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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Azabicyclo[2.2.1]Hept-5-En-3-One supplier in China

Cas:49805-30-3

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Azabicyclo[2.2.1]hept-5-en-3-one Manufacturer/High quality/Best price/In stock

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White to yellowish crystal Complies Identification HPLC

High quality 2-azabicyclo(2.2.1)hept-5-en-3-one with best price cas:49805-30-3

Cas:49805-30-3

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FOB Price: $250.0 / 350.0

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 2-Azabicyclo[2.2.1]hept-5-en-3-one CAS No. 49805-30-3 Appearance Yellowish to off-white powder Assay ≥99% Capacity 200mt/year

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Gram

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Azabicyclo[2.2.1]Hept-5-En-3-One

Cas:49805-30-3

Min.Order:1 Metric Ton

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Chemwill Asia Co., Ltd.

CHemwill -- 2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

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Henan Tianfu Chemical Co., Ltd.

2-Azabicyclo[2.2.1]hept-5-en-3-one Basic information Product Name: 2-Azabicyclo[2.2.1]hept-5-en-3-one Synonyms: 4-Amino-2-cyclopentene-1-carboxylic acid;4-AMINO-2-CYCLOPENTENE-1-CARBOXYL

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Kilogram

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

TopCAS 49805-30-3 with fast shipping

Cas:49805-30-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

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Henan Sinotech Import&Export Corporation

zabicyclo [Alias]: 2-azabicyclo [2.2.1] hept-5-ene-3-one [CAS No.]: 49805-30-3 [Formula]: C6H7NO [Molecular Weight]: 109.13 [Appearance]: white to pale yellow crystals [Content]: ≥97.0% [Purity]: ≥99.0% Specification: 25 kg / barrel,

Azabicyclo

Cas:49805-30-3

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Azabicyclo[2.2.1]hept-5-en-3-one 49805-30-3

Cas:49805-30-3

Min.Order:1 Kilogram

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Kilogram

FOB Price: $68.0 / 75.0

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Qingdao Beluga Import and Export Co., LTD

2-Azabicyclo[2.2.1]hept-5-en-3-one CAS:49805-30-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qualit

2-Azabicyclo[2.2.1]hept-5-en-3-one CAS:49805-30-3

Cas:49805-30-3

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

(±)-2-Azabicyclo[2.2.1]Hept-5-En-3-One (Vince Lactam)

Cas:49805-30-3

Min.Order:0

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

2-Azabicyclo[2.2.1]hept-5-en-3-one (Vince lactam)

Cas:49805-30-3

Min.Order:100 Gram

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:0 Metric Ton

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Azabicyclo

Cas:49805-30-3

Min.Order:10 Kilogram

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:4 Kilogram

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:100 Metric Ton

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-azabicyclo(2.2.1)hept-5-en-3-one

Cas:49805-30-3

Min.Order:10 Gram

FOB Price: $100.0

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Azabicyclo

Cas:49805-30-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

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HANGZHOU YUNUO CHEMICAL CO.,LTD

moderate price & quick delivery Appearance:solid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Intermediate for pharmaceuticals. Product Dat

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Kilogram

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Siwei Development Group Ltd.

Product name: Vince Lactam(2-Azabicyclo[2.2.1]hept-5-en-3-one CAS No.:49805-30-3 Molecule Formula:C6H7NO Molecule Weight:109.13 Purity: 98.0% Package: 25kg/drum Description:White or off-white crystalline powder Manufacture Standards:E

High Quality Vince Lactam(2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Kilogram

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Azabicyclo[2.2.1]hept-5-en-3-one

Cas:49805-30-3

Min.Order:1 Gram

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Synthetic route

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

cyanogen chloride
506-77-4

cyanogen chloride

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With sodium hydroxide In methanol at 0 - 5℃; for 8h; pH=4 - 5; Diels-Alder Cycloaddition;95%
P-toluenesulfonyl cyanide
19158-51-1

P-toluenesulfonyl cyanide

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
79.3%
P-toluenesulfonyl cyanide
19158-51-1

P-toluenesulfonyl cyanide

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With acetic acid In dichloromethane 1) 10 deg C, 3 h, 2) 20 deg C, 1 h;56%
With oxonium Yield given. Multistep reaction;
isocyanate de chlorosulfonyle
1189-71-5

isocyanate de chlorosulfonyle

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

A

(+/-)-6-azabicyclo[3.2.0]hept-3-en-7-one
97911-48-3, 138127-85-2, 146864-12-2, 63838-48-2

