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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:

1,2-Epoxyhexane

Cas:1436-34-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Oxirane, 2-butyl-

Cas:1436-34-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,2-Epoxyhexane

Cas:1436-34-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 1436-34-6 with best price

Cas:1436-34-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

Cas:1436-34-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Oxirane, 2-butyl- 1436-34-6

Cas:1436-34-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

1,2-EPOXYHEXANE CAS:1436-34-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

1,2-EPOXYHEXANE CAS:1436-34-6

Cas:1436-34-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Oxirane, 2-butyl-

Cas:1436-34-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Oxirane, 2-butyl-

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Oxirane, 2-butyl-

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Quality Oxirane, 2-butyl

Cas:1436-34-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 1,2-epoxyhexane

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Other

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

Cas:1436-34-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1,2-EPOXYHEXANE

Cas:1436-34-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

Cas:1436-34-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

Cas:1436-34-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

Cas:1436-34-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

Oxirane, 2-butyl-

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,2-Epoxyhexane

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,2-epoxyhexane

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Other

inquiry

Kunshan Push Trading Co.,LTD

ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Good and stabilized factory price. 2.

1,2-Epoxyhexane

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Oxirane, 2-butyl-

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1,2-Epoxyhexane 25ml

Cas:1436-34-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 1,2-EPOXYHEXANE Synonyms: BUTYLOXIRAN;BUTYLOXIRANE;1-HEXENE OXIDE;1,2-HEXYLENE OXIDE;1,2-EPOXYHEXAN;1,2-EPOXYHEXANE;1,2-Hexene oxide;1,2-hexeneoxide CAS: 1436-34-6 MF: C6H12O MW: 100.16 Appearance:white powder Storage:Room tem

1436-34-6---1,2-EPOXYHEXANE

Cas:1436-34-6

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

1,2-EPOXYHEXANE

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

1,2-EPOXYHEXANE

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

1,2-Epoxyhexane

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2-Epoxyhexane

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China Application:SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

best seller Application:API

1,2-EPOXYHEXANE

Cas:1436-34-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

1-hexene
592-41-6

1-hexene

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With C20H24CoN2O6(1+)*NO3(1-)*H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction;100%
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation;99%
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h;99%
1-iodo-2-hexanol

1-iodo-2-hexanol

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With Al2O3-Na2CO3 catalyst at 40 - 45℃; for 0.00833333h; Microwave irradiation;98%
1,2-epoxy-5-hexene
10353-53-4

1,2-epoxy-5-hexene

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With [Fe(nacnac)dippCH2SiMe3]; N-butylamine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In benzene-d6 at 20℃; for 1h; Sealed tube; Schlenk technique; Glovebox; Inert atmosphere;91%
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

hexan-1-ol
111-27-3

hexan-1-ol

Conditions
ConditionsYield
With tert.-butylhydroperoxide; Y2(N3)(nic)2(OH)3(Hnic)(H2O) In acetonitrile at 68 - 70℃; for 24h;A 85%
B 10%
trans-2-hexene
4050-45-7

trans-2-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

trans-2,3-epoxyhexane
6124-91-0

trans-2,3-epoxyhexane

cis-2,3-epoxyhexane
6124-90-9

cis-2,3-epoxyhexane

D

butyraldehyde
123-72-8

butyraldehyde

Conditions
ConditionsYield
With oxygen; titanium(IV) oxide for 19h; Irradiation;A n/a
B 66%
C n/a
D n/a
1,2-epoxy-2-hexyl(triphenyl)silane
119101-55-2

1,2-epoxy-2-hexyl(triphenyl)silane

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With potassium fluoride; N-benzyl-N,N,N-triethylammonium chloride In dimethyl sulfoxide for 2h; Ambient temperature;65%
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

