CAS No.108-67-8,Mesitylene Suppliers,MSDS download

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality mesitylene supplier in China

Cas:108-67-8

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Mesitylene

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

Mesitylene suppliers in China

Cas:108-67-8

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Colorless,transparent liquid Complies Content% ≥99.90

Top purity Mesitylene with high quality and best price cas:108-67-8

Cas:108-67-8

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FOB Price: $3.0 / 10.0

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Jinan Finer Chemical Co., Ltd

Product description: Product name Mesitylene CAS number 108-67-8 Assay ≥99% Appearance Colorless transparent liquid Capacity 1000mt/year Application Trimellitic acid, antioxi

Mesitylene

Cas:108-67-8

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Henan Allgreen Chemical Co.,Ltd

high quality Good price Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:China Main Port

Mesitylene

Cas:108-67-8

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply trimehylbenzene

Cas:108-67-8

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Chemwill Asia Co., Ltd.

Mesitylene -- CHemwill

Cas:108-67-8

Min.Order:1 Metric Ton

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1,3,5-trimethylbenzene

Cas:108-67-8

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on

Mesitylene

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Henan Sinotech Import&Export Corporation

Products Name: 1,3,5 - three toluene CAS : 108-67-8 Molecular formula: C9H12 Molecular weight: Appearance : Colorless transparent liquid Usage : It is used in the p

Mesitylene CAS: 108-67-8

Cas:108-67-8

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Mesitylene with CAS:108-67-8

Cas:108-67-8

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Mesitylene CAS#108-67-8 CAS NO.108-67-8

Cas:108-67-8

Min.Order:10 Gram

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Lonwin Chemical Group Limited

Mesitylene CAS：108-67-8 Specification ProName: 1,3,5-trimethylbenzene CasNo: 108-67-8 Molecular Formula: C9H12 Appearance: ask Application: intermediates DeliveryTime: Within 3 days after payment PackAge: foil aluminium bag/vacuum packing

Factory supply Mesitylene

Cas:108-67-8

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Triumph International Development Limilted

Appearance:Store in a cool,dry place and keep away from direct strong light Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manu

Mesitylene

Cas:108-67-8

Min.Order:100 Metric Ton

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,3,5-Trimethylbenzene

Cas:108-67-8

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1.3.5-TRIMETHYLBENZENE

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Mesitylene

Cas:108-67-8

Min.Order:4 Kilogram

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Mesitylene

Cas:108-67-8

Min.Order:10 Gram

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:colourless liquid with an aromatic odour Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Organic synthetic raw materia

Mesitylene-

Cas:108-67-8

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Mesitylene suppliers in China

Cas:108-67-8

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

Mesitylene CAS NO.: 108-67-8

Cas:108-67-8

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

1,3,5-Trimethylbenzene

Cas:108-67-8

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Mesitylene

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Mesitylene

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

Mesitylene

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Mesitylene

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JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Mesitylene(1,3,5-Timerhylbenzene)

Cas:108-67-8

Min.Order:100 Gram

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Wuhan Fortuna Chemical Co.,Ltd

good quality and cheap price Package:25kg/200kg Application:as intermediates Transportation:by courier/sea/air

Mesitylene

Cas:108-67-8

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Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

1,3,5-Trimethylbenzene

Cas:108-67-8

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Synthetic route

: 3112-82-1
(2,4,6-trimethylphenyl) phenyl sulfone

A: 618-41-7
Benzenesulfinic acid

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With lithium amalgam In N,N-dimethyl-formamide for 2h; Ambient temperature;	A 99% B 100%

: 85656-15-1
C31H38OSi

A: 4705-87-7
1,2,3,3-tetramethyl-1H-indene

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
electrlysis, at 1.5 V, electrolyte: tetrabutylammonium perchlorate, in CH2Cl2;	A 100% B 166 %
In dichloromethane electrolysis, at 1.5 V; electrolyte: tetrabutylammonium perchlorate;	A 100% B 166 %

: 110-91-8
morpholine

: 75732-01-3
mesitylcopper(I)

A: 77590-49-9
C4H8NO(1-)*Cu(1+)

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of amine;; evapd. or filtered; elem. anal.;;	A n/a B 100%

...Expand

: 75732-01-3
mesitylcopper(I)

: 7664-41-7
ammonia

A: 77590-45-5
amino-copper

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of NH3;; evapd. or filtered; elem. anal.;;	A n/a B 100%