(+/-)-6-azabicyclo[3.2.0]hept-3-en-7-one

B

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

C

(+/-)-2,4-diazabicyclo[4.3.0]non-8-ene-3,5-dione

(+/-)-2,4-diazabicyclo[4.3.0]non-8-ene-3,5-dione

Conditions
ConditionsYield
Stage #1: isocyanate de chlorosulfonyle; cyclopenta-1,3-diene In diethyl ether at -60℃; for 2h;
Stage #2: With potassium hydroxide; sodium sulfite In diethyl ether at 0℃; for 0.5h;
A 46%
B n/a
C n/a
isocyanate de chlorosulfonyle
1189-71-5

isocyanate de chlorosulfonyle

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With sodium thiosulfate Yield given;
In dichloromethane at 20℃; for 0.166667h;
3-(Methanesulfonyl)-2-azabicyclo<2.2.1>hepta-2,5-diene

3-(Methanesulfonyl)-2-azabicyclo<2.2.1>hepta-2,5-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With acetic acid In dichloromethane for 1h; Ambient temperature; Yield given;
With acetic acid In dichloromethane for 1h; Mechanism; Ambient temperature;
(1S,4R)-1-(2-Aza-bicyclo[2.2.1]hepta-2,5-diene-3-sulfonylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one

(1S,4R)-1-(2-Aza-bicyclo[2.2.1]hepta-2,5-diene-3-sulfonylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With acetic acid Yield given;
3-tosyl-2-azabicyclo [2.2.1]hepta-2,5-diene
49805-27-8

3-tosyl-2-azabicyclo [2.2.1]hepta-2,5-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With acetic acid
benzenesulfonyl cyanide
24224-99-5

benzenesulfonyl cyanide

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With l-menthol ethylaluminum dichloride; water 1.) CH2Cl2, -25 deg C, 24 h, 2. ) CH2Cl2; Yield given. Multistep reaction;
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: CH2Cl2 / 2 h / Ambient temperature
2: AcOH / CH2Cl2 / 1 h / Ambient temperature
View Scheme
methanesulfonyl cyanide
24225-08-9

methanesulfonyl cyanide

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

Conditions
ConditionsYield
With acetic acid In dichloromethane; water
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

(1S,4R)-4-aminocyclopent-2-enecarboxylic acid hydrochloride
61865-62-1

(1S,4R)-4-aminocyclopent-2-enecarboxylic acid hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 20℃; for 24h;100%
With hydrogenchloride In water for 1h; Heating;90%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

3-oxo-2-aza-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid tert-butyl ester
162427-15-8

3-oxo-2-aza-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With dmap; triethylamine In tetrahydrofuran at 20℃;100%
With dmap; triethylamine In dichloromethane for 24h; Ambient temperature;99%
With dmap; triethylamine In chloroform for 5h; Ambient temperature;95%
triphenylbismuthane
603-33-8

triphenylbismuthane

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

rel-(1S,4R)-2-phenyl-2-azabicyclo[2.2.1]hept-5-en-3-one
186586-76-5

rel-(1S,4R)-2-phenyl-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With copper diacetate; triethylamine In dichloromethane for 24h; Ambient temperature;100%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2-Azabicyclo[2.2.1]heptan-3-one
24647-29-8

2-Azabicyclo[2.2.1]heptan-3-one

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethyl acetate99%
With palladium 10% on activated carbon; hydrogen In ethyl acetate99%
With hydrogen; palladium on activated charcoal In ethyl acetate at 20℃; under 2625.2 Torr;97%
With hydrogen; palladium on activated charcoal In ethyl acetate under 760 Torr; Ambient temperature;
methanol
67-56-1

methanol

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2-Nitrobenzenesulfonyl chloride
1694-92-4

2-Nitrobenzenesulfonyl chloride

methyl 4-(2-nitrobenzenesulfonylamino)cyclopent-2-enecarboxylate

methyl 4-(2-nitrobenzenesulfonylamino)cyclopent-2-enecarboxylate

Conditions
ConditionsYield
Stage #1: methanol; 2-azabicyclo[2.2.1.]hept-5-en-3-one With sulfuryl dichloride at 20℃; for 3h;
Stage #2: 2-Nitrobenzenesulfonyl chloride With triethylamine In dichloromethane at 0℃; for 1.5h; Further stages.;
98%
diisopropyl hydrogenphosphonate
1809-20-7

diisopropyl hydrogenphosphonate

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

diisopropyl(3-oxo-2-azabicyclo[2.2.1]hept-5-en-2-yl)phosphonate
1417780-51-8

diisopropyl(3-oxo-2-azabicyclo[2.2.1]hept-5-en-2-yl)phosphonate

Conditions
ConditionsYield
With copper diacetate; potassium carbonate In toluene at 80℃; under 760.051 Torr; for 0.666667h; Reagent/catalyst; Molecular sieve;97%
(E)-3-methoxy-2-methylacryloyl isocyanate
132151-65-6