Conditions
ConditionsYield
With poly{[CuMg(pyridine-2,5-dicarboxylate)2(H2O)4]*2H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 24h; Catalytic behavior;A 22%
B 61%
With dihydrogen peroxide; large pore titanium silicate (MCM-41) In methanol at 55.9℃; for 5h; Product distribution; other hydrocarbon; var. oxidation compounds; var. time;
With urea-hydrogen peroxide; tegafur In methanol at 39.85℃; for 12h; Product distribution; Further Variations:; Reagents;
cis-2-hexene
7688-21-3

cis-2-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

trans-2,3-epoxyhexane
6124-91-0

trans-2,3-epoxyhexane

cis-2,3-epoxyhexane
6124-90-9

cis-2,3-epoxyhexane

D

butyraldehyde
123-72-8

butyraldehyde

Conditions
ConditionsYield
With oxygen; titanium(IV) oxide for 19h; Irradiation;A n/a
B n/a
C 61%
D n/a
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

n-hexan-2-ol
626-93-7

n-hexan-2-ol

C

n-hexan-2-one
591-78-6

n-hexan-2-one

Conditions
ConditionsYield
With iodosylbenzene; (n-Bu4N)4H(Mn)PW11O39 In acetonitrile at 24℃; for 2h; Product distribution; other reagent, other catalysts, other time;A 58%
B n/a
C 3.5%
With sodium tetrahydroborate; 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride; oxygen In ethanol; benzene for 24h; Product distribution;
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

n-hexan-2-one
591-78-6

n-hexan-2-one

Conditions
ConditionsYield
With iodosylbenzene; (n-Bu4N)4H(Mn)PW11O39 In acetonitrile at 24℃; for 2h;A 58%
B 3.5%
With tert.-butylhydroperoxide; 2C21H13N3O6(2-)*4Co(2+)*HO(1-)*17H2O In neat (no solvent) at 50℃; for 4h; Green chemistry;A 80 %Chromat.
B 20 %Chromat.
With C60H62Fe2Li2N10O7(2+)*2ClO4(1-); dihydrogen peroxide; acetic acid In water; acetonitrile at 30℃; for 3h;A 15 %Chromat.
B n/a
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

rac-2-hydroxyhexanoic acid
636-36-2, 6064-63-7

rac-2-hydroxyhexanoic acid

C

valeric acid
109-52-4

valeric acid

Conditions
ConditionsYield
With [γ-W10SiO36(PhPO)2][TBA]4; dihydrogen peroxide In acetonitrile at 90 - 120℃; for 0.833333h; microwave irradiation;A 50%
B n/a
C n/a
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

1-hexene-3-ol
4798-44-1

1-hexene-3-ol

Conditions
ConditionsYield
With iodosylbenzene; meso-tetrakis(tetraphenyl)porphyrin iron(III) chloride In benzene at 20℃; for 1h;A 40%
B 3%
With 1H-imidazole; C44H28MnN4O12S4(1+)*C2H3O2(1-); tetrabutylammonium periodite In dichloromethane at 20℃; for 4h; Reagent/catalyst;A 14%
B 7%
With P450 In phosphate buffer at 37℃; pH=7.4; Enzyme kinetics;
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

hexanal
66-25-1

hexanal

Conditions
ConditionsYield
With dihydrogen peroxide In acetonitrile at 65 - 68℃; for 24h;A 35%
B 13%
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

1-hexene-3-ol
4798-44-1

1-hexene-3-ol

C

1-hexene-3-one
1629-60-3

1-hexene-3-one

D

hexanal
66-25-1

hexanal

Conditions
ConditionsYield
With iodosylbenzene; 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride In benzene for 2h; Ambient temperature; anaerobic cond.;A 29%
B 4%
C 3%
D 1%
With iodosylbenzene; 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride In benzene at 20℃; for 1h; Product distribution; regioselectivity of the oxidation of olefins in presence of various metalloporphyrins;A 29%
B 4%
C 3%
D 1%
5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride In benzene for 2h; Product distribution; Mechanism; Ambient temperature; variations of pH, reagents, pO2, T;A 29%
B 4%
C 3%
D 1%
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

