As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:576-83-0
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inquiryGood supplier high quality 2-Bromomesitylene 576-83-0 manufacturer Product Details Overview Quick Details Pro Name;2-Bromomesitylene CAS NO:576-83-0 Purity:99% Application: API Appearance:normal MF: C9H11Br Place of Origin: J
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryProduct Description Product website: http://www.finerchem.com Product Name 2,4,6-Trimethylbromobenzene CAS No.
Cas:576-83-0
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inquiryThe company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White or off-white Solid Storage:Sealed, dry, m
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Cas:576-83-0
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inquiryHebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:576-83-0
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inquiryName:2,4,6-Trimethybromombenzene CAS NO:576-83-0 Grade:Medical scientific research and export Molecular formula:C9H11Br Molecular weight:199.09 Product Quality 12 years of chemical raw materials Mature operation of the industry System stab
Cas:576-83-0
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Type:Other
inquiry2,4,6-Trimethybromombenzene Basic information Product Name: 2,4,6-Trimethybromombenzene Synonyms: 2-bromo-1,3,5-trimethyl-benzen;Mesitylene, 2-b
Cas:576-83-0
Min.Order:1 Kilogram
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:576-83-0
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:576-83-0
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:576-83-0
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inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
Cas:576-83-0
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Cas:576-83-0
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryProduct Name: 2,4,6-Trimethybromombenzene Synonyms: 2,4,6-trimethybromombenzene;2,4,6-Trimethylphenyl bromide;2,4,6-TRIMETHYLBROMOBENZENE;2-BROMO-1,3,5-TRIMETHYLBENZENE;2-BROMOMESITYLENE;2-Bromomesifylene;1-bromo-2,4,6-trimethylbenzene;1-Bromom
Cas:576-83-0
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:576-83-0
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:576-83-0
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:576-83-0
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:576-83-0
Min.Order:4 Kilogram
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:576-83-0
Min.Order:100 Gram
FOB Price: $100.0 / 2000.0
Type:Lab/Research institutions
inquiryProduct name: 2-Bromomesitylene CAS No.:576-83-0 Molecule Formula:C9H11Br Molecule Weight:199.09 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS SP
Cas:576-83-0
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:576-83-0
Min.Order:1 Kilogram
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inquiryGMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:576-83-0
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Cas:576-83-0
Min.Order:1 Gram
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inquiryTriumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Material Sourcing): (
Cas:576-83-0
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inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:576-83-0
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inquiryWhy is SINOWAY: 1) Specialized in pharmaceutical and healthcare industrial for 34 years. 2) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days. 4) We have warehouse in USA with quickly shipment . 5) We c
Cas:576-83-0
Min.Order:25 Kilogram
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Type:Trading Company
inquiryLocated in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h
Conditions | Yield |
---|---|
With N-Bromosuccinimide; perchloric acid In tetrachloromethane for 22h; Ambient temperature; | 99% |
With hydrogen bromide; dihydrogen peroxide In water at 20℃; for 24h; Darkness; | 98% |
