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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Tolylboronic acid Manufacturer/High quality/Best price/In stock

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Tolylboronic Acid supplier in China

Cas:16419-60-6

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

2-Tolylboronic acid CAS No.:16419-60-6 Name: 2-Tolylboronic acid Synonyms: 2-Methylphenylboronic acid Molecular Structure:

High purity 2-Tolylboronic acid CAS No.:16419-60-6

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

2-Methylphenylboronic acid

Cas:16419-60-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 16419-60-6 2-Tolylboronic acid Manufacturer

Cas:16419-60-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

o-Tolylboronic acid

Cas:16419-60-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

2-Tolylboronic acid Basic information Product Name: 2-Tolylboronic acid Synonyms: 2-METHYLPHENYLBORONIC ACID;2-METHYLBENZENEBORONIC ACID;2-TOLYLBORONIC ACID;AKOS BR

2-Tolylboronic acid 16419-60-6

Cas:16419-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

2-Tolylboronic Acid; CAS No. 16419-60-6

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 16419-60-6 with best quality

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 2-Methylphenylboronic acid Synonyms: o-Tolylboronic acid CAS:16419-60-6 MF: C7H9BO2S Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Syntheses Material Intermediates Transpor

2-Methylphenylboronic acid

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry pla

High quality 2-tolylboronic acid cas 16419-60-6

Cas:16419-60-6

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronicacid, B-(2-methylphenyl)- 16419-60-6

Cas:16419-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Agrochemical Intermediates, 2-Tolylboronic acid CAS:16419-60-6

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $30.8 / 36.2

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

2-Tolylboronic acid CAS:16419-60-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

2-Tolylboronic acid CAS:16419-60-6

Cas:16419-60-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boronicacid, B-(2-methylphenyl)-

Cas:16419-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/52.html Product Name 2-Tolylboronic acid CAS No. 16419-60-6

2-Tolylboronic acid

Cas:16419-60-6

Min.Order:1 Gram

FOB Price: $45.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Boronicacid, B-(2-methylphenyl)-

Cas:16419-60-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Methylphenylboronic Acid, O-Tolyboronic Acid

Cas:16419-60-6

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

2-methylphenylboronic acid

Cas:16419-60-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-methylphenylboronic acid

Cas:16419-60-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

o-tolylboronic acid

Cas:16419-60-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Methyl-1-phenylboronic acid

Cas:16419-60-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Methylbenzeneboronic acid

Cas:16419-60-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Tolylboronic Acid

Cas:16419-60-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 2-Tolylboronic Acid CAS No.: 16419-60-6 Molecule Formula:C7H9BO2S Molecule Weight:168.02 Purity: 98.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITE

Lower Price 2-Tolylboronic Acid on stock

Cas:16419-60-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Tolylboronic acid

Cas:16419-60-6

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Purity 2-Tolylboronic acid

Cas:16419-60-6

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

2-Tolylboronic acid Basic information Product Name: 2-Tolylboronic acid Synonyms: AKOS BRN-0017;2-METHYLPHENYLBORONIC ACID;2-METHYLBENZENEBORONIC ACID;2-TOLYLBORONIC ACID;TOLUENE-2-BORONIC ACID;O-TOLYLBORONIC ACID;O-METHYLPHENYLBORONIC ACID;o

2-Tolylboronic acid

Cas:16419-60-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-methylphenylboronic acid

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Tolylboronic acid

Cas:16419-60-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Synthetic route

2-methylphenylboronic acid pinacol ester
195062-59-0

2-methylphenylboronic acid pinacol ester

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-methylphenylboronic acid pinacol ester With potassium hydrogen difluoride In methanol at 20℃; for 0.25h;
Stage #2: With chloro-trimethyl-silane; water In acetonitrile for 1h;
100%
With hydrogenchloride; polystyrene boronic acid In acetonitrile at 20℃; for 18h;90%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