1-hexene oxide dimer
96128-93-7

1-hexene oxide dimer

Conditions
ConditionsYield
With dihydrogen peroxide; iron(III) chloride In acetonitrile at -5℃; for 0.166667h; Product distribution; Mechanism; other alkenes, alkanes, alcohols, ethers, aldehydes, thioethers and sulfoxides; other temperature, other time;A 71 % Chromat.
B 10 % Chromat.
6-iodo-1,2-epoxyhexane
94444-14-1

6-iodo-1,2-epoxyhexane

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With methanol; tert.-butyl lithium 1.) Et2O, pentane, -78 deg C.; Yield given. Multistep reaction;
methanol
67-56-1

methanol

1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

2-n-hexyl methyl ether
25246-71-3

2-n-hexyl methyl ether

C

hexyl methyl ether
4747-07-3

hexyl methyl ether

Conditions
ConditionsYield
With dihydrogen peroxide; Ti-β zeolite at 59.9℃; for 5h; Product distribution; var. of catalyst;
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

n-hexan-2-ol
626-93-7

n-hexan-2-ol

C

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

D

1-hexene-3-ol
4798-44-1

1-hexene-3-ol

E

hexanal
66-25-1

hexanal

F

hexan-1-ol
111-27-3

hexan-1-ol

Conditions
ConditionsYield
With europioum(III) chloride; oxygen; propionic acid; zinc In 1,2-dichloro-ethane at 40℃; for 1h; Product distribution; various catalysts, various solvents, other alkenes;
methanol
67-56-1

methanol

1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

1-hydroxy-2-methoxyhexane
80717-22-2

1-hydroxy-2-methoxyhexane

C

1-methoxy-2-hexanol
80717-20-0

1-methoxy-2-hexanol

Conditions
ConditionsYield
With Ti-Beta catalyst; dihydrogen peroxide at 50℃; for 2h; Product distribution; selectivity to epoxide; var. olefins; other catalyst and oxidating agent; var. reaction time;
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

n-hexan-2-one
591-78-6

n-hexan-2-one

C

hexanal
66-25-1

hexanal

D

hexanoic acid
142-62-1

hexanoic acid

E

valeric acid
109-52-4

valeric acid

Conditions
ConditionsYield
Product distribution; Ambient temperature; electrochemical oxidation, var. voltage, var. anodes;
(+-)-1-chloro-hexan-2-ol

(+-)-1-chloro-hexan-2-ol

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With sodium hydroxide; diethyl ether
With sodium hydroxide; water
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

pentanal
110-62-3

pentanal

C

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

Conditions
ConditionsYield
With dihydrogen peroxide; peroxy-niobic acid In water at 34.85℃; for 24h;A 27 % Chromat.
B 20 % Chromat.
C 15 % Chromat.
1-bromohexan-2-ol
26818-04-2

1-bromohexan-2-ol

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With ammonia
1-hexene
592-41-6

1-hexene

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

C

1-hexene-3-ol
4798-44-1

1-hexene-3-ol

D

1-hexene-3-one
1629-60-3

1-hexene-3-one

Conditions
ConditionsYield
With dihydrogen peroxide; [Ti,Al]-Beta In methanol at -240.15℃; for 3h; Product distribution; Further Variations:; Catalysts;
β-hydroxy-n-hexyl(tetraphenylporphyrinato)rhodium(III)

β-hydroxy-n-hexyl(tetraphenylporphyrinato)rhodium(III)

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate In benzene-d6 at 25℃; for 0.0833333h;
1-hexene
592-41-6

1-hexene

[[2,6-iPr2C6H3-N=C(Me)-C(Me)=N-C6H3(2,6-iPr2)]Pd-(CH2)3C(O)OMe](1+)

[[2,6-iPr2C6H3-N=C(Me)-C(Me)=N-C6H3(2,6-iPr2)]Pd-(CH2)3C(O)OMe](1+)