With gold(III) chloride; N-Bromosuccinimide In dichloromethane at 20℃; for 12h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With potassium phosphate; tetrabuthylammonium tribromide In acetonitrile at 100℃; for 16h; | 94% |
Conditions | Yield |
---|---|
With N-Bromosuccinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 6h; | 88% |
With tert.-butylnitrite; copper(ll) bromide In acetonitrile |
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h; | 80% |
1,3,5-trimethyl-benzene
A
2,4,6-trimethylphenyl bromide
B
2,4-dibromomesitylene
Conditions | Yield |
---|---|
With bromine In tetrachloromethane Product distribution / selectivity; | A 73% B n/a |
With bromine; silica gel In tetrachloromethane at 20℃; | A 13% B 70 % Chromat. |
With N-Bromosuccinimide; toluene-4-sulfonic acid In dichloromethane Product distribution; Ambient temperature; var. catalyst, var solvent, var. aromatic; |
1,3,5-trimethyl-benzene
A
2,4,6-trimethylphenyl bromide
B
2-bromomesitylene
Conditions | Yield |
---|---|
With chloroamine-T; iron(II) bromide In dichloromethane for 189.6h; Ambient temperature; | A 51% B 0.3% |
With bromine at 100℃; for 4h; Reflux; Ionic liquid; |
1,3,5-trimethyl-benzene
A
1-bromomethyl-3,5-dimethylbenzene
B
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
With sodium bromate; sodium hydrogensulfite In cyclohexane; water at 50℃; for 4h; Bromination; | A 50% B 11% |
With bromine at 120℃; for 6h; UV-irradiation; Title compound not separated from byproducts; | |
With N-Bromosuccinimide at 150℃; under 2625.26 Torr; for 0.0666667h; microwave irradiation; | A 42 % Chromat. B 6 % Chromat. |
isopropyl mesityl sulfone
A
2,4,6-trimethylphenyl bromide
B
2,4,6-trimethylbenzenesulfonyl bromide
Conditions | Yield |
---|---|
Stage #1: isopropyl mesityl sulfone With n-butyllithium In tetrahydrofuran; hexane at -63℃; for 1h; Stage #2: With bromine In tetrahydrofuran; hexane at -55℃; for 1.5h; Further stages.; | A 6% B 5% C 48% D 37% |
Conditions | Yield |
---|---|
With sodium bromide; sodium chloride In water; glycerol at 21 - 23.5℃; Product distribution; Kinetics; investigations of thermal dediazoniation in various solvents as a function of viscosity; the reaction are diffusion controlled; | A 14.5% B 6% |
Conditions | Yield |
---|---|
With copper(ll) bromide |
Conditions | Yield |
---|---|
With bromine In dichloromethane at -30℃; for 0.166667h; |
bromine
nitric acid
1,3,5-trimethyl-benzene
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
je nach dem Mengenverhaeltnis der Verbindungen; |
aluminium bromide
1,3,5-trimethyl-benzene
A
2,4,6-trimethylphenyl bromide
A
bromobenzene
B
1-phenyl-2,4,6-trimethylbenzene
C
2,4,6-trimethylphenyl bromide
D
1,3,5-trimethyl-benzene
Conditions | Yield |
---|---|
With bromine In diethyl ether for 0.5h; Ambient temperature; Yield given; |
A
2-methylphenyl bromide
B
2,4,6-trimethylphenyl bromide
C
2,2',4,6-tetramethylbiphenyl
Conditions | Yield |
---|---|
With bromine In diethyl ether for 0.5h; Ambient temperature; Yield given; |
A
2,4,6-trimethylphenyl bromide
B
2,4-dibromotoluene
C
2,2',4,6-tetramethylbiphenyl
Conditions | Yield |
---|---|
With bromine In diethyl ether for 0.5h; Ambient temperature; Yield given. Further byproducts given; |
A
2-bromo-1-chlorobenzene
B
2,4,6-trimethylphenyl bromide
C
chlorobenzene
Conditions | Yield |
---|---|
With bromine In diethyl ether for 0.5h; Ambient temperature; Yield given; |
A
2,4,6-trimethylphenyl bromide
B
Di-tert-butyl-bromsilan
Conditions | Yield |
---|---|
With bromine In pentane at -5 - 20℃; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With trimethylsilyl bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 55℃; for 2h; | A 87 % Chromat. B 13 % Chromat. |
With trimethylsilyl bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; copper(I) bromide at 70℃; Schiemann reaction; | A 4 % Chromat. B 96 % Chromat. |
2,4,6-trimethyl 1-deuterio benzene
A
2,4,6-trimethylphenyl bromide
B
C9H10(2)HBr
Conditions | Yield |
---|---|
With gold(III) chloride; N-Bromosuccinimide In 1,2-dichloro-ethane at 20℃; for 6h; Kinetics; |
