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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hubei Vanz Pharm Co.,Ltd

1 high purity 2 able to provide COA/HNMR/HPLC 3 High quality 4 low price 5 Best service Appearance:white powder Storage:rm Package:bag/bottle/drum Application:pharmaceutical intermediate Transportation:common transportation Port:Shanghai, Wuh

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:whit

3-BroMobiphenyl

Cas:2113-57-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,1'-Biphenyl, 3-bromo-

Cas:2113-57-7

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 2113-57-7 3-Bromobiphenyl Manufacturer

Cas:2113-57-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--2113-57-7--3-Bromobiphenyl factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relati

TIANFUCHEM--2113-57-7--3-Bromobiphenyl factory price

Cas:2113-57-7

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

1,1'-Biphenyl, 3-bromo- / LIDE PHARMA- Factory supply / Best price

Cas:2113-57-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

CAS:2113-57-7 3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 2113-57-7 with best quality

Cas:2113-57-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name: 3-Bromobiphenyl CAS No.: 2113-57-7 Molecular formula C12H9Br Appearance: light yellow liquid Assay: 98.0% Structural formul

3-Bromobiphenyl CAS:2113-57-7

Cas:2113-57-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,1'-Biphenyl, 3-bromo- 2113-57-7

Cas:2113-57-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

About Product Details Items Specifications Test Results Appearance White to white crystalline powde

China Biggest Factory Manufacturer Supply 3-Bromobiphenyl CAS 2113-57-7

Cas:2113-57-7

Min.Order:100 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Industrial disinfectant, 3-Bromobiphenyl CAS:2113-57-7

Cas:2113-57-7

Min.Order:1 Kilogram

FOB Price: $168.0 / 181.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

3-Bromobiphenyl CAS: 2113-57-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedi

3-Bromobiphenyl CAS: 2113-57-7

Cas:2113-57-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

Name: 1,1'-Biphenyl, 3-bromo- Synonyms: PBB 2; A-2885; A815156; 113b577; AM83052; RP05622; SY015795; AN-50402; CJ-25736; ACT07931; SC-15043; BC003378; AC1Q253K; I01-2451; AC1L27Z0; AC-18410; W-107572; CJ-05682; AK-84655; AS-14527; AJ-27964; KB-30

3-Bromobiphenyl 2113-57-7

Cas:2113-57-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2113-57-7

Cas:2113-57-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

3-Bromobiphenyl CAS NO.2113-57-7

Cas:2113-57-7

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Colorless to pale yellow liquid Storage:R.T Package:25kg/Barrel Application:Organic synthesis intermediates, used as raw materials for pesticides and fungicides. Can be used as an industrial disinfectant. Transportation:Express/Sea/Air Po

Factory price ready stock 3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1-bromo-3-phenylbenzene

Cas:2113-57-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

advantage: 1. The best price, satisfactory quality; 2. customers have the right to choose the delivery of parcels (EMS, DHL, FedEx, UPS); 3. customers have the right to choose from the recent effective packaging methods of their products packaging

Best price/In stock 3-Bromobiphenyl 2113-57-7

Cas:2113-57-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Bromobiphenyl

Cas:2113-57-7

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-Bromobiphenyl

Cas:2113-57-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Synthetic route

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine In water; toluene at 100℃; for 24h;98%
With barium dihydroxide; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water for 6h; Suzuki coupling; Heating;92%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water for 8h; Inert atmosphere; Reflux;80%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With C27H23ClNO3PPd; potassium carbonate In ethanol; water at 50℃; for 7h; Temperature; Suzuki-Miyaura Coupling; Schlenk technique;94%
With palladium diacetate In ethanol at 20℃; for 0.25h; Suzuki-Miyaura Coupling; chemoselective reaction;86%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene at 90℃; for 3h;70%
(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
Stage #1: benzene With potassium permanganate; acetic acid Microwave irradiation;
Stage #2: (3-bromophenyl)boronic acid for 0.5h; Microwave irradiation;
91%
With potassium permanganate; acetic acid Heating;90%
With manganese triacetate for 0.5h; Heating;89%
With iron(III) trifluoromethanesulfonate; di-tert-butyl peroxide; 4,7-bis[4-(trifluoromethyl)phenyl]-1,10-phenanthroline at 80℃; for 24h;76%
With NH-pyrazole; potassium phosphate; iron(III) sulphate heptahydrate; 1,4,7,10-tetraazacyclododecan at 80℃; for 48h;55%
3-bromophenylhydrazine hydrochloride
27246-81-7