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 82 percent / NBS / H2O
2: NH3*H2O
View Scheme
oxirane
75-21-8

oxirane

1-hexene
592-41-6

1-hexene

aqueous HOCl

aqueous HOCl

nonylphenol ethoxylate

nonylphenol ethoxylate

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With sodium hydroxide; sodium chloride In water
1,3-Dichloropropane
142-28-9

1,3-Dichloropropane

1-chloro-3-hydroxypropane
627-30-5

1-chloro-3-hydroxypropane

A

glycidyl methyl ether
930-37-0

glycidyl methyl ether

B

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

C

2,3-Dichloroprop-1-ene
78-88-6

2,3-Dichloroprop-1-ene

D

2-chloroallyl alcohol
5976-47-6

2-chloroallyl alcohol

E

1,2,2-trichloropropane
3175-23-3

1,2,2-trichloropropane

F

1,2-Dichloropropane
26198-63-0, 78-87-5

1,2-Dichloropropane

G

(Z)-1,3-dichloropropene
10061-01-5

(Z)-1,3-dichloropropene

H

1,2,3-trichloro-1-propene
13116-58-0

1,2,3-trichloro-1-propene

I

(1Z)-1,2,3-trichloroprop-1-ene
96-19-5, 13116-58-0, 13116-57-9

(1Z)-1,2,3-trichloroprop-1-ene

J

1,3,3-trichloro-propene
2953-50-6

1,3,3-trichloro-propene

K

1t,3,3-trichloro-propene
2598-01-8

1t,3,3-trichloro-propene

L

chlorodibromomethane
124-48-1

chlorodibromomethane

M

1,1,2-trichloropropane
598-77-6

1,1,2-trichloropropane

N

2,3-Dichloro-1-propanol
616-23-9

2,3-Dichloro-1-propanol

O

1,3-Dichloro-2-propanol
96-23-1

1,3-Dichloro-2-propanol

P

1,2,3-trichloropropane
96-18-4

1,2,3-trichloropropane

Q

3,3-dichloropropene
563-57-5

3,3-dichloropropene

R

3,3-dichloroallyl chloride
2567-14-8

3,3-dichloroallyl chloride

S

acetaldehyde
75-07-0

acetaldehyde

T

allyl alcohol
107-18-6

allyl alcohol

U

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

V

chloroacetone
78-95-5

chloroacetone

W

cyclopentanone
120-92-3

cyclopentanone

X

chlorobenzene
108-90-7

chlorobenzene

Y

isopropyl alcohol
67-63-0

isopropyl alcohol

Z

3-monochloro-1,2-propanediol
96-24-2

3-monochloro-1,2-propanediol

[

acrolein
107-02-8

acrolein

\

epichlorohydrin
106-89-8

epichlorohydrin

]

(E)-1,3-dichloro-prop-1-ene
10061-02-6

(E)-1,3-dichloro-prop-1-ene

Conditions
ConditionsYield
With sodium hydroxide; water at 45 - 62.4℃; under 112.511 - 750.075 Torr; Product distribution / selectivity;
Rh(III)(tetra(p-sulfonatophenyl)porphyrinato)(CH2CH(OD)CH2CH2CH2CH3)(OD2)(4-)
1167549-15-6

Rh(III)(tetra(p-sulfonatophenyl)porphyrinato)(CH2CH(OD)CH2CH2CH2CH3)(OD2)(4-)

A

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

B

[(TSPP)Rh(D)(D2O)](4-)

[(TSPP)Rh(D)(D2O)](4-)

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 20℃; for 0.0833333h;
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