(E)-3-methoxy-2-methylacryloyl isocyanate

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2--2-azabicyclo<2.2.1>hept-5-en-3-one
136994-68-8

2--2-azabicyclo<2.2.1>hept-5-en-3-one

Conditions
ConditionsYield
In benzene at 50℃; for 5h;96%
benzyl bromide
100-39-0

benzyl bromide

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

(1SR,4RS)-2-benzyl-2-azabicyclo[2.2.1]hept-5-en-3-one

(1SR,4RS)-2-benzyl-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
Stage #1: 2-azabicyclo[2.2.1.]hept-5-en-3-one With potassium hydroxide In dimethyl sulfoxide at 20℃; for 0.5h;
Stage #2: With tetra-(n-butyl)ammonium iodide In dimethyl sulfoxide for 0.25h;
Stage #3: benzyl bromide In dimethyl sulfoxide at 0 - 20℃;
96%
methanol
67-56-1

methanol

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

methyl 4-aminocyclopent-2-ene-1-carboxylate Hydrochloride

methyl 4-aminocyclopent-2-ene-1-carboxylate Hydrochloride

Conditions
ConditionsYield
With hydrogenchloride95%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

(–)-methyl (1S,4R)-4-aminocyclopent-2-ene-1-carboxylate hydrochloride
229613-83-6

(–)-methyl (1S,4R)-4-aminocyclopent-2-ene-1-carboxylate hydrochloride

Conditions
ConditionsYield
With hydrogenchloride In methanol; toluene94.4%
With hydrogenchloride In methanol94.9%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

phenylboronic acid
98-80-6

phenylboronic acid

rel-(1S,4R)-2-phenyl-2-azabicyclo[2.2.1]hept-5-en-3-one
186586-76-5

rel-(1S,4R)-2-phenyl-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With copper diacetate; triethylamine In acetonitrile at 20℃; for 36h; Reflux;92%
With copper diacetate; triethylamine In dichloromethane for 64h; Ambient temperature;12%
2-bromo-2-(2-ethyl)dioxolane
18742-02-4

2-bromo-2-(2-ethyl)dioxolane

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2-(2-[1,3]dioxolan-2-yl-ethyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one
1023307-00-7

2-(2-[1,3]dioxolan-2-yl-ethyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
Stage #1: 2-azabicyclo[2.2.1.]hept-5-en-3-one With potassium hydroxide; benzyltriethylammonium bromide; potassium carbonate In acetonitrile at 20℃; for 0.0833333h;
Stage #2: 2-bromo-2-(2-ethyl)dioxolane In acetonitrile for 1h; Heating; Further stages.;
92%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

p-methoxybenzyl chloride
824-94-2

p-methoxybenzyl chloride

2-(4'-methoxybenzyl)-2-azabicyclo<2.2.1>hept-5-en-3-one
133636-61-0

2-(4'-methoxybenzyl)-2-azabicyclo<2.2.1>hept-5-en-3-one

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide91%
With tetra-(n-butyl)ammonium iodide; lithium hexamethyldisilazane In tetrahydrofuran; N,N-dimethyl-formamide -78 deg C to r.t.;66%
With tetra-(n-butyl)ammonium iodide; lithium hexamethyldisilazane 1) THF, -78 deg C, 30 min, 2a) DMF, -78 to RT, 2b) RT, 24h; Yield given. Multistep reaction;
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

exo-cis-5,6-Dihydroxy-2-azabicyclo<2.2.1>heptan-3-one
77745-22-3

exo-cis-5,6-Dihydroxy-2-azabicyclo<2.2.1>heptan-3-one

Conditions
ConditionsYield
With potassium permanganate In water; acetone for 1h; Ambient temperature;91%
tert-butyldicarbonate
34619-03-9

tert-butyldicarbonate

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

3-oxo-2-aza-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid tert-butyl ester
162427-15-8

