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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,3-Dibromobenzene with high purity

Cas:108-36-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

1,3-Dibromobenzene CAS No.:108-36-1 Name: 1,3-Dibromobenzene Molecular Structure Molecular Formula: C6H4Br2 Molecular Weight: 235.90 CAS Registry Number: 108-36-1 EINECS: 203-574-2

High purity 1,3-Dibromobenzene CAS No.:108-36-1

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1,3-dibromobenzene

Cas:108-36-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 108-36-1 1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specifica

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

m-Dibromobenzene

Cas:108-36-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1,3-Dibromobenzene-

Cas:108-36-1

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

108-36-1 1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 108-36-1 with high-quality service

Cas:108-36-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

cas 108-36-1 Name 1,3-Dibromobenzene Appearance Pale yellow liquid Application Used in organic synthesis Appearance: brown-yel

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear colorless to light yellow liquid Storage:room temperature Package:200kg/Drum Application:1,3-Dibromobenzene is used in Suzuki coupling reaction for the preparation of [n]metacyclophanes. It is used to prepare 5-(3-bromo-phenyl)-2,

1,3-Dibromobenzene factory price

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,3-Dibromobenzene 108-36-1

Cas:108-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Organic Synthesis, 1,3-Dibromobenzene CAS:108-36-1

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $32.4 / 36.8

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

1,3-Dibromobenzene CAS:108-36-1 Qingdao Belugas Import and Export Co., L td. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

1,3-Dibromobenzene CAS:108-36-1

Cas:108-36-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

Name: 1,3-Dibromobenzene Synonyms: D0169; K-0606; AM84332; AS03513; RP28199; A801864; CM12169; AJ-20653; STR07103; CJ-03273; SC-00296; W-108722; BC002638; BC675855; BP-21249; EBD26568; KB-64463; ACT03347; ZB011550; AN-42872; AK-88659; I01-0465; AC1L1

1,3-Dibromobenzene 108-36-1

Cas:108-36-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Company information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big cust

Factory Price 1, 3-Dibromobenzene CAS 108-36-1

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $7.0 / 10.0

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

1,3-dibromobenzene CAS: 108-36-1 Specification mp -7 °c bp 218-219 °c(lit.) density 1.952 g/ml at 25 °c(lit.) vapor density 8.16 (vs air) vapor pressure 5 mm hg ( 66 °c

Factory supply 1,3-dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:clear colourless to light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Interme

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1,3-Dibromobenzene

Cas:108-36-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,3-Dibromobenzene

Cas:108-36-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Synthetic route

2,6-dibromobenzenediazonium o-benzenedisulfonimide

2,6-dibromobenzenediazonium o-benzenedisulfonimide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With dihydrogen peroxide In tetrahydrofuran for 0.333333h; Heating;92%
Multi-step reaction with 2 steps
1: 95 percent / aq. NaOH / 0.5 h / 0 - 5 °C
2: 11 percent / aq. HI; HBF4 / acetonitrile / 24 h / 60 °C
View Scheme
Multi-step reaction with 2 steps
1: 95 percent / aq. NaOH / 0.5 h / 0 - 5 °C
2: 12 percent / aq. HCl; Cu / acetonitrile / 0.25 h / 20 - 25 °C
View Scheme
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With bromine; dibromoisocyanuric acid In dichloromethane at 20℃; for 24h; UV-irradiation;92%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

(3,5-dibromophenyl)trimethyltin
17197-37-4

(3,5-dibromophenyl)trimethyltin

A

(3,5-dibromophenyl)dimethylbutyltin

(3,5-dibromophenyl)dimethylbutyltin

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C

n-butyltrimethyltin
1527-99-7

n-butyltrimethyltin

D

(3-bromophenyl)trimethylstannane
17113-76-7

(3-bromophenyl)trimethylstannane

Conditions
ConditionsYield
In diethyl ether; hexane byproducts: C4H9Br; n-BuLi in hexane adding to an ether soln. of the stannane at -78°C, stirring for 30 min, hydrolyzing with 2 N HCl, org. layer sepg., drying over MgSO4; identified by gas chromy. and chromato-mass spectrometry;A 1%
B 82%
C n/a
D 13%
2,6-dibromoaniline
608-30-0