A

2,2'-dimethyl-1,1'-biphenyl
605-39-0

2,2'-dimethyl-1,1'-biphenyl

B

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With cesium fluoride; Pd(dba)2 In tolueneA n/a
B 97%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-methylphenyl bromide With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: With Trimethyl borate In tetrahydrofuran at -78 - 20℃;
92%
Stage #1: 2-methylphenyl bromide With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; diisopropopylaminoborane; triethylamine; triphenylphosphine In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
35%
With n-butyllithium; Triisopropyl borate
potassium o-tolyltrifluoroborate

potassium o-tolyltrifluoroborate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With iron(III) chloride; water In tetrahydrofuran at 20℃; for 0.5h;92%
With water; silica gel at 20℃; for 1h; Inert atmosphere;61%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

diisopropopylaminoborane
22092-92-8

diisopropopylaminoborane

water
7732-18-5

water

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: ortho-tolylmagnesium bromide; diisopropopylaminoborane In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: water With hydrogenchloride In tetrahydrofuran at 0℃; for 0.583333h; Inert atmosphere;
88%
Trimethyl borate
121-43-7

Trimethyl borate

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;88%
Trimethyl borate
121-43-7

Trimethyl borate

Triisopropyl borate
5419-55-6

Triisopropyl borate

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: Triisopropyl borate; 2-methylphenyl bromide With magnesium; ethylene dibromide In tetrahydrofuran at 40 - 60℃; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran for 6h; Inert atmosphere; Reflux;
85%
(2-tolyl)tributyltin
68971-87-9

(2-tolyl)tributyltin

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With borane; water In tetrahydrofuran for 1h; Heating;83%
2-methylphenyl N-methyliminodiacetic acid borate

2-methylphenyl N-methyliminodiacetic acid borate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-methylphenyl N-methyliminodiacetic acid borate With sodium hydroxide In tetrahydrofuran for 0.416667h;
Stage #2: In aq. phosphate buffer; diethyl ether pH=7;
82%
2-methylphenyl triflate
66107-34-4

2-methylphenyl triflate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-methylphenyl triflate With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; diisopropopylaminoborane; triethylamine; triphenylphosphine In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
78%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

Trimethyl borate
121-43-7

Trimethyl borate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With sulfuric acid In diethyl ether 2M o-tolyl-magnesium bromide added dropwise with stirring at -60°C for 2 h to trimethylborate in ethyl ether, temp. allowed to rise to 0°C, water added, pH adjusted to pH 3 with 2M sulfuric acid; filtered, extd. (ethyl ether), evapd., washed (petroleum ether), recrystd. (water);73%
In diethyl ether
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: ortho-methylphenyl iodide With diisopropopylaminoborane; triethylamine; triphenylphosphine; palladium dichloride In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
73%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: ortho-tolylmagnesium bromide With Trimethyl borate In tetrahydrofuran at -78 - 20℃;
Stage #2: With hydrogenchloride In water
63%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

o-toluidine
95-53-4

o-toluidine

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: o-toluidine With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h;
63%
Stage #1: o-toluidine With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With potassium carbonate In water at 20℃; for 0.333333h;
(2-methylphenyl)lithium
6699-93-0

(2-methylphenyl)lithium

diborane
19287-45-7

diborane

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With copper(I) bromide In not given Li educt added to CuBr slurry in ether at 0°C under N2, reacted for 10 min, B2H6 soln. added, stirred for 18 h at room temp.; hydrolyzed with H2O, then with aq. NaOH, extd. with ether, aq. phase acidified with aq. HCl, extd. with ether, exts. dried (MgSO4), ether removed, solid recrystd. (petroleum ether);60%
hydrogenchloride
7647-01-0

hydrogenchloride

Trimethyl borate
121-43-7

Trimethyl borate

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-methylphenyl bromide With iodine; magnesium In tetrahydrofuran at 50 - 60℃; for 2h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at -15 - 20℃; for 2h; Inert atmosphere;
Stage #3: hydrogenchloride In tetrahydrofuran; water at 0℃; pH=2 - 3;
50%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

2-methylphenyl diazonium tetrafluoroborate
2093-46-1

2-methylphenyl diazonium tetrafluoroborate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 0.25h;36%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

triisobutyl borate
13195-76-1

triisobutyl borate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With diethyl ether und anschliessenden Hydrolyse;
(2-methylphenyl)dichloroborane
4250-48-0

(2-methylphenyl)dichloroborane

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With water
(2-methylphenyl)dichloroborane
4250-48-0

(2-methylphenyl)dichloroborane

water
7732-18-5

water

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

tri-o-tolylboroxine
7294-50-0

tri-o-tolylboroxine

water
7732-18-5

water

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

bis(2-tolyl) mercury
616-99-9

bis(2-tolyl) mercury

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: BCl3 / 150 - 180 °C
2: water
View Scheme
Trimethyl borate
121-43-7