...Expand

: 99506-43-1
2,4,6-trimethylphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

: 7647-14-5
sodium chloride

A: 17157-02-7
9-iodo-m-carborane

B: 17819-85-1
9-chloro-m-carborane

C: 4028-63-1
iodomesitylene

D: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaF, water and chloroform was vigorously stirred under reflux at 56°C, 2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;	A 0% B 100% C 100% D 0%

...Expand

: 82965-02-4
hexyl 2,4,6-trimethylbenzenesulfonate

A: 108-67-8
1,3,5-trimethyl-benzene

B: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With lithium amalgam In N,N-dimethyl-formamide; toluene Product distribution; Mechanism; further solvents;	A 85% B 99%

: 576-83-0
2,4,6-trimethylphenyl bromide

: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With potassium fluoride In tetrahydrofuran; water at 80℃; for 8h; Time; Schlenk technique; Sealed tube; Inert atmosphere;	99%
With [2-(di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride; isopropyl alcohol; sodium t-butanolate at 100℃; for 48h; Inert atmosphere; Sealed tube; Green chemistry;	89%
With isopropyl alcohol at 20℃; for 24h; UV-irradiation; chemoselective reaction;	88%

: 75732-01-3
mesitylcopper(I)

: 109-73-9
N-butylamine

A: 77590-46-6
copper(I) n-butylamide

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of amine;; evapd. or filtered; elem. anal.;;	A n/a B 98%

...Expand

: 3112-79-6
dimesityl sulfone

A: 59057-35-1
2,4,6-trimethylbenzenesulphinic acid

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With lithium amalgam In N,N-dimethyl-formamide for 2h; Ambient temperature;	A 92% B 97%

: 106-51-4
p-benzoquinone

: 2633-66-1
2-mesitylmagnesium bromide

A: 4-hydroxy-4-(2,4,6-trimethylphenyl)-2,5-cyclohexadiene

B: 123-31-9
hydroquinone

C: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran Grignard reaction;	A 97% B 3% C 4%

...Expand

: 75732-01-3
mesitylcopper(I)

: 111-92-2
dibutylamine

A: 77590-48-8
copper(I) N,N-di-n-butylamide

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., stirring overnight;; evapd. in vac., washed with hexane, dried in vac., crystd. from hexane at -15°C; elem. anal.;;	A n/a B 95%

...Expand

: 95-49-8
2-methylchlorobenzene

: 5980-97-2
mesitylboronic acid

A: 89970-02-5
2,2',4,6-tetramethylbiphenyl

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With potassium phosphate; tris(dibenzylideneacetone)dipalladium (0); tricyclohexylphosphine In toluene at 90℃; for 37h; Suzuki cross-coupling; Title compound not separated from byproducts.;	A 93% B 5%

...Expand

: ethylmesitylsilane

A: 108-67-8
1,3,5-trimethyl-benzene

B: ethyl iodosilane

Conditions

Conditions	Yield
With hydrogen iodide at -35℃; for 168000h; sealed tube;	A n/a B 92%

: 75732-01-3
mesitylcopper(I)

: 109-89-7
diethylamine

A: 71426-07-8
copper(I) N,N-diethylamide

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of amine;; evapd. or filtered; elem. anal.;;	A n/a B 92%

...Expand

: 480-63-7
mesitylenecarboxylic acid

: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With [Au(1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene)(O2CAd)] In toluene at 140℃; for 20h;	90%
With triethylsilane; palladium diacetate; 2,2-dimethylpropanoic anhydride; 1,4-di(diphenylphosphino)-butane In toluene at 160℃; for 15h; chemoselective reaction;	90%
With Nafion-H In toluene at 100℃; for 12h;	80%

: 110-89-4
piperidine

: 75732-01-3
mesitylcopper(I)

A: 73680-02-1
copper piperidide

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of amine;; evapd. or filtered; elem. anal.;;	A n/a B 90%

...Expand

: 82965-02-4
hexyl 2,4,6-trimethylbenzenesulfonate

A: 145385-15-5
lithium 2,4,6-trimethylbenzenesulfinate

B: 108-67-8
1,3,5-trimethyl-benzene

C: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With lithium amalgam In 1,4-dioxane; toluene Product distribution; Mechanism; further solvents;	A 21% B 61% C 88%

...Expand

: 75732-01-3
mesitylcopper(I)