2,6-dibromoaniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
Stage #1: 2,6-dibromoaniline With sulfuric acid; sodium nitrite In water at 0 - 5℃; for 3h;
Stage #2: With hypophosphorous acid In water at 70 - 80℃; for 3h; Reagent/catalyst; Temperature;
81%
Diazotization.Behandlung der Diazoniumsalz-Loesungen mit H3PO2 bei 5grad;
With tetrahydrofuran; n-Amyl nitrite
3-bromobenzenediazonium o-benzenedisulfonimide

3-bromobenzenediazonium o-benzenedisulfonimide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;80%
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;78%
C10H13Br2N3
401631-86-5

C10H13Br2N3

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1,3-dibromo-2-iodo-benzene
19821-80-8

1,3-dibromo-2-iodo-benzene

Conditions
ConditionsYield
With tetrafluoroboric acid; hydrogen iodide In acetonitrile at 60℃; for 24h;A 11%
B 79%
C10H13Br2N3
401631-86-5

C10H13Br2N3

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1,3-dibromo-2-chlorobenzene
19230-27-4

1,3-dibromo-2-chlorobenzene

Conditions
ConditionsYield
With hydrogenchloride; copper In acetonitrile at 20 - 25℃; for 0.25h;A 12%
B 79%
3-bromophenyl trifluoromethanesulfonate
66107-31-1

3-bromophenyl trifluoromethanesulfonate

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; triisobutylaluminum; butanone; potassium bromide In toluene at 100℃; for 24h; Inert atmosphere;78%
(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 81℃; for 8h;65%
7-(Dibrommethylen)bicyclo<2.2.1>hepta-2,5-dien

7-(Dibrommethylen)bicyclo<2.2.1>hepta-2,5-dien

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

6,6-Dibromfulven
41605-39-4

6,6-Dibromfulven

C

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
at 450℃; under 0.0001 Torr; for 4h; Title compound not separated from byproducts;A n/a
B 60%
C n/a
isophthalic acid
121-91-5

isophthalic acid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With Bromotrichloromethane; bromine; dibromoisocyanuric acid at 120℃; for 60h; Time; UV-irradiation;17%
tetrachloromethane
56-23-5

tetrachloromethane

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

cyclohexene
110-83-8

cyclohexene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

ethyl nitrite
109-95-5

ethyl nitrite

2,4-dibromo-aniline
615-57-6

2,4-dibromo-aniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

ethanol
64-17-5

ethanol

3-bromo-benzenediazonium; tribromoide

3-bromo-benzenediazonium; tribromoide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With aluminium trichloride
With aluminium trichloride
3,5-dibromoaniline
626-40-4

3,5-dibromoaniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite
2,4-dibromo-aniline
615-57-6

2,4-dibromo-aniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With ethyl nitrite
Diazotization.Behandlung der Diazoniumsalz-Loesungen mit H3PO2 bei 5grad;
ueberfuehrung in das Diazoniumnitrat und erhitzen desselben mit Wasser;
2,6-dibromobenzaldehyde
67713-23-9

2,6-dibromobenzaldehyde

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With potassium hydroxide
Acetanilid
103-84-4

Acetanilid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-bromoaniline
591-19-5

3-bromoaniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

benzene
71-43-2

benzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

Conditions
ConditionsYield
With aluminium trichloride beim Bromieren;
bromobenzene
108-86-1

bromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With hypobromous acid In 1,4-dioxane; water at 25℃; Rate constant;A 1 % Chromat.
B 64.3 % Chromat.
C 35.7 % Chromat.
1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With bromobenzene; Cu-HZSM-5 zeolite at 399.9℃; Mechanism; Product distribution;A 11.6 % Chromat.
B 3.2 % Chromat.
1,2,3-tribromobenzene
608-21-9