Trimethyl borate

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

tert.-butyl lithium
594-19-4

tert.-butyl lithium

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran; pentane
borane
13283-31-3

borane

tetra-o-tolyltin
5728-01-8

tetra-o-tolyltin

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With water In tetrahydrofuran; diethyl ether; ethanol to THF soln. of Sn compd. added BH3 (N2, room temp.),refluxed (4 h), added H2O,stirred (30 min),extd. (Et2O), dried (MgSO4),evapd. in vac.,heated with pentane,filtered ArB(OH)2; ArB(OH)2 recrystd. from H2O; identified by m. p., IR, NMR;
Triisopropyl borate
5419-55-6

Triisopropyl borate

2-bromo-3,4-dimethoxybenzylaldehyde
55171-60-3

2-bromo-3,4-dimethoxybenzylaldehyde

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran dissolved aromatic bromide in THF, added n-BuLi dropwise, mixt. stirredat -78°C for 15 min; added freshly distd. ((CH3)2CHO)3B, stirredat -78°C for 30 min, warmed to room temp., stirred for further 20 min; cooled to 0°C, acidified, extracted with CH2Cl2, dried, evapd. under vac.;>99
Triisopropyl borate
5419-55-6

Triisopropyl borate

2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran dissolved aromatic bromide in THF, added n-BuLi dropwise, mixt. stirredat -78°C for 15 min; added freshly distd. ((CH3)2CHO)3B, stirredat -78°C for 30 min, warmed to room temp., stirred for further 20 min; cooled to 0°C, acidified, extracted with CH2Cl2, dried, evapd. under vac.;>99
Trimethyl borate
121-43-7

Trimethyl borate

2-bromo-3,4-dimethoxybenzylaldehyde
55171-60-3

2-bromo-3,4-dimethoxybenzylaldehyde

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran dissolved aromatic bromide in THF, added n-BuLi dropwise, mixt. stirredat -78°C for 15 min; added freshly distd. (CH3O)3B, stirred at -78°C for 30 min, warmed to room temp., stirred for further 20 min; cooled to 0°C, acidified, extracted with CH2Cl2, dried, evapd. under vac.;>99
Trimethyl borate
121-43-7

Trimethyl borate

2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran dissolved aromatic bromide in THF, added n-BuLi dropwise, mixt. stirredat -78°C for 15 min; added freshly distd. (CH3O)3B, stirred at -78°C for 30 min, warmed to room temp., stirred for further 20 min; cooled to 0°C, acidified, extracted with CH2Cl2, dried, evapd. under vac.;>99
dimethoxy-o-tolyl-borane
110180-68-2

dimethoxy-o-tolyl-borane

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; water Inert atmosphere;2.07 g
With hydrogenchloride In water at 20℃; Inert atmosphere; Schlenk technique;
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

tri-o-tolylboroxine
7294-50-0

tri-o-tolylboroxine

Conditions
ConditionsYield
In benzene Heating;100%
With sulfuric acid
(dehydration);
2-bromo-pyridine
109-04-6

2-bromo-pyridine

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2-(2-methylphenyl)pyridine
10273-89-9

2-(2-methylphenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 18h; Inert atmosphere; Reflux;100%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; N,N-dimethyl-formamide at 120℃; for 12h; Suzuki Coupling; Inert atmosphere;96%
With potassium phosphate tribasic heptahydrate; palladium diacetate In ethylene glycol at 80℃; for 1h; Suzuki coupling;94%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4'-methoxy-2-methylbiphenyl
92495-54-0

4'-methoxy-2-methylbiphenyl

Conditions
ConditionsYield
With C31H26N6O4Pd; potassium carbonate In water at 100℃; for 3h; Suzuki-Miyaura coupling;100%
With C38H53Cl2N2O2PPd*CH2Cl2; tetrabutylammomium bromide; potassium hydroxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Schlenk technique;100%
With potassium phosphate; (PdCl2)(2-pyridyl)-6-isopropyl cis piperidine complex In water; N,N-dimethyl-formamide at 110℃; for 2h;99%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4-(2-methylphenyl)benzoic acid
5748-43-6