: 62-53-3
aniline

A: 77590-50-2
copper(I) anilide

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of aniline;; evapd. or filtered; elem. anal.;;	A n/a B 88%

...Expand

: 75732-01-3
mesitylcopper(I)

: 75-64-9
tert-butylamine

A: 77590-47-7
copper(I) t-butylamide

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In tetrahydrofuran THF, ambient temp., excess of amine;; evapd. or filtered; elem. anal.;;	A n/a B 87%

...Expand

: 82965-02-4
hexyl 2,4,6-trimethylbenzenesulfonate

A: 59057-35-1
2,4,6-trimethylbenzenesulphinic acid

B: 108-67-8
1,3,5-trimethyl-benzene

C: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With lithium amalgam In 1,4-dioxane at 23℃; for 2h;	A 69% B 10% C 85%

...Expand

: C23H26BF6O(1-)*K(1+)

A: 1547-23-5
C5H3F5

B: 21223-06-3
1,1,1-trifluoro-2-trifluoromethyl-2-butene

C: 4,4,4-Trifluoro-3-trifluoromethyl-but-1-ene

D: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In solid at 200℃; under 0.07 Torr; for 0.0125h;	A 11% B 48% C 3% D 83%

...Expand

: 576-83-0
2,4,6-trimethylphenyl bromide

: 1631-73-8
trimethylstannane

A: 1527-99-7
n-butyltrimethyltin

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With n-butyllithium In hexane 2-bromomesitylene (1 equiv.) and TMTH (1 equiv.) in hexane cooled to 0°C under Ar, n-BuLi (1 equiv., 2.40 M in hexane) added, stirred for 5 h at reflux temp., quenched with water; analyzed by GC;	A 83% B 38%
With n-butyllithium In hexane 2-bromomesitylene (1 equiv.) and TMTH (1 equiv.) in hexane cooled to 0°C under Ar, n-BuLi (1 equiv., 2.40 M in hexane) added, stirred for 15 min, quenched with water; analyzed by GC;	A 33% B 11%

...Expand

: 576-83-0
2,4,6-trimethylphenyl bromide

A: 392-69-8
1-fluoro-2,4,6-trimethylbenzene

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
Stage #1: 2,4,6-trimethylphenyl bromide With n-butyllithium In tetrahydrofuran; hexane at 0℃; Flow reactor; Stage #2: With N-fluorobis(benzenesulfon)imide In tetrahydrofuran; hexane at 0℃; Reagent/catalyst; Flow reactor;	A 82% B 10%

: 2571-52-0
cyanomesitylene

: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triisopropyl phosphite; chlorotriisopropylsilane In ethyl-cyclohexane at 160℃; for 15h; Inert atmosphere;	81%
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triisopropyl phosphite; chlorotriisopropylsilane In ethylcyclohexane at 160℃; for 15h; Inert atmosphere;	81%

: 392-69-8
1-fluoro-2,4,6-trimethylbenzene

: 128190-66-9, 25088-58-8
potassium enolate of acetone

A: 42797-68-2
1-(2,4,6-trimethylphenyl)-2-propanone

B: 27645-30-3
1-(2,4,6-Trimethylphenyl)-2-propanol

C: 88-05-1
2,4,6-trimethylaniline

D: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With ammonia; potassium amide at -33℃; Product distribution; Rate constant;	A 2.8% B 5.6% C 11.7% D 80%
With ammonia; potassium amide at -33℃;	A 1.8 % Chromat. B 3.1 % Chromat. C 18.2 % Chromat. D 77 % Chromat.
With ammonia; potassium amide at -33℃;	A 2.8 % Chromat. B 5.6 % Chromat. C 11.7 % Chromat. D 80 % Chromat.

...Expand

: bis(mesityl)(η8-cyclo-octatetraene)zirconium(IV)*0.5Et2O

A: bis{zirconium(IV)(η8-cyclooctatetraene)(μ-2,4-dimethyl-6-CH2C6H2)}

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In diethyl ether complex is suspended in Et2O at room temp. for 2 d, thermal decomposition (N2); elem. anal.;	A 50% B 78%

: 99506-43-1
2,4,6-trimethylphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

: sodium fluoride

A: 17157-02-7
9-iodo-m-carborane

B: 73050-37-0
9-fluoro-m-carborane

C: 4028-63-1
iodomesitylene

D: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
In chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaF, water and chloroform was vigorously stirred under reflux at 56°C, 2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;	A 16% B 78% C 75% D 14%