3-bromophenylhydrazine hydrochloride

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With potassium permanganate; acetic acid Heating;90%
With manganese triacetate Heating;73%
3-bromophenyl trifluoromethanesulfonate
66107-31-1

3-bromophenyl trifluoromethanesulfonate

phenylzinc(II) bromide
38111-44-3

phenylzinc(II) bromide

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
bis(diphenylphosphino)propanepalladium(II) dichloride In tetrahydrofuran at 60℃; for 11h; Negishi cross-coupling reaction;90%
3-bromobenzene-1-diazonium tetrafluoroborate

3-bromobenzene-1-diazonium tetrafluoroborate

8-phenylhexahydro-1,3,2-oxazaborolo[2,3-b]-1,3,2-oxazaborol-4-ium-8-uide

8-phenylhexahydro-1,3,2-oxazaborolo[2,3-b]-1,3,2-oxazaborol-4-ium-8-uide

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With 1% Pd/C In methanol at 50℃; for 0.5h; Suzuki-Miyaura reaction; Inert atmosphere;90%
bis-(3-bromo-benzoyl)-peroxide
1829-88-5

bis-(3-bromo-benzoyl)-peroxide

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
at 100℃; for 12h; Sealed tube;89%
With meta-dinitrobenzene
bromobenzene
108-86-1

bromobenzene

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
Stage #1: bromobenzene; 1-Bromo-3-iodobenzene With magnesium In tetrahydrofuran for 1h; Inert atmosphere; Reflux; Green chemistry;
Stage #2: In tetrahydrofuran at 50 - 85℃; for 8h; Green chemistry;
84.69%
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With diethyl bromomethylmalonate; [4,4′-di-tert-butyl-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C}iridium(III) hexafluorophosphate; caesium carbonate at 80℃; for 22h; Irradiation;82%
With dipotassium peroxodisulfate; silver nitrate In acetonitrile at 120℃; for 24h; Glovebox; Schlenk technique; Sealed tube; Inert atmosphere;55%
3-bromobenzylamine
10269-01-9

3-bromobenzylamine

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver nitrate In acetonitrile at 120℃; for 10h; Inert atmosphere; Sealed tube; Green chemistry;82%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

chlorobenzene
108-90-7

chlorobenzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
Stage #1: 1-Bromo-3-iodobenzene; chlorobenzene With magnesium In tetrahydrofuran for 1h; Inert atmosphere; Reflux; Green chemistry;
Stage #2: In tetrahydrofuran; water; toluene at 50 - 85℃; for 8h; Inert atmosphere; Reflux; Green chemistry;
81.37%
iodobenzene
591-50-4

iodobenzene

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
Stage #1: iodobenzene; 1-Bromo-3-iodobenzene With magnesium In tetrahydrofuran for 1h; Inert atmosphere; Reflux; Green chemistry;
Stage #2: In tetrahydrofuran at 50 - 85℃; for 8h; Green chemistry;
80.61%
meta-bromotoluene
591-17-3

meta-bromotoluene

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver nitrate In acetonitrile at 120℃; for 20h; Sealed tube; Schlenk technique; Inert atmosphere;80%
2-Phenyl-1,3,2-dioxaborinane
4406-77-3

2-Phenyl-1,3,2-dioxaborinane

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With potassium phosphate In 1,4-dioxane at 115℃; for 30h; Suzuki-Miyaura Coupling; Inert atmosphere;77%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C19H16NS(1+)*F6P(1-)

C19H16NS(1+)*F6P(1-)

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: C19H16NS(1+)*F6P(1-) In tetrahydrofuran; hexane at -78 - 23℃; for 1.5h; Inert atmosphere;
71%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
70%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

A

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

B

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With disodium[(N,N’-bis(2-hydroxy-5-sulfonatobenzyl)-1,2-diphenyl-1,2-diaminoethano)palladate(II)]; caesium carbonate In water at 80℃; for 1h; Suzuki-Miyaura Coupling;A 68%
B 24%
With potassium phosphate; {1,3-di(NHP(piperidinyl)2)C6H3}PdCl In toluene at 100℃; for 0.0833333h; Suzuki reaction;A 76 % Chromat.
B 24 % Chromat.
With potassium carbonate; [{P(NC4H8NMe)3}2PdCl2] In methanol at 20℃; for 2h; Suzuki-Miyaura coupling reaction;
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With 1,10-Phenanthroline; potassium 2-methylbutan-2-olate at 80℃; for 24h; Inert atmosphere;65%
3-bromophenyl trifluoromethanesulfonate
66107-31-1