Conditions
ConditionsYield
With water; erbium(III) triflate In acetonitrile at 25℃; for 1h;100%
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In water; acetonitrile at 40℃; for 2h; Catalytic behavior; Reagent/catalyst;100%
With water at 40℃; for 8h; Autoclave;99%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With triphenylphosphine at 200℃; for 6h;100%
With carbon monoxide; C29H32IrN5O; bis(trifluoromethane)sulfonimide lithium In benzene-d6 at 80℃; under 7500.75 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Schlenk technique; chemoselective reaction;98%
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating;88%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

carbon dioxide
124-38-9

carbon dioxide

4-butyl-1,3-dioxolan-2-one
66675-43-2

4-butyl-1,3-dioxolan-2-one

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; 1,3,5-trimethyl-benzene; 2-hydroxyresorcinol In butanone at 45℃; under 3750.38 - 7500.75 Torr; for 18h; Autoclave;100%
With C26H42N5(3+)*3Br(1-); 1,1'-hexane-1,6-diylbis(1-methylpyrrolidinium) bis(trifluromethane)sulfonamide at 80℃; under 30003 Torr; for 3h; Autoclave; Green chemistry;100%
With potassium iodide In neat (no solvent) at 80℃; under 5250.53 Torr; Catalytic behavior; Autoclave;100%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

o-bromobenzyl alcohol
18982-54-2

o-bromobenzyl alcohol

(R)-1-(2-bromobenzyloxy)-2-hexanol

(R)-1-(2-bromobenzyloxy)-2-hexanol

Conditions
ConditionsYield
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 24h;100%
With Co(salen) macrocycles 1(OTs) In acetonitrile at 4℃; for 24h; optical yield given as %ee; enantioselective reaction;97%
pyrrolidine
123-75-1

pyrrolidine

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

1-n-butyl-2-pyrrolidinyl ethanol
225117-10-2

1-n-butyl-2-pyrrolidinyl ethanol

Conditions
ConditionsYield
With calcium bistrifluoroacetate In neat (no solvent) at 40℃; for 31h; regioselective reaction;100%
With zinc(II) chloride In acetonitrile for 12h; Heating;66%
With C8H18N2(2+)*2C2F6NO4S2(1-) In dichloromethane at 20℃; for 24h; Reagent/catalyst; Molecular sieve; Schlenk technique; Inert atmosphere; regioselective reaction;
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

trans-2-butylcyclopropanecarboxylic acid ethyl ester
878-15-9, 5532-44-5, 5595-61-9

trans-2-butylcyclopropanecarboxylic acid ethyl ester

Conditions
ConditionsYield
With n-butyllithium In 1,2-dimethoxyethane; hexane at 130℃; for 16h; Sealed tube;100%
With n-butyllithium In 1,2-dimethoxyethane at 130℃; for 18h; Sealed tube; Inert atmosphere;68%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

methylamine
74-89-5

methylamine

1-(methylamino)hexan-2-ol
1343267-21-9

1-(methylamino)hexan-2-ol

Conditions
ConditionsYield
With calcium bistrifluoroacetate In neat (no solvent) at 40℃; for 31h; regioselective reaction;100%
In methanol; water at 140℃; under 15514.9 Torr; for 0.166667h; Flow reactor;75%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

2-butyl thiirane
4468-63-7, 59854-39-6

2-butyl thiirane

Conditions
ConditionsYield
With ruthenium trichloride; ammonium thiocyanate In acetonitrile at 25℃; for 0.25h;99%
With ammonium thiocyanate at 60℃; for 0.366667h; Neat (no solvent);97%
With cross-linked polystyrene supported aluminium chloride; thiourea In acetonitrile for 2h; Heating;95%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

acetone
67-64-1

acetone

4-butyl-2,2-dimethyl-[1,3]dioxolane
93339-59-4

4-butyl-2,2-dimethyl-[1,3]dioxolane

Conditions
ConditionsYield
erbium(III) triflate at 20℃; for 1h;99%
With trichloro(trifluoromethanesulfonato)titanium(IV); n-tetrabutylammonium hydroxide In water for 0.166667h; Ambient temperature;93%
With 12-molybdo phosphoric acid n-hydrate at 20℃; for 0.0166667h; neat (no solvent);93%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