4-(2-methylphenyl)benzoic acid

Conditions
ConditionsYield
With disodium hydrogenphosphate; disodium bis(2-aminopyrimidine-4,6-diolate)palladium acetate In water at 50 - 120℃; for 0.166667h; Microwave irradiation;100%
With disodium hydrogenphosphate; Pd(OAc)2(2-amino-4,6-dihydroxypyrimidine disodium salt)2 In water at 120℃; for 0.166667h; Suzuki-Miyaura coupling; Microwave irradiation;99%
With 4C3H6N6*Pd(2+)*2C2H3O2(1-); sodium carbonate In water at 80℃; for 2h; Suzuki-Miyaura Coupling; Green chemistry;97%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With N-iodo-succinimide; [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) at 90℃; for 0.0833333h; Reagent/catalyst; Microwave irradiation;100%
With potassium fluoride; iodine In 1,4-dioxane at 80℃; for 1h;88%
With copper(I) oxide; ammonium hydroxide; oxygen; potassium iodide In water at 25℃; for 24h;81%
2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

1-(2′-methyl-[1,1′-biphenyl]-2-yl)ethanone
217468-51-4

1-(2′-methyl-[1,1′-biphenyl]-2-yl)ethanone

Conditions
ConditionsYield
With potassium phosphate; CyJohnPhos; polymer-incarcerated palladium In water; toluene for 2h; Suzuki-Miyaura coupling; Heating;100%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; ethanol Product distribution; Heating; Suzuki coupling of bromo-acylbenzenes resp. bromo-indole carbaldehydes with boronic acids;98%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; ethanol rt, 15 min; reflux, 48 h;98%
1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2-methyl-4'-tert-butylbiphenyl

2-methyl-4'-tert-butylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; palladium-incarcerated polystyrene-based copolymer; tris(o-methoxyphenyl)phosphine In water; toluene for 2h; Suzuki-Miyaura coupling; Heating;100%
With C25H29N3; potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 90℃; for 2h; Suzuki-Miyaura Coupling;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In toluene at 110℃; for 1.5h; Suzuki-Miyaura reaction;98%
3-Chloropyridine
626-60-8

3-Chloropyridine

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

3-(p-methylphenyl)pyridine
90395-49-6

3-(p-methylphenyl)pyridine

Conditions
ConditionsYield
With potassium phosphate monohydrate; R-Phos; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 0.333333h; Suzuki-Miyaura reaction; Inert atmosphere;100%
With NHC-Pd(II)-Im; potassium tert-butylate In water at 80℃; for 12h; Suzuki-Miyaura coupling;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In tetrahydrofuran; toluene at 100℃; for 10h; Suzuki-Miyaura reaction;97%
para-bromotoluene
106-38-7

para-bromotoluene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2,4'-dimethylbiphenyl
611-61-0

2,4'-dimethylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; water In toluene at 100℃; for 1h; Suzuki coupling reaction;100%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate In 1,4-dioxane; water at 50℃; for 5h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
With potassium carbonate In water at 80℃; for 3h; Suzuki coupling;99%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2,2'-dimethyl-1,1'-biphenyl
605-39-0

2,2'-dimethyl-1,1'-biphenyl

Conditions
ConditionsYield
With potassium phosphate monohydrate; R-Phos; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 20℃; for 1h; Suzuki coupling; Inert atmosphere;100%
With dichloro bis(acetonitrile) palladium(II); C10H11N3S; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 1h; Suzuki Coupling; Schlenk technique; Inert atmosphere;99%
With potassium fluoride; monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) In toluene at 20℃; for 14h; Suzuki coupling;98%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

para-chloroacetophenone
99-91-2

para-chloroacetophenone

4-acetyl-2'-methylbiphenyl
56917-39-6

4-acetyl-2'-methylbiphenyl

Conditions
ConditionsYield
With potassium fluoride; tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 6h; Suzuki cross-coupling;100%
With C38H53Cl2N2O2PPd*CH2Cl2; tetrabutylammomium bromide; potassium hydroxide In water at 80℃; for 6h; Suzuki-Miyaura Coupling; Schlenk technique;100%
With caesium carbonate; palladium diacetate In toluene for 21h; Suzuki coupling; Heating;99%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

4-acetyl-2'-methylbiphenyl
56917-39-6

4-acetyl-2'-methylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; water In toluene at 100℃; for 1h; Suzuki coupling reaction;100%
With potassium carbonate; N,N-diethylaminopropyl-Al2O3-Pd(OAc)2 In ethanol; water at 80℃; for 2h; Suzuki-Miyaura reaction; microwave irradiation;100%
With potassium carbonate In ethanol; water at 20℃; for 0.5h; Suzuki-Miyaura reaction; Inert atmosphere;100%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4-chloro-5-methoxy-2-methyl-2H-pyridazin-3-one
14628-57-0