...Expand

: 85014-36-4
1,3-dimethyl-5-methylenecyclohexane

: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With n-butyllithium; potassium 2-methylbutan-2-olate Mechanism; 1) r.t., 16 h, 2) reflux, 6 h; further reagent: D2O;	76%

: 1272-71-5
bis(mesitylene)vanadium(0)

A: 25377-37-1, 27790-75-6, 82009-22-1
Tetrakis(pyridin)-dichlorovanadin(II)

B: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With pyridine; 3-chloroprop-1-ene In toluene soln. of V-complex in toluene was treated with CH2=CHCH2Cl (inert atmosphere), the mixt. was stirred at room temp. for 24 h; the mother liquor contained org. compounds, products of the reaction of CH2=CHCH2Cl with either toluene or mesitylene (CLG-MS); filtered, ppt. was dissolved in pyridine, soln. was filtered and concd.to give the crystals of VCl2*4Py; identified by comparison of the IR spectrum with that of authentic sample;	A 75% B 75%

Yield

With pyridine; 3-chloroprop-1-ene In toluene soln. of V-complex in toluene was treated with CH2=CHCH2Cl (inert atmosphere), the mixt. was stirred at room temp. for 24 h; the mother liquor contained org. compounds, products of the reaction of CH2=CHCH2Cl with either toluene or mesitylene (CLG-MS); filtered, ppt. was dissolved in pyridine, soln. was filtered and concd.to give the crystals of VCl2*4Py; identified by comparison of the IR spectrum with that of authentic sample;

A 75%
B 75%

: 67-56-1
methanol

: 67-64-1
acetone

A: 700-12-9
pentamethylbenzene,

B: 87-85-4
Hexamethylbenzene

C: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With aluminum oxide at 420℃; flowrate: 33 ml/ h;	A n/a B 74% C n/a

...Expand

: 98-88-4
benzoyl chloride

: 108-67-8
1,3,5-trimethyl-benzene

: 954-16-5
2,4,6-Trimethylbenzophenon

Conditions

Conditions	Yield
With iron oxide supported on HY zeolite In neat (no solvent) at 110℃; for 3h; Friedel-Crafts Acylation;	100%
With iodine; phosphorus trichloride at 160℃; for 36h; Inert atmosphere;	99%
With C4F9SO3H at 165℃; for 2h;	98%

: 64-19-7
acetic acid

: 108-67-8
1,3,5-trimethyl-benzene

: 1667-01-2
2,4,6-Trimethylacetophenone

Conditions

Conditions	Yield
With heptafluorobutyric anhydride at 100℃; for 3h; Friedel-Crafts acetylation;	100%
With cross-linked polystyrene-supported aluminum triflate at 80℃; for 2.8h; Friedel-Crafts acylation; Neat (no solvent); chemoselective reaction;	94%
With trifluoromethylsulfonic anhydride at 20℃; for 0.0666667h; Friedel-Crafts acylation;	93%

: 75-36-5
acetyl chloride

: 108-67-8
1,3,5-trimethyl-benzene

: 1667-01-2
2,4,6-Trimethylacetophenone

Conditions

Conditions	Yield
With hierarchical nanocrystalline zeolite ZSM-5 at 50℃; for 2h; Temperature;	100%
With iron(III) oxide at 20℃; for 0.166667h; Friedel Crafts acylation; regioselective reaction;	96%
With benzyltributylammonium tetrachloroferrate at 50℃; for 0.0666667h; Friedel-Crafts reaction;	94%

: 108-67-8
1,3,5-trimethyl-benzene

: 1839-63-0
1,3,5-trimethylcyclohexane

Conditions

Conditions	Yield
With 5% Ru/MgO; hydrogen In tetrahydrofuran at 120℃; under 7600.51 Torr; for 8h;	100%
With Ti8O8(14+)6C8H4O4(2-)4O(2-)3.3Li(1+)0.7Co(2+)0.7C4H8O0.7H(1-); hydrogen In neat (no solvent) at 160℃; under 37503.8 Torr; for 18h;	84%
at 108℃; Thermodynamic data; Hydrogenation;

: 108-67-8
1,3,5-trimethyl-benzene

: 603-71-4
nitromesitylene

Conditions

Conditions	Yield
With dinitrogen tetraoxide In dichloromethane at -78℃; for 3h; Irradiation;	100%
With dinitrogen tetraoxide In dichloromethane at 25℃; for 24h;	100%
With nitric acid; sulfuric acid In dichloromethane at 25℃; for 0.03h;	100%