1,2,3-tribromobenzene

benzene
71-43-2

benzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

2,6-dibromo-1,1'-biphenyl
59080-32-9

2,6-dibromo-1,1'-biphenyl

C

2,3-dibromo-biphenyl

2,3-dibromo-biphenyl

D

2'-bromo-1,1':3',1'-terphenyl

2'-bromo-1,1':3',1'-terphenyl

Conditions
ConditionsYield
at 25℃; for 24h; Irradiation;A 9.5 % Chromat.
B 14.0 % Chromat.
C 12.0 % Chromat.
D 3.3 % Chromat.
1,2,4-tribromobenzene
615-54-3

1,2,4-tribromobenzene

A

bromobenzene
108-86-1

bromobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

D

benzene
71-43-2

benzene

E

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With potassium hydroxide; hydrogen; palladium on activated charcoal In 2,2,4-trimethylpentane at 50℃; for 0.666667h; Product distribution; var. cat.: Raney-Ni, add. of Aliquat 336;A 18 % Chromat.
B 3 % Chromat.
C 1 % Chromat.
D 42 % Chromat.
E 30 % Chromat.
Ethyl hexanoate
123-66-0

Ethyl hexanoate

1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1-(3,5-Dibromo-phenyl)-hexan-1-one

1-(3,5-Dibromo-phenyl)-hexan-1-one

C

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

D

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
n-hexanoic anhydride
2051-49-2

n-hexanoic anhydride

1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1-(3,5-Dibromo-phenyl)-hexan-1-one

1-(3,5-Dibromo-phenyl)-hexan-1-one

C

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

D

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
With hydrocarbon substituted imidazolidine at 20℃;
With 1,3-bis(1,1-dimethylethyl)imidazolidin-2-ylidene In 1,4-dioxane at 120℃; for 4h;
With 1,2,3,4-tetrakis(carbazol-9-yl)-5,6-dicyanobenzene; triethylamine In 1-methyl-pyrrolidin-2-one at 20℃; for 1.33333h; Inert atmosphere; Irradiation;98 %Chromat.
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

ethyl acetate
141-78-6

ethyl acetate

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

3,5-dibromoacetophenone
14401-73-1

3,5-dibromoacetophenone

C

1,1-Bis-(3,5-dibromo-phenyl)-ethanol

1,1-Bis-(3,5-dibromo-phenyl)-ethanol

D

Acetic acid 1,1-bis-(3,5-dibromo-phenyl)-ethyl ester

Acetic acid 1,1-bis-(3,5-dibromo-phenyl)-ethyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Yield given. Multistep reaction;
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

Hexanoyl chloride
142-61-0

Hexanoyl chloride

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1-(3,5-Dibromo-phenyl)-hexan-1-one

1-(3,5-Dibromo-phenyl)-hexan-1-one

C

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

D

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
1H-imidazole
288-32-4

1H-imidazole

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1,3-bis(1H-imidazol-1-yl)benzene
69506-91-8

1,3-bis(1H-imidazol-1-yl)benzene

Conditions
ConditionsYield
With 1-sulfanyl-2-(dimethylaminomethyl)-3-Me3Si-benzene-Cu(I); potassium carbonate In 1-methyl-pyrrolidin-2-one at 160℃; for 16h;100%
With copper(l) iodide; potassium carbonate In dimethyl sulfoxide at 150℃; for 48h;99%
With copper(l) iodide; dimethylaminoacetic acid; potassium carbonate In dimethyl sulfoxide at 110℃; for 48h; Inert atmosphere;93%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-tetramethyl-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,2-dioxaborolane
196212-27-8

4,4,5,5-tetramethyl-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,2-dioxaborolane

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide at 90℃; for 48h; Inert atmosphere; Schlenk technique;100%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 80℃; for 16h; Inert atmosphere; Schlenk technique;96%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki-Miyaura Coupling;93%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

m-Anisidine
536-90-3

m-Anisidine

N,N'-bis(3-methoxyphenyl)-1,3-benzenediamine
202127-21-7

N,N'-bis(3-methoxyphenyl)-1,3-benzenediamine

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate; bis(diphenylphosphinyl)ferrocene In toluene at 100 - 110℃; for 12h;100%
With [(π-cinnamyl)Pd(tBuXPhos)]OTf In water at 45℃; for 36h;91%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-(t-butyl)-4-methoxyphenyl boronic acid
196960-96-0