4-chloro-5-methoxy-2-methyl-2H-pyridazin-3-one

5-methoxy-2-methyl-4-(2-methylphenyl)-3(2H)-pyridazinone
335349-37-6

5-methoxy-2-methyl-4-(2-methylphenyl)-3(2H)-pyridazinone

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 120℃; Suzuki cross-coupling;100%
bromobenzene
108-86-1

bromobenzene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2-methylbiphenyl
643-58-3

2-methylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; water In toluene at 100℃; for 1h; Suzuki coupling reaction;100%
With potassium phosphate tribasic trihydrate In ethanol; water at 50℃; for 1.25h; Suzuki coupling;99%
With cetyltrimethylammonim bromide; sodium hydroxide In water at 25℃; for 1h; Catalytic behavior; Suzuki Coupling; Microwave irradiation;99%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4-(N,N-diethylamino)benzenediazonium tetrafluoroborate
347-46-6

4-(N,N-diethylamino)benzenediazonium tetrafluoroborate

4-N,N-diethylamino-2'-methylbiphenyl

4-N,N-diethylamino-2'-methylbiphenyl

Conditions
ConditionsYield
[(1,3-dimesitylimidazol-2-ylidene)(naphthoquinone)Pd(0)]2 In methanol at 50℃; for 1h; Suzuki coupling;100%
4-bromopyridin
1120-87-2

4-bromopyridin

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4-(2-methylphenyl)pyridine
30456-66-7

4-(2-methylphenyl)pyridine

Conditions
ConditionsYield
With potassium phosphate; palladium-incarcerated polystyrene-based copolymer; tris(o-methoxyphenyl)phosphine In water; toluene for 2h; Suzuki-Miyaura coupling; Heating;100%
With potassium phosphate; tris(o-methoxyphenyl)phosphine; polymer-incarcerated palladium In water; toluene for 2h; Suzuki-Miyaura coupling; Heating;88%
With potassium phosphate tribasic trihydrate; trans-[(2-mesitylpy)2PdCl2] In methanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;64%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

4-methyloxycarbonyl-2'-methyl-1,1'-biphenyl
89900-99-2

4-methyloxycarbonyl-2'-methyl-1,1'-biphenyl

Conditions
ConditionsYield
With potassium phosphate; tris(o-methoxyphenyl)phosphine; polymer-incarcerated palladium In water; toluene for 2h; Suzuki-Miyaura coupling; Heating;100%
With potassium phosphate; C18H9F5NOP(2-)*Pd(2+)*C3H7NO In ethanol at 20℃; for 6h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;88%
1-bromo-2,4,6-tri-tert-butylbenzene
3975-77-7

1-bromo-2,4,6-tri-tert-butylbenzene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

1-methxyl-2-[2-methyl-2-(3,5-di-tert-buthylphenyl)propyl]benzene

1-methxyl-2-[2-methyl-2-(3,5-di-tert-buthylphenyl)propyl]benzene

Conditions
ConditionsYield
With potassium phosphate monohydrate; Ethyl 4-bromobenzoate; C52H49PRu; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 8h; Inert atmosphere;100%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 100℃; for 18h; Suzuki-Miyaura coupling;96%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

3-bromo-1-phenylsulfonyl indole
99655-68-2

3-bromo-1-phenylsulfonyl indole

3-(2-methylphenyl)-1-(phenylsulfonyl)-1H-indole
883141-48-8

3-(2-methylphenyl)-1-(phenylsulfonyl)-1H-indole

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; ethanol; water for 18h; Suzuki-Miyaura coupling; Heating;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; ethanol; water Suzuki-Miyaura reaction; Reflux;68%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Na{2-CH3-C6H4B(OH)3}

Na{2-CH3-C6H4B(OH)3}

Conditions
ConditionsYield
With sodium hydroxide In toluene100%
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2'-methylbiphenyl-2-carboxaldehyde
7111-68-4

