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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:1 Gram

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Type:Lab/Research institutions

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Suzhou Sinosun Imp.&Exp. Corporation

We supply good quality 1-Bromo-3-iodobenzene CAS# 591-18-4 at competitive price. Our 1-Bromo-3-iodobenzene CAS# 591-18-4 has been exported to many countries and regions. If you are looking for 1-Bromo-3-iodobenzene CAS# 591-18-4 suppliers in China,

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:50 Kilogram

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Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-Bromo-3-Iodobenzene supplier in China

Cas:591-18-4

Min.Order:1 Metric Ton

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Wuhan Fortuna Chemical Co.,Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Light yellow to colorless transparent liquid Storage:Refriger

Good quality 1-Bromo-3-iodobenzene CAS 591-18-4 with favorable price

Cas:591-18-4

Min.Order:25 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:shanghai

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:1 Kilogram

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min ----------------------------------------------------------------------------------------------

High purity m-bromoiodobenzene CAS:591-18-4

Cas:591-18-4

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 591-18-4 1-BroMo-3-iodobenzene Manufacturer

Cas:591-18-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Bromoiodobenzene

Cas:591-18-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

1-Bromo-3-iodobenzene Basic information Product Name: 1-Bromo-3-iodobenzene Synonyms: 1-bromo-3-iodo-benzen;Benzene, 1-bromo-3-iodo-;m-Bromoiodobenzene;1-BROMO-3-IODOBENZENE;3-BROMOIODOB

best offer 1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

1-Bromo-3-iodobenzene CAS NO 591-18-4

Cas:591-18-4

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 591-18-4 with best quality

Cas:591-18-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name: 1-Bromo-3-iodobenzene CAS No.: 591-18-4 Appearance: light yellow to red liquid Assay: ≥98.0% Appearance:light yellow to red liquid Storage:Preserve

1-Bromo-3-iodobenzene CAS:591-18-4

Cas:591-18-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-3-iodo- 591-18-4

Cas:591-18-4

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

1-Bromo-3-iodobenzene CAS: 591-18-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

1-Bromo-3-iodobenzene CAS: 591-18-4

Cas:591-18-4

Min.Order:1 Gram

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Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-3-iodo-

Cas:591-18-4

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 1.Product name:1-Bromo-3-iodobenzene 2.CAS No.591-18-4 3.MF:C6H4BrI 4.Assay:98.0%min(GC) 5.Appearance:Pale yellow liquid Items Technical index Product name

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:10 Gram

FOB Price: $1.0 / 2.0

Type:Other

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's custo

BEST PRICE/1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1-Bromo-3-Iodobenzene

Cas:591-18-4

Min.Order:0

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Type:Manufacturers

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcin

m-bromoiodobenzene1-bromo-3-iodobenzene; 3-bromoiodobenzene

Cas:591-18-4

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 591-18-4 1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:0 Metric Ton

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Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply m-bromoiodobenzene

Cas:591-18-4

Min.Order:0 Metric Ton

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Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-bromo-3-iodo-

Cas:591-18-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:100 Gram

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Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Bromo-3-Iodobenzene

Cas:591-18-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High quality 1-Bromo-3-Iodobenzene supplier in China

Cas:591-18-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

1-Bromo-3-iodobenzeneCAS NO.: 591-18-4

Cas:591-18-4

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

1-Bromo-3-iodobenzene

Cas:591-18-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Synthetic route

m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With N-iodo-succinimide; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; iodine; caesium carbonate In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;80%
With 1-iodo-3,5,5-trimethylhydantoin In tetrachloromethane for 15h; Concentration; Reagent/catalyst; Solvent; Time; Reflux; Irradiation;61%
(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With N-iodo-succinimide In acetonitrile at 81℃; for 6h;77%
carbon monoxide
201230-82-2

carbon monoxide

3-bromo-1-iodylbenzene
150177-91-6

3-bromo-1-iodylbenzene

A

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

B

isophthalic acid
121-91-5

isophthalic acid

C

m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

Conditions
ConditionsYield
With sodium tetrachloropalladate; sodium carbonate In water at 40℃; for 5.5h; Yields of byproduct given;A n/a
B 14%
C 76%
3-bromobenzoyl chloride
1711-09-7

3-bromobenzoyl chloride

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 100℃; for 12h;72%
bromobenzene
108-86-1

bromobenzene

phenol
108-95-2

phenol

A

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

B

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

C

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With tert.-butylhydroperoxide; iodine at 289.9℃; for 0.0272222h; Product distribution;A 47.6%
B 28.9%
C 23.5%
3-Iodoaniline
626-01-7