3-bromophenyl trifluoromethanesulfonate

phenylmagnesium bromide

phenylmagnesium bromide

A

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

B

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With lithium bromide; bis(diphenylphosphino)propanepalladium(II) dichloride In diethyl ether at 0℃; for 2h; Kumada cross-coupling reaction;A 20%
B 60%
(3-Bromophenyl)methanol
15852-73-0

(3-Bromophenyl)methanol

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With tert.-butylhydroperoxide; 1,2-Dinitrobenzene In decane at 150℃; for 12h; Inert atmosphere; Sealed tube;59%
bromobenzene
108-86-1

bromobenzene

phenol
108-95-2

phenol

A

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

B

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

C

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With tert.-butylhydroperoxide; iodine at 289.9℃; for 0.0272222h; Product distribution;A 22.7%
B 18.4%
C 58.9%
3-bromostyrene
2039-86-3

3-bromostyrene

benzene
71-43-2

benzene

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With tert.-butylhydroperoxide; 1,2-Dinitrobenzene In decane at 150℃; for 12h; Inert atmosphere; Sealed tube;56%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

benzene
71-43-2

benzene

A

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

B

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With 1-(2-hydroxyethyl)piperazine; potassium tert-butylate at 100℃; for 24h; Sealed tube; Inert atmosphere;A 50%
B 25%
3-bromobenzene-1-diazonium tetrafluoroborate

3-bromobenzene-1-diazonium tetrafluoroborate

tributylphenylstannane
960-16-7

tributylphenylstannane

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With (triphenylphosphine)gold(I) chloride In acetonitrile at 20℃; for 16h; Inert atmosphere;44%
1-(3-bromophenyl)cyclohexanol
19920-85-5

1-(3-bromophenyl)cyclohexanol

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With copper; Selectfluor In acetonitrile at 80℃; for 24h; chemoselective reaction;41%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

benzene
71-43-2

benzene

A

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

B

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
With potassium tert-butylate; vasicine at 20 - 110℃; for 72h; Schlenk technique; Inert atmosphere;A 24%
B 19%
bromobenzene
108-86-1

bromobenzene

N-sulphinylphenylhydrazine
17420-03-0

N-sulphinylphenylhydrazine

A

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

B

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

C

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

D

diphenyldisulfane
882-33-7

diphenyldisulfane

E

S, SO2

S, SO2

Conditions
ConditionsYield
at 135℃; for 72h; Further byproducts given;A 20.9%
B 6.9%
C 12.7%
D 1.1%
E n/a
at 135℃; for 72h; Further byproducts given;A 19.5%
B 8.1%
C 12.9%
D 1.1%
E n/a
bromobenzene
108-86-1

bromobenzene

N-sulphinylphenylhydrazine
17420-03-0

N-sulphinylphenylhydrazine

A

S-Phenyl benzenethiosulfonate
1212-08-4

S-Phenyl benzenethiosulfonate

B

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

C

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

D

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

E

S, SO2

S, SO2

Conditions
ConditionsYield
at 135℃; for 72h; Further byproducts given;A 0.2%
B 20.9%
C 6.9%
D 12.7%
E n/a
bromobenzene
108-86-1

bromobenzene

N-sulphinylphenylhydrazine
17420-03-0

N-sulphinylphenylhydrazine

A

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

B

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

C

diphenyl sulfide
139-66-2

diphenyl sulfide

D

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

E

S, SO2

S, SO2

Conditions
ConditionsYield
at 135℃; for 72h; Further byproducts given;A 20.9%
B 6.9%
C 0.8%
D 12.7%
E n/a
pyridine
110-86-1

pyridine

bromobenzene
108-86-1

bromobenzene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

A

2-phenylpyridine
1008-89-5

2-phenylpyridine

B

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

C

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

D

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

Conditions
ConditionsYield
at 70℃;
2-ethylhexyl 3-sulfanylpropanoate
50448-95-8

2-ethylhexyl 3-sulfanylpropanoate

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

2-ethylhexyl 3-([1,1'-biphenyl]-3-ylthio)propanoate

2-ethylhexyl 3-([1,1'-biphenyl]-3-ylthio)propanoate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 110℃; for 18h; Inert atmosphere;100%
(3-bromophenyl)(pyridin-2-yl)methanone
206357-82-6