3-(t-butyl)-4-methoxyphenyl boronic acid

1,3-bis(3-tert-butyl-4-methoxyphenyl)benzene
1202392-73-1

1,3-bis(3-tert-butyl-4-methoxyphenyl)benzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); barium hydroxide monohydrate In ISOPROPYLAMIDE; water at 80℃; for 48h; Suzuki-Miyaura double cross-coupling; Inert atmosphere;100%
(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

methyl iodide
74-88-4

methyl iodide

3-benzyl-8-(3-bromo-phenyl)-8-methoxy-3-aza-bicyclo[3.2.1]octane
778582-06-2

3-benzyl-8-(3-bromo-phenyl)-8-methoxy-3-aza-bicyclo[3.2.1]octane

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In hexanes; diethyl ether at -78℃; for 1h;
Stage #2: (1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one In hexanes; diethyl ether at -78℃; for 0.75h;
Stage #3: methyl iodide In tetrahydrofuran at 20℃; for 60h;
100%
(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-benzyl-8-(3-bromo-phenyl)-8-hydroxy-3-aza-bicyclo[3.2.1]octane
778581-93-4

3-benzyl-8-(3-bromo-phenyl)-8-hydroxy-3-aza-bicyclo[3.2.1]octane

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In hexanes; diethyl ether at -78℃; for 1.33333h;
Stage #2: (1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one In hexanes; diethyl ether at -78 - 20℃;
Stage #3: With ammonium chloride In water at 20℃; for 18h;
100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

5-{4,4,5,5-tetramethyl-1,3,2-(2-dioxaborolanyl)}-2-{(E)-2-phenyl-2-diphenylborylethenyl}pyridine
1160604-94-3

5-{4,4,5,5-tetramethyl-1,3,2-(2-dioxaborolanyl)}-2-{(E)-2-phenyl-2-diphenylborylethenyl}pyridine

1,3-bis[5-{(E)-2-(2-phenyl-2-diphenyl-borylethenyl)pyridyl}]benzene
1160604-69-2

1,3-bis[5-{(E)-2-(2-phenyl-2-diphenyl-borylethenyl)pyridyl}]benzene

Conditions
ConditionsYield
With sodium hydroxide; bis(tri-t-butylphosphine)palladium(0) In tetrahydrofuran; water at 60℃; for 12h; Inert atmosphere;100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C22H39BO3Si
1254941-69-9

C22H39BO3Si

C38H58O2Si2
1254941-70-2

C38H58O2Si2

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In tetrahydrofuran; water at 65℃; for 12h; Suzuki-Miyaura coupling;100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

3,3''-dimethoxy-1,1':3',1''-terphenyl
171820-21-6

3,3''-dimethoxy-1,1':3',1''-terphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol at 80℃; for 36h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

m-phenylenediamine
108-45-2

m-phenylenediamine

Conditions
ConditionsYield
With C24H12Cu2F9N4O7; tetrabutylammomium bromide; ammonia; caesium carbonate In water at 110 - 140℃; for 16h;99%
With {(o-C6H4(NCHC6H4O)2)cobalt(II)}2; ammonia at 150℃; under 1500.15 Torr; for 10h; Autoclave; Inert atmosphere; Large scale;73%
With ammonia; water; copper(II) sulfate at 175 - 180℃;
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-trimethylstannyl-pyridine
59020-06-3

4-trimethylstannyl-pyridine

1,3-bis(4-pyridyl)benzene
170165-79-4

1,3-bis(4-pyridyl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In toluene at 110℃;99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With tri-n-butyllithium magnesate complex In toluene at 0℃; for 1.5h;
Stage #2: N,N-dimethyl-formamide In toluene at 0℃; for 0.5h;
Stage #3: With citric acid at 20℃;
99%
Stage #1: 1,3-dibromobenzene With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at 0 - 5℃; for 1h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 0℃; for 1h; Further stages.;
90%
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 0.583333h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at -78 - 20℃; for 1.5h;
63.21%
pyrrolidine
123-75-1

pyrrolidine

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1-(3-bromophenyl)-pyrrolidine
219928-13-9