3-Iodoaniline

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
Ueberfuehrung in das Diazoperbromid und Zersetzung;
3-bromoaniline
591-19-5

3-bromoaniline

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With iodine
1-Iod-3-(trimethylsilyl)benzol
63520-49-0

1-Iod-3-(trimethylsilyl)benzol

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With bromine
3-iodobenzoyl chloride
1711-10-0

3-iodobenzoyl chloride

A

2-<(trichloromethyl)thio>pyridine
66832-24-4

2-<(trichloromethyl)thio>pyridine

B

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt at 100℃; for 0.0833333h; Heating; Yield given. Yields of byproduct given;
sodium phenoxide
139-02-6

sodium phenoxide

m-bromodiphenyliodonium iodide
81447-71-4

m-bromodiphenyliodonium iodide

A

bromobenzene
108-86-1

bromobenzene

B

diphenylether
101-84-8

diphenylether

C

iodobenzene
591-50-4

iodobenzene

D

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

E

3-bromodiphenyl ether
6876-00-2

3-bromodiphenyl ether

F

benzene
71-43-2

benzene

Conditions
ConditionsYield
In water at 60℃; Product distribution; Mechanism; relative rates of decomposition of the 9-I-2 intermediate;
bis-(3-bromo-benzoyl)-peroxide
1829-88-5

bis-(3-bromo-benzoyl)-peroxide

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With iodobenzene In benzene
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
With Iodine monochloride; N-ethyl-N,N-diisopropylamine; Wang resin 1.) DMF, 40-50 deg C, 2.) CH2Cl2; Yield given. Multistep reaction;
iodine
7553-56-2

iodine

3-bromo-benzenediazonium; bromide
63467-81-2

3-bromo-benzenediazonium; bromide

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

iodine
7553-56-2

iodine

3-bromo-benzenediazonium; dichloride iodide

3-bromo-benzenediazonium; dichloride iodide

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

iodine
7553-56-2

iodine

m-bromobenzene diazonium nitrate

m-bromobenzene diazonium nitrate

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

iodine
7553-56-2

iodine

3-bromo-benzenediazonium; hexachloroplatinate (IV)

3-bromo-benzenediazonium; hexachloroplatinate (IV)

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

iodine
7553-56-2

iodine

3-bromophenyldiazonium chloride
20893-74-7

3-bromophenyldiazonium chloride

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromo-benzenediazonium; tribromoide

3-bromo-benzenediazonium; tribromoide

iodine

iodine

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromo-benzenediazonium; sulfate

3-bromo-benzenediazonium; sulfate

iodine

iodine

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

diethyl ether
60-29-7

diethyl ether

3-bromo-phenyl magnesium (1+); bromide

3-bromo-phenyl magnesium (1+); bromide

iodine

iodine

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

m-bis(trimethylsilyl)benzene
2060-89-1

m-bis(trimethylsilyl)benzene

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: IBr
2: Br2
View Scheme
4-Methyl-1-pentene
691-37-2

4-Methyl-1-pentene

bis(3-bromophenyl)iodonium triflate
1426083-16-0

bis(3-bromophenyl)iodonium triflate

A

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

B

6-bromo-1,1-dimethyl-1,2,3,4-tetrahydronaphthalene
176088-47-4

6-bromo-1,1-dimethyl-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
With copper(I) trifluoromethanesolfonate toluene complex In dichloromethane at 70℃; for 24h; Molecular sieve; Inert atmosphere; Sealed tube;A n/a
B 82 %Spectr.
3-bromobenzoyl chloride
1711-09-7

3-bromobenzoyl chloride

1-iodo-4-n-propylbenzene
126261-84-5

1-iodo-4-n-propylbenzene

A

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

B

4-propylbenzoyl chloride
52710-27-7

4-propylbenzoyl chloride

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 100℃; for 12h; Time;
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

2-(3-bromophenyl)ethynyltrimethylsilane
3989-13-7

2-(3-bromophenyl)ethynyltrimethylsilane

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; trimethylamine for 0.5h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique; Reflux;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In acetonitrile at 20℃; for 1h; Inert atmosphere;99%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; copper(l) iodide; triethylamine In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;93%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-pyridylboronic acid
1692-25-7

