-50-4

iodobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With potassium tetrachloropalladate(II); L-arginine; potassium hydroxide In water at 80℃; for 2h; Reagent/catalyst;95%
With potassium phosphate; copper(l) iodide; lithium amide In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; chemoselective reaction;79%
Multi-step reaction with 2 steps
1: 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; caesium carbonate / 1,4-dioxane / 24 h / Reflux
2: 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; caesium carbonate / 1,4-dioxane / 144 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: Pd(tris[2-(diphenylphosphino)ethyl]phosphine tetrasulfide)(dibenzylideneacetone); caesium carbonate / isopropyl alcohol / 6 h / 80 °C
2: Pd(tris[2-(diphenylphosphino)ethyl]phosphine tetrasulfide)(dibenzylideneacetone); caesium carbonate / isopropyl alcohol / 24 h / 80 °C
View Scheme
Multi-step reaction with 3 steps
1: ammonia; potassium carbonate / water; ethanol / 20 °C / UV-irradiation; Green chemistry
2: potassium carbonate / water; ethanol / 20 °C / UV-irradiation; Green chemistry
3: potassium carbonate / water; ethanol / 20 °C / UV-irradiation; Green chemistry
View Scheme
phenyl copper
3220-49-3

phenyl copper

lithium diphenylamide
5856-89-3

lithium diphenylamide

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With chloranil at -60℃;94%
bromobenzene
108-86-1

bromobenzene

aniline
62-53-3

aniline

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;92%
With dichloro{1,10-[dicyclohexylbenzyl]-3,3'-o-xylyldibenzimidazolidin-2,2'-diylidene}palladium (II); potassium tert-butylate In 1,2-dimethoxyethane at 80℃; for 15h; Buchwald-Hartwig amination; Inert atmosphere;92%
With potassium hydroxide In water for 24h; Buchwald-Hartwig reaction; Reflux; Inert atmosphere;88%
4-(diphenylamino)phenylboronic pinacol ester
267221-88-5

4-(diphenylamino)phenylboronic pinacol ester

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With silver nitrate; triethylamine In ethanol; water at 80℃; for 0.916667h;92%
With copper(ll) sulfate pentahydrate; oxygen; diisopropylamine In ethanol; water at 80℃; for 24h; Green chemistry;61%
4-N,N-diphenylamino-1-bromobenzene
36809-26-4

4-N,N-diphenylamino-1-bromobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With 1,4-dioxane; 1,10-Phenanthroline; sodium hydride In mineral oil at 140℃; for 22h; Schlenk technique; Inert atmosphere;90%
With tributyl-amine; tetrabutylammonium tetrafluoroborate In acetonitrile at 20℃; for 1.8h; Inert atmosphere; Electrolysis;80%
With formic acid; C59H60N6O2Pt; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 4h; Inert atmosphere; Sealed tube; UV-irradiation;74 %Spectr.
diphenylamine
122-39-4

diphenylamine

1,4-Cyclohexanedione
637-88-7

1,4-Cyclohexanedione

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
toluene-4-sulfonic acid88.2%
toluene-4-sulfonic acid In toluene for 12h; Heating;88%
iodobenzene
591-50-4

iodobenzene

N-phenyl-1-naphthylamine
90-30-2

N-phenyl-1-naphthylamine

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
potassium hydroxide; copper In various solvent(s) at 160℃; for 8h;88%
diphenylamine
122-39-4

diphenylamine

chlorobenzene
108-90-7

chlorobenzene

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

N-(2-biphenyl)aniline
35887-50-4

N-(2-biphenyl)aniline

Conditions
ConditionsYield
With 2,2,6,6-tetramethylpiperidinyl-lithium In diethyl ether; cyclohexane at 25℃; for 24h; Inert atmosphere;A n/a
B 87%
diphenylamine
122-39-4

diphenylamine

phenylboronic acid
98-80-6

phenylboronic acid

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With CoCuFe2O4; potassium hydroxide In ethanol at 60℃; for 5h; Green chemistry;85%
With potassium carbonate In ethanol; water at 70℃; for 8h; Chan-Lam Coupling;40 %Chromat.
bromobenzene
108-86-1

bromobenzene

aniline
62-53-3

aniline

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With C46H58Br2N4O4Pd; potassium tert-butylate In 1,2-dimethoxyethane at 80℃; for 15h; Inert atmosphere; Buchwald-Hartwig amination;A 84%
B 16%
With water; sodium t-butanolate In N,N-dimethyl-formamide at 120℃; for 3h; Schlenk technique;A 40%
B 60%
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 135℃; for 10.5h; Product distribution; Further Variations:; Catalysts; high pressure;
bromobenzene
108-86-1

