Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti
Cas:108-39-4
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inquiryItems Standard Result Appearance Colorless to light yellow liquid Colorless transparent liquid Purity
Cas:108-39-4
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Cas:108-39-4
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inquiryProduct description: Product name m-Cresol CAS number 108-39-4 Assay ≥99% Appearance Colorless to yellowish liquid Capacity 2000mt/year Application Pesticides, medicines, fra
M-Cresol--99.5% Min CAS No. 108-39-4 Appearance: Colorless or light yellow transparent liquid Purity (HPLC): 99.5% Min. Appearance:transparent liquid to light yellow liquid Storage:Warehouse ventilation, away from open flame, high temperatur
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Cas:108-39-4
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Cas:108-39-4
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inquiryProduct Name m-Cresol CAS 108-39-4 CAS number 108-39-4 Molecular Formula C7H8O Appearance
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Cas:108-39-4
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Cas:108-39-4
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Lonwin Industry group limited as a professional manufactor & exporter of chemical materials ,we totally haver more than 270 stuffs, we have been on this line for more than 9 years. Our chemical materials are exported to lot of countries and reg
Cas:108-39-4
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Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:108-39-4
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inquiryM-Cresol CAS NO.108-39-4Appearance:white Storage:Keep in dry and cool place Package:according to customers' requirements Application:For chemical research Bio-chemical Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or C
Superior quality Appearance:colourless to light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Dye intermediates used in color film
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Product name: M-Cresol CAS No.:108-39-4 Molecule Formula:C7H8O Molecule Weight:108.14 Purity: 99.0% Package: 200kg/drum Description:Colorless to light yellow liquid Manufacture Standards:Enterprise Standard TESTING
We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediates (Flu
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Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 2h; Ambient temperature; | 100% |
With 20 % Pd(OH)2/C; hydrogen In methanol at 20℃; under 760.051 Torr; for 3h; | 70% |
ethyl (m-tolyl)carbonate
3-methyl-phenol
Conditions | Yield |
---|---|
With sodium hydrogen telluride In ethanol for 0.5h; Quantum yield; Heating; buffer: deoxygen. acetic acid; | 100% |
(3-methylphenoxy)trimethylsilane
3-methyl-phenol
Conditions | Yield |
---|---|
With water; potassium carbonate In ethanol at 75℃; for 10h; | 100% |
With Nanoporous Na+-Montmorillonite Perchloric Acid In ethanol at 20℃; for 0.05h; | 91% |
triethyl(3-methylphenoxy)silane
3-methyl-phenol
Conditions | Yield |
---|---|
With water; potassium carbonate In ethanol at 75℃; for 10h; | 99% |
1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methylbenzene
3-methyl-phenol
Conditions | Yield |
---|---|
With water; potassium carbonate In ethanol at 75℃; for 12h; | 98% |
With sodium cyanide In ethanol; water at 80℃; for 17h; chemoselective reaction; | 83.7% |
With iodine In methanol for 22h; Ambient temperature; | 33% |
4-iodo-3-methyl-phenol
3-methyl-phenol
Conditions | Yield |
---|---|
With potassium carbonate; isopropyl alcohol; palladium diacetate; triphenylphosphine at 90℃; for 14h; | 98% |
m-tolylboronic acid
3-methyl-phenol
Conditions | Yield |
---|---|
With dihydrogen peroxide at 20℃; for 0.166667h; Green chemistry; | 98% |
With sodium perborate tetrahydrate In neat (no solvent) at 25℃; for 0.166667h; Green chemistry; | 98% |
With solid poly(N-vinylpyrrolidone)-hydrogen peroxide complex (PVD-H2O2 complex) In dichloromethane at 20℃; regioselective reaction; | 97% |
Conditions | Yield |
---|---|
With ammonium bicarbonate In water at 20℃; for 2h; Schlenk technique; | 97% |
tetrahydro-2-(3-methylphenoxy)-2H-pyran
3-methyl-phenol