(3-bromophenyl)(pyridin-2-yl)methanone

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

[1,1‘-biphenyl]-2-yl(3-bromophenyl)(pyridin-2-yl)methanol

[1,1‘-biphenyl]-2-yl(3-bromophenyl)(pyridin-2-yl)methanol

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.666667h;
Stage #2: (3-bromophenyl)(pyridin-2-yl)methanone In tetrahydrofuran; hexane at -78 - 20℃; for 16h;
99%
3-Ethoxycyclohex-2-en-1-one
5323-87-5

3-Ethoxycyclohex-2-en-1-one

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

4''-ethoxy-5'',6''-dihydro-2''H-[1,1':3',1'':1'',1''':3''',1''''-quinquephenyl]-2''-one

4''-ethoxy-5'',6''-dihydro-2''H-[1,1':3',1'':1'',1''':3''',1''''-quinquephenyl]-2''-one

Conditions
ConditionsYield
With tris(1-adamantyl)phosphine; palladium diacetate; lithium hexamethyldisilazane In toluene at 70℃; for 0.55h; Inert atmosphere;99%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

1‐(3‐nitrophenyl)‐3‐phenylbenzene
78626-53-6

1‐(3‐nitrophenyl)‐3‐phenylbenzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In 1,2-dimethoxyethane; water for 16h; Suzuki Coupling; Inert atmosphere; Reflux;98%
2,5-dichloro-2,5-dimethyl hexane
6223-78-5

2,5-dichloro-2,5-dimethyl hexane

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

6-(3-bromophenyl)-1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalene
288259-76-7

6-(3-bromophenyl)-1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalene

Conditions
ConditionsYield
With aluminium trichloride In 1,2-dichloro-ethane at 0℃; Condensation;97%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

3-methoxy-[1,1';3',1'']terphenyl
156941-81-0

3-methoxy-[1,1';3',1'']terphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene for 3h; Suzuki coupling; Heating;97%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

phenylmethanethiol
100-53-8

phenylmethanethiol

[1,1'-biphenyl]-3-yl(benzyl)sulfane
94306-39-5

[1,1'-biphenyl]-3-yl(benzyl)sulfane

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; Inert atmosphere; Sealed tube;97%
With tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; Inert atmosphere; Sealed tube;97%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

9-(4-biphenylyl)-3,3'-bicarbazole
1346669-48-4

9-(4-biphenylyl)-3,3'-bicarbazole

9-([1,1'-biphenyl]-3-yl)-9’-([1,1'-biphenyl]-4-yl)-9H,9'H-3,3'-bicarbazole

9-([1,1'-biphenyl]-3-yl)-9’-([1,1'-biphenyl]-4-yl)-9H,9'H-3,3'-bicarbazole

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl; 9-(4-biphenylyl)-3,3'-bicarbazole With potassium tert-butylate In toluene for 0.5h; Inert atmosphere;
Stage #2: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; XPhos In toluene for 10h; Reflux;
97%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

aniline
62-53-3

aniline

N-phenyl-[1,1′-biphenyl]-3-amine
198275-79-5

N-phenyl-[1,1′-biphenyl]-3-amine

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 2h; Inert atmosphere; Reflux;95%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; for 24h;85%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

benzamide
55-21-0

benzamide

N-biphenyl-3-yl-benzamide

N-biphenyl-3-yl-benzamide

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; N,N`-dimethylethylenediamine In toluene for 120h; Reflux;95%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

3-(2,2,2-trifluoroethoxy)-1,1'-biphenyl

3-(2,2,2-trifluoroethoxy)-1,1'-biphenyl

Conditions
ConditionsYield
With C43H59NO2PPd(1+)*CH3O3S(1-); caesium carbonate In toluene at 80℃; Schlenk technique; Inert atmosphere;95%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

2-(4-aminophenyl)-10H-chromeno[3,2-b]pyridin-10-one

2-(4-aminophenyl)-10H-chromeno[3,2-b]pyridin-10-one

2(4-([1,1'-biphenyl]-3-ylamino)phenyl)-10H-chromeno[3,2-b]pyridin-10-one

2(4-([1,1'-biphenyl]-3-ylamino)phenyl)-10H-chromeno[3,2-b]pyridin-10-one

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 12h;95%
(R)-2,2'-(2,2'-bis(methoxymethoxy)-1,1'-binaphthyl-3,3'-diyl)bis(4,4',5,5'-tetramethyl-1,3,2-dioxaborolane)

(R)-2,2'-(2,2'-bis(methoxymethoxy)-1,1'-binaphthyl-3,3'-diyl)bis(4,4',5,5'-tetramethyl-1,3,2-dioxaborolane)