bromobenzene

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With potassium tert-butylate; urea; tri tert-butylphosphoniumtetrafluoroborate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In 1,4-dioxane at 100℃; for 19h;83%
With potassium tert-butylate; urea; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane at 100℃; for 19h;83%
Multi-step reaction with 2 steps
1: 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; caesium carbonate / 1,4-dioxane / 96 h / Reflux
2: 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; caesium carbonate / 1,4-dioxane / 144 h / Reflux
View Scheme
nitrobenzene
98-95-3

nitrobenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With potassium phosphate; bis(acetylacetonato)palladium(II); dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine In n-heptane at 130℃; for 24h; Buchwald-Hartwig Coupling; Sealed tube; Inert atmosphere;83%
With potassium phosphate; bis(acetylacetonato)palladium(II); BrettPhos In n-heptane at 130℃; for 24h;83%
tri(p-bromophenyl)amine
4316-58-9

tri(p-bromophenyl)amine

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With methanol; gold; hydrogen; caesium carbonate at 100℃; under 3800.26 Torr; for 132h;82%
diphenylamine
122-39-4

diphenylamine

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

Conditions
ConditionsYield
With potassium hydroxide at 60℃; for 0.5h; Catalytic behavior; Green chemistry;81%
2-[10-(N-phenylamino)-1'-(4-nitrophenyl)]methylcyclohexanone

2-[10-(N-phenylamino)-1'-(4-nitrophenyl)]methylcyclohexanone

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

(E)-2-[(4-nitrophenyl)methylene]cyclohexanone
22114-45-0, 56005-41-5

(E)-2-[(4-nitrophenyl)methylene]cyclohexanone

C

6-(4-nitrophenyl)-5-phenyl-5,6,7,8,9,10-hexahydrophenanthridine

6-(4-nitrophenyl)-5-phenyl-5,6,7,8,9,10-hexahydrophenanthridine

Conditions
ConditionsYield
Stage #1: 2-[10-(N-phenylamino)-1'-(4-nitrophenyl)]methylcyclohexanone; 2-(trimethylsilyl)phenyl trifluoromethanesulfonate With potassium fluoride; 18-crown-6 ether In acetonitrile at 20℃; Inert atmosphere;
Stage #2: With hydrogenchloride In water; acetonitrile for 1h; Inert atmosphere; Reflux;
A 15%
B 15%
C 80%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

tri(p-bromophenyl)amine
4316-58-9

tri(p-bromophenyl)amine

Conditions
ConditionsYield
With N-Bromosuccinimide; triethylamine In N,N-dimethyl-formamide at 20℃;100%
With bromine In chloroform at 0 - 20℃; for 1h;97%
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 12h; Cooling with ice;94%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

4-nitrophenyldiphenylamine
4316-57-8

4-nitrophenyldiphenylamine

Conditions
ConditionsYield
With sodium nitrate; acetic acid In chloroform at 85℃; Inert atmosphere;100%
With 3-(ethoxycarbonyl)-1-(5-methyl-5-(nitrosooxy)hexyl)pyridin-1-ium bis(trifluoromethanesulfonyl)imide at 20℃; for 3h; Ionic liquid;89%
With dinitrogen trioxide In dichloromethane at 0℃;42%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
15546-43-7

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl

Conditions
ConditionsYield
Stage #1: N,N-diphenylaminobenzene With methanesulfonic acid In dichloromethane at 0℃;
Stage #2: With chloranil In dichloromethane at 0 - 20℃; for 0.0166667h; Reagent/catalyst; Solvent; Time;
99%
With 5% rhodium-on-charcoal; trifluoroacetic acid at 50℃; for 1h; Reagent/catalyst; Green chemistry; regioselective reaction;99%
Stage #1: N,N-diphenylaminobenzene With copper(II) perchlorate In acetonitrile at 25℃; for 12h;
Stage #2: With potassium carbonate In water; acetonitrile at 25℃; for 0.5h; Further stages.;
81%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

tris(4-iodophenyl)amine
4181-20-8

tris(4-iodophenyl)amine

Conditions
ConditionsYield
Stage #1: N,N-diphenylaminobenzene With trifluorormethanesulfonic acid; [bis(pyridine)iodine]+ tetrafluoroborate In dichloromethane at 0 - 20℃; for 21h;
Stage #2: With water; sodium thiosulfate In dichloromethane
99%
Stage #1: N,N-diphenylaminobenzene With trifluorormethanesulfonic acid; [bis(pyridine)iodine]+ tetrafluoroborate In dichloromethane at 0 - 20℃; for 21h;
Stage #2: With sodium thiosulfate In dichloromethane; water
99%
With iodine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 20℃;97%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

N,N-bis(4-bromophenyl)aniline
81090-53-1

N,N-bis(4-bromophenyl)aniline

Conditions
ConditionsYield
With N-Bromosuccinimide In ethyl acetate at 20℃; for 24h;99%
With N-Bromosuccinimide In ethyl acetate at 20℃; for 24h;99%
With N-Bromosuccinimide In N,N-dimethyl-formamide at 0℃; for 4h;90%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