3-pyridylboronic acid

3-(3'-bromophenyl)pyridine
4422-32-6

3-(3'-bromophenyl)pyridine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 100℃; Inert atmosphere;100%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 18h; Reflux;90.9%
With palladium diacetate; sodium carbonate; triphenylphosphine In 1,2-dimethoxyethane; water for 18h; Inert atmosphere; Reflux;88%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

ethyl 1-(2,5-difluorophenyl)-5-({3-[(2-ethylhexyl)oxy]-3-oxopropyl}thio)-1H-pyrazole-3-carboxylate
1138037-06-5

ethyl 1-(2,5-difluorophenyl)-5-({3-[(2-ethylhexyl)oxy]-3-oxopropyl}thio)-1H-pyrazole-3-carboxylate

ethyl 5-[(3-bromophenyl)thio]-1-(2,5-difluorophenyl)-1H-pyrazole-3-carboxylate
1138037-34-9

ethyl 5-[(3-bromophenyl)thio]-1-(2,5-difluorophenyl)-1H-pyrazole-3-carboxylate

Conditions
ConditionsYield
Stage #1: ethyl 1-(2,5-difluorophenyl)-5-({3-[(2-ethylhexyl)oxy]-3-oxopropyl}thio)-1H-pyrazole-3-carboxylate With sodium ethanolate In ethanol at 0 - 20℃;
Stage #2: 1-Bromo-3-iodobenzene; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 80℃; for 2h;
100%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3,3’-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-phenylene)dipyridine

3,3’-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-phenylene)dipyridine

3,3'-(3'-bromobiphenyl-3,5-diyl)dipyridine
1258975-28-8

3,3'-(3'-bromobiphenyl-3,5-diyl)dipyridine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 100℃; Inert atmosphere;100%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

aniline
62-53-3

aniline

3-bromo-N-phenylbenzamide
63710-33-8

3-bromo-N-phenylbenzamide

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl-formamide at 100℃; under 750.075 Torr; for 8h; Schlenk technique; Inert atmosphere;100%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

2-methyl-4-(3-bromophenyl)-3-butyn-2-ol

2-methyl-4-(3-bromophenyl)-3-butyn-2-ol

Conditions
ConditionsYield
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique;100%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diethylamine In N,N-dimethyl-formamide at 130℃; for 1h; Microwave irradiation;
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

[(3-cyanopropyl)diisopropylsilyl]acetylene
1057407-31-4

[(3-cyanopropyl)diisopropylsilyl]acetylene

4-{[(3-bromophenyl)ethynyl]diisopropylsilyl}butanenitrile

4-{[(3-bromophenyl)ethynyl]diisopropylsilyl}butanenitrile

Conditions
ConditionsYield
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;100%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

1,4-bis(3-ethynylphenyl)-8,8-dimethoxy-4,4a,5,7a-tetrahydro-1H-1,4-methanocyclopenta[d]pyridazine

1,4-bis(3-ethynylphenyl)-8,8-dimethoxy-4,4a,5,7a-tetrahydro-1H-1,4-methanocyclopenta[d]pyridazine

1,4-bis(3-((3-bromophenyl)ethynyl)phenyl)-8,8-dimethoxy-4,4a,5,7a-tetrahydro-1H-1,4-methanocyclopenta[d]pyridazine

1,4-bis(3-((3-bromophenyl)ethynyl)phenyl)-8,8-dimethoxy-4,4a,5,7a-tetrahydro-1H-1,4-methanocyclopenta[d]pyridazine

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine In tetrahydrofuran at 70℃; for 10h; Inert atmosphere;100%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

dimethyl (3-bromophenyl)phosphonate
15104-42-4

dimethyl (3-bromophenyl)phosphonate

Conditions
ConditionsYield
With palladium diacetate at 90℃; Sealed tube;99.8%
With palladium diacetate at 90℃; Sealed tube;99.8%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

phenylacetylene
536-74-3

phenylacetylene

1-phenyl-2-(m-bromo)phenylacetylene
29778-29-8

1-phenyl-2-(m-bromo)phenylacetylene

Conditions
ConditionsYield
With palladium on activated charcoal; choline chloride; triethylamine; glycerol at 60℃; for 3h; Sonogashira Cross-Coupling;99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 20℃; for 18h; Inert atmosphere;98%
With triethylamine In neat (no solvent) at 20℃; for 6h; Sonogashira Cross-Coupling;96%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