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

(R)-3,3'-di([1,1'-biphenyl]-3-yl)-[1,1'-binaphthalene]-2,2'-diol

(R)-3,3'-di([1,1'-biphenyl]-3-yl)-[1,1'-binaphthalene]-2,2'-diol

Conditions
ConditionsYield
Stage #1: (R)-2,2'-(2,2'-bis(methoxymethoxy)-1,1'-binaphthyl-3,3'-diyl)bis(4,4',5,5'-tetramethyl-1,3,2-dioxaborolane); 3-bromobiphenyl With tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 120℃; Alkaline conditions;
Stage #2: With hydrogenchloride In 1,4-dioxane; methanol; dichloromethane; water at 80℃;
95%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

phenylacetylene
536-74-3

phenylacetylene

1-(m-biphenylyl)-2-phenylethyne
263916-95-6

1-(m-biphenylyl)-2-phenylethyne

Conditions
ConditionsYield
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) at 80℃; for 5h; Hagihara coupling;94%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

2-(diisopropylsilyl)pyridine
1232692-92-0

2-(diisopropylsilyl)pyridine

C23H27NSi
1232692-97-5

C23H27NSi

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With n-butyllithium In tetrahydrofuran; hexanes at -78℃; Inert atmosphere;
Stage #2: 2-(diisopropylsilyl)pyridine In tetrahydrofuran; hexanes at -78 - -30℃; Inert atmosphere;
93%
Stage #1: 3-bromobiphenyl With n-butyllithium In tetrahydrofuran; hexanes at -78℃; Inert atmosphere;
Stage #2: 2-(diisopropylsilyl)pyridine In tetrahydrofuran; hexanes at -78 - 30℃; Inert atmosphere;
93%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

C12H6(2)H3Br

C12H6(2)H3Br

Conditions
ConditionsYield
With water-d2; potassium carbonate; silver carbonate; cyclohexyldiphenylphosphine In toluene at 120℃; for 12h;93%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

3-iodo-1,1'-biphenyl
20442-79-9

3-iodo-1,1'-biphenyl

Conditions
ConditionsYield
With copper(l) iodide; cis-N,N'-dimethyl-1,2-diaminocyclohexane; sodium iodide In 1,4-dioxane Reflux; Inert atmosphere;92%
With iodine; sodium iodide In acetonitrile at 20℃; for 36h; Inert atmosphere; UV-irradiation; Green chemistry;87%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

[1,1'-biphenyl]-3-yldicyclohexylphosphane
640735-28-0

[1,1'-biphenyl]-3-yldicyclohexylphosphane

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With n-butyllithium In diethyl ether; hexane at -20℃; for 2h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In diethyl ether; hexane at 20℃; for 6h; Cooling;
92%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

4-tert-butyl-dimethylsilyloxyphenylboronic acid anhydride
123088-32-4

4-tert-butyl-dimethylsilyloxyphenylboronic acid anhydride

[1,1’:3’,1’’-terphenyl]-4-ol
139265-73-9

[1,1’:3’,1’’-terphenyl]-4-ol

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 95℃; Suzuki reaction;91%
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With methanol; magnesium at 20℃;91%
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 5h;83%
With sodium formate In water; isopropyl alcohol at 50℃; for 0.00222222h; microflow reactor;99 %Chromat.
Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With iodine; magnesium In tetrahydrofuran at 20℃; for 2.5h; Inert atmosphere; Reflux;
Stage #2: With copper(I) bromide dimethylsulfide complex In tetrahydrofuran at -78℃; for 0.333333h; Inert atmosphere;
Stage #3: fullerene-C60 In tetrahydrofuran; 1,2-dichloro-benzene at -78 - 20℃; Inert atmosphere;
91%
3-(2-nitrophenyl)-1H-indole
56366-31-5

3-(2-nitrophenyl)-1H-indole

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

C26H18N2O2
1373266-33-1

C26H18N2O2

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; trans-1,2-cyclohexanediamine In 1,4-dioxane at 120℃; for 18h;90%
9,9-dimethyl-9H-fluoren-2-ylamine
108714-73-4

9,9-dimethyl-9H-fluoren-2-ylamine

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

N-((1,1'-biphenyl)-3-yl)-9,9-dimethyl-9H-fluorene-2-amine

N-((1,1'-biphenyl)-3-yl)-9,9-dimethyl-9H-fluorene-2-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; XPhos In toluene at 108℃; for 4h; Buchwald-Hartwig Coupling; Inert atmosphere;90%
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; XPhos In toluene at 108℃; for 4h; Inert atmosphere;74.94%

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