3-oxo-2-aza-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With dmap In tetrahydrofuran91%
With dmap In tetrahydrofuran91%
With dmap In tetrahydrofuran91%
methanol
67-56-1

methanol

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

cis-4-amino-2-cyclopentenecarboxylic acid methyl ester hydrochloride
77745-25-6

cis-4-amino-2-cyclopentenecarboxylic acid methyl ester hydrochloride

Conditions
ConditionsYield
With hydrogenchloride for 22h; Heating;89%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

methyl iodide
74-88-4

methyl iodide

(1SR,4RS)-2-methyl-2-azabicyclo[2.2.1]hept-5-en-3-one

(1SR,4RS)-2-methyl-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
Stage #1: 2-azabicyclo[2.2.1.]hept-5-en-3-one With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.5h;
Stage #2: methyl iodide In tetrahydrofuran; mineral oil at 20℃; for 72h; Inert atmosphere;
87%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

cis-4-amino-2-cyclopentene-1-carboxylic acid methyl ester hydrogen sulfate

cis-4-amino-2-cyclopentene-1-carboxylic acid methyl ester hydrogen sulfate

Conditions
ConditionsYield
With sulfuric acid In methanol85.8%
3-pyridylboronic acid
1692-25-7

3-pyridylboronic acid

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

rel-(1S,4R)-2-(pyridin-3-yl)-2-azabicyclo[2.2.1]hept-5-en-3-one
1236057-45-6

rel-(1S,4R)-2-(pyridin-3-yl)-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With trimethylamine-N-oxide; copper diacetate; potassium hydroxide In acetonitrile at 20 - 80℃; Microwave irradiation;85%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2-Nitrobenzenesulfonyl chloride
1694-92-4

2-Nitrobenzenesulfonyl chloride

2-(2-Nitro-benzenesulfonyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one
191467-21-7

2-(2-Nitro-benzenesulfonyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran at -78℃;83%
3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

rel-(1S,4R)-2-(3-methoxyphenyl)-2-azabicyclo[2.2.1]hept-5-en-3-one
1070242-17-9

rel-(1S,4R)-2-(3-methoxyphenyl)-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With trimethylamine-N-oxide; copper diacetate; potassium hydroxide In acetonitrile at 20 - 80℃; Microwave irradiation;83%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2-(3-bromophenyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one

2-(3-bromophenyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With Al2O3#dotCu(2+); potassium carbonate In N,N-dimethyl-formamide at 110℃; for 16h; Inert atmosphere;82%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

propargyl bromide
106-96-7

propargyl bromide

2-prop-2-ynyl-2-azabicyclo[2.2.1]hept-5-en-3-one
1023306-62-8

2-prop-2-ynyl-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
Stage #1: 2-azabicyclo[2.2.1.]hept-5-en-3-one With sodium hydride In N,N-dimethyl-formamide at 20℃; for 1h;
Stage #2: propargyl bromide In N,N-dimethyl-formamide at 20℃; for 1h; Further stages.;
81%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

(1RS,2SR,4RS,5SR)-3-oxa-6-azatricyclo[3.2.1.02,4]octan-7-one
127801-86-9, 137038-08-5

(1RS,2SR,4RS,5SR)-3-oxa-6-azatricyclo[3.2.1.02,4]octan-7-one

Conditions
ConditionsYield
With potassium hydroxide; oxone In methanol; water for 5h; Ambient temperature; pH 6;80%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 48h; Ambient temperature;59%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

6-chloropyridin-3-ylboronic acid
444120-91-6

6-chloropyridin-3-ylboronic acid

rel-(1S,4R)-2-(6-chloropyridin-3-yl)-2-azabicyclo[2.2.1]hept-5-en-3-one
1236057-46-7

rel-(1S,4R)-2-(6-chloropyridin-3-yl)-2-azabicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
With trimethylamine-N-oxide; copper diacetate; potassium hydroxide In acetonitrile at 20 - 80℃; Microwave irradiation;80%
tributylsulfoammonium betaine

tributylsulfoammonium betaine

2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

C6H7NO4S*C12H27N

C6H7NO4S*C12H27N

Conditions
ConditionsYield
In acetonitrile at 30℃; for 24h; Inert atmosphere;80%
2-azabicyclo[2.2.1.]hept-5-en-3-one
49805-30-3

2-azabicyclo[2.2.1.]hept-5-en-3-one

2-bromobenzoic acid chloride
7154-66-7

2-bromobenzoic acid chloride

2-(2-bromo-benzoyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one

2-(2-bromo-benzoyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-one

Conditions
ConditionsYield
Stage #1: 2-azabicyclo[2.2.1.]hept-5-en-3-one With sodium hydride In tetrahydrofuran at 20℃; for 0.75h;
Stage #2: 2-bromobenzoic acid chloride In tetrahydrofuran at 20℃;
79%
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