1,2-bis(3-bromophenyl)acetylene
153404-60-5

1,2-bis(3-bromophenyl)acetylene

Conditions
ConditionsYield
With copper(l) iodide; water; 1,8-diazabicyclo[5.4.0]undec-7-ene; bis-triphenylphosphine-palladium(II) chloride In benzene at 20℃; for 18h; Product distribution; Further Variations:; Catalysts; Reaction partners; Reagents; Solvents; temperature dependence; Sonogashira reaction;99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran; water at 20℃; for 16h; Sonogashira coupling;81%
Stage #1: 1-Bromo-3-iodobenzene; trimethylsilylacetylene With potassium carbonate In methanol; acetonitrile at 40℃; Sonogashira Cross-Coupling;
Stage #2: 1-Bromo-3-iodobenzene In methanol; acetonitrile at 40℃; Sonogashira Cross-Coupling; chemoselective reaction;
76%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; water; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 20℃; for 18h; Inert atmosphere; Schlenk technique; Darkness;
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

ethyl acrylate
140-88-5

ethyl acrylate

ethyl (2E)-3-(3-bromophenyl)prop-2-enoate
59114-88-4

ethyl (2E)-3-(3-bromophenyl)prop-2-enoate

Conditions
ConditionsYield
With sodium acetate; aluminum oxide; ruthenium In N,N-dimethyl-formamide at 115℃; for 12h; Heck-type olefination;99%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

tris-iso-propylsilyl acetylene
89343-06-6

tris-iso-propylsilyl acetylene

1-bromo-3-[(triisopropylsilyl)ethynyl]benzene

1-bromo-3-[(triisopropylsilyl)ethynyl]benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 40℃; for 17h;99%
With diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 24h; Sonogashira coupling;87%
With copper; palladium; triethylamine In tetrahydrofuran Sonogashira coupling;80%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

m-bromoiodobenzene dichloride
936252-06-1

m-bromoiodobenzene dichloride

Conditions
ConditionsYield
With hydrogenchloride; sodium hypochlorite at 15℃; for 0.666667h;99%
With hydrogenchloride; ammonium cerium (IV) nitrate In water; acetic acid at 20℃; for 1h;88%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromoaniline
591-19-5

3-bromoaniline

Conditions
ConditionsYield
With copper(l) iodide; ascorbic acid In ammonia at 25℃; for 18h; liquid NH3;99%
With copper(I) oxide; ammonium hydroxide; C17H14N2O3; potassium hydroxide In ethanol at 60℃; for 24h; Schlenk technique; Inert atmosphere;93%
With iron(III) oxide; sodium hydroxide; copper(l) iodide; ammonia In ethanol; water at 90℃; for 16h;89%
With acetamidine hydrochloride; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 20h; Inert atmosphere; Green chemistry;72%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

3'-bromo-2,4,6-trimethyl(diphenyliodonium) trifluoromethanesulfonate
1203709-76-5

3'-bromo-2,4,6-trimethyl(diphenyliodonium) trifluoromethanesulfonate

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 2h;99%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 2.08333h;55%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 2h;55%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

thiophenol
108-98-5

thiophenol

1,3-bis(phenylthio)benzene
2974-10-9

1,3-bis(phenylthio)benzene

Conditions
ConditionsYield
With 1,2,3,4-tetrahydroquinolin-8-ol; caesium carbonate; copper(I) bromide In N,N-dimethyl-formamide at 130℃; for 48h; Inert atmosphere; chemoselective reaction;99%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

2,2-dimethyl-N-(prop-2-ynyl)propionamide
178320-73-5

2,2-dimethyl-N-(prop-2-ynyl)propionamide

N-(3-(3-bromophenyl)prop-2-ynyl)pivalamide

N-(3-(3-bromophenyl)prop-2-ynyl)pivalamide

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine at 20℃; for 0.5h; Inert atmosphere;99%
N-acetylcystein
616-91-1

N-acetylcystein

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

(R)-2-acetamido-3-((3-bromophenyl)thio)propanoic acid
113276-93-0

(R)-2-acetamido-3-((3-bromophenyl)thio)propanoic acid

Conditions
ConditionsYield
Stage #1: N-acetylcystein; 1-Bromo-3-iodobenzene With C53H46NO4PPdS In tetrahydrofuran at 20℃; for 0.0166667h; Schlenk technique;
Stage #2: With triethylamine In tetrahydrofuran at 20℃; for 0.0833333h; Schlenk technique; Inert atmosphere; chemoselective reaction;
99%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-(benzofuran-2-yl)-1,1,1,3,5,5,5-heptamethyltrisiloxane
1583285-91-9

3-(benzofuran-2-yl)-1,1,1,3,5,5,5-heptamethyltrisiloxane

2-(3’-bromophenyl)benzofuran

2-(3’-bromophenyl)benzofuran

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; potassium hydroxide In para-xylene at 20 - 50℃; for 13h; Inert atmosphere; Schlenk technique; Glovebox;99%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