1,3,5-trimethyl-benzene
A
2,4,6-trimethylphenyl bromide
B
2,4,6-tribromomesitylene
C
2,4-dibromomesitylene
Conditions | Yield |
---|---|
With Oxone; quartz; sodium bromide In n-heptane for 0.333333h; Milling; |
2-mesitylmagnesium bromide
A
2,4,6-trimethylphenyl bromide
B
1,3,5-trimethyl-benzene
Conditions | Yield |
---|---|
With C44H45Br3N4Ni In benzene-d6 Inert atmosphere; | A 50 %Spectr. B 33 %Spectr. |
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 16 h / 30 °C / Sealed tube 2: sodium bromide / [(2)H6]acetone; water / 0.17 h / 20 °C View Scheme |
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: dichloromethane; toluene / 1 h / 0 °C 2: 16 h / 30 °C / Sealed tube 3: sodium bromide / [(2)H6]acetone; water / 0.17 h / 20 °C View Scheme |
A
Z-1-bromo-2-chloroethylene
B
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
With sodium bromide In [(2)H6]acetone; water at 20℃; for 0.166667h; stereoselective reaction; | A n/a B n/a |
2,4,6-trimethylphenyl bromide
1,5-diamino-3-azapentane
(2,4,6-Me3C6H2NHCH2CH2)2NH
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene Heating; | 100% |
2,4,6-trimethylphenyl bromide
thiophen-2-yl magnesium bromide
2-(2,4,6-trimethylphenyl)thiophene
Conditions | Yield |
---|---|
Stage #1: thiophen-2-yl magnesium bromide With dichloro(1,3-bis(2,6-bis(3-pentyl)phenyl)imidazolin-2-ylidene)(3-chloropyridyl)palladium(II); zinc(II) chloride In tetrahydrofuran at 23℃; for 0.333333h; Inert atmosphere; Stage #2: 2,4,6-trimethylphenyl bromide In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 23℃; for 24h; Negishi coupling; Inert atmosphere; | 100% |
2,4,6-trimethylphenyl bromide
4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)aniline
2′,4′,6′-trimethylbiphenyl-4-amine
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane for 17h; Suzuki-Miyaura Coupling; Inert atmosphere; Reflux; | 100% |
2,4,6-trimethylphenyl bromide
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In water; toluene at 95℃; for 20h; Suzuki-Miyaura Coupling; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With 2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | 99% |
With copper(l) iodide; sodium azide; N,N`-dimethylethylenediamine In dimethyl sulfoxide at 100℃; for 10h; Inert atmosphere; | 72% |
Stage #1: 2,4,6-trimethylphenyl bromide With magnesium In tetrahydrofuran Inert atmosphere; Stage #2: With 3-tert-butyl-3-phenyloxaziridine In tetrahydrofuran; toluene at -45℃; for 2h; Inert atmosphere; Stage #3: With ammonium chloride In tetrahydrofuran; water; toluene Reagent/catalyst; Inert atmosphere; | 31% |
2,4,6-trimethylphenyl bromide
phenylboronic acid
1-phenyl-2,4,6-trimethylbenzene
Conditions | Yield |
---|---|
With caesium carbonate; palladium diacetate; P(i-BuNCH2CH2)3N In toluene at 80℃; Suzuki cross-coupling reaction; | 99% |
With [(trineopentylphosphine)PdCl2]2; sodium carbonate In water; toluene at 23℃; for 17h; Catalytic behavior; Temperature; Reagent/catalyst; Solvent; Suzuki-Miyaura Coupling; Sealed tube; Inert atmosphere; | 99% |
With palladium diacetate; N,N'-dicyclohexylethylenediimine; caesium carbonate In 1,4-dioxane at 80℃; for 4h; Suzuki-Miyaura cross-coupling reaction; | 97% |
2,4,6-trimethylphenyl bromide
2-methoxy-phenylamine
N-(2-methoxyphenyl)-N-(2,4,6-trimethylphenyl)amine
Conditions | Yield |
---|---|
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃; | 99% |
With palladium diacetate; 9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene; sodium t-butanolate In toluene at 80℃; for 68h; | 97% |
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 120℃; for 24h; Glovebox; Inert atmosphere; | 79% |
With 5,5-dimethyl-1,9-(PPh2)2-xanthene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; |
2,4,6-trimethylphenyl bromide
2-Methylphenylboronic acid
2,2',4,6-tetramethylbiphenyl
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran; toluene at 60℃; for 16h; Inert atmosphere; | 99% |
With potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 18h; Reagent/catalyst; Concentration; Temperature; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; | 98% |