Conditions | Yield |
---|---|
Stage #1: tetrahydro-2-(3-methylphenoxy)-2H-pyran With aluminium(III) triflate In methanol at 20 - 25℃; for 2h; Inert atmosphere; Stage #2: With water; sodium hydrogencarbonate In methanol; dichloromethane at 20 - 25℃; Inert atmosphere; | 96% |
With methanol at 20℃; for 0.833333h; | 87% |
Conditions | Yield |
---|---|
With copper dichloride In methanol; water for 3h; Heating; | 95% |
With Tris buffer; water; alpha cyclodextrin at 25℃; under 1500120 Torr; Rate constant; pH 8.3; further pressures; meta and para specific hydrolysis catalyzed by α-CD, pressure effects on, pressure dependence of log k, activation volume for the acylation, ΔV of CD-complex formation; |
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; N-methylaniline In diethyl ether; xylene at 120℃; for 6.5h; | 95% |
With trimethylsilyl iodide at 105 - 114℃; for 0.25h; Microwave irradiation; Inert atmosphere; | 92% |
With 1,3-dimethyl-2-imidazolidinone; sodium hexamethyldisilazane In tetrahydrofuran at 185℃; for 12h; further reagent: LDA; | 87% |
Conditions | Yield |
---|---|
gold(0):poly(N-vinyl-2-pyrrolidine) nanocluster In phosphate buffer at 46.84℃; for 24h; pH=6.86; | A 95% B 4% |
Conditions | Yield |
---|---|
With hydrogen; 0.75% Pd/Al2O3 at 180℃; Product distribution / selectivity; | 94.7% |
With hydrogen at 180℃; Product distribution / selectivity; | 60.07% |
With hydrogen; palladium on activated charcoal at 180℃; for 0 - 48h; Product distribution / selectivity; | 45.54% |
m-methylcyclohexanol
A
3-methyl-phenol
B
toluene
C
3-Methylcyclohexanone
Conditions | Yield |
---|---|
platinum; potassium oxide at 425℃; | A 94% B 1.8% C 4.2% |
platinum; potassium oxide at 300℃; Product distribution; Kinetics; other content of catalyst, other temperature; |
Conditions | Yield |
---|---|
Stage #1: 1-amino-3-methylbenzene With sulfuric acid at 20℃; Cooling with ice; Stage #2: With sodium nitrite In water Reflux; | 93% |
Stage #1: 1-amino-3-methylbenzene With tetrafluoroboric acid In water at 20℃; for 0.0333333h; Stage #2: With sodium nitrite In water at 0℃; for 0.5h; Stage #3: With copper(I) oxide; copper(II) sulfate In water at 0 - 20℃; for 0.5h; | 53% |
With phosphoric acid; water at 280℃; | |
Diazotization; | |
Stage #1: 1-amino-3-methylbenzene With isopentyl nitrite In N,N-dimethyl-formamide Flow reactor; Stage #2: With water In N,N-dimethyl-formamide Heating; Flow reactor; |
Kohlensaeure-butyl-m-tolyl-ester
N-butylamine
A
n-butylcarbamic acid n-butyl ester
B
3-methyl-phenol
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide | A 92% B n/a |
1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methylbenzene
3-methyl-phenol
Conditions | Yield |
---|---|
In water; N,N-dimethyl-formamide at 20℃; for 3h; | 92% |
(2-methyl-4-hydroxyphenyl)boronic acid
3-methyl-phenol
Conditions | Yield |
---|---|
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); water In toluene at 90℃; for 1h; Microwave irradiation; Green chemistry; | 92% |
Conditions | Yield |
---|---|
Stage #1: meta-bromotoluene With copper(l) iodide; 2-methyl-8-quinolinol; tetra(n-butyl)ammonium hydroxide In water; dimethyl sulfoxide at 130℃; for 14h; Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide at 20℃; | 91% |
With copper(I) oxide; tetra(n-butyl)ammonium hydroxide; 1,10-phenanthroline-4,7-diol In water at 110℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Green chemistry; | 87% |
With copper(l) iodide; potassium hydroxide In water at 120℃; for 8h; Inert atmosphere; | 80% |
Conditions | Yield |
---|---|
With palladium on activated charcoal; formic acid; N,N-dimethyl-formamide for 5h; Heating; | 90% |
With sodium hydroxide; iron at 200℃; im geschlossenen Gefaess; |
Conditions | Yield |
---|---|
Stage #1: 3-Iodotoluene With copper(l) iodide; tetra(n-butyl)ammonium hydroxide In water at 60℃; for 24h; Inert atmosphere; Sealed tube; Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; for 2h; Inert atmosphere; chemoselective reaction; | 89% |
Stage #1: 3-Iodotoluene With copper(l) iodide; cesiumhydroxide monohydrate; 1,3-diphenylpropanedione In water; dimethyl sulfoxide at 130℃; for 24h; Inert atmosphere; Stage #2: With hydrogenchloride In dichloromethane; water; dimethyl sulfoxide at 20℃; Inert atmosphere; chemoselective reaction; | 84% |
With tetra(n-butyl)ammonium hydroxide In water; dimethyl sulfoxide at 150℃; for 0.333333h; Flow reactor; | 84% |
Conditions | Yield |
---|---|
With triethanolamine In water at 20℃; for 18h; Sonication; Irradiation; Green chemistry; | 89% |
With methylene blue; N-ethyl-N,N-diisopropylamine In water; acetonitrile at 20℃; for 7h; Schlenk technique; Irradiation; |
m-hydroxybenzyl bromide
3-methyl-phenol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In 2-methyltetrahydrofuran at -15 - 20℃; for 24.16h; | 89% |
Conditions | Yield |
---|---|
With Pd(2+)*2C2H6OS*2BF4(1-)*6C12H6N2O4(2-)*4Zr(4+)*4HO(1-)*4O(2-); oxygen In dimethyl sulfoxide at 100℃; under 760.051 Torr; for 35h; Sealed tube; Inert atmosphere; | 86% |
With ethene; 5%-palladium/activated carbon In acetonitrile at 80℃; under 2280.15 Torr; for 24h; Autoclave; | 86% |
With oxygen; 6C12H6N2O4(2-)*6Zr(4+)*4HO(1-)*4O(2-)*6Pd(2+)*12C2H6OS*12BF4(1-) In dimethyl sulfoxide at 100℃; for 35h; Inert atmosphere; | 86% |
3-hydroxybenzyl iodide
3-methyl-phenol
Conditions | Yield |
---|---|
With indium; water for 5h; ultrasound; | 86% |
Conditions | Yield |
---|---|
With oxygen; eosin Y disodium salt In acetonitrile for 20h; Sealed tube; Irradiation; | 86% |
Conditions | Yield |
---|---|
With aluminum (III) chloride; choline chloride; urea; sodium hydroxide at 180℃; for 6h; Green chemistry; | 85.7% |
Conditions | Yield |
---|---|
With bis(benzonitrile)palladium(II) dichloride In benzene for 20h; Heating; | 85% |
With 12-TPA/SBA 15 In 1,4-dioxane at 110℃; | 72% |
3-methyl-phenol
Conditions | Yield |
---|---|
With oxalyl dichloride In 1,2-dichloro-ethane at 20℃; for 2.66667h; | 85% |
Conditions | Yield |
---|---|
With pyridine In dichloromethane | 100% |
at 20℃; for 0.666667h; | 100% |
With Sulfate; titanium(IV) oxide In chloroform at 61℃; for 0.05h; | 99% |
Conditions | Yield |
---|---|
With sodium hydroxide In water for 0.00416667h; microwave irradiation; | 100% |
With alkaline solution |
Conditions | Yield |
---|---|
Stage #1: 3-methyl-phenol With sodium hydride In N,N-dimethyl-formamide at 20℃; Stage #2: N,N-Dimethylcarbamoyl chloride In N,N-dimethyl-formamide at 20℃; for 0.5h; | 100% |
Stage #1: 3-methyl-phenol With pyridine; potassium carbonate In acetonitrile for 0.333333h; Stage #2: N,N-Dimethylcarbamoyl chloride In acetonitrile for 2h; | 85% |
With pyridine In benzene |
methanesulfonyl chloride
3-methyl-phenol
3-methylphenyl methanesulfonate
Conditions | Yield |
---|---|
With triethylamine In ethyl acetate at 0 - 20℃; for 0.166667h; Green chemistry; | 100% |
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere; | 80.5% |
With pyridine | |
With triethylamine In dichloromethane at 0℃; |
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 1h; Ambient temperature; | 100% |
bromoacetic acid methyl ester
3-methyl-phenol
m-tolyloxyacetic acid methyl ester
Conditions | Yield |
---|---|
With potassium carbonate In butanone for 5.5h; Heating; | 100% |
With caesium carbonate In N,N-dimethyl-formamide at 25℃; for 4h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 24h; | 89% |
With potassium carbonate In N-methyl-acetamide |
3-methyl-phenol
<2H3>-m-cresol
Conditions | Yield |
---|---|
With perchloric acid; d(4)-methanol at 75℃; for 144h; Inert atmosphere; | 100% |
With water-d2; phosphorus tribromide for 5h; Heating; | 81% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 2h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 80℃; | |
With potassium carbonate In dimethyl sulfoxide Heating; | |
KF-Al2O3; 18-crown-6 ether In acetonitrile for 24h; Heating / reflux; | |
With potassium carbonate In N,N-dimethyl-formamide for 8h; Inert atmosphere; Heating; |
Conditions | Yield |
---|---|
With sodium carbonate; tris(triphenylphosphine)ruthenium(II) chloride at 140℃; for 4h; | 100% |
With tris(triphenylphosphine)ruthenium(II) chloride; sodium carbonate at 120℃; for 4h; Inert atmosphere; regioselective reaction; | 86% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone Reflux; | 100% |
With potassium carbonate In N,N-dimethyl-formamide; toluene at 20℃; for 7h; Inert atmosphere; | 91% |
Stage #1: 3-methyl-phenol With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 0.5h; Inert atmosphere; Stage #2: propargyl bromide In N,N-dimethyl-formamide at 20℃; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
Stage #1: 3-methyl-phenol With sodium hydride In tetrahydrofuran; mineral oil at 23℃; for 1h; Inert atmosphere; Stage #2: N,N-diethylcarbamyl chloride In tetrahydrofuran; mineral oil at 23℃; for 16h; Inert atmosphere; | 100% |
Stage #1: 3-methyl-phenol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.583333h; Stage #2: N,N-diethylcarbamyl chloride In tetrahydrofuran; mineral oil at 0 - 20℃; for 12.08h; | 85% |
With potassium carbonate In acetonitrile at 85℃; for 18h; | 32% |
3-methyl-phenol
2,4-dinitrophenyl benzoate
A
3-methylphenyl benzoate
B
potassium 2,4-dinitrophenolate
Conditions | Yield |
---|---|
With potassium hydrogencarbonate In N,N-dimethyl-formamide at 25℃; for 5h; | A 100% B n/a |
4'-methoxy-4-nitro-2,6-bis(trifluoromethyl)biphenyl
3-methyl-phenol
C22H16F6O2
Conditions | Yield |
---|---|
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 90℃; for 31h; Inert atmosphere; | 100% |
t-butyldimethylsiyl triflate
3-methyl-phenol
1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methylbenzene
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; | 100% |
triisopropylsilyl trifluoromethanesulfonate
3-methyl-phenol
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; | 100% |
Conditions | Yield |
---|---|
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran at 50℃; for 16h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In butanone at 70 - 86℃; for 66h; | 100% |
Conditions | Yield |
---|---|
With hydrogen In water at 20℃; under 7500.75 Torr; for 6h; Autoclave; | 99.7% |
With nickel(II) oxide; hydrogen; palladium In hexane at 80℃; under 7500.75 Torr; for 10h; | 89% |
With hydrogen; palladium on activated charcoal In hexane at 120℃; under 37503 Torr; Rate constant; var. solvents; |
3-methyl-phenol
2-cyanobenzyl chloride
2-(3-methylphenoxymethyl)benzonitrile
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 6h; | 99.3% |
-butyl vinyl ether
3-methyl-phenol
1-(n-butoxy)-1-(3-methylphenoxy)ethane
Conditions | Yield |
---|---|
With trifluoroacetic acid at 60 - 65℃; | 99% |
With phosphoric acid at 20℃; |
Conditions | Yield |
---|---|
With [μN,κP,κC,κN-{2-(i-Pr2PO),6-(CH2NBn)-(C6H3)}Ni]2 In benzene at 50℃; for 36h; | 99% |
With sodium 3-methylphenoxide | |
N-benzyl-trimethylammonium hydroxide Heating; | |
With [{kp,kc,kp-2,6-(i-Pr2PO)2C6H3}Ni(NCMe)][OSO2CF3]; triethylamine In benzene-d6 at 20℃; for 4h; Michael condensation; | 100 %Spectr. |
With [{kp,kc,kp-2,6-(i-Pr2PO)2C6H3}Ni(NCMe)][OSO2CF3]; triethylamine In toluene at 60℃; for 24h; Inert atmosphere; |
Conditions | Yield |
---|---|
With sodium hydroxide In tetrahydrofuran; water at 0 - 20℃; for 2h; Green chemistry; | 99% |
With aluminum dodecatungstophosphate at 20℃; for 0.133333h; | 95% |
In pyridine at 45℃; | 75% |
Conditions | Yield |
---|---|
With benzyltrimethylammonium tribromide In methanol; dichloromethane | 99% |
With bromine; acetic acid Ambient temperature; | 98% |
With benzyltrimethylazanium tribroman-2-uide In methanol; dichloromethane for 1h; Ambient temperature; reagent 3.1 equivalent; | 93% |
Conditions | Yield |
---|---|
With titanium superoxide; dihydrogen peroxide; acetic acid In water at 50℃; for 1h; | 99% |
With dipyridinium dichromate In dichloromethane Ambient temperature; | 95% |
With oxygen In water; acetonitrile at 40℃; under 15001.5 Torr; for 1h; Green chemistry; | 89% |
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 20℃; for 3h; | 99% |
With sodium hydroxide; tetrabutylammomium bromide; potassium carbonate at 112℃; for 0.0833333h; Irradiation; | 95% |
With sodium hydroxide; tetrabutylammomium bromide; potassium carbonate at 112℃; for 0.0833333h; microwave irradiation; | 95% |
Conditions | Yield |
---|---|
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 16h; | 99% |
With 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; polysytrene-immobilized chiral Co-salen complex In tetrahydrofuran at 20℃; for 24h; | 96% |
In acetonitrile at 23℃; for 14h; enantioselective reaction; | 95% |
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 20℃; for 19h; optical yield given as %ee; enantioselective reaction; | 91% |
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