1-(3-bromophenyl)-pyrrolidine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 4.5h; Sealed tube;99%
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 4.5h; Sealed tube;99%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 80℃; for 4.5h;78%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

(3-bromophenyl)trimethylsilane
17878-47-6

(3-bromophenyl)trimethylsilane

Conditions
ConditionsYield
In water99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N-methylaniline
100-61-8

N-methylaniline

N1,N3-dimethyl-N1,N3-diphenylbenzene-1,3-diamine
308123-55-9

N1,N3-dimethyl-N1,N3-diphenylbenzene-1,3-diamine

Conditions
ConditionsYield
With (6-Dipp)PdCl2-SPhos; sodium t-butanolate In neat (no solvent) at 110℃; for 24h; Buchwald-Hartwig Coupling;99%
With potassium hexamethylsilazane In 1,4-dioxane at 100℃; for 1h; metal-free Buchwald-Hartwig amination; Inert atmosphere;96 %Chromat.
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-methoxy-3-methylbenzonitrile
53078-71-0

4-methoxy-3-methylbenzonitrile

(3-bromophenyl)(4-methoxy-3-methylphenyl)methanimine
1260433-04-2

(3-bromophenyl)(4-methoxy-3-methylphenyl)methanimine

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In diethyl ether at -78℃; for 0.5h;
Stage #2: 4-methoxy-3-methylbenzonitrile In diethyl ether at -78 - 20℃; for 2h;
Stage #3: With ammonium acetate
99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

(4-(benzyloxy)-3-methoxyphenyl)boronic acid
243990-53-6

(4-(benzyloxy)-3-methoxyphenyl)boronic acid

4,4''-bis(benzyloxy)-3,3''-dimethoxy-1,1':3',1''-terphenyl

4,4''-bis(benzyloxy)-3,3''-dimethoxy-1,1':3',1''-terphenyl

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In N,N-dimethyl-formamide at 60℃; Suzuki Coupling; Inert atmosphere;99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1,5-dibromo-2,4-diiodobenzene
96843-23-1

1,5-dibromo-2,4-diiodobenzene

Conditions
ConditionsYield
With sulfuric acid; iodine at 125 - 135℃; for 48h; Inert atmosphere;98.6%
With sulfuric acid; iodine at 125 - 135℃; for 6h;70%
With sulfuric acid; iodine at 130℃; for 6h; Inert atmosphere; Schlenk technique;60%
morpholine
110-91-8

morpholine

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-(3-morpholinophenyl)morpholine
51100-94-8

4-(3-morpholinophenyl)morpholine

Conditions
ConditionsYield
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 24h;98%
With C30H25BrN3PPdS; potassium carbonate In iso-butanol at 100℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere;77.3%
With potassium hexamethylsilazane In 1,4-dioxane at 100℃; for 0.5h; metal-free Buchwald-Hartwig amination; Inert atmosphere;86 %Chromat.
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4,4’’-dimethoxy-1,1′:3′,1’’-terphenyl
1568-74-7

4,4’’-dimethoxy-1,1′:3′,1’’-terphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 20℃; for 4h; Suzuki-Miyaura Coupling;98%
With potassium phosphate; C17H15N4O3S(1-)*Na(1+); palladium dichloride In water at 100℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Green chemistry;92%
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;90%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-bicyclo[4.2.0]octa-1,3,5-trienylboronic acid
195730-31-5

4-bicyclo[4.2.0]octa-1,3,5-trienylboronic acid

1,3-bis(benzocyclobuten-4-yl)benzene

1,3-bis(benzocyclobuten-4-yl)benzene

Conditions
ConditionsYield
With borax; tetrabutylammomium bromide; palladium dichloride In ethanol at 20℃; for 3h; Suzuki coupling;98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(3,5-dibromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
408492-26-2