With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; palladium diacetate; potassium carbonate In water at 20℃; for 22h; Suzuki-Miyaura coupling; | 94% |
Benzophenone imine
2,4,6-trimethylphenyl bromide
N-(diphenyl methylene)-2,4,6-trimethylaniline
Conditions | Yield |
---|---|
With potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0); 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In 1,4-dioxane at 80℃; for 10h; | 99% |
Conditions | Yield |
---|---|
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry; | 99% |
With [Pd(N,N'-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)-imidazol-2-ylidene)(acetylacetonate)Cl]; lithium hexamethyldisilazane In 1,4-dioxane at 110℃; for 3h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; | 95% |
With (SIPr)Pd(cinnanmyl)Cl; potassium tert-butylate In 1,2-dimethoxyethane at 20℃; for 0.5h; Buchwald-Hartwig reaction; | 94% |
Conditions | Yield |
---|---|
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry; | 99% |
With (2-mesityl-1H-inden-3-yl)dicyclohexyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 1,2-dimethoxyethane at 120℃; for 24h; Buchwald-Hartwig amination; Inert atmosphere; | 98% |
With air; potassium 2-methylbutan-2-olate; [(1,3-(2,6-iPr2C6H3)2-1,3-dihydroimidazol-2-ylidene)PdCl2]2 In 1,2-dimethoxyethane for 4h; Heating; | 92% |
Conditions | Yield |
---|---|
With potassium fluoride In tetrahydrofuran; water at 80℃; for 8h; Time; Schlenk technique; Sealed tube; Inert atmosphere; | 99% |
With [2-(di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride; isopropyl alcohol; sodium t-butanolate at 100℃; for 48h; Inert atmosphere; Sealed tube; Green chemistry; | 89% |
With isopropyl alcohol at 20℃; for 24h; UV-irradiation; chemoselective reaction; | 88% |
2,4,6-trimethylphenyl bromide
2,6-dimethylaniline
N-(2,4,6-trimethylphenyl)-N-(2,6-dimethylphenyl)amine
Conditions | Yield |
---|---|
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃; | 99% |
With sodium t-butanolate; palladium diacetate In toluene at 80℃; for 4h; Buchwald-Hartwig amination; | 98% |
With tris-(dibenzylideneacetone)dipalladium(0); rac-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole; sodium t-butanolate In toluene at 110℃; for 20h; Inert atmosphere; | 98% |
2,4,6-trimethylphenyl bromide
1-Naphthylboronic acid
1-(2,4,6-trimethylphenyl)naphthalene
Conditions | Yield |
---|---|
With potassium phosphate; C29H37O2P; palladium diacetate In toluene at 110℃; for 3h; Reagent/catalyst; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 99% |
With C36H43Br2ClN2Pd; potassium tert-butylate In isopropyl alcohol at 20℃; for 2h; Reagent/catalyst; Suzuki Coupling; Inert atmosphere; Schlenk technique; Glovebox; | 97% |
With (IPr)Pd(cinnanmyl)Cl; potassium tert-butylate In isopropyl alcohol at 20℃; for 3.5h; Suzuki-Miyaura coupling; | 89% |
2,4,6-trimethylphenyl bromide
phenylacetylene
1-(phenylethynyl)-2,4,6-trimethylbenzene
Conditions | Yield |
---|---|
With pyrrolidine; triphenylphosphine; 1-butyl-3-methylimidazolium Tetrafluoroborate; bis(η3-allyl-μ-chloropalladium(II)) at 130℃; for 48h; Heck alkynylation; | 99% |
With caesium carbonate; Pd[1,3,5,7-Me4-2,4,8-trioxa-6-Ph-6-phosphaadamantane]2*dba In acetonitrile at 60℃; for 12h; Sonogashira reaction; | 93% |
With dichloro[1-(3,5-dimethylbenzyl)-3-(4-adamantylbenzyl)-5,6-dimethylbenzimidazole-2-ylidene]triphenylphosphine palladium(II); potassium tert-butylate In N,N-dimethyl-formamide at 100℃; for 3h; Reagent/catalyst; Sonogashira Cross-Coupling; Schlenk technique; | 90% |
Conditions | Yield |
---|---|
Stage #1: 2,4,6-trimethylphenyl bromide With magnesium In tetrahydrofuran Stage #2: 4-Methoxybenzophenone In tetrahydrofuran for 18h; Heating; | 99% |
2,4,6-trimethylphenyl bromide
trans-2-phenylvinylboronic acid
(E)-2,4,6-trimethylstilbene
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In tetrahydrofuran at 40℃; for 24h; Suzuki-Miyaura coupling; | 99% |