: 108-67-8
1,3,5-trimethyl-benzene

: 1667-04-5
2-bromomesitylene

Conditions

Conditions	Yield
With hydrogenchloride; sodium peroxide In acetic acid at 20 - 25℃; for 4h;	100%
With 1-Cl+SbCl6- In dichloromethane at 25℃; for 1h;	98%
With sodium chlorite; trichloroacetic acid In dichloromethane at 20℃; for 1h; Chlorination;	95%

: 50-00-0
formaldehyd

: 108-67-8
1,3,5-trimethyl-benzene

: 21988-87-4
1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene

Conditions

Conditions	Yield
With hydrogen bromide; acetic acid at 95℃; for 12h;	100%
With hydrogen bromide; acetic acid at 95℃; for 12h; Inert atmosphere;	99%
With sulfuric acid; potassium bromide In acetic acid at 90 - 95℃; for 6h;	97%

: 166112-18-1
4-aminofuroxan-3-carboxylic acid azide

: 108-67-8
1,3,5-trimethyl-benzene

: 433683-21-7
3-azidocarbonyl-4-(2,4,6-trimethylphenylazo)furoxan

Conditions

Conditions	Yield
Stage #1: 4-aminofuroxan-3-carboxylic acid azide With phosphoric acid; sulfuric acid; sodium nitrite at 0 - 2℃; for 1h; Stage #2: 1,3,5-trimethyl-benzene In pyridine at 0 - 20℃;	100%

: 124-38-9
carbon dioxide

: 108-67-8
1,3,5-trimethyl-benzene

: 480-63-7
mesitylenecarboxylic acid

Conditions

Conditions	Yield
With Et3SiB(C6F5)4 at 20℃; under 22502.3 Torr; for 18h; Reagent/catalyst;	100%
With aluminum tri-bromide; Triphenylsilyl chloride at 20℃; under 22502.3 Torr; for 3h; Autoclave;	97%
With aluminum (III) chloride at 30℃; under 15001.5 Torr; for 5h; Pressure; Temperature;	95.2%

: 108-67-8
1,3,5-trimethyl-benzene

: 766-97-2
4-n-methylphenylacetylene

: 612824-37-0
1-(4-methylphenyl)-1-(2,4,6-trimethylphenyl)ethene

Conditions

Conditions	Yield
With trifluoroacetic acid In dichloromethane at 30℃; for 24h; Cooling with ice;	100%
With Cu-exchanged tungstophosphoric acid at 80℃; for 3h; neat (no solvent); regioselective reaction;	91%
With trifluorormethanesulfonic acid; copper(II) bis(trifluoromethanesulfonate) at 20℃; for 20h;	84%

: 70316-95-9
tri-μ-chlorobis[(.eta-benzene)ruthenium(II)] tetrafluoroborate

: 108-67-8
1,3,5-trimethyl-benzene

: (η-benzene)(η-mesitylene)ruthenium tetrafluoroborate

Conditions

Conditions	Yield
In water; trifluoroacetic acid under dry conditions mixt. of Ru complex, mesitylene, and CF3COOH refluxed for 1.5 h, 48% aq. HBF4 added; pptd. by careful addn. of Et2O; elem. anal.;	100%

: 86197-44-6
bis(pentafluorophenyl)(η6-anisole)cobalt(II)

: 108-67-8
1,3,5-trimethyl-benzene

: bis(pentafluorophenyl)(η6-mesitylene)cobalt(II)

Conditions

Conditions	Yield
In chloroform-d1 byproducts: anisole; mol. ratio 1/1; not isolated, detected by NMR;	100%

: 623-73-4
diazoacetic acid ethyl ester

: 108-67-8
1,3,5-trimethyl-benzene

: ethyl 1,3,5-trimethylcyclohepta-1,3,5-triene-7-carboxylate

Conditions

Conditions	Yield
With Ag3(μ2-(3,5-(CF3)2PyrPy))3 In dichloromethane at 20℃; Buchner Ring Enlargement;	100%
With dirhodium tetraacetate In dichloromethane at 25℃; for 60h; Buchner Ring Enlargement; Inert atmosphere;	77%
Stage #1: 1,3,5-trimethyl-benzene With dirhodium tetraacetate In dichloromethane Inert atmosphere; Stage #2: diazoacetic acid ethyl ester In dichloromethane at 23℃; for 60h; Inert atmosphere;	77%