3-methyl-phenol
108-39-4

3-methyl-phenol

(S)-1-(3-methylphenoxy)hexan-2-ol

(S)-1-(3-methylphenoxy)hexan-2-ol

Conditions
ConditionsYield
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 16h;99%
With 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; polysytrene-immobilized chiral Co-salen complex In tetrahydrofuran at 20℃; for 24h;96%
In acetonitrile at 23℃; for 14h; enantioselective reaction;95%
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 20℃; for 19h; optical yield given as %ee; enantioselective reaction;91%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

phenol
108-95-2

phenol

(2S)-1-phenoxyhexan-2-ol

(2S)-1-phenoxyhexan-2-ol

Conditions
ConditionsYield
With 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; polystyrene-immobilized chiral Co-salen complex In tetrahydrofuran at 20℃; for 17h;99%
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 12h;97%
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 4℃; for 24h; optical yield given as %ee; enantioselective reaction;97%
In acetonitrile at 23℃; for 16h; enantioselective reaction;92%
Stage #1: 1,2-Epoxyhexane With 3 A molecular sieve; fluorous (R,R)-(salen)cobalt(III) In various solvent(s) for 0.0833333h;
Stage #2: phenol In various solvent(s) for 18h;
53%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

tert-butyl carbamate
4248-19-5

tert-butyl carbamate

B

((S)-2-hydroxyhexyl)carbamic acid tert-butyl ester

((S)-2-hydroxyhexyl)carbamic acid tert-butyl ester

Conditions
ConditionsYield
With air; 4-nitro-benzoic acid; (R,R)-((t-Bu)4-salen)Co(II) In various solvent(s) at 20℃; for 24h;A n/a
B 99%
With (1R,2R)-(-)-N,N'-bis(3,5-di-tert-butylsalicydene)-1,2-cyclohexanediaminocobalt(II); 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; 4-nitro-benzoic acid at 20℃; for 10h; optical yield given as %ee; enantioselective reaction;
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

poly(hexene oxide)

poly(hexene oxide)

Conditions
ConditionsYield
C64H74Cl2Co2N4O4; bis(triphenylphosphoranylidene)-ammonium acetate In toluene at 0℃; for 15h;99%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

hexan-1-ol
111-27-3

hexan-1-ol

C12H26O2
1247064-78-3

C12H26O2

Conditions
ConditionsYield
With Co(salen) macrocycles 1(OTs) In acetonitrile at 20℃; for 4h; optical yield given as %ee; enantioselective reaction;99%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

1-chloro-hexan-2-ol
52802-07-0

1-chloro-hexan-2-ol

Conditions
ConditionsYield
With chloro-trimethyl-silane; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; for 1h; ring opening reaction;98%
With magnesium; tin(ll) chloride In tetrahydrofuran for 0.5h; Ambient temperature;77%
With water; silica gel; lithium chloride for 17h; Ambient temperature;76%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

2-monochlorophenol
95-57-8

2-monochlorophenol

(2S)-1-(2-chlorophenoxy)hexan-2-ol

(2S)-1-(2-chlorophenoxy)hexan-2-ol

Conditions
ConditionsYield
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 6h;98%
In acetonitrile at 23℃; for 6h; enantioselective reaction;97%
With water; macrocyclic salen type Co In acetonitrile at 4℃; for 10h;95%
With 4 A molecular sieve; lutidinium p-toluene sulfonate; chiral oligo-(salen)Co(OTs) complexes In acetonitrile at 30℃; Kinetics; Further Variations:; concentration of catalyst; concentration of reagent;
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

2-Nitrobenzyl alcohol
612-25-9

2-Nitrobenzyl alcohol

(S)-1-(2-nitrobenzyloxy)-2-hexanol

(S)-1-(2-nitrobenzyloxy)-2-hexanol

Conditions
ConditionsYield
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 24h;98%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