(E)-tert-butyl (1-methyl-2-oxoindolin-3-ylidene)carbamate

(E)-tert-butyl (1-methyl-2-oxoindolin-3-ylidene)carbamate

tert-butyl (3-(4-(diphenylamino)phenyl)-1-methyl-2-oxoindolin-3-yl)carbamate

tert-butyl (3-(4-(diphenylamino)phenyl)-1-methyl-2-oxoindolin-3-yl)carbamate

Conditions
ConditionsYield
With C21H17F3OP(1+)*C32H12BF24(1-) In 1,2-dichloro-ethane at 20℃; for 0.0833333h; Friedel-Crafts Alkylation;99%
1H-imidazole
288-32-4

1H-imidazole

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

C39H21F18N7O6

C39H21F18N7O6

Conditions
ConditionsYield
Stage #1: 1H-imidazole; N,N-diphenylaminobenzene In acetonitrile for 0.5h;
Stage #2: trifluoroacetic anhydride In acetonitrile for 1.5h;
98.32%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

5-hexylbicyclo[2.2.1]hept-2-ene
22094-83-3

5-hexylbicyclo[2.2.1]hept-2-ene

polymer, Mw 1371000, Mn 349000; monomer(s): 5-hexyl-2-norbornene, 80 mol percent in feed; N,N-diphenylaniline, 20 mol percent in feed

polymer, Mw 1371000, Mn 349000; monomer(s): 5-hexyl-2-norbornene, 80 mol percent in feed; N,N-diphenylaniline, 20 mol percent in feed

Conditions
ConditionsYield
{(η6-toluene)Ni(C6F5)2} In toluene at 20℃; for 24h;98%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

tris(phenyl-2,4,6-d3)amine
21223-02-9

tris(phenyl-2,4,6-d3)amine

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate; water-d2 In chloroform-d1 at 80℃; for 24h; Sealed tube; regioselective reaction;98%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

4-(diphenylamino)benzaldehyde
4181-05-9

4-(diphenylamino)benzaldehyde

Conditions
ConditionsYield
Stage #1: N,N-dimethyl-formamide With trichlorophosphate In 1,2-dichloro-ethane at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: N,N-diphenylaminobenzene In 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;
97.6%
With trichlorophosphate at 35 - 40℃; Inert atmosphere;96%
Stage #1: N,N-diphenylaminobenzene; N,N-dimethyl-formamide With trichlorophosphate In 1,2-dichloro-ethane at 0 - 45℃; Vilsmeier-Haack reaction;
Stage #2: With water In 1,2-dichloro-ethane Vilsmeier-Haack reaction; Cooling with ice;
96%
tricyanomethane
454-50-2

tricyanomethane

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

triphenylammonium tricyanomethanide

triphenylammonium tricyanomethanide

Conditions
ConditionsYield
In water at 50℃; for 3h;97%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

chloranil
118-75-2

chloranil

A

2,3,5,6-tetrachlorobenzene-1,4-diol
87-87-6

2,3,5,6-tetrachlorobenzene-1,4-diol

B

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
15546-43-7

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.0166667h; Molecular sieve;A 96%
B 83%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

4-(diphenylamino)benzaldehyde
4181-05-9

4-(diphenylamino)benzaldehyde

Conditions
ConditionsYield
With trichlorophosphate In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 0.5h; Reflux;95%
Stage #1: N,N-diphenylaminobenzene With trichlorophosphate In N,N-dimethyl-formamide for 1h;
Stage #2: With sodium hydroxide
85%
With N,N-dimethyl-formamide; trichlorophosphate at 100℃; for 6h;52.74%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

acetyl chloride
75-36-5

acetyl chloride

(1,1',1''-[nitrilotri(4,1-phenylene)]tri(ethan-1-one))
4181-21-9

(1,1',1''-[nitrilotri(4,1-phenylene)]tri(ethan-1-one))

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; Friedel-Crafts Acylation; Inert atmosphere;95%
With aluminum (III) chloride In dichloromethane at 0℃; for 12h;95%
With aluminum (III) chloride In dichloromethane Reflux;92%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

2,7-dibromo-(9-phenyl-9H-fluoren-9-ol)
132717-37-4

2,7-dibromo-(9-phenyl-9H-fluoren-9-ol)

tris(4-(2,7-dibromo-9-phenyl-9H-fluoren-9-yl)phenyl)amine

tris(4-(2,7-dibromo-9-phenyl-9H-fluoren-9-yl)phenyl)amine

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 2h; Inert atmosphere; Schlenk technique;95%
N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

4-N,N-diphenylamino-1-bromobenzene
36809-26-4

4-N,N-diphenylamino-1-bromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In tetrachloromethane for 4h; Reflux;94%
With N-Bromosuccinimide In tetrachloromethane for 4h; Heating;93%
With N-Bromosuccinimide In tetrachloromethane for 4h; Inert atmosphere; Reflux;93%

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