2-(3,5-dibromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; cyclopentyl methyl ether; 1,1'-di(pyridin-2-yl)-1,1',3,3'-tetrahydro-2,2'-bibenzo[d][1,3,2]diazaborole at 100℃; for 16h; Schlenk technique; Inert atmosphere;98%
Stage #1: bis(pinacol)diborane With C24H28ClIrN2O In n-heptane; isopropyl alcohol at 75℃; for 1h; Sealed tube; Inert atmosphere;
Stage #2: 1,3-dibromobenzene In n-heptane; isopropyl alcohol Sealed tube; Inert atmosphere;
98%
With 4,4'-di-tert-butyl-2,2'-bipyridine; [Ir(COD)(OMe)]2 In tetrahydrofuran at 80℃; for 16h;
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl 3-bromobenzoate
69038-74-0

tert-butyl 3-bromobenzoate

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃;
Stage #3: With citric acid In tetrahydrofuran; hexane; toluene Further stages.;
98%
Stage #1: 1,3-dibromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃; for 1h; Inert atmosphere;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃; for 2h; Inert atmosphere;
98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-(difluoromethoxy)-3,5-dimethylbenzonitrile
1260433-19-9

4-(difluoromethoxy)-3,5-dimethylbenzonitrile

(3-bromophenyl)(4-(difluoromethoxy)-3,5-dimethylphenyl)methanimine
1260433-20-2

(3-bromophenyl)(4-(difluoromethoxy)-3,5-dimethylphenyl)methanimine

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In diethyl ether at -78℃; for 0.5h; Inert atmosphere;
Stage #2: 4-(difluoromethoxy)-3,5-dimethylbenzonitrile In tetrahydrofuran; diethyl ether at 0 - 20℃; for 2h;
Stage #3: With ammonium acetate In tetrahydrofuran; methanol; diethyl ether
98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

3'-bromo-2-methoxybiphenyl
337535-26-9

3'-bromo-2-methoxybiphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; toluene for 24h; Suzuki reaction; Reflux; Inert atmosphere;98%
Stage #1: 1,3-dibromobenzene; 2-Methoxyphenylboronic acid With sodium carbonate In ethanol; toluene for 0.5h; Sealed tube; Inert atmosphere;
Stage #2: With tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 80℃; Inert atmosphere;
57.76%
Stage #1: 1,3-dibromobenzene; 2-Methoxyphenylboronic acid With sodium carbonate In ethanol; toluene for 0.5h; Inert atmosphere;
Stage #2: With tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 80℃; Sealed tube; Inert atmosphere;
57.76%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

diphenyl diselenide
1666-13-3

diphenyl diselenide

3,5-dibromophenyl phenyl selenide
1393715-73-5

3,5-dibromophenyl phenyl selenide

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; bis(pinacol)diborane; 4,4'-di-tert-butyl-2,2'-bipyridine In tetrahydrofuran at 80℃; for 24h; Inert atmosphere;
Stage #2: diphenyl diselenide With [2,2]bipyridinyl; copper(l) chloride In water; dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere; regioselective reaction;
98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N-methyl-4-(trifluoromethyl)-2-pyridinamine

N-methyl-4-(trifluoromethyl)-2-pyridinamine

1,3-bis(N-methyl-N′-(4-trifluoromethylpyridin-2-yl)amino)benzene

1,3-bis(N-methyl-N′-(4-trifluoromethylpyridin-2-yl)amino)benzene

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 130℃; for 24h; Inert atmosphere; Sealed tube;98%
4,4'-(hexafluoroisopropylidene)diphenol
1478-61-1

4,4'-(hexafluoroisopropylidene)diphenol

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

polymer, hydroxyl-terminated; monomer(s): bisphenol A6F; 1,3-dibromobenzene

polymer, hydroxyl-terminated; monomer(s): bisphenol A6F; 1,3-dibromobenzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; potassium carbonate In N,N-dimethyl-formamide; toluene at 135 - 145℃; Ullmann reaction;97%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

2,4-dibromonitrobenzene
51686-78-3

2,4-dibromonitrobenzene

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 0 - 20℃; for 1.5h;97%
With sulfuric acid; nitric acid In dichloromethane at 0 - 20℃; for 0.5h;95%
With sulfuric acid; nitric acid at 20℃; for 5h;90%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene
30389-25-4

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene

C30H8F42

C30H8F42

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium acetate; palladium diacetate In tetrahydrofuran; N,N-dimethyl-formamide at 120℃; for 84h;97%

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