2'-methylbiphenyl-2-carboxaldehyde

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate In tetrahydrofuran at 20℃; for 6h; Suzuki coupling; Inert atmosphere;100%
With potassium phosphate monohydrate; 1‐ethyl‐2‐(1‐ethylindol-2-yl)benzoimidazole; palladium diacetate In 1,4-dioxane at 60℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;90%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In N,N-dimethyl-formamide for 6h; Suzuki Coupling; Inert atmosphere; Reflux;82%
2-chloro-5-[5-(methoxymethyl)-1,3,4-oxadiazol-2-yl]pyridine
848952-90-9

2-chloro-5-[5-(methoxymethyl)-1,3,4-oxadiazol-2-yl]pyridine

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

5-[5-(methoxymethyl)-1,3,4-oxadiazol-2-yl]-2-(2-methylphenyl)pyridine

5-[5-(methoxymethyl)-1,3,4-oxadiazol-2-yl]-2-(2-methylphenyl)pyridine

Conditions
ConditionsYield
With caesium carbonate; [2-[(dimethylamino-kN)methyl]phenyl-kC](tricyclohexylphosphine)(trifluoroacetato-kO)-palladium In 1,4-dioxane at 20℃; for 21h; Heating / reflux;100%
4-bromo-3-trifluoromethylbenzoic acid methyl ester
107317-58-8

4-bromo-3-trifluoromethylbenzoic acid methyl ester

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

methyl 2'-methyl-2-(trifluoromethyl)biphenyl-4-carboxylate
1140462-05-0

methyl 2'-methyl-2-(trifluoromethyl)biphenyl-4-carboxylate

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 3h; Suzuki-Miyaura coupling; Reflux; Inert atmosphere;100%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 3h; Heating / reflux;80%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 3h; Inert atmosphere; Reflux;
methyl 3-(acetyloxy)methyl-4-bromobenzoate
254746-41-3

methyl 3-(acetyloxy)methyl-4-bromobenzoate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

methyl 2-[(acetyloxy)methyl]-2'-methylbiphenyl-4-carboxylate
1140462-17-4

methyl 2-[(acetyloxy)methyl]-2'-methylbiphenyl-4-carboxylate

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 2h; Heating / reflux;100%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 2h; Suzuki-Miyaura coupling; Reflux;
methyl 4-bromo-3-(methoxymethyl)benzoate
1141473-84-8

methyl 4-bromo-3-(methoxymethyl)benzoate

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

methyl 2-(methoxymethyl)-2’-methylbiphenyl-4-carboxylate
1141473-85-9

methyl 2-(methoxymethyl)-2’-methylbiphenyl-4-carboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 110℃; for 1h; Inert atmosphere;100%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 1h; Heating / reflux;
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 1h; Suzuki-Miyaura coupling; Reflux; Inert atmosphere;
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene Inert atmosphere; Reflux;
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 1h; Suzuki-Miyura coupling; Inert atmosphere of N2; Reflux;
2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

ortho-cresol
95-48-7

ortho-cresol

Conditions
ConditionsYield
With 3,3'-dihexyloxy-1,1'-binaphthylidene-4,4'-dione; potassium hydroxide In tetrahydrofuran; water at 20℃;100%
With dihydrogen peroxide at 20℃; for 0.25h; Green chemistry;98%
With water; oxygen; sodium sulfite at 50℃; for 1h; Green chemistry;97%
6-bromo-N-cyclohexyl-N-methylpyridin-2-amine
1225280-81-8

6-bromo-N-cyclohexyl-N-methylpyridin-2-amine

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

N-cyclohexyl-N-methyl-6-o-tolylpyridin-2-amine
1309609-65-1

N-cyclohexyl-N-methyl-6-o-tolylpyridin-2-amine

Conditions
ConditionsYield
With potassium phosphate; dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium(II) In toluene at 80℃; for 0.25h; Suzuki coupling;100%
piperidine
110-89-4

piperidine

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

Glyoxilic acid
298-12-4

Glyoxilic acid

2-(piperidin-1-yl)-2-o-tolylacetic acid
1017212-36-0

2-(piperidin-1-yl)-2-o-tolylacetic acid

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
3-bromobenzo[b]thiophene-2-carbaldehyde
10135-00-9

3-bromobenzo[b]thiophene-2-carbaldehyde

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

3-o-tolylbenzo[b]thiophene-2-carbaldehyde
1393176-58-3

3-o-tolylbenzo[b]thiophene-2-carbaldehyde

Conditions
ConditionsYield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In water at 130℃; for 0.75h; Microwave irradiation; Inert atmosphere; Sealed tube;100%
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