Dichlorophenylphosphine
644-97-3

Dichlorophenylphosphine

bis(3-bromophenyl)(phenyl)phosphine oxide

bis(3-bromophenyl)(phenyl)phosphine oxide

Conditions
ConditionsYield
Stage #1: 1-Bromo-3-iodobenzene With isopropylmagnesium chloride In tetrahydrofuran at -40 - -20℃; for 2h;
Stage #2: Dichlorophenylphosphine In tetrahydrofuran at 20℃; for 2h;
Stage #3: With dihydrogen peroxide at 20℃; for 0.5h;
99%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

Conditions
ConditionsYield
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;98%
With potassium carbonate In water; acetone at 60℃; for 24h; Suzuki coupling;98%
With sodium carbonate In water; N,N-dimethyl-formamide at 90℃; for 2h; Suzuki cross-coupling reaction;84%
With palladium; potassium carbonate In methanol; acetonitrile at 20℃; for 3.5h; Suzuki Coupling;81%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine In water; toluene at 100℃; for 24h;98%
With barium dihydroxide; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water for 6h; Suzuki coupling; Heating;92%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water for 8h; Inert atmosphere; Reflux;80%
4-dibenzofurylboronic acid
100124-06-9

4-dibenzofurylboronic acid

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

1-bromo-3-(4-dibenzofuranyl)benzene
887944-90-3

1-bromo-3-(4-dibenzofuranyl)benzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 4h; Reflux; Inert atmosphere;98%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 90℃; for 2 - 3h;87%
Stage #1: 4-dibenzofurylboronic acid; 1-Bromo-3-iodobenzene With potassium carbonate In ethanol; water; toluene at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene for 2h; Reflux; Inert atmosphere;
78.8%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

9H-carbazole
86-74-8

9H-carbazole

9-(3-bromophenyl)carbazole
185112-61-2

9-(3-bromophenyl)carbazole

Conditions
ConditionsYield
With copper; potassium carbonate In N,N-dimethyl-formamide at 130℃;98%
With potassium phosphate; copper(l) iodide; trans-1,2-cyclohexanediamine In toluene for 4h;96%
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 110℃;90%
iodobenzene
591-50-4

iodobenzene

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromobenzophenone
1016-77-9

3-bromobenzophenone

Conditions
ConditionsYield
Stage #1: iodobenzene With gallium; aluminium at 120℃; for 20h; Inert atmosphere;
Stage #2: 1-Bromo-3-iodobenzene In toluene at 20℃; for 3h;
98%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

diphenyl diselenide
1666-13-3

diphenyl diselenide

3-bromophenyl phenyl selenide
856074-00-5

3-bromophenyl phenyl selenide

Conditions
ConditionsYield
With copper(II) sulfide; iron; potassium carbonate In dimethyl sulfoxide at 110℃; for 3h; Inert atmosphere; chemoselective reaction;98%
With tetrabutylammomium bromide; potassium hydroxide In water at 100℃; for 9h; chemoselective reaction;88%
With magnesium In N,N-dimethyl-formamide at 110℃; for 30h; Inert atmosphere; Schlenk technique; Green chemistry;78%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

ethyl iodide
75-03-6

ethyl iodide

1-bromo-2-ethyl-3-iodobenzene
1344998-09-9

1-bromo-2-ethyl-3-iodobenzene

Conditions
ConditionsYield
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 3h; Inert atmosphere;98%
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - -50℃; for 4h; Inert atmosphere;
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - -50℃; for 4h; Inert atmosphere;
2-aminobutanol
96-20-8, 13054-87-0

2-aminobutanol

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

2-(3-bromophenylamino)-1-butanol
1184497-56-0

2-(3-bromophenylamino)-1-butanol

Conditions
ConditionsYield
With copper(l) chloride; potassium hydroxide at 20℃; for 8h; Neat (no solvent);98%
With copper(l) iodide; potassium hydroxide In water at 100℃; for 12h; Sealed tube;92%
trimethyl(prop-1-ynyl)silane
6224-91-5

trimethyl(prop-1-ynyl)silane

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

1-bromo-3-(prop-1-yn-1-yl)benzene
66952-36-1

1-bromo-3-(prop-1-yn-1-yl)benzene

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; triethylamine In tetrahydrofuran; toluene at 20℃; for 17h; Schlenk technique; Inert atmosphere;98%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrafluoroammonium fluoride; triethylamine In tetrahydrofuran; toluene at 20℃; for 17h; Inert atmosphere;86%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrafluoroammonium fluoride; triethylamine In tetrahydrofuran; toluene at 20℃; for 17h; Inert atmosphere;86%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrafluoroammonium fluoride; triethylamine In tetrahydrofuran; toluene at 20℃; for 17h; Inert atmosphere;86%
With triethylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride In tetrahydrofuran; toluene at 20℃; Inert atmosphere;80%

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