: (η6-toluene)Ni(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)

: 108-67-8
1,3,5-trimethyl-benzene

: [(η6-mesitylene)Ni(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)]

Conditions

Conditions	Yield
In pentane at 20℃; Inert atmosphere;	100%

: 1,3-dihydroxy-1H-1λ3-benzo[d][1,2]iodoxol-1-yl trifluoromethanesulfonate

: 108-67-8
1,3,5-trimethyl-benzene

: 2-(mesityl-λ3-iodanyl)benzoic acid triflate salt

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid In dichloromethane at 20℃; for 24h; Inert atmosphere;	100%
In 2,2,2-trifluoroethanol at 20℃; for 24h;	89%

: 2-(4,4,4-trifluoro-3-hydroxy-3-phenylbut-1-yn-1-yl)phenol

: 108-67-8
1,3,5-trimethyl-benzene

: 4-mesityl-2-phenyl-2-(trifluoromethyl)-2H-chromene

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 50℃; for 16h;	100%

: 108-24-7
acetic anhydride

: 108-67-8
1,3,5-trimethyl-benzene

: 1667-01-2
2,4,6-Trimethylacetophenone

Conditions

Conditions	Yield
With indium(III) triflate; lithium perchlorate In nitromethane at 20℃;	99%
With antimonypentachloride; lithium perchlorate In dichloromethane for 0.5h; Heating;	95%
With nano-sulfated titania at 50℃; for 1h; Friedel Crafts acylation; neat (no solvent);	95%

: 65-85-0
benzoic acid

: 108-67-8
1,3,5-trimethyl-benzene

: 954-16-5
2,4,6-Trimethylbenzophenon

Conditions

Conditions	Yield
With trifluoroacetic anhydride; bismuth(lll) trifluoromethanesulfonate at 30℃; for 12h; Friedel-Crafts acetylation;	99%
With pyridin-2-yl trifluoromethanesulfonate; trifluoroacetic acid for 5h; Heating;	96%
With cross-linked polystyrene-supported aluminum triflate at 80℃; for 2.9h; Friedel-Crafts acylation; Neat (no solvent); chemoselective reaction;	93%

: 108-67-8
1,3,5-trimethyl-benzene

: 4028-63-1
iodomesitylene

Conditions

Conditions	Yield
With tetrafluoroboric acid; [bis(pyridine)iodine]+ tetrafluoroborate In diethyl ether; dichloromethane for 0.1h; Ambient temperature;	99%
With Oxone; potassium iodide In methanol at 20℃; for 24h;	99%
With ammonium nitrate; sulfuric acid; iodine In water; acetonitrile at 60℃; for 0.166667h; regioselective reaction;	98%

: 108-67-8
1,3,5-trimethyl-benzene

: 53779-84-3
2,4-diiodomesitylene

Conditions

Conditions	Yield
With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride In acetic acid at 70℃; for 28h;	99%
With iodine; 1-(p-methylbenzenesulfonyloxy)-1,2-benziodoxol-3(1H)-one In acetonitrile for 18h; Ambient temperature;	99%
With iodine; 1-(p-methylbenzenesulfonyloxy)-1,2-benziodoxol-3(1H)-one In acetonitrile for 16h; Ambient temperature;	99%

: 108-67-8
1,3,5-trimethyl-benzene

: 576-83-0
2,4,6-trimethylphenyl bromide

Conditions

Conditions	Yield
With N-Bromosuccinimide; perchloric acid In tetrachloromethane for 22h; Ambient temperature;	99%
With hydrogen bromide; dihydrogen peroxide In water at 20℃; for 24h; Darkness;	98%
With gold(III) chloride; N-Bromosuccinimide In dichloromethane at 20℃; for 12h; Inert atmosphere;	98%

: 874-60-2
4-methyl-benzoyl chloride

: 108-67-8
1,3,5-trimethyl-benzene

: 1146-84-5
2,4,6,4'-tetramethylbenzophenone

Conditions

Conditions	Yield
With C4F9SO3H at 165℃; for 2h;	99%
With In(OSO2CF3)3 for 0.0666667h; Friedel-Crafts acylation reaction; microwave irradiation;	88%
With copper(II) ferrite In neat (no solvent) at 80℃; for 18h; Friedel-Crafts Acylation;	79%