With potassium tert-butylate; ClPd[N,N(2,6-iPr2C6H3)2-imidazol-2-yl]cinnamyl In isopropyl alcohol at 20℃; for 1.5h; Suzuki-Miyaura cross-coupling reaction; | 92% |
tetramethyldivinyldisiloxane
2,4,6-trimethylphenyl bromide
2,4,6-trimethylstyrene
Conditions | Yield |
---|---|
With johnphos; bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 40℃; for 24h; | 99% |
2,4,6-trimethylphenyl bromide
2-chloro-5-methoxyaniline
2-chloro-5-methoxy-N-(2,4,6-trimethylphenyl)aniline
Conditions | Yield |
---|---|
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene for 18h; Inert atmosphere; Reflux; | 99% |
1,5-diaminopentane
2,4,6-trimethylphenyl bromide
N1,N5-dimesitylpentane-1,5-diamine
Conditions | Yield |
---|---|
With sodium t-butanolate; (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate In 1,2-dimethoxyethane at 100℃; for 6h; | 99% |
2,4,6-trimethylphenyl bromide
N,N-dimethyl-formamide
cyanomesitylene
Conditions | Yield |
---|---|
Stage #1: 2,4,6-trimethylphenyl bromide With n-butyllithium In tetrahydrofuran; hexane at -70 - 0℃; Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at 0℃; for 1h; Stage #3: With ammonia; iodine In tetrahydrofuran; hexane; water at 0 - 20℃; | 99% |
Stage #1: 2,4,6-trimethylphenyl bromide With n-butyllithium In tetrahydrofuran; hexane at -70 - 0℃; for 0.583333h; Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at 0℃; for 1h; Stage #3: With ammonia; iodine In tetrahydrofuran; hexane; water at 0 - 20℃; for 2h; | 99% |
Stage #1: 2,4,6-trimethylphenyl bromide; N,N-dimethyl-formamide With magnesium In tetrahydrofuran at 20℃; Stage #2: With ammonia; iodine In tetrahydrofuran; water at 20℃; | 79% |
2,4,6-trimethylphenyl bromide
(1-methyl-1H-pyrazol-4-yl)boronic acid
4-mesityl-1-methyl-1H-pyrazole
Conditions | Yield |
---|---|
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); rac-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole In water; butan-1-ol at 100℃; for 24h; Suzuki coupling; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With palladium diacetate; 2,2'-bis(diphenylphosphino)biphenyl; copper(l) chloride In N,N-dimethyl-formamide at 80℃; for 14h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); XPhos In tetrahydrofuran at 20 - 80℃; for 15.25h; Suzuki coupling; Inert atmosphere; | 99% |
n-octyne
2,4,6-trimethylphenyl bromide
(E)-1,3,5-trimethyl-3-(oct-1-en-1-yl)benzene
Conditions | Yield |
---|---|
Stage #1: n-octyne With bis(pentamethylcyclopentadienyl)zirconium(IV) dichloride; dichloroalane bis(tetrahydrofuran) solvate In tetrahydrofuran Reflux; Inert atmosphere; Stage #2: 2,4,6-trimethylphenyl bromide With 1,4-diaza-bicyclo[2.2.2]octane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; XPhos In tetrahydrofuran for 2h; Reflux; Inert atmosphere; | 99% |
2,4,6-trimethylphenyl bromide
2,4,6-triisopropylphenylboronic acid
Conditions | Yield |
---|---|
With BI-DIME; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; | 99% |
2,4,6-trimethylphenyl bromide
p-tolylboronic pinacol ester
2,4,4',6-tetramethyl-1,1'-biphenyl
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide In neat (no solvent) at 110℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
Stage #1: furan With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 0.5h; Inert atmosphere; Stage #2: indium(III) chloride In tetrahydrofuran at -78 - 25℃; for 0.5h; Stage #3: 2,4,6-trimethylphenyl bromide With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; dicylclohexylphosphino(2',4',6'-triisopropyl)biphenyl In tetrahydrofuran; methanol for 15h; Reflux; | 99% |
2,4,6-trimethylphenyl bromide
(2,6-dimethoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With [Pd(1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)(cinnamyl)Cl]; potassium 2-methylbutan-2-olate In 1,4-dioxane at 110℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; | 99% |
With potassium phosphate; C29H37O2P; palladium diacetate In toluene at 110℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 81% |
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