1,3-dithiol-2-thione
930-35-8

1,3-dithiol-2-thione

2-Butyl-1-oxa-4,6,9-trithiaspiro<4.4>non-7-en
138197-10-1

2-Butyl-1-oxa-4,6,9-trithiaspiro<4.4>non-7-en

Conditions
ConditionsYield
With magnesium(II) perchlorate In acetonitrile for 12h; Heating;97%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

2-(Trimethylsilyl)ethanol
2916-68-9

2-(Trimethylsilyl)ethanol

(S)-1-(2-trimethylsilyl ethoxy)-2-hexanol

(S)-1-(2-trimethylsilyl ethoxy)-2-hexanol

Conditions
ConditionsYield
With water; macrocyclic salen-type Co-complex In acetonitrile at 4℃; for 2h;97%
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 3h;97%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

benzylamine
100-46-9

benzylamine

1-(benzylamino)hexan-2-ol

1-(benzylamino)hexan-2-ol

Conditions
ConditionsYield
With calcium bistrifluoroacetate In neat (no solvent) at 40℃; for 31h; regioselective reaction;97%
With sulfated zirconia at 60℃; for 6h;82%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

(2-hydroxy-5-methylphenyl)triphenylphosphonium iodide

(2-hydroxy-5-methylphenyl)triphenylphosphonium iodide

(2-(2-hydroxyhexyloxy)-5-methylphenyl)triphenylphosphonium iodide

(2-(2-hydroxyhexyloxy)-5-methylphenyl)triphenylphosphonium iodide

Conditions
ConditionsYield
In chlorobenzene at 100℃; for 2h;97%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

2-Hydroxyhexylazide
124718-84-9

2-Hydroxyhexylazide

Conditions
ConditionsYield
With sodium azide; cerium(III) chloride In water; acetonitrile for 6h; Heating;96%
With PEG-400; sodium azide at 20℃; for 0.75h;95%
With sodium azide; ammonium chloride In methanol; water at 20℃; for 24h;94%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

acetic anhydride
108-24-7

acetic anhydride

pentane-1,2-diyl diacetate
22007-57-4, 140238-23-9, 140238-24-0

pentane-1,2-diyl diacetate

Conditions
ConditionsYield
With tributylphosphine In toluene Heating;96%
With zeolite HY at 20℃; for 9.5h;95%
With sodium phosphate dibasic dodecahydrate for 2h; Catalytic behavior; Reagent/catalyst; Reflux;90%
With antimony(III) fluoride for 2h; Reflux; regioselective reaction;80%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

methanol
67-56-1

methanol

(R)-1-methoxy-2-hexanol

(R)-1-methoxy-2-hexanol

Conditions
ConditionsYield
With Co(salen) macrocycles 1(OTs) In acetonitrile at 20℃; for 3h; optical yield given as %ee; enantioselective reaction;96%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

(2S)-1-(2-bromophenoxy)hexan-2-ol
233770-25-7

(2S)-1-(2-bromophenoxy)hexan-2-ol

Conditions
ConditionsYield
In acetonitrile at 23℃; for 6h; Reagent/catalyst; enantioselective reaction;96%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

carbon disulfide
75-15-0

carbon disulfide

4-n-butyl-1,3-dithiolane-2-thione

4-n-butyl-1,3-dithiolane-2-thione

Conditions
ConditionsYield
With 1-n-butyl-3-methylimidazolim bromide; potassium hydroxide; lithium bromide In neat (no solvent) at 70℃; for 24h; chemoselective reaction;96%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

2-hydroxyhexyl methacrylate
48063-75-8

2-hydroxyhexyl methacrylate

Conditions
ConditionsYield
orthosilicic acid tetrakis-2,2,6,6-tetramethyl-4-hydroxy-1-oxylpiperidyl ester at 120℃; for 6h;95.2%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

p-cresol
106-44-5

p-cresol

1-p-tolyloxy-hexan-2-ol

1-p-tolyloxy-hexan-2-ol

Conditions
ConditionsYield
